• Title/Summary/Keyword: hydration capacity

Search Result 61, Processing Time 0.022 seconds

A Study on the Evaluation System of Jointed Concrete Pavement (콘크리트포장 줄눈부의 평가에 관한 기법연구)

  • Park, Je-Seon;Lee, Joo-Hyung;Hong, Chang-Woo;Lee, Jung-Ho
    • Journal of Industrial Technology
    • /
    • v.19
    • /
    • pp.245-251
    • /
    • 1999
  • The joint in the concrete pavement provides a control against transverse or longitudinal cracking at slab, which may be caused by temperature or moisture variation during or after hydration. Without control of cracking, random crack may cause more serious distresses and result in structural or functional failure of pavement system. Sometimes, joint itself, purposed to control crack, may cause a distresses in joint due to its inherent weakness in structural integrity. Thus, the load transfer capacity in joint is very important for serviceability and durability. The purpose of this dissertation was to develop an evaluation system at joints of jointed concrete pavement using finite element analysis was performed using ILLI-SLAB program with a selected variables which might affect fairly to on the performance of transverse joints. The most significant variables were selected from precise analysis. It was concluded that the variables which most significantly affect to pavement deflections are the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G), and limiting criteria on the performance of joints at JCP at 300pci, 500,000 lb/in. respectively.

  • PDF

The Characterization of Crosslinked SPEEK Based Ion Exchange Membranes Prepared by EB Irradiation Method (전자선을 이용해 가교된 SPEEK 기본 물질로 하는 이온 교환막의 특성 분석)

  • Song, Ju-Myung;Shin, Junhwa;Sohn, Joon-Yong;Nho, Young-Chang
    • Journal of Radiation Industry
    • /
    • v.5 no.2
    • /
    • pp.151-157
    • /
    • 2011
  • Crosslinked SPEEK/PVDF membrane were prepared by EB radiation method with various contents of PVDF. The prepared membranes were subjected to a comparative study of proton exchange membranes for fuel cell appreciations. The crosslinked SPEEK/PVDF membranes were characterized by using DMA, DSC and SAXS. The DMA data indicate that the ionic modulus values and cluster $T_g$ decrease with increasing PVDF content. Thus, it was suggested that the number of clustering in the crosslinked membranes can be reduced with increasing PVDF content. The DSC results were shown that the degree of crystalline of the membrane increased with increasing PVDF content. The morphology of the crosslinkied membranes was shown that with increasing PVDF content, the number of crystalline domain of the SPEEK/PVDF membranes increased but ionic aggregation of the membranes decreased. The water uptake behavior, ionic exchange capacity (IEC) and proton conductivity were decreased with increasing PVDF content. The overall findings suggest that the crosslinked membranes offer the possibility for improving the performance of PEMFC, provided that the membranes have thermal and hydration stability.

Solidification/Stabilization of Arsenic Contaminated Soil Using Cement-Based Synthesized Materials (시멘트계 합성물질을 이용한 비소 오염 토양의 고형화/안정화)

  • Kim, Ran;YHong, Seong Hyeok;Jung, Bahng Mi;Chae, Hee Hun;Park, Joo Yang
    • Journal of the Korean GEO-environmental Society
    • /
    • v.13 no.2
    • /
    • pp.59-65
    • /
    • 2012
  • Solidification/Stabilization(S/S) is one of the remediation technologies that have been applied for treating inorganic hazardous wastes. This study investigated the reduction of arsenic concentration of arsenic-contaminated soil using by S/S. The binder plays a role in controlling the mobility and solubility of the contaminants in S/S process, so it is important to determine the optimum binder content. Therefore, this study evaluated the effectiveness of S/S using four different binders(cement, zero valent iron, and monosulfate and ettringite(cement-based synthesized materials) at the binder content ranged between 5%(wt.) and 20%(wt.). The leachability of arsenic in 1 N HCl was different depending on the types of binders: cement(71.41%) > monosulfate(47.45%) > ettringite(46.36%) > ZVI(33.08%) at the binder content of 20%. Additionally, three kinds of a mixture binder were prepared using cement and additives(monosulfate, ettringite, calcium sulfoaluminate(CSA)) and tested for arsenic reduction. The highest arsenic removal capacity was found at the mass ratio of cement to the additive, 4:1 in all experiments using a mixture binder, regardless of the additives types. A mixture binder(cement and additives) resulted in higher arsenic removal relative to the arsenic removal when cement was used alone.

Physicochemical Characteristics of Filefish and Cod Skin Collagen (말쥐치피 및 대구피 콜라겐의 물리화학적 특성)

  • Kim, Se-Kwon;Kang, Ok-Ju;Kwak, Dong-Chae
    • Applied Biological Chemistry
    • /
    • v.36 no.3
    • /
    • pp.163-171
    • /
    • 1993
  • The collagens from filefish (Novoden modestus) and cod (Gadus macrocephalus Tilesius) skin were isolated and their physicochemical properties were investigated. Glutamic acid, hydroxyproline, valine and phenylalanine in the filefish skin collagen (FSC) were presented at higher levels than those of cod skin collagen (CSC), but the contents of glycine, proline and serine were contrary. The content of essential amino acids of FSC (265 residues/1000 residues) was higher than CSC (229 residues). The solubilities of both collagens were the lowest at pH 7.0, but precipitously increased at acid zone(below pH 5.0). FSC has lower viscosity than CSC. Furthermore, while the viscosities of both collagens were the lowest at pH 7.0, the viscosities of FSC and CSC were the highest at pH 4.0 and pH 2.0, respectively. The denaturation temperature of $FS(25^{\circ}C)$ was higher than $CSD\;(17^{\circ}C)$. The free hydrophobic residue contents of FSC and CSC tended to increase till $60^{\circ}C,\;and\;50^{\circ}C$ respectively, and to decrease thereafter. Hydration capacities of both collagens were the lowest at pH 7.0, and CSC had the superior hydration capacity to FSC. In addition, emulsifying and emulsifying stability of CSC was also superior to FSC.

  • PDF

Analysis on Adsorption Rate & Mechanism on Chloride Adsorption Behavior with Cement Hydrates (시멘트 수화물의 염소이온 흡착거동에 따른 메커니즘 및 해석기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
    • /
    • v.27 no.1
    • /
    • pp.85-92
    • /
    • 2015
  • The chloride ions, responsible for the initiation of the corrosion mechanism, intrude from the external medium into the concrete. A part of the intruding chloride ions will be retained by the hydration products of the binder in concrete, either through chemical adsorption or by physical adsorption. Since the hydration products of cement are responsible for the chloride binding in concrete, this study focused on the chloride binding in individual hydrate. The purpose of this study is to explore the time dependant behaviors of chloride ions adsorption with cement hydrates, focused on its mechanism. AFt phase and CH phase were not able to absorb chloride ion, however, C-S-H phase and AFm phase had a significant chloride adsorption capacity. In particular, AFm phase showed a chemical adsorption with slow rate in 40 days, while C-S-H phase showed binding behaviors with 3 stages including momentary physical adsorption, physico-chemical adsorption, and chemical adsorption. Based on the results, this study suggested theoretical approach to depict chloride adsorption behavior with elapsed time of C-S-H phase and AFm phase effectively. It is believed that the approach suggested in this study can provide us with a good solution to understand the mechanism on chloride adsorption with hydrates and to calculate a rate of chloride penetration with original source of chloride ions, for example, marine sand at initial time or sea water penetration later on.

A Study on Moisture Transport of Artificial Lightweight Concrete (인공경량골재 콘크리트의 수분이동 특성에 관한 연구)

  • Lee, Chang Soo;Choi, Sang Hyun;Park, Jong Hyok;Kim, Young Ook
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.29 no.4A
    • /
    • pp.373-384
    • /
    • 2009
  • For the first step on the quantitative evaluation of shrinkage reduction and differential shrinkage analysis of lightweight aggregate concrete, this study sets the moisture transport model of concrete by pre-absorbed water of porous lightweight aggregates and measured effective moisture diffusion coefficient, moisture capacity, degree of humidity supply and degree of humidity consumption by water binder ratio and aggregate type. The effective moisture diffusion coefficient in steady state caused by humidity difference between inside and outside of concrete had low value as low water-binder ratio. And in case of same water-binder ratio, effective moisture diffusion of mixtures used normal aggregates were lower than those used lightweight aggregates. To determine moisture store capability of concrete - moisture capacity, moisture contents were measured in 9 humidity conditions. As a result moisture contents of mixtures used lightweight aggregates was higher than mixtures used normal aggregates in all humidity conditions. This study measured lightweight aggregates' degree of humidity supply that applicable to normal atmospheric environment (above RH 50%) and made it quantitatively. Also amount of moisture release was set as a exponential function that represents a clear trend proportion to time and inverse proportion to humidity of the surroundings. As the result of measurement about degree of moisture consumption inside concrete following the internal consumption caused by cement hydration self-drying, it was showed that rapid decrease of humidity, around 10%, at early ages (7~10 days) when water-binder ratio is 0.3 and slow decrease around 5% and 1% when water-binder ratio is 0.4 and 0.5.

Comparison of the Hydration, Gelatinization and Saccharification Properties of Processing Type Rice for Beverage Development (음료 개발을 위한 가공용 쌀의 수화, 호화 및 당화특성 비교)

  • Shin, Dong-Sun;Choi, Ye-Ji;Sim, Eun-Yeong;Oh, Sea-Kwan;Kim, Si-Ju;Lee, Seuk Ki;Woo, Koan Sik;Kim, Hyun-Joo;Park, Hye-Young
    • The Korean Journal of Food And Nutrition
    • /
    • v.29 no.5
    • /
    • pp.618-627
    • /
    • 2016
  • This study evaluated the hydration, gelatinization, and saccharification properties of rice processing for beverage development. The properties of rice were studied on 10 rice cultivars (Samkwang, Ilpum, Seolgaeng, Anda, Dasan-1, Goami-4, Danmi, American rice, Chinese rice, and Thai rice) and employing four kinds of pre-treatment methods (dry grain, wet grain, dry flour, and wet flour). The results showed that moisture content of rice was between 11.88~15.26%. Increase in soaking time along with highest water absorption was noted in American rice cultivar (46.81%). The water binding capacity of Thai rice was higher when compared to that of other rice flours. In addition, solubility and swelling power of rice were 4.52~26.65% and 0.19~2.05%, respectively. The amylose content of Goami-4 was higher in rice processing. Using a rapid visco analyzer (RVA), the initial pasting temperature of Danmi cultivar was found to be the highest; the peak viscosities of Anda cultivar and Dasan-1 cultivar, and Chinese rice were higher than of those of other rice flours. After saccharification, the pH, soluble solids content, and reducing sugar content of rice processed through different pre-treatment methods were in the range of 6.22~7.08, $4.67{\sim}16.07^{\circ}Brix$, and 0.35~11.67% (w/w), respectively. In terms of color values, the L-value of dry grain, a-value of wet (grain, flour), and b-value of dry sample (grain, flour) were found to be the highest. Assessment of various factors and cultivars characteristics of the raw grains are of importance in the development of rice beverage.

Enhancing the Moisturizing Ability of the Skin Softener using Nanoemulsion Based on Phospholipid Liposome

  • Lee, Jinseo;Park, Su In;Heo, Soo Hyeon;Kim, Miok;Shin, Moon Sam
    • International Journal of Advanced Culture Technology
    • /
    • v.8 no.1
    • /
    • pp.236-242
    • /
    • 2020
  • In this paper, we present the improvement in low moisturizing ability and stability that existing skin softeners have due to the low oil content, by developing skin softener using nanoemulsion of phospholipid liposome, based on the properties of nanoemulsion in cosmetic formulation. In this study, two types of oil; dimethicone (DC 200/6cs) or medium chain triglyceride (MCT), and two kinds of lecithin; unsaturated or saturated were respectively applied to produce nanoemulsion. In the particle size analysis of nanoemulsion, the droplet size of nanoemulsion containing DC200/6cs and unsaturated lecithin was the smallest, and all nanoemulsion showed high stability in the measurement of zeta potential. Therefore, with the smallest particle size and high stability, moisture contents and trans epidermal water loss(TEWL) were measured using the skin softener of DC200/6cs and unsaturated lecithin contained nanoemulsion, and the measurement was compared with the non-oil skin softener and the skin softener with only small amount of oil. The results showed that the moisture content of the skin softener using nanoemulsion increased greatly than other two skin softeners, showing high hydration ability and water retention capacity, and TEWL decreased greatly, therefore preventing the evaporation of moisture from the skin. As a result, the oil content and stability of the skin softener was improved by utilizing nanoemulson based of phospholipid liposome, and it is expected to be used in various ways in cosmetic industry.

Effects of Atrial Natriuretic Peptide on Renal and Hormonal Balances in terms of Aging in Rabbits (연령증가에 따른 Atrial Natriuretic Peptide의 신장과 호르몬 효과)

  • Kim, Jong-Duk;Kim, Suhn-Hee;Kim, Jung-Soo;Cho, Kyung-Woo
    • The Korean Journal of Physiology
    • /
    • v.23 no.1
    • /
    • pp.51-66
    • /
    • 1989
  • Mammalian cardiocytes secrete atrial natriuretic peptides (ANPs) into plasma, which cause marked natriuresis, diuresis, vasorelaxation and inhibition of hormone secretions. Aging influences the ability of the kidney both to conserve and to excrete sodium; i.e., in old animals, the excretory capacity of sodium is reduced and the time required to excrete sodium load is prolonged. Therefore, it is possible that animals differing in ages may respond differently to ANP. In the present study, we determined whether the renal, hormonal and vascular effects of ANP may be influenced by aging in conscious rabbits. The plasma renin concentration decreased with aging but plasma ANP concentration was significantly lower only in 24-month-old rabbits. Plasma aldosterone concentration and atrial ANP content did not change by aging. In 1-month-old rabbits, ANP (atriopeptin III, 3 ug/kg) administered intravenously caused hypotension and decreased in plasma renin and aldosterone concentrations, but did not cause diuresis and natriuresis. In 2 to 5 month-old rabbits, ANP caused hypotension, decreases in Plasma renin and aldosterone concentrations and marked renal effects. However, in 24-month-old rabbits, all the above effects of ANP was blunted. With hydration of physiological saline at a rate of 15 ml/kg/h for 2hr, urine volume and glomerular filtration rate did not change but the electrolyte excretion as well as fractional excretion of sodium significantly increased. The plasma concentrations of active renin and aldosterone were decreased but plasma inactive renin and ANP concentrations were increased. The changes in renal function and plasma level of hormone showed no differences in different ages. These results suggest that the peripheral vascular receptors to ANP may develop earlier than those in the kidney, and the attenuated vascular and renal responses to ANP in the old age may be due to age-related modifications in renal function and blood vessel.

  • PDF

Evaluation of the Performance on Coating on Roller Compacted Concrete Pavement for Bike Roads (자전거도로용 롤러 전압 콘크리트 포장의 코팅에 따른 성능 평가)

  • Lee, Chang-Ho;Lee, Seung-Woo;Kim, Seong-Kil
    • International Journal of Highway Engineering
    • /
    • v.13 no.1
    • /
    • pp.79-86
    • /
    • 2011
  • Recently, usage bicycle is encouraged to reduce fuel consumption and air pollution. For this purpose, bike road constructions are actively performed. However, types of pavement used in bike roads have high construction cost and performance comparing the required capacity of bike roads. Thus, an economical pavement type for construction is necessary for the effective development. Roller compacted concrete pavement have good requirements, such as easy construction and low costs, high structural performance of hydration and internal communication aggregation on compaction for bicycle roads. However, the pool landscape surface and resistance to deicer damage cannot be applied to the construction of bicycle roads. Thus, for solving this problem used coating which may have effect of improving the landscape and environmental resistance. To examine this effect were evaluated performance of roller compacted concrete pavement on the coating.