• Analytical Science and Technology
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• v.18 no.6
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• pp.535-541
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• 2005

The formation of aldehydes as by-product was investigated in the treatment of humic acid by Ozone/GAC hybrid process. Ozone/GAC hybrid process was operated under varying initial pH (pH 3~pH 11) and temperature ($0^{\circ}C$, $20^{\circ}C$, $40^{\circ}C$) at an ozone dose of 0.08 g $O_3/g$ DOC and GAC amount of 16.5 v/v%. The results were compared with those of GAC adsorption and ozone alone process. The formed aldehydes were derivatized by PFBOA method and quantified by GC/PDECD. Formaldehyde and glyoxal were identified as the substantial aldehydes in the treatment of humic acid by ozone/GAC hybrid process. Quantities of formaldehyde and glyoxal formed in ozone/GAC hybrid process were less than one in ozone alone process. In ozone/GAC hybrid process, formaldehyde was produced with a considerable concentration of 400 ppb at pH 11 and pH 7 at the beginning of the treatment, and then the concentration was decreased with time. And, the concentrations of formaldehyde and glyoxal were increased with an increase of temperature. They were respectively 520 ppb and 120 ppb at the beginning of the treatment at $40^{\circ}C$.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.9
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• pp.989-994
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• 2005

The treatment efficiency and the degradation characteristics of humic acid were investigated in three processes-GAC adsorption, Ozone alone and Ozone/GAC hybrid process, in which $UV_{254}$, DOC, molecular size distribution and surface change of GAC were evaluated. DOC removal rate in Ozone/GAC hybrid profess(ca. 80%) was higher than the arithmetic sum of Ozone alone(38%) and GAC adsorption(19%). This result approves that the combined Ozone/GAC hybrid process brings synergistic effects on DOC removal from the HA containing water. $UV_{254}$ decrease rate was also at the highest in Ozone/GAC hybrid process from the three processes. It may be interpreted that the granular activated carbon in Ozone/GAC hybrid process acts as not only an adsorbent but also a catalyst for ozonation, and futhermore offers an additional reaction site between adsorbed organic matter and ozone. In the study of molecular sire distribution, there was no significant change of molecular size distribution in the GAC adsorption process during the reaction time of 120 min. In Ozone alone process, the fraction of molecular size over 30 kDa was decreased a little at the beginning and left constant after 10 min. But in Ozone/GAC hybrid process, the molecules size over 30 kDa of HA was significantly decreased from 36.3% to 3.9%. And also the fraction of smaller molecular size below 0.5 kDa was increased from 4.8%(untreated HA) to 12.3%(in Ozone alone) and 40.1%(in Ozone/GAC) respectively at the reaction time of 120 min.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.9
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• pp.33-39
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• 2020

Self-piercing rivets are often used in the automotive industry, among other industries, as mechanical components to join multiple materials such as aluminum alloys. Self-piercing rivets have a strong sealing property, although there is considerable scope for their performance improvement. In this study, to enhance the performance of self-piercing rivets, the hybrid self-piercing riveting (SPR) technique, using the existing SPR and structural adhesive, was proposed. Moreover, heterogeneous material specimens subjected to the hybrid SPR technique were manufactured and tested. The joint strength of the test pieces of different materials was evaluated through finite element analyses.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.757-760
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• 2005

The technology of rapid prototyping (RP) is used for design verification, function test and fabrication of prototype. The current issues in RP are improvement in accuracy and application of various materials. In this paper, a hybrid rapid prototyping system is introduced which can fabricate nano composites using various materials. This hybrid system adopts RP and machining process, so material deposition and removal is performed at the same time in a single station. As examples, micro gears and a composite scaffold were fabricated using photo cured polymer with nano powders such as carbon black and hydroxyapatite. From the micro gear samples the hybrid RP technology showed higher precision than those made by casting or deposition process.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.9 no.2
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• pp.1-5
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• 2010

According to the high demand of hybrid components, the hybrid materials development and processing technology were increased in the industry field. Although hybrid materials have various machining technologies, the research about them has rarely been proceed. This study is to carry out results about design technology of miniaturized high-speed air spindle and machining characteristics of hybrid materials using that. We studied machining characteristics in Nickel-Chrome alloy(Ni-Cr) according to change rotating speed using miniaturized high-speed air spindle. As the following results, the change of surface shape and roughness was investigated as the processing conditions such as rotating speed of miniaturized high-speed air spindle.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.4
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• pp.459-469
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• 2016

Gas hydrate desalination process is based on a liquid to solid (Gas Hydrate, GH) phase change followed by a physical process to separate the GH from the remaining salty water. The GH based desalination process show 60.5-90% of salt rejection, post treatment like reverse osmosis (RO) process is needed to finally meet the product water quality. In this study, the energy consumption of the GH and RO hybrid system was investigated. The energy consumption of the GH process is based on the cooling and heating of seawater and the heat of GH formation reaction while RO energy consumption is calculated using the product of pressure and flow rate of high pressure pumps used in the process. The relation between minimum energy consumption of RO process and RO recovery depending on GH salt rejection, and (2) energy consumption of electric based GH process can be calculated from the simulation. As a result, energy consumption of GH-RO hybrid system and conventional seawater RO process (with/without enregy recovery device) is compared. Since the energy consumption of GH process is too high, other solution used seawater heat and heat exchanger instead of electric energy is suggested.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2010.05a
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• pp.657-658
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• 2010

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2011.06a
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• pp.745-746
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• 2011

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.1
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• pp.35-40
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• 2007

The new PEI(poly(epoxy-imide))-nano Silica film has been synthesized via in situ CS sol process, and the chemical bonding and microstructure of nano silica dispersed in resin were examined by FT-IR, TAG and SEM. The dielectric properties of these hybrid films over a given temperature and frequency ranges have been studied in a point of view of stable chemical bonding of nano Silica filler. The results from IR spectra and SEM photograph indicated that PEI-Silica hybrid film prepared with nano CS sol process has been synthesized in uniform and chemical bonding. The decrease property of dielectric constant with CS content, tangent loss consistent of given frequency and temperature has been explained in terms of the chain movement of polymer through chemical bonging and size effect of nano silica. The new PEI-CS sol hybrid film with such stable chemical and dielectric properties was expected to be used as a high functional coating application in ET, IT and electric power products.

• Transactions of Materials Processing
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• v.20 no.2
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• pp.160-166
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• 2011

Weight reduction while maintaining functional requirements is one of the major goals in the automotive industry. The use of lightweight magnesium alloys offers great potential for reducing weight because of the low density of these alloys. However, the formability and the surface quality of the final magnesium alloy product for auto-body structures are not acceptable without a careful optimization of the design parameters. In order to overcome some of the main formability limitations in the stamping of magnesium alloys, a new approach, the so-called "hybrid technology", has been recently proposed for body-in-white structural components. Within this approach, necessary level of mechanical joining can be obtained through the use of lightweight material-steel adhesion promoters. This paper presents the development process of an automotive hybrid hood assembly using magnesium alloy sheets. In the first set of material pairs, the selected materials are magnesium alloy AZ31B alloy and steel(SGCEN) as inner and outer panels, respectively. In order to optimize the design of the inner panel, the stamping process was analyzed with the finite element method (FEM). Laser welding by CW Nd:YAG were used to join the magnesium alloy sheets. Based on the simulation results and mechanical test results of the joints, the determination of die design variables and their influence on formability were discussed. Furthermore, a prototype based on the proposed design was manufactured and the static stiffness test was carried out. The results demonstrate the feasibility of the proposed hybrid hood with a weight reduction of 25.7%.