• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.427-427
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• 2016

Organic-inorganic hybrid perovskite have attracted significant attention as a new revolutionary light absorber for photovoltaic device due to its remarkable characteristics such as long charge diffusion lengths (100-1000nm), low recombination rate, and high extinction coefficient. Recently, power conversion efficiency of perovskite solar cell is above 20% that is approached to crystalline silicon solar cells. Planar heterojunction perovskite solar cells have simple device structure and can be fabricated low temperature process due to absence of mesoporous scaffold that should be annealed over 500 oC. However, in the planar structure, controlling perovskite film qualities such as crystallinity and coverage is important for high performances. Those controlling methods in one-step deposition have been reported such as adding additive, solvent-engineering, using anti-solvent, for pin-hole free perovskite layer to reduce shunting paths connecting between electron transport layer and hole transport layer. Here, we studied the effect of alkali metal halide to control the fabrication process of perovskite film. During the morphology determination step, alkali metal halides can affect film morphologies by intercalating with PbI2 layer and reducing $CH3NH3PbI3{\cdot}DMF$ intermediate phase resulting in needle shape morphology. As types of alkali metal ions, the diverse grain sizes of film were observed due to different crystallization rate depending on the size of alkali metal ions. The pin-hole free perovskite film was obtained with this method, and the resulting perovskite solar cells showed higher performance as > 10% of power conversion efficiency in large size perovskite solar cell as $5{\times}5cm$. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma optical emission spectrometry (ICP-OES) are analyzed to prove the mechanism of perovskite film formation with alkali metal halides.

• Advances in nano research
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• 제13권2호
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• pp.187-197
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• 2022

The synthesis of organic and hybrid organic-inorganic perovskites directly from solution improves the cost- and energy-efficiency of processing. To date, numerous research efforts have been devoted to investigating the influence of the various solvent parameters for the synthesis of lead halide perovskites, focused on the effects of different single solvents on the efficiency of the resulting perovskites. In this work, we investigated the effect of solvent blends for the first time on the structure and phase of perovskites produced via the Lewis base vapor diffusion method to develop a new synthetic approach for water-stable CsPbBr₃ particles with nanometer-sized dimensions. Solvent blends prepared with DMF and water-miscible solvents with different Gutmann's donor numbers (D_N) affect the Pb ions differently, resulting in a variety of lead bromide species with various colors. The use of a DMF/isopropanol solvent mixture was found to induce the formation of the Ruddlesden-Popper perovskite based on lead bromide. This perovskite undergoes a blue color shift in the solvated state owing to the separation of nanoplatelets. In contrast, the replacement of isopropanol with DMSO, which has a high DN, induces the formation of spherical CsPbBr₃ perovskite nanoparticles that exhibit green emission. Finally, the integration of acetone in the solvent system leads to the formation of lead bromide complexes with a yellow-orange color and the perovskite CsPbBr₃.

• 한국항행학회논문지
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• 제6권1호
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• pp.17-26
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• 2002

본 논문에서는 비교적 구조가 간단하고 계산량이 적어 시스템에 적용하기가 쉬운 감산형 간섭제거(subtractive interference cancellation) 기법의 대표적인 방식인 순차 간섭제거(SIC : Successive Interference Cancellation) 기법과 병렬 간섭제거(PIC : Parallel Interference Cancellation) 기법의 성능을 분석하고, 이들을 결합한 복합 간섭제거(HIC : Hybrid Interference Cancellation) 기법의 성능을 분석한다. 잡음과 MAI (Multiple Access Interference)가 존재하는 채널환경에서 간섭제거를 위해 데이터를 추정할 때 연판정(soft decision)을 수행하는 SIC 기법과 HIC 기법의 오율식을 각각 유도하고, 각 간섭제거 방식의 성능을 수치계산과 시뮬레이션을 통해 각각 구하여 비교, 분석하였다. 그 결과, HIC 기법은 전력제어의 완전성 여부에 관계없이 다른 방식들에 비해 MAI를 효과적으로 제거하여 BER(Bit Error Rate) 성능을 향상시키며 시스템의 용량도 증가시킴을 알 수 있었다. 그 이유는 HIC 기법에서 전단에 사용하는 SIC에 의해 불완전 전력제어 하에서 발생되는 원근문제(near-far problem)가 해결되고, 후단에 사용하는 PIC에 의해 성능 개선이 이루어질 수 있기 때문이다.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제10권3호
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• pp.950-975
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• 2016

Device-to-Device (D2D) communication underlaying cellular networks is a promising add-on component for future radio communication systems. It provides more access opportunities for local device pairs and enhances system throughput (ST), especially when mobile relays (MR) are further enabled to facilitate D2D links when the channel condition of their desired links is unfavorable. However, mutual interference is inevitable due to spectral reuse, and moreover, selecting a suitable transmission mode to benefit the correlated resource allocation (RA) is another difficult problem. We aim to optimize ST of the hybrid system via joint consideration of mode selection (MS) and RA, which includes admission control (AC), power control (PC), channel assignment (CA) and relay selection (RS). However, the original problem is generally NP-hard; therefore, we decompose it into two parts where a hierarchical structure exists: (i) PC is mode-dependent, but its optimality can be perfectly addressed for any given mode with additional AC design to achieve individual quality-of-service requirements. (ii) Based on that optimality, the joint design of MS, CA and RS can be viewed from the graph perspective and transferred into the maximum weighted independent set problem, which is then approximated by our greedy algorithm in polynomial-time. Thanks to the numerical results, we elucidate the efficacy of our mechanism and observe a resulting gain in MR-aided D2D communication.

• 멤브레인
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• 제24권6호
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• pp.472-483
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• 2014

본 연구는 거대고리 금속 이온 착화합물과 유도체를 이용하여 미세 다공성 구조를 가지는 분리막의 제조에 관한 것이다. 고분자와 금속이온 리간드 착물 시스템을 이용함으로써 기존의 방법들에 비해 상 전이 과정을 보다 정교하게 제어할 수 있었다. 금속염, cyclohexanedione dioxime, hydroxyphenylboronic acid와의 축합 반응을 통하여 금속 clathrochelate 착물을 얻을 수 있었다. PES, PVP, BE와 금속 clathrochelate 착물을 DMF에 녹인 후 비용매 유도 상 전이법을 통하여 유무기 혼성고분자막을 제조하였다. 제조된 분리막의 구조는 FE-SEM과 microflow permporometer로 조사하였다. p-Hydroxyphenyl group을 가지는 Fe(II) clathrochelate 착물의 첨가는 분리막의 구조에 있어 기공 크기 분산도를 좁혀주고, 표면의 기공 밀도를 높여 주었으며 최대 기공 크기를 감소시킴을 볼 수 있었다.

• 한국산학기술학회논문지
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• 제21권1호
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• pp.649-655
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• 2020

본 연구는 제4차 산업혁명기반 스마트팜 분야의 중소·중견기업 종사자를 대상으로 관련 교육 수요를 조사·분석하여 효과적인 교육전략을 제시하는 데 목적이 있다. 교육전략 도출을 위해 스마트팜 기술 분야 도출, 교육수요조사 실시, 교육수요조사 결과를 바탕으로 IPA 분석과 Borich 요구도 분석을 시행하였다. 연구결과, 교육수요조사에서는 생산시스템 분야와 지능형 농작업기에 대한 요구가 높게 나타났다. 세부적으로 Borich 요구도 분석에서 병충해 방지 및 진단기술(8.03), 네트워크 및 분석SW 연계기술(7.83), 지능형 농작업기-농업동력 기계시스템-전기에너지 하이브리드 기술(7.43)의 순으로 높게 나타났다. 반면, 스마트 식물 공장(4.09), 생육조절을 위한 조명기술(4.46), 구조물 건설기술(4.62)은 낮은 요구도를 보였다. 이를 기반으로 한 IPA 포트폴리오 분석 결과는 집중노력영역의 네트워크 및 분석SW연계기술, CAN기반 복합센터 활용 기술은 시급히 교육이 이루어져야 하는 분야로 나타났다. 그러나 스마트공장플랫폼개발, 생육조절조명기술, 구조물건설기술 등과 같이 이미 상용화된 기술에 대해서는 과잉영역으로 나타났다. 본 연구결과를 바탕으로 스마트팜 분야의 수요를 반영하여 중소·중견기업 산업현장 맞춤형 교육 프로그램을 전략적으로 제시하고, 교육프로그램 운영방안의 제안이 가능하다.

• Asian-Australasian Journal of Animal Sciences
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• 제21권7호
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• pp.917-922
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• 2008

A disintegrin-like and metalloprotease (reprolysin type) with thrombospondin type 1 motif (ADAMTS1) plays a critical role in follicular rupture and represents a major advance in the proteolytic events that control ovulation. In this study, a 9,026-bp DNA sequence containing the full coding region, all 8 introns and part of the 5'and 3' untranslated region of the porcine ADAMTS1 gene was obtained. Analysis of the ADAMTS1 gene using the porcine radiation hybrid panel indicated that pig ADAMTS1 is closely linkage with microsatellite marker S0215, located on SSC13q49. The open reading frame of its cDNA covered 2,844 bp and encoded 947 amino acids. The coding region of porcine ADAMTS1 as determined by sequence alignments shared 85% and 81% identity with human and mouse cDNAs, respectively. The deduced protein contained 947 amino acids showing 85% sequence similarity both to the human and mouse proteins, respectively. Comparative sequencing of three pig breeds revealed one single nucleotide polymorphism (SNP) within exon 7 of which a G-C substitution at position 6006 changes a codon for arginine into a codon for proline. The substitution was situated within a PvuII recognition site and developed as a PCR-RFLP marker for further use in population variation investigations and association analysis with litter size. Allele frequencies of this SNP were investigated in seven pig breeds/lines. An association analysis in a new Qingping female line suggested that different ADAMTS1 genotypes have significant differences in litter size (p<0.01).

• 한국전자파학회논문지
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• 제13권10호
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• pp.1089-1097
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• 2002

본 논문에서는 선박에 탑재하여 해상에서 이동 중 위성통신을 수행하는 능동 위상배열 안테나 시스템의 설계, 제작 및 시험을 소개한다. 안테나와 시스템은 광역 하이브리드 추져, 송수신 겸용 안테나 소자, 비대칭 배열, 송수신간의 간섭 억압, 및 주파수 스캔 효과를 보상하는 위상제어 기술 등의 새로운 구조와 기술을 적용한다. 안테나는 32$\times$4 이차원 배열을 가진 송수신 겸용 안테나이다. 안테나는 두개의 빔을 가진다. 안테나 사용 주파수는 수신 7.25 - 7.75 GHz 송신 7.9 - 8.4 GHz이다. 안테나 지향 이득은 수신 35.4 dBi와 송신 35.7 dBi이며, 최대 54 %의 효율을 가진다. 전자 빔 스캔 범위는 앙각 $\pm$35$^{\circ}$와 방위각 $\pm$4$^{\circ}$이다. 안테나는 방위각 360$^{\circ}$ 무한회선과 앙각 $\pm$$10^{\circ}$의 기계적 제어가 가능한 하이브리드 추적 운동을 할 수 있다. 안테나 3 dB 빔폭은 2.2$^{\circ}$이며, 부엽 레벨 -14 dB와 교차편파 억압 송신 21 dB의 특성을 가진다. 안테나는 근역전계 측정 시설을 이용하여 측정하였다. 시스템 성능은 선박 모의 운동 시뮬레이터 위에서 위성 중계기 시뮬레이터를 사용하여 시험하였다. 운동 상태에서 위성 추적 성능은 추적 오차가 3 dB 이내이다. 안테나 시스템은 변조된 위성방송 신호를 주파수 변환하여 안테나 시스템의 변조 신호 송수신 시험에 사용하였다.

• Bulletin of the Korean Chemical Society
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• 제26권11호
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• pp.1653-1668
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• 2005

Assembly of hybrid mesophases through the combination of amphiphilic block copolymers, acting as structuredirecting agents, and silicon sources using low acid catalyst concentration regimes is a versatile strategy to produce large quantities of high-quality ordered large-pore mesoporous silicas in a very reproducible manner. Controlling structural and textural properties is proven to be straightforward at low HCl concentrations with the adjustment of synthesis gel composition and the option of adding co-structure-directing molecules. In this account, we illustrate how various types of large-pore mesoporous silica can easily be prepared in high phase purity with tailored pore dimensions and tailored level of framework interconnectivity. Silica mesophases with two-dimensional hexagonal (p6mm) and three-dimensional cubi (Fm$\overline{3}$m, Im$\overline{3}$m and Ia$\overline{3}$d) symmetries are generated in aqueous solution by employing HCl concentrations in the range of 0.1−0.5 M and polyalkylene oxide-based triblock copolymers such as Pluronic P123 $(EO_{20}-PO_{70}-EO_{20})$ and Pluronic F127 $(EO_{106}-PO_{70}-EO_{106})$. Characterizations by powder X-ray diffraction, nitrogen physisorption, and transmission electron microscopy show that the mesoporous materials all possess high specific surface areas, high pore volumes and readily tunable pore diameters in narrow distribution of sizes ranging from 4 to 12 nm. Furthermore, we discuss our recent advances achieved in order to extend widely the phase domains in which single mesostructures are formed. Emphasis is put on the first synthetic product phase diagrams obtained in $SiO_2$-triblock copolymer-BuOH-$H_2O$ systems, with tuning amounts of butanol and silica source correspondingly. It is expected that the extended phase domains will allow designed synthesis of mesoporous silicas with targeted characteristics, offering vast prospects for future applications.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.432.2-432.2
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• 2014

Recently, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED)[1]. In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[2] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QD LED, two kinds of hybrid organic materials, [poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo)(F8BT) + poly(N,N'-bis (4-butylphenyl)-N,N'-bis(phenyl)benzidine (poly-TPD)] and [4,4'-N,N'-dicarbazole-biphenyl (CBP) + poly-TPD], were adopted as hole transport layer having high highest occupied molecular orbital (HOMO) level for improving hole transport ability. At a low-operating voltage of 8 V, the device emits orange and red spectral radiation with high brightness up to 2450 and 1420 cd/m2, and luminance efficacy of 1.4 cd/A and 0.89 cd/A, respectively, at 7 V applied bias. Also, the carrier transport mechanisms for the QD LEDs are described by using several models to fit the experimental I-V data.