• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.120-127
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• 2011

For the development of the environment-friendly insulating composite materials, natural cellulose (wood chip and sawdust) was used as a core material and activated Hwangtoh was used as a binder. Various specimens were prepared with the water/binder ratio and natural cellulose/binder ratio. The physical properties of these specimens were then investigated through compressive and flexural strength test, absorption test, hot water resistance test, thermal conductivity, measurement of pore distribution and observation of micro-structures using scanning electron microscope (SEM). Results showed that the absorption ratio increased with the increase of natural cellulose/binder ratio but decreased remarkably with the increase of polymer/binder ratio. The compressive and flexural strength development varied appreciably with the increase of water/binder ratio and natural cellulose/binder ratio. On the other hand, thermal conductivity decreased with the increase of natural cellulose/binder ratio and polymer/binder ratio. Through SEM, it was found that activated Hwangtoh that reacted with water formed a hydrate crystal leading to the compact structure and the total pore volume of the specimen using activated Hwangtoh was smaller than that of the non-activated Hwangtoh.

• Architectural research
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• v.11 no.1
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• pp.25-33
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• 2009

This study presents the testing of 15 hwangtoh-based cementless concrete mixes to explore the significance and limitations of the development of eco-friendly concrete without carbon dioxide emissions while maintaining various beneficial effects. Hwangtoh, which is a kind of kaolin, was incorporated with inorganic materials, such as calcium hydroxide, to produce a cement-less binder. The main variables investigated were the water-to-binder ratio and fine aggregate-to-total aggregate ratio to ascertain the reliable mixing design of hwangtoh-based cementless concrete. The variation of slump with elapsed time was recorded in fresh concrete specimens. Mechanical properties of hardened concrete were also measured: including compressive strength gain, splitting tensile strength, moduli of rupture and elasticity, stress-strain relationship, and bond resistance. In addition, mechanical properties of hwangtoh-based cement-less concrete were compared with those of ordinary portland cement (OPC) concrete and predictions obtained from the design equations specified in ACI 318-05 and CEB-FIP for OPC concrete, wherever possible. Test results show that the mechanical properties of hwangtoh-based concrete were significantly influenced by the water-to-binder ratio and to less extend by fine aggregate-to-total aggregate ratio. The moduli of rupture and elasticity of hwangtoh-based concrete were generally lower than those of OPC concrete. In addition, the stress-strain and bond stress-slip relationships measured from hwangtoh-based concrete showed little agreement with the design model specified in CEB-FIP. However, the measured moduli of rupture and elasticity, and bond strength were higher than those given in ACI 318-05 and CEB-FIP. Overall, the test results suggest that the hwangtoh-based concrete shows highly effective performance and great potential as an environmental-friendly building material.

• Journal of Korean Society of Rural Planning
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• v.11 no.3 s.28
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• pp.53-57
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• 2005

Up to recently building are constructed focusing on the convenience of residential condition. However, environmental-friendly materials is required for construction as people are spending more time inside buildings and causes of many problems like sick-building syndrome are known due to the noxious gases and polluted air originated from construction materials. Although loess(hwangtoh) is an environmental-friendly material, it has limitations in compressive strength far a construction material. The purpose of this study is to suggest the optimal ratio of loess(hwangtoh) mortar by tests of compressive strength comparing with standard strength of floor finishing mortar and evaluate the usability of loess(hwangtoh) mortar for floor finishing material through an impact test, a cracking test and a abrasion test. Based on the results of this study, 86% of loess(hwangtoh) and 14% of inorganic binder is suggested for the optimal mixture ratio of loess(hwangtoh) mortar. Moreover, the characteristics of loess(hwangtoh) is suitable for floor finishing material in impact, crack, abrasion.

• Journal of the Korea Institute of Building Construction
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• v.13 no.1
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• pp.1-9
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• 2013

There has recently been a great deal of research into the appropriate building materials for eco-friendly construction. In the field of earth architecture, there have been walls made of pure earth or with rammed earth including a small amount of cement. The purpose of the study is to investigate the possibility increasing compressive strength through a more eco-friendly composition by using Hwangtoh binder rather than cement to increase the strength performance of rammed earth. It was found that the more the ratio of binder was increased, the more the strength was increased, but enhancement did not increase noticeably in the lower part that did not compact completely, and proper height to pour earth is 200 mm. When stone dust was added, compressive strength was lower than when adding fine aggregate and coarse aggregate, but a finer surface texture was provided.

• Journal of the Korea Concrete Institute
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• v.20 no.5
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• pp.549-555
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• 2008

In this paper, the applicability of Hwangtoh, as an alternative of cement paste, is investigated for the solution of internal heat and shrinkage caused by the hydration of cement paste. Several small-sized specimens of Hwangtoh and ordinary portland concrete (OPC) were compared as to compressive strength, heat of hydration, and shrinkage strain. Moreover, the applicability to the construction structures was reviewed through the test of large-size specimens. The 28-day compressive strength of Hwangtoh concrete (HBC), ranged 18 to 33 MPa, can reach that of OPC. Not only the maximun internal temperature of HBC was read about 1/4 of OPC as it is cured, but also its shrinkage decreased more than the OPC did. Therefore, Hwangtoh binder is more favorable than cement binder in terms of its hydration heat and shrinkage under the construction of concrete.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.793-800
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• 2006

This paper reports test results to assess the influence of superplasticizers and different admixture on the flow and compressive strength development of cementless mortar using developed hwangtoh binder. Test specimens were classified into four groups: series for I the mixing ratio of superplasticizers, series II for a kind and replacement level of admixtures according to the variation of water/hwangtoh binder ratio, series III for the specific surface area and replacement level of ground granulated blast-furnace slag and series IV for the replacement level of powered superplasticizer agent developed to improve slump loss of concrete. The proper replacement level of each admixture is proposed for enhancement the flow and compressive strength of the hwangtoh binder mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.649-652
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• 2008

In this paper, the applicability of hwangtoh, as an alternative of cement paste, is investigated for the solution of internal heat and shrinkage caused by the hydration of cement paste. Several small-sized specimens of hwangtoh and ordinary portland concrete(OPC) were compared as to compressive strength, heat of hydration, and shrinkage strain. Moreover, the applicability of mass structure was reviewed through the test of large-size specimens. The 28-day compressive strength of hwangtoh concrete(HBC), ranged 18 to 33 Mpa, can reach that of ordinary portland concrete. Not only the maximin internal temperature of HBC was read about 1/4 of OPC as it is cured, but also its drying shrinkage decreased as lower as 50% of OPC starting from 60 days. Therefore, hwangtoh binder is more favorable than cement one in the view of hydration heat and shrinkage under the construction of mass structures.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.389-390
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• 2010

this study is preliminary experimental research for develop methods to utilize the natural Hwangtoh as replacement materials for the cement in concrete, via alkali activation at $60^{\circ}C$ using NaOH solution and liquefied $Na_2SiO_3$ in a manufacture process of Hwangtoh concrete binder.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.25-26
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• 2011

The objective of this study is to develop the prototype system for microwave heating in a manufacture process of alkali activated Hwangtoh binder as replacement materials for the cement in concrete. In order to achieve this, four research phases are carried out as follows: 1) establishment of a system concept 2) deduction of a system element 3) design of the entire system 4) making of the prototype system for microwave heating.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.121-127
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• 2011

In this study, possible use of indigenous natural loess (Hwangtoh) as a new binding material via geopolymerization process is examined. Hwangtoh pastes with four different mix proportions of varying alkali liquid concentrations (6 M, 8 M) and the constituents of the binder as well as the alkali liquid at a constant liquid-to-binder ratio of 0.55 were prepared. Analysis of the natural loess (Hwangtoh) paste was carried out as follows : 1) Measurement of compressive strength and weight of cubic specimens versus curing time; 2) Analysis by X-ray diffraction (XRD) and scanning electron microscope (SEM) about reaction product; 3) Porosity analysis of hardened Hwangtoh paste. The result showed that it is possible to prepare Hwangtoh paste with 29.1 MPa at the age of 7 day by using alkali solution (made as 1 : 4.5 the mass ratio of liquefied $Na_2SiO_3$ and NaOH solution and applying the curing temperature of $60^{\circ}C$). Compressive strength development with respect to the degree of moisture evaporation from the paste seems to be independent of curing temperature. Therefore, it seems that higher early strength of the paste specimens cured at higher temperature can be attributed to both higher rate of reaction and moisture evaporation.