• 한국자동차공학회논문집
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• 제10권2호
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• pp.48-54
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• 2002

Since photocatalysts are activated by lights of UV wavelengths, plasma is alternatively used as a light source for a photocatalytic reactor. Light intensity generated by plasma is proportional to the surface area of catalytic material, and this, in many practical applications, is prescribed by the geometry of a plasma generator. Thus, it is crucial to increase the surface area far sufficient light intensity for photocatalytic reaction. For example, in a pack-bed type reactor, multitudes of beads are used as a substrate in order to increase the surface area. Honeycomb monolith type substrate, which has very good surface area to volume ratio, has been difficult to apply plasma as a light source due to the fact that light penetration depth through the honeycomb monolith was too short to cover sufficient area, thus resulting in poor intensity for photocatalytic reaction. In this study, nonthermal plasma generation through a photocatalytic reactor of honeycomb monolith substrate is investigated to lengthen this short penetration depth. The ceramic honeycomb monolith substrate used in this study has the same length as a three way catalyst used fur automotive applications, and it is shown that sufficient light intensity for photocatalytic reaction can also be obtained with honeycomb monolith type reactor.

• 한국자동차공학회논문집
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• 제10권2호
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• pp.40-47
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• 2002

Because UV wavelength lights can activate photocatalysts, plasma is used as a light source of a photocatalytic reactor. Even though plasma has good intensity for photo reaction, substrate of catalyst coating was limited by the geometry of plasma generator. Usually bead type substrate was used for a pack bed type reactor. Honeycomb monolith type substrate was used with UV lamps instead plasma, due to the light penetration the honeycomb monolith length was too short to show good activity In this study a photocatalytic reactor, which is using a honeycomb monolith substrate, was investigated with plasma as an activation light source. As a parametric study the effects of 1311owing factors on plasma generation and power consumption are examined; supply voltage, substrate length, environment condition, catalyst loading and ratio. Using the test results, the practicability test was done with simulated synthetic gases representing bad smells and automotive exhaust gases.

• 공업화학
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• 제30권2호
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• pp.151-154
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• 2019

코디어라이트 허니컴 표면에 알루미나 워시코트 지지체를 형성시키고 비교적 단순한 건식 코팅 공정으로 산화철 촉매를 코팅함으로써 실제 환경에 효과적으로 적용이 가능한 모노리스 구조 촉매를 제조하였다. 허니컴 통로 벽 구석으로 형성된 워시코트 알루미나 미세 기공으로 균일하게 코팅된 산화철 촉매를 확인하였으며, 일산화탄소 산화 반응에 적용하기 위하여 산화철 촉매의 열처리 효과를 검증하였다. $350^{\circ}C$ 부근에서 열처리한 산화철 촉매가 가장 우수한 촉매 성능을 발휘하였고, $200^{\circ}C$ 이상의 온도 영역에서 100% 전환율을 나타내었다.

• 대한화학회지
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• 제56권5호
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• pp.563-570
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• 2012

Solid acid Mo(VI)/$ZrO_2$ with 2-10% Mo(VI) was coated on honeycomb monoliths by impregnation method. These catalytic materials were characterized by BET, $NH_3$-TPD/n-butylamine back titration, PXRD and SEM techniques. Phenyl salicylate (Salol) was synthesized via transesterification of methyl salicylate and phenol over these catalytic materials. An excellent yield (91.0%) of salol was obtained under specific reaction conditions. The effect of poisoning of acid sites of the catalytic material by adsorbing different bases and its effect on total surface acidity, powder XRD phases and catalytic activity was studied. A triangular correlation between the surface acidity, powder XRD phases and catalytic activity of Mo(VI)/$ZrO_2$ was observed. The thermally regenerated catalytic material was reused repeatedly with a consistent high yield of salol.

• 공업화학
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• 제29권1호
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• pp.18-21
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• 2018

본 연구에서는 대용량 구조 촉매의 제조 및 활용 가능성을 확인하고자 셀 밀도가 높은 세라믹 허니컴 구조체와 온도조절 화학기상증착법을 활용하여 촉매를 제조하고 건식 개질 반응에 대한 촉매 활성을 평가하였다. 셀 밀도 600 cpsi 코디어라이트 허니컴(CDR)을 대상으로 니켈을 코팅한 NiO/CDR 촉매는 코팅 조건과 시간을 조절함으로써 허니컴 구조체 셀 내부까지 충분한 균일 증착이 가능하였다, $800^{\circ}C$, 공간속도 $10,000h^{-1}$과 $CH_4$와 $CO_2$를 1 : 1로 주입한 조건에서 $CH_4$는 약 83%, $CO_2$는 약 90% 이상의 우수한 전환율을 보여 건식 개질 반응에 효과적으로 적용이 가능하다는 것을 확인하였다. 이 결과를 토대로 대면적, 대용량 촉매 제조 시 온도조절 화학기상증착법이 매우 유용하게 활용될 수 있음을 확인하였다.

• 한국연소학회지
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• 제10권1호
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• pp.20-26
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• 2005

In the present study, catalytic combustion of hydrogen-air premixture in a millimeter scale monolith coated with Pt catalyst was investigated. As the combustor size decreases, the heat loss increases in proportion with the inverse of the scale of combustion chamber and combustion efficiency decreases in a conventional type of combustor. Combustion reaction assisted by catalyst can reduce the heat loss by decreasing the reaction temperature at which catalytic conversion takes place. Another advantage of catalytic combustion is that ignition is not required. Platinum was coated by incipient wetness method on a millimeter scale monolith with cell size of $1{\times}1mm$. Using this monolith as the core of the reaction chamber, temperatures were recorded at various locations along the flow direction. Burnt gas was passed to a gas chromatography system to measure the hydrogen content after the reaction. The measurements were made at various volume flow rate of the fuel-air premixture. The gas chromatography results showed the reaction was complete at all the test conditions and the reacting species penetrated the laminar boundary layer at the honeycomb and made contact with the catalyst coated surface. At all the measuring locations, the record showed monotonous increase of temperature during the measurement duration. And the temperature profile showed that the peak temperature is reached at the point nearest to the gas inlet and decreasing temperature along the flow direction.

• 한국수소및신에너지학회논문집
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• 제18권2호
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• pp.109-115
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• 2007

Solar energy conversion to hydrogen was carried out via a two-step thermochemical water splitting using metal oxide redox pair. To simulate the solar radiation, a 7 kW short arc Xe-lamp was used. Partially reduced iron oxide and cerium oxide have the water splitting ability, respectively. So, $Fe_3O_4$ supported on $CeO_2$ was selected as the active material. $Fe_3O_4/CeO_2$(20 wt/80 wt%) was prepared by impregnation method, then the active material was washcoated on the ceramic honeycomb monolith made of mullite and cordierite. Oxygen was released at the reduction step($1673{\sim}1823\;K$) and hydrogen was produced from water at lower temperature($873{\sim}1273\;K$). The result demonstrate the possibility of the 2-step thermochemical water splitting hydrogen production by the active material washcoated monolith. And hydrogen and oxygen was produced separately without any separation process in a monolith installed reactor. But the SEM and EDX analysis results revealed that the support used in this experiment is not suitable due to the thermal instability and coating material migration.

• 한국추진공학회지
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• 제11권1호
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• pp.18-26
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• 2007

마이크로위성의 임무능력 향상을 위한 과산화수소 단일추진제 마이크로 추력기를 개발하였다. 단일 추진제 추력기의 핵심 요소인 촉매를 모노리스 지지체에 담지/제작하였으며 특성속도 효율, 반응지연 시간 측정을 통해 추력기 성능평가를 수행하였다. 실험결과 정상상태 설계 유량에서 96.0%의 높은 특성속도 효율을 확인하였다.

• 한국안전학회지
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• 제10권3호
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• pp.56-61
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• 1995

The behaviors of flame propagation and quenching in a pipe were investigated to make a design criteria of flame arrester. The effects of sealing condition of pipe end, pipe diameter and lengh were studied, and also the effects of thickness of ceramic honycomb monolith on the quenching ability were discussed. Experimental results showed that the flame velocity in case of closed pipe was increased about twenty times faster than that of opened and the sealing coditions of pipe end and length showed significant effects on it. The quenching ability of ceramic honycomb monolith was Increased with thickness and coincided well with Palmer's equation.

• 청정기술
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• 제27권4호
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• pp.332-340
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• 2021

최근 사업장 질소산화물(NOx) 배출허용기준 강화(2019년 1월 적용)에 따라 다량 배출사업장에서 배출되는 질소산화물을 배출허용기준 이하로 만족하기 위한 노력이 필요하다. 대표적인 질소산화물 저감 방법으로 선택적 촉매 환원법(selective catalytic reduction, SCR)을 주로 사용하고 있으며, 일반적으로 세라믹 허니컴(ceramic honeycomb) 촉매를 사용하고 있다. 본 연구에서는 높은 열적 안정성과 기계적 강도를 가지는 금속지지체 탈질 코팅촉매를 적용하여 제철소에서 배출되는 질소산화물를 저감하기 위한 연구를 수행하였다. 금속지지체 코팅촉매는 최적화된 촉매슬러리(catalyst slurry) 코팅방법을 통해 제조하였고, 내마모 시험과 굽힙 시험을 통해 코팅된 촉매가 균일하고 강건하게 부착되어 있음을 확인하였다. 금속지지체가 가지는 우수한 열전도 특성으로 인해 저온영역(200 ~ 250 ℃)에서 세라믹 허니컴 촉매보다도 우수한 탈질효율을 보였다. 또한 경제적인 촉매 설계를 위해 금속지지체 표면 상에 코팅되는 촉매의 최적 코팅량을 확인하였다. 이러한 연구결과를 바탕으로 제철소 배기가스 모사환경에서 상용급 금속지지체 코팅촉매에 대한 준파일럿 탈질 성능평가를 수행하였고, 저온영역(220 ℃)에서도 배출허용기준치(60 ppm 이하)을 만족하는 우수한 성능을 나타내었다. 따라서 물리화학적 특성이 우수한 금속지지체 코팅촉매가 최소량의 촉매 사용으로도 우수한 탈질 성능을 나타내었으며, 넓은 비표면적을 가지는 고밀도 금속지지체 적용을 통해 배연 탈질 촉매 반응기의 콤팩트화 및 소형화가 가능하였다. 이러한 결과를 바탕으로, 본 연구에서 사용된 금속지지체 코팅촉매는 제철소뿐만 아니라 화력발전, 소각장, 선박, 건설기계 등 다양한 산업 분야에 적용할 수 있는 새로운 형태의 촉매가 될 것이다.