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http://dx.doi.org/10.5012/jkcs.2012.56.5.563

Honeycomb Monolith Coated with Mo(VI)/ZrO2 as a Versatile Catalyst System for Liquid Phase Transesterification  

Thimmaraju, N. (Chemistry Research Laboratory, HMS Institute of Technology)
Pratap, S.R. (Chemistry Research Laboratory, HMS Institute of Technology)
Senthilkumar, M. (Department of Chemistry, SKP Engineering College)
Mohamed Shamshuddin, S.Z. (Chemistry Research Laboratory, HMS Institute of Technology)
Publication Information
Journal of the Korean Chemical Society / v.56, no.5, 2012 , pp. 563-570 More about this Journal
Abstract
Solid acid Mo(VI)/$ZrO_2$ with 2-10% Mo(VI) was coated on honeycomb monoliths by impregnation method. These catalytic materials were characterized by BET, $NH_3$-TPD/n-butylamine back titration, PXRD and SEM techniques. Phenyl salicylate (Salol) was synthesized via transesterification of methyl salicylate and phenol over these catalytic materials. An excellent yield (91.0%) of salol was obtained under specific reaction conditions. The effect of poisoning of acid sites of the catalytic material by adsorbing different bases and its effect on total surface acidity, powder XRD phases and catalytic activity was studied. A triangular correlation between the surface acidity, powder XRD phases and catalytic activity of Mo(VI)/$ZrO_2$ was observed. The thermally regenerated catalytic material was reused repeatedly with a consistent high yield of salol.
Keywords
Honeycomb monolith; Mo(VI)/$ZrO_2$; Transesterification; Salol; Solid acids;
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  • Reference
1 Aline Aroux Molecular Sieves-Acidity and Basicity; Springer- Verlag: Berlin, Heidelberg, 2008; p 69.
2 Song, X.; Sayari, A. Catal. Rev. Sci. Eng. 1996, 38, 329.   DOI
3 Yadav, G. D.; Nair, J. J. Microporous Mesoporous Mater. 1999, 33, 1.   DOI   ScienceOn
4 Hino, M.; Arata, K. Chem. Commun. 1980 851.
5 Reddy, B. M.; Reddy, V. R. Synth. Commun. 1999, 29(16), 2789.   DOI
6 Reddy, B. M.; Reddy, V. R.; Manohar, B. Synth. Commun. 1999, 29, 1235.   DOI
7 Reddy, B. M.; Sreekanth, P. M. Synth. Commun. 2002, 32, 2815   DOI
8 Reddy, B. M.; Patil, M. K.; Reddy, B. T. Catal. Lett. 2008, 125(1-2), 97.   DOI
9 Nijhuis, T. A.; Kreutzer, M. T.; Romijn, A. C. J.; Kapteijn, F.; Moulijn, J. A. Chem. Eng. Sci. 2001, 56, 823.   DOI
10 Heck, R. M.; Gulati, S.; Rarranto, R. J. Chem. Eng. J. 2001, 82, 149.   DOI
11 Reddy, B. M.; Patil, M. K. Chem. Rev. 2009, 109(6), 2185.   DOI
12 Vane, J. R.; Botting, R. M., Eds.; Aspirin and Other Salicylates, 1st ed.; Chapman & Hall: London, 1992
13 Patil, K. C.; Hegde, M. S.; Tanu, R.; Aruna, H. T. Chemistry of Nano Crystalline Oxide Materials, Combustion Synthesis, Properties and Applications; World Scientific Publishing Pvt. Ltd: Singapore, 2008.
14 Benesi, H. A. J. Phys. Chem. 1957, 6, 970.
15 Kumbhar, P. S.; Yadav, V. M.; Yadav, G. D. in: Leyden, D. E.; Collins, W. T., Eds.; Chemically Modified Oxide Surfaces; Gordon & Breach: 1989; p 81.
16 Reddy, B. M.; Reddy, V. R. Synth. Commun. 1999, 29(16), 2789.   DOI
17 Chary, K. V. R.; Reddy, K. R.; Kishan, G.; Niemantsverdriet, J. W.; Mestl, G. J. Catal. 2004, 226, 283   DOI
18 Corma, A.; Ibora, S.; Miquel, S.; Primo, J. J. Catal. 1998, 173, 315.   DOI   ScienceOn
19 Otera, J. Chem. Rev. 1993, 93, 1449.   DOI