• Title/Summary/Keyword: homogeneous mixture

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Multi-Scale Heterogeneous Fracture Modeling of Asphalt Mixture Using Microfabric Distinct Element Approach

  • Kim Hyun-Wook;Buttler William G.
    • International Journal of Highway Engineering
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    • v.8 no.1 s.27
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    • pp.139-152
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    • 2006
  • Many experimental and numerical approaches have been developed to evaluate paving materials and to predict pavement response and distress. Micromechanical simulation modeling is a technology that can reduce the number of physical tests required in material formulation and design and that can provide more details, e.g., the internal stress and strain state, and energy evolution and dissipation in simulated specimens with realistic microstructural features. A clustered distinct element modeling (DEM) approach was implemented In the two-dimensional particle flow software package (PFC-2D) to study the complex behavior observed in asphalt mixture fracturing. The relationship between continuous and discontinuous material properties was defined based on the potential energy approach. The theoretical relationship was validated with the uniform axial compression and cantilever beam model using two-dimensional plane strain and plane stress models. A bilinear cohesive displacement-softening model was implemented as an intrinsic interface and applied for both homogeneous and heterogeneous fracture modeling in order to simulate behavior in the fracture process zone and to simulate crack propagation. A disk-shaped compact tension test (DC(T)) with heterogeneous microstructure was simulated and compared with the experimental fracture test results to study Mode I fracture. The realistic arbitrary crack propagation including crack deflection, microcracking, crack face sliding, crack branching, and crack tip blunting could be represented in the fracture models. This micromechanical modeling approach represents the early developmental stages towards a 'virtual asphalt laboratory,' where simulations of laboratory tests and eventually field response and distress predictions can be made to enhance our understanding of pavement distress mechanisms, such its thermal fracture, reflective cracking, and fatigue crack growth.

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Determination of Air Fuel Ratio according to Fuel Composition (I) -Eltinge Chart as a Reference Exhaust Composition- (연료 조성에 따른 공연비 산정 (I) -기준 배기 조성으로서 Eltinge 차트-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1548-1562
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    • 2003
  • This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

Development of Poloxamer-Based Solid Suppository Containing Diclofenac Sodium (폴록사머를 이용한 디클로페낙 고형 좌제의 개발)

  • Yong, Chul-Soon;Oh, Yu-Kyoung;Kim, Jung-Ae;Kim, Yong-Il;Park, Sang-Man;Yang, Joon-Ho;Rhee, Jong-Dal;Choi, Han-Gon
    • Journal of Pharmaceutical Investigation
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    • v.34 no.2
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    • pp.91-94
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    • 2004
  • To develop a poloxamer-based solid suppository with poloxamer mixtures, the melting points of various formulations composed of P 124 and P 188 were investigated. To investigate the effect of poloxamer to the dissolution ad dissolution mechanism of diclofenac sodium from the suppository the dissolution of diclofenac sodium delivered by the poloxamer-based suppository was performed. Furthermore, to investigate the mucoadhesive property of the poloxamer-based sold suppository, the identification test in the rectum was carried out after its rectal administration in rats. The poloxamer mixtures composed of P 124 and P 188 were homogeneous. Ver small amounts of P 188 affected the melting points of poloxamer mixtures. In particular, the poloxamer mixture [P 124/P 188 (97/3%)] with the melting point of about $32^{\circ}C$ was a sold for at room temperature and instantly melted at physiological temperature. Furthermore, very small amounts of P 188 in the poloxamer-based suppository hardly affected the dissolution rates of diclofenac sodium from the suppository. Dissolution mechanism analysis showed the dissolution of diclofenac sodium was proportional to the time. At 4 h after administration, the blue colo of poloxamer-based suppository [diclofenac sodium/poloxamer mixture (2.5/97.5%)] with the P 124/ P 188 ratio of (97/3%) and blue lake in the rectum was faded. However, the position of suppository in the rectum did not significantly change with time. Thus, it retained in thε rectum for at least 4 h. Our results indicated that the poloxamer-based sold suppository with P 124 and P 188 would be a candidate of rectal dosage form for diclofenac sodium.

The Effect of Fuel Injection Timing on Combustion and Power Characteristics in a DI CNG Engine (직분식 CNG 엔진에서 연료 분사시기의 변화가 연소 및 출력 특성에 미치는 영향)

  • Kang, Jeong-Ho;Yoon, Soo-Han;Lee, Joong-Soon;Park, Jong-Sang;Ha, Jong-Yul
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.193-200
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    • 2007
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its lower harmful emissions, including $CO_2$, and high thermal efficiency. In particular, natural gas is seen as an alternative fuel for heavy-duty Diesel Engines because of the lower resulting emissions of PM, $CO_2$ and $NO_x$. Almost all CNG vehicles use the PFI-type Engine. However, PFI-type CNG Engines have a lower brake horse power, because of reduced volumetric efficiency and lower burning speed. This is a result of gaseous charge and the time losses increase as compared with the DI-type. This study was conducted to investigate the effect of injection conditions (early injection mode, late injection mode) on the combustion phenomena and performances in the or CNG Engine. A DI Diesel Engine with the same specifications used in a previous study was modified to a DI CNG Engine, and injection pressure was constantly kept at 60bar by a two-stage pressure-reducing type regulator. In this study, excess air ratios were varied from 1.0 to the lean limit, at the load conditions 50% throttle open rate and 1700rpm. The combustion characteristics of the or CNG Engine - such as in-cylinder pressure, indicated thermal efficiency, cycle-by-cycle variation, combustion duration and emissions - were investigated. Through this method, it was possible to verify that the combustion duration, the lean limit and the emissions were improved by control of injection timing and the stratified mixture conditions. And combustion duration is affected by not only excess air ratio, injection timing and position of piston but gas flow condition.

The Microstructure and Coarsening Behavior of Cr2O3 Dispersoid in ODS Cu Produced by Reactive Milling (반응성 밀링에 의해 제조된 Cr2O3 분산강화형 Cu 합금의 미세조직과 입자조대화)

  • Park, Eun-Bum;Hwang, Seung-Joon
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.4
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    • pp.171-179
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    • 2018
  • Copper powder dispersed with 4 vol.% of $Cr_2O_3$ was successfully produced by a simple milling at 210 K with a mixture of $Cu_2O$, Cu and Cr elemental powders, followed by Hot Pressing (HP) at 1123 K and 50 MPa for 2h to consolidate the milled powder. The microstructure of the HPed material was characterized by standard metallographic techniques such as XRD (X-ray Diffraction), TEM and STEM-EDS. The results of STEMEDS analysis showed that the HPed materials comprised a mixture of nanocrystalline Cu matrix and $Cr_2O_3$ dispersoid with a homogeneous bimodal size distribution. The mechanical properties of the HPed materials were characterized by micro Vickers hardness test at room temperature. The thermodynamic considerations on the heat of formation, the incubation time to ignite MSR (Mechanically induced Self-sustaining Reaction), and the adiabatic temperature for the heat of displacement reaction between the oxide-metal are made for the delayed formation of $Cr_2O_3$ dispersoid in terms of MSR suppression. The results of TEM observation and hardness test indicated that the relatively large dispersoids in the HPed materials are attributed to the significant coarsening for the high temperature consolidation; this leads to the low Vickers hardness value. Based on the thermodynamic calculation for the operating processes with a limited number of parameters, the formation kinetics and coarsening of the $Cr_2O_3$ dispersoid are discussed.

Effect of $UO_2$ Powder Property and Oxygen Potential on Sintering Characteristics of $UO_2-Gd_2O_3$ Fuel

  • Song, Kun-Woo;Kim, Keon-Sik;Yoo, Ho-Sik;Jung, Youn-Ho
    • Nuclear Engineering and Technology
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    • v.30 no.2
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    • pp.128-139
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    • 1998
  • The effect of UO$_2$ powder property and oxygen potential on characteristics of sintered UO$_2$-Gd$_2$O$_3$ fuel pellets has been investigated. Two types of powder, mixture of AUC-UO$_2$ and Gd$_2$O$_3$powders (type I) and mixture of ADU-UO$_2$ and Gd$_2$O$_3$powders (type II), have been prepared, pressed, and sintered at 168$0^{\circ}C$ for 4 hours. Four sintering atmospheres with different mixing ratios of $CO_2$to H$_2$ gas ranging from 0 to 0.3 have been used. UO$_2$-Gd$_2$O$_3$ fuel has lower sintered density than UO$_2$ fuel, and the density drop is larger for powder type I than for powder type II. As the oxygen potential increases, the sintered density of UO$_2$-2wt% Gd$_2$O$_3$pellets increases but that of UO$_2$-10wt% Gd$_2$O$_3$ pellets decreases. It is found that pores are newly formed in UO$_2$-10wt% Gd$_2$O$_3$ pellets in accordance with the decrease in density. The grain size of UO$_2$-Gd$_2$O$_3$ fuel increases and a short range G4 distribution becomes homogeneous as the oxygen potential increases. A long range ed distribution and grain structure are inhomogeneous for powder type II. The lattice parameter of (U,Gd)O$_2$solid solution decreases linearly with Gd$_2$O$_3$ content. The dependence of UO$_2$-Gd$_2$O$_3$fuel characteristics on powder type and sintering atmosphere have been discussed.

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Electrical Resistivity of the $\beta$-SiC+39vol.%$ZrB_2$ Composites ($\beta$-SiC+39vol.%$ZrB_2$ 복합체의 전기저항률)

  • Shin, Yong-Deok;Ju, Jin-Young;Yoon, Se-Won;Hwang, Chul;Lee, Jong-Deok;Song, Joon-Tae
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1916-1918
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    • 1999
  • The electrical conductive mechanism and temperature dependence of electrical resistivity of ${\beta}-SiC+ZrB_2$ composites with $Al_2O_3+Y_2O_3$ contents were investigated. The electrical resistivity of hot-pressed composites was measured by the Pauw method from $25^{\circ}C$ to $700^{\circ}C$. The electrical resistivity of the composites showed the PTCR(Positive Temperature Coefficient Resistivity) and follow the electrical conduction model for a homogeneous mixture of two kind of particles with different conductivity. Also, the electrical resistivity versus temperature curves indicate the formation of local chains of $ZrB_2$ particles.

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Grafting of Performed Polyacrylonitrile onto Cellulose Acetate (Polyacrylonitrile과 셀룰로오스 아세테이트의 그라프팅에 관한 연구)

  • 이명구;원종명
    • Journal of Korea Foresty Energy
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    • v.17 no.1
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    • pp.30-35
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    • 1998
  • The cellulose modification can be made in steps, giving a range of new products having properties quite different from the parent cellulose. Effective molecular weight control and narrow molecular weight distribution of the polyacrylonitrile can be accomplished by anionic polymerization technique. Preformed polyacrylonitrile was grafted precisely onto cellulose acetate by SN$_2$ reaction mechanism in a simple and effective way under homogeneous reaction condition. The 3.5g of completely dried cellulose acetate(DS=2.4) dissolved in 50ml of dry THF was transferred to the 215m1 polyacrylonitrile solution. The mixture was stirred vigorously under nitrogen atmosphere for 2 hrs. FTIR spectra of cellulose acetate and grafted cellulose acetate were taken, and their characteristic bands were identified.

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VELOCITY DISTRIBUTION OF DARK MATTER GALACTIC HALO

  • OH K. S.
    • Journal of The Korean Astronomical Society
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    • v.30 no.1
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    • pp.95-106
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    • 1997
  • We investigate the velocity distribution of dark matter in the disk of a galaxy like the Milky Way at the solar radius. Using N-body simulations with the total mass and z-component of angular momentum conserved, we calculate the response of a dissipationless dark matter galactic halo during the dissipational collapse of the baryonic matter in spiral galaxy formation. The initial distribution of dark matter and baryonic particles is assumed to be a homogeneous mixture based on a King model. The baryonic matter is assumed to contract, forming the final luminous components of the galaxy, namely the disk and, in some cases, a bulge and central point. Both slow and fast growth of the luminous components are considered. We find that the velocity distribution of dark matter particles in a reference frame rotating slowly about the galaxy center in the plane of the disk is similar to a Maxwellian, but it is somewhat boxier, being flatter at the peak and truncated in the tails of the distribution. We tabulate parameters for the best-fitting Maxwellian and modified-Maxwellian distributions. There is no significant difference between slow collapse and fast collapse for all these results. We were unable to detect any effect of disk formation on the z-dependence of the dark matter density distribution.

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Fabrication of $CaSO_4$ : Tm, $CaSO_4$ : Tm-PTFE TLD Radiation Sensors and Its Characteristics ($CaSO_4$ : Tm, $CaSO_4$ : Tm-PTFE TLD 소자의 제작과 특성에 관한 연구)

  • Park, Myeong-Hwan;Lee, Joon-Il
    • Journal of radiological science and technology
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    • v.16 no.1
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    • pp.107-115
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    • 1993
  • In this study, to develop highly sensitive radiation sensors, $CaSO_4$ : Tm phosphors and its disc-type TLD elements embedded PTFE(polytetrafluoroethylene) are fabricated. The highest sensitivity of $CaSO_4$ : Tm phosphors is obtained when phosphors have been doped with 0.5mol % Tm and sintered in atmosphere at $600^{\circ}C$ for two hours. Fabricated disc-type elements are made from a homogeneous mixture of phosphors and PTFE powder. They are first cold-pressed and then polymerized at $370^{\circ}C$ in air for one hour. The dose dependence of the prepared $CaSO_4$ : Tm TLD radiation sensors is linear within the range of $100{\mu}Gy{\sim}10Gy$ for X-rays and ${\gamma}-rays$. The response of $CaSO_4$ : Tm to 30keV X-rays is ten times higher than that of 1.25MeV $^{60}Co\;{\gamma}-rays$. The fading rate of the main peak is about 2% per a month. The spectral peaks of TL emission spectrum are at about 350nm and 475nm. The $CaSO_4$ : Tm TLD radiation sensors prepared in this work may be used as radiation dosimeter for personal and environmental monitoring because of their high sensitivity and little fading.

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