• Title/Summary/Keyword: homeotropic

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Liquid Crystal Orientation Mechanism: Competition Between Rubbing and Ion-beam Method

  • Kim, Ji-Ho;Han, Jeong-Min;Shon, Jin-Geun
    • Journal of Electrical Engineering and Technology
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    • v.8 no.6
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    • pp.1457-1461
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    • 2013
  • The effect of liquid crystal (LC) alignment on a homeotropic polyimide (PI) surface induced by ion beam (IB) irradiation and rubbing process was studied. LC alignment was not affected by IB irradiation with an exposure time of 10 s, and an IB irradiation with an exposure time of 60 s more effectively oriented the LCs on the PI layer than the rubbing process. It was assumed that the LC alignment depended on the C-O bonds created from the C=O bonds on the PI surface broken by IB irradiation after an exposure time of 60 s, which resulted in a strong surface energy that transformed the homeotropic LC alignment to homogeneous states.

Pretilt Angle Properties of Mixture Nematic Liquid crystal for Mobile Information Device (휴대용 통신단말에 사용되는 혼합액정계에서의 프리틸트각 특성에 관한 연구)

  • Han, Jeongmin;Seo, Daeshik
    • Journal of Satellite, Information and Communications
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    • v.10 no.1
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    • pp.67-70
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    • 2015
  • We studied the state of the dual liquid crystal (LC) alignment which displays both homeotropic and homogeneous alignment on blended polyimide (PI) layer. The research was conducted using rubbing method at different imidizing temperatures and the blended PI was made using homeotropic PI having an alkyl side chain and homogeneous PI without the side chain. The uniform LC alignments were achieved, and have thermal stability. The results of contact angles were similar to that of pretilt angles.

Liquid crystal alignment effect and synthesis of photo-polymer material containing cholesteryl moiety for homeotropic alignment (Cholesteryl 기를 함유한 수직배향용 광폴리머 재료의 합성 및 배향 효과)

  • 황정연;서대식;한은주
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.770-775
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    • 2000
  • A new photo-polymer material of the copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy)chalcone-cholesteryl methacrylate) for homeotropic alignment was synthesized and the electro-optical (EO) performance for the photo-aligned vertical-aligned (VA)-LC display (LCD) was studied. Good thermal stabilities of synthesized copolymer were obtained by TGA(Thermogravimetric Analysis) measurement. Good voltage-transmittance (V-T) and response time characteristics for the photo-aligned VA-LCD with polarized UV exposure in oblique direction($\theta$$_{i}$=30$^{\circ}$) on a copolymer-1 (2%) surfaces for 1 min were observed. but, light leakage in the off-state was observed. Therefore, we achieved excellent V-T and response time characteristics for the photo-aligned VA-LCD with UV exposure on a copolymer-3 (30%) surfaces for 3 min.n.

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Improving switching time from homeotropic state to planar state in cholesteric liquid crystal by olymer stabilization

  • Kim, Tae-Jin;Lim, Tong-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.437-438
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    • 2005
  • A polymer stabilization method is employed to reduce the transition time from field-induced homeotropic(H) state to reflecting planar(P) state in the cholesteric liquid crystal(ChLC) display. To stabilize ChLC by polymer, we mixed ChLC with diacrylate of 2 $wt%{\sim}6$ wt%. Two samples were made with different method of stabilization. For one sample the diacrylate of 2 wt% was polymerized with the ChLC in P state, while for the other sample diacrylate of 16 wt% was polymerized with ChLC in H state. In the former case, the transition time was 1000 times faster then those in the pure sample. In the latter sample, the transition time was 1700 times faster than those in pure ChLC sample.

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Homeotropic liquid crystal cell without vertical alignment layers

  • Jeng, Shie-Chang;Wang, Hsing-Lung;Kuo, Chia-Wei;Lin, Yan-Rung;Liao, Chi-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.496-498
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    • 2007
  • This paper reports our observation that the addition of nanoparticles in the negative dielectric anisotropic liquid crystal (LC) cell can exhibit the properties of vertical alignment without using alignment layers. The electro-optical properties of this nanoparticles-induced vertical alignment in the LC cell are very similar to the conventional homeotropic LC cell with alignment layers. This technique can be used to fabricate a flexible LC display demanding low temperature process

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Alignment Effect of a Nematic Liquid Crystal on Deposited SiOx Thin-Film Surface with e-beam Evaporation

  • Oh, Yong-Cheul;Lee, Dong-Gyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.6
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    • pp.305-308
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    • 2006
  • We have studied liquid crystal (LC) aligning capabilities for homeotropic alignment and the control of tilt angles on the $SiO_{x}$ thin film by electron beam evaporation method. A high tilt angle of about $86.5^{\circ}$ was obtained, and also the suitable tilt angle of the NLC on the $SiO_{x}$ thin film at $20{\sim}50\;nm$ thickness with e-beam evaporation can be achieved. The uniform LC alignment on the $SiO_{x}$ thin film surfaces with electron beam evaporation can be achieved. It is considerated that the LC alignment on the $SiO_{x}$ thin film by electron beam evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $SiO_{x}$ thin film surface created by evaporation.

LC Aligning Properties for Homeotropic Alignment of NLC on the SiOx Thin Film as Incident Angle of Electron Beam Evaporation Angle

  • Kim, Jong-Hwan;Kang, Hyung-Ku;Han, Jin-Woo;Kang, Soo-Hee;Kim, Young-Hwan;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.1
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    • pp.21-25
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    • 2006
  • In this study, liquid crystal (LC) aligning properties for homeotropic alignment on the $SiO_x$ thin film by electron beam evaporation method with electron beam system in accordance with the evaporation angles were investigated. Also, the control of pretilt angles homeotropic aligned LC on $SiO_x$ thin film as the function of the evaporation angles were studied. The uniform vertical LC alignment on the $SiO_x$ thin film surfaces with electron beam evaporation was achieved with all of the thin film angle conditions. It is considerated that the LC alignment on the $SiO_x$ thin film by electron beam evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $SiO_x$ thin film surface created by evaporation. The values of the pretilt angles according to the evaporation angle were from about $0.7^{\circ}$ to about $3.4^{\circ}$. The highest pretilt angles of about $3.4^{\circ}$ in aligned NLC on the $SiO_x$ thin film surfaces by electron beam evaporation were measured under the condition of $45^{\circ}$. Also, good LC alignment states on the treated $SiO_x$ thin film layer by electron beam evaporation were observed at annealing temperature of $250^{\circ}C$. Consequently, the high pretilt angle and the good thermal stability of LC alignment on the $SiO_x$ thin film by electron beam evaporation can be achieved.

Liquid Crystal-based Imaging of Enzymatic Reactions at Aqueous-liquid Crystal Interfaces Decorated with Oligopeptide Amphiphiles

  • Hu, Qiongzheng;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1262-1266
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    • 2010
  • In this study, we investigated the use of liquid crystals to selectively detect the activity of enzymes at interfaces decorated with oligopeptide-based membranes. We prepared a mixed monolayer of tetra(ethylene glycol)-terminated lipids and carboxylic acid-terminated lipids at the aqueous-liquid crystal (LC) interface. The 17 amino-acid oligopeptide SNFKTIYDEANQFATYK was then immobilized onto this mixed monolayer through N-hydroxysuccinimide-activation of the carboxylic acid groups. We examined the orientational behavior of nematic 4-cyano-4'-pentylbiphenyl (5CB) after conjugation of the 17 amino-acid oligopeptide with the mixed monolayer assembled at the interface. Immobilization of the oligopeptide caused orientational transitions in 5CB, with a change from homeotropic (perpendicular) to tilted alignment, which was primarily due to the reorganization of the monolayer. The orientation of the 5CB molecules returned to its homeotropic state after contacting the interface containing ${\alpha}$-chymotrypsin, which can cleave the immobilized oligopeptide. Control experiments confirmed that the enzymatic activity of ${\alpha}$-chymotrypsin triggered the ordering transitions in the LC. These results suggest that the LC can provide a facile method for selective detection of enzymatic activity.

Homeotropic Alignment Effect of a Nematic Liquid Crystal on Oblique Deposited SiOx Thin-film with e-beam Evaporation

  • Choi, Dai-Seub
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.274-277
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    • 2007
  • In this study, liquid crystal(LC) aligning capabilities for homeotropic alignment on the $SiO_x$ thin film by electron beam evaporation method were investigated. Also, the control of pretilt angles and thermal stabilities of the nematic liquid crystal(NLC) treated on $SiO_x$ thin film were investigated. A high pretilt angle of about $86.5^{\circ}$ was obtained, and also the suitable pretilt angle of the NLC on the $SiO_x$ thin film at $10{\sim}50nm$ thickness with e-beam evaporation can be achieved. The uniform LC alignment and good thermal stabilities on the $SiO_x$ thin film surfaces with electron beam evaporation can be achieved. It is considered that the LC alignment on the $SiO_x$ thin film by electron beam evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $SiO_x$ thin film surface created by evaporation.