• 제목/요약/키워드: hollow microsphere

검색결과 26건 처리시간 0.026초

중공 유리 마이크로스피어를 활용한 경량 소재 개발 (Development of a Lightweight Construction Material Using Hollow Glass Microspheres)

  • 이난경;문주혁
    • 대한토목학회논문집
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    • 제42권4호
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    • pp.449-455
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    • 2022
  • 콘크리트는 가장 많이 사용되는 건설재료이다. 콘크리트의 비교적 높은 자중은 압축강도 발현과 수축저항성에서 이점을 갖지만, 초장대교량이나 초고층빌딩에 적용되기에는 구조물 자체의 무게가 큰 폭으로 증가하게 되어 거대 구조물의 형상을 제약하는 조건이 되기도 한다. 이러한 문제를 해결하고자, 경량골재를 사용하는 경량 콘크리트 개발이 많이 진행되어 왔으나, 경량 골재의 경우 다공질 구조로 인해 자체 강도가 작기 때문에, 일반적으로 경량 콘크리트는 일반 콘크리트에 비해서 낮은 강도를 가지게 된다. 본 연구에서는 기존의 경량 콘크리트의 한계점을 극복한 경량을 유지하면서 고강도를 만족시키는 건설재료를 개발하고자 하였다. 중공 유리 마이크로스피어를 낮은 물-시멘비율의 매트릭스에 다량으로 사용하는 방법을 적용해 보았으며, 네 가지 다른 종류의 마이크로스피어를 사용하여 그 적용성을 살펴보았다. 실험결과, 마이크로스피어의 종류와 관계 없이 밀도 1.7 g/cm3를 유지하면서 압축강도 60 MPa와 80 MPa를 각각 상온양생과 고온양생 조건에서 만족하는 것을 확인할 수 있었다.

Si 결합 다공성 탄화규소의 미세구조 및 통기도 특성 -카본 함량 변화 중심 (Microstructure and Permeability Property of Si Bonded Porous SiC with Variations in the Carbon Content)

  • 송인혁;박미정;김해두;김영욱;배지수
    • 한국세라믹학회지
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    • 제47권6호
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    • pp.546-552
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    • 2010
  • The achievement of high gas permeability is a key factor in the development of porous SiC ceramics for applications of hot gas filter, vacuum chuck, and air spindle. However, few reports on the gas permeability of porous SiC ceramics can be found in the literature. In this paper, porous SiC ceramics were fabricated at temperatures ranging from $1600^{\circ}C$ to $1800^{\circ}C$ using the mixing powders of SiC, silicon, carbon and boron as starting materials. In some samples, expanded hollow microspheres as a pore former were used to make a cellular pore structure. It was possible to produce Si bonded SiC ceramics with porosities ranging from 42% to 55%. The maximum bending strength was 58MPa for the carbon content of 0.2 wt% and sintering temperature of $1700^{\circ}C$. The increase of air permeability was accelerated by addition of hollow microsphere as a pore former.

피브로인 미립구 및 중공미립구의 제조 (Fabrication of Fibroin Microspheres and Hollow Spheres)

  • 박철완;이신영;허원
    • 폴리머
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    • 제34권4호
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    • pp.321-325
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    • 2010
  • 피브로인은 실크섬유에서 대량으로 얻어지는 생물고분자이며 수술 봉합사로 장기간 사용되어 생체적합성이 확인되었다. 따라서, 본 연구에서는 생체재료로 사용할 수 있는 피브로인 미립구를 제조하였다. 데칸과 혼합유화제로 이루어진 연속상에 재생 피브로인 액적을 분산시킨 후 건조시켜 형성된 미립구를 회수하여 에탄올 등으로 세척 건조 후 수득하였다. 안정한 유중수형(W/O) 에멀션을 600 rpm으로 교반하는 조건하에서 구형의 피브로인 미립구를 얻 을 수 있었다. 주사전자현미경 사진을 통하여 상압 및 감압하에서 건조된 미립구의 수평균 직경은 각각 21.6 및 8.5 ${\mu}m$로 확인되었다. 토모그래피로 미립구는 내부구조가 채워져 있으나 크기에 따라 중공미립구임을 확인하였고 중탄 산나트륨을 도입하여 중공미립구도 제조하였다.

중공 미소 유리구를 이용한 LED 스크린 모아레 억제 (Suppression of Moiré Fringes Using Hollow Glass Microspheres for LED Screen)

  • 홍송은;나정필;정모세;김기은;박종운
    • 반도체디스플레이기술학회지
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    • 제22권3호
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    • pp.28-35
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    • 2023
  • Moiré patterns emerge due to the interference between the non-emission area of the LED screen and the grid line in an image sensor of a video recording device when taking a video in the presence of the LED screen. To reduce the moiré intensity, we have fabricated an anti-moiré filter using hollow glass microspheres (HGMs) by slot-die coating. The LED screen has a large non-emission area because of a large pitch (distance between LED chips), causing more severe moiré phenomenon, compared with a display panel having a very narrow black matrix (BM). It is shown that HGMs diffuse light in such a way that the periodicity of the screen is broken and thus the moiré intensity weakens. To quantitatively analyze its moiré suppression capability, we have calculated the spatial frequencies of the moiré fringes using fast Fourier transform. It is addressed that the moiré phenomenon is suppressed and thus the amplitude of each discrete spatial frequency term is reduced as the HGM concentration is increased. Using the filter with the HGM concentration of 9 wt%, the moiré fringes appeared depending sensitively on the distance between the LED screen and the camera are almost completely removed and the visibility of a nature image is enhanced at a sacrifice of luminance.

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Ultrasensitive metal-oxide gas sensors obtained using colloidal templates

  • Kim, Il-Doo;Rothschild Avner;Hyodo Takeo;Tuller Harry L..
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.247-247
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    • 2006
  • Chemical and physical synthesis routes were combined to prepare macroporous thin films of semiconducting metal-oxides such as $CaCu_{3}Ti_{4}O_{12}\;and\;TiO_{2}$ by sputtering onto (PMMA) microsphere templated substrates. Subsequently, the colloidal templates were removed by thermal decomposition. The remaining inorganic films comprised a monolayer of hollow hemispheres with diameter commensurate with that of the microspheres. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications.

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Synthesis of Hyaluronic Acid Microsphere Crosslinked with Polyethylene Glycol Diglycidyl Ether Prepared by A Simple Fluidic Device

  • Yuk, Sujeong;Jeong, Dayeon;Lee, Yongjun;Lee, Deuk Yong
    • 대한의용생체공학회:의공학회지
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    • 제42권6호
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    • pp.251-258
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    • 2021
  • Hyaluronic acid (HA) microspheres (MSs) crosslinked with polyethylene glycol diglycidyl ether (PEGDE) are prepared using a simple fluidic device (SFD) to investigate the optimized parameters. A solution mixture of PEGDE in 2-methyl-1-propanol was prepared as a continuous phase in SFD. HA solutions of 1 wt% concentration were introduced into SFD as a discontinuous phase. The HA solution prepared by stirring for more than 48 h exhibited spherical MSs at the needle tip inside the ring cap. As the flow rate of the continuous phase increased from 0.7 to 1.9 mL/min, the diameter of the MS decreased from 173±36 ㎛ to 129±13 ㎛. Although the PEGDE concentration in the range of 0.2 to 1.8 vol% did not affect the diameter of the MS, the microstructure of MS, consisting of inner hollow void and wall, was changed. The inner void and wall size decreased and increased from 79.5 ㎛ to 57.2 ㎛ and from 10.3 ㎛ to 21.4 ㎛, respectively, with increasing PEGDE concentration from 0.2 vol% to 1.8 vol%. FT-IR peaks located around 2867 cm-1 and 1088 cm-1 indicated that the HA MS prepared at different PEGDE concentrations were chemically crosslinked. The HA MSs containing different PEGDE concentrations exhibited quantitative cell viability of more than 98%. L-929 cells adhered well to the HA MSs and proliferated continuously with increasing culture time to 48 h regardless of PEGDE concentration, implying that the HA MSs are clinically safe and effective.