• Membrane Journal
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• v.15 no.2
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• pp.157-164
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• 2005

In this study, composite hollow fiber membranes were developed for the recovery of olefin monomers in polyolefin industry off-gases. Polyetherimide (PEI) hollow fiber support membranes were fabricated from spinning solutions containing PEI, NMP and polyethylene glycol (PEG). The influence of dope solution and inner coagulant composition on the permeation properties and structure of hollow fiber supports was examined. PDMS was used as a selective layer and coated on PEI hollow fiber support. The thickness of active layer was controlled by changing coating solution concentration. The permeation properties of hollow fiber supports and composite membranes were characterized with a pure gas permeation test. The optimized composite hollow fiber membrane has $10\;{\mu}m$ selective layer and shows excellent separation performance; the ideal selectivity of olefins over nitrogen is in the following order: 1-butylene (6.4) > propylene (17) > ethylene (97), which selectivity data are similar to the intrinsic olefin/nitrogen selectivities of PDMS. This confirms that the new composite hollow fiber membranes suitable for olefin off-gas recovery has developed successfully.

• Membrane Journal
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• v.11 no.2
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• pp.83-88
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• 2001

A methodology for enhancing the bond strength of a coating layer with a support has been established in preparing low-pressure reverse osmosis mO) hollow fiber which would experience shear badly in flowing feed un it. Prior to coating process, the support membrane, ultrafiltratiun polysulfone(PS) hollow fibers was pretreated with a reaction solution containing glutaraldehyde (GAl which has a good affinity to the suppurt membrane material as well as a reactivity to some of the cunstituents of cuating layer subsequently formed on the support by interfacial polymerization. Therefore, the reactant GA distributed unifonnly over the support layer through the pretreatment could provide a strong adhesive bond between the coating layer and the support, sticking fast to the support membrane through physical bond and, at the same time, connecting its functional group with the coating laycr by chemical bonding. Due to the strong adhesive bond, the resulting hollow fiber membrane showed an excellent long-tcnn stability in pcnneation.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.174-179
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• 2021

Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

• Membrane Journal
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• v.33 no.4
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• pp.222-232
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• 2023

In this study, a hollow fiber support membrane was prepared by a non-solvent induced phase separation (NIPS) method using a polysulfone (PSf). The prepared hollow fiber support membrane was coated with PDMS and Pebax to prepare a hollow fiber composite membrane. The prepared composite membrane was measured for permeance and selectivity for pure CO₂, H₂, O₂ and N₂. Gas separation performance of the module having the highest selectivity (CO₂/H₂) among the prepared composite membrane modules was measured according to the change in stage cut using simulated gas. The composition of the simulated gas used at this time was 70% CO₂ and 30% H₂. In the 1 stage experiment, it was possible to obtain values of about 60% of H₂ concentration and 12% of H₂ recovery. In order to overcome the low H₂ concentration and recovery, 2 stage serial test was performed, and through this, it was possible to achieve 70% H₂ concentration and 70% recovery. Through this, it was possible to derive a separation process configuration for CO₂/H₂ separation.

• Membrane and Water Treatment
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• v.10 no.4
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• pp.287-298
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• 2019

Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

• Korean Membrane Journal
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• v.7 no.1
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• pp.19-27
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• 2005

PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

• Membrane Journal
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• v.27 no.1
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• pp.60-67
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• 2017

Recently, the economic, social and environmental significance of the water industry is increasing significantly due to rapid global urbanization, population growth, and imbalance in demand and supply of water resulted by climate change. The type of these water industries are all different and they can be distinguished by the kinds of membranes used. Mainly, polymer materials that have excellent physical and chemical stability are used, but recently various methods of assigning hydrophilicity have been introduced due to their hydrophobic properties. In this study, hydrophilic polymers of four types were introduced into a commercially available hollow support to assign hydrophilicity. Furthermore, the morphology of the coated hollow support through FE-SEM was confirmed as well. Also the contact angle was measured to examine the degree of hydrophilicity of the coated hollow support with each polymer. Finally,.effect of different time on water permeability as well as the relationship between water permeability and hydrophilic polymers were investigated. As a result, the coating with 1 wt% of pluronic has good hydrophilicity degree, and shows the excellent water permeability without blocking the pore of the hollow fiber. Therefore, it can be concluded that the hydrophilic coating using pluronic polymer is most suitable as the water treatment.

• Membrane Journal
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• v.23 no.2
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• pp.176-184
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• 2013

To investigate the performance of VOC separation, composite hollow fiber membrane was prepared which composed of poly (ether imide) support prepared by phase separation method and poly (dimethylsiloxane) coating active layer. The performances of the membranes for the application of recovery process in terms of their morphology, gas permeance test for $N_2$ and $O_2$ gases. Durability against benzene, toluene and xylene was also investigated. And permeation test for multi-component VOCS through the membrane with different feed concentration and stage-cut were investigated. Permeance of PEI supported membrane and the membranes coated with PDMS decreased from 45,000 GPU to 63 GPU and 49,450 to 30 GPU for $N_2$ and $O_2$, respectively. Recovery efficiency and concentration of VOCs in permeate increased with decreasing stage-cut. VOCs concentration in permeate proportionally increased with increasing feed concentration but concentration ratio and recovery efficiency showed any noticeable changes with feed concentration change.

• Membrane Journal
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• v.25 no.5
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• pp.391-397
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• 2015

The porous support polyvinylidene fluoride (PVDF) with a salting out based on the hollow fiber membrane polyethyleneimine (PEI) and polyvinylsulfonic acid (PVSA) by coating with by phase separated and pressurization (PSP) method to produce a multilayer membrane. The resulting membranes were characterized under the various conditions, such as the heat treatment temperature, coating concentration, feed concentration, cross-linking time and cross-link agent concentration in terms of flux and rejection rate for NaCl 100 ppm solution at 4 atm. The best results were PEI 20,000 ppm and PVSA 1,000 ppm, PEI 15% with a 2% malic acid aqueous solution coated by PSP method the hollow fiber membrane heat-treated for 1 minute showed flux 24.3 LMH, the rejection of 82.1%.

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.274-280
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• 2014

Polysulfone (PSf) hollow fiber membranes were prepared via the nonsolvent induced phase separation technique. The cosolvent of ${\gamma}$-butyrolactone (GBL) was added to the polymer solution containing a mixture of PSf and N,N-dimethylacetamide (DMAc). Water was utilized as a precipitation nonsolvent. The morphology of prepared membranes was investigated using a field emission scanning electron microscopy. The fabricated membrane showed a typical asymmetric structure such as the dense layer on the porous support layer by the addition of GBL to the polymer solution. As the concentration of GBL increased, the asymmetric porous structure was shown to be more intensified. It was thought that the added GBL played a role of enhancing the liquid-liquid phase separation of the polymer solution, since the cosolvent of GBL might change the thermodynamic solubility parameter of the doping solution. Permeation properties through the prepared hollow fiber membranes were characterized by measuring the pure water flux and the solute rejection using $0.05{\mu}m$ polystyrene latex (PSL) beads. Experimental results revealed that the use of PEG as the internal coagulant enhanced the pure water flux up to 130 times compared to the use of EG while the rejection of the PSL beads decreased only 5%.