• 제목/요약/키워드: hole transport

검색결과 339건 처리시간 0.028초

Improvement of the luminous efficiency of organic light emitting diode using LiF anode buffer layer

  • 박원혁;김강훈
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
    • /
    • pp.147-147
    • /
    • 2015
  • The multilayer structure of the organic light emitting diode has merits of improving interfacial characteristics and helping carriers inject into emission layer and transport easier. There are many reports to control hole injection from anode electrode by using transition metal oxide as an anode buffer layer, such as V2O5, MoO3, NiO, and Fe3O4. In this study, we apply thin films of LiF which is usually inserted as a thin buffer layer between electron transport layer(ETL) and cathode, as an anode buffer layer to reduce the hole injection barrier height from ITO. The thickness of LiF as an anode buffer layer is tested from 0 nm to 1.0 nm. As shown in the figure 1 and 2, the luminous efficiency versus current density is improved by LiF anode buffer layer, and the threshold voltage is reduced when LiF buffer layer is increased up to 0.6 nm then the device does not work when LiF thickness is close to 1.0 nm As a result, we can confirm that the thin layer of LiF, about 0.6 nm, as an anode buffer reduces the hole injection barrier height from ITO, and this results the improved luminous efficiency. This study shows that LiF can be used as an anode buffer layer for improved hole injection as well as cathode buffer layer.

  • PDF

Solution-Processed Quantum-Dots Light-Emitting Diodes with PVK/PANI:PSS/PEDOT:PSS Hole Transport Layers

  • Park, Young Ran;Shin, Koo;Hong, Young Joon
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
    • /
    • pp.146-146
    • /
    • 2015
  • We report the enhanced performance of poly(N-vinylcarbozole) (PVK)/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)-based quantum-dot light-emitting diodes by inserting the polyaniline:poly (p-styrenesulfonic acid) (PANI:PSS) interlayer. The QD-LED with PANI:PSS interlayer exhibited a higher luminance and luminous current efficiency than that without PANI:PSS. Ultraviolet photoelectron spectroscopy results exhibited different electronic energy alignments of QD-LEDs with/without the PANI:PSS interlayer. By inserting the PANI:PSS interlayer, the hole-injection barrier at the QD layer/PVK interface was reduced from 1.45 to 1.23 eV via the energy level down-shift of the PVK layer. The reduced barrier height alleviated the interface carrier charging responsible for the deterioration of the current and luminance efficiency. This suggests that the insertion of PANI:PSS interlayer in QD-LEDs contributed to (i) increase the p-type conductivity and (ii) reduce the hole barrier height of QDs/PVK, which are critical factors leading to improve the efficiency of QD-LEDs.

  • PDF

Slim hole 경사 환형관내 고-액 혼합유동 특성에 관한 연구 (Solid-liquid mixture flow characteristics in an inclined slim hole annulus)

  • 서병택;한상목;우남섭;김영주;황영규
    • 대한설비공학회:학술대회논문집
    • /
    • 대한설비공학회 2008년도 하계학술발표대회 논문집
    • /
    • pp.1315-1320
    • /
    • 2008
  • An experimental study was carried out to study the solid-liquid mixture upward flow in a vertical and inclined annulus with rotating inner cylinder. Lift forces acting on a fluidized particle plays a central role in many importance applications, such as the removal of drill cuttings in horizontal drill holes, sand transport in fractured reservoirs, sediment transport and cleaning of particles from surfaces, etc. Field measurements have revealed that the pressure drop over a borehole during drilling of a slim oil well or a well with a long reach can depend significantly on the rotation speed of the drill pipe. An accurate prediction of the annular frictional pressure drop is therefore important for conditions where the annular clearance is small. Effect of annulus inclination and drill pipe rotation on the carrying capacity of drilling fluid, particle rising velocity, and pressure drop in the slim hole annulus have been measured for fully developed flows of water and of aqueous solutions.

  • PDF

Synthesis of Conjugated Polymers with Fluorene and Biphenylamine and Application to PLED Devices

  • Park, Eun-Jung;Kwon, Hyeok-Yong;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.458-460
    • /
    • 2008
  • Four kinds of copolymers with fluorene and biphenylamine units were synthesized by palladium-catalyzed polycondensation reaction. These polymers were characterized in terms of their UV/Visible and photoluminescence (PL) properties in solution and film state. These polymers were also studied as a hole transporting material in the polymer light emitting diode (PLED) devices.

  • PDF

정공 주입층 및 수송층에 따른 고분자 유기발광다이오드의 특성 연구 (The Properties of Hole Injection and Transport Layers on Polymer Light Emitting Diode)

  • 신상배;장호정
    • 마이크로전자및패키징학회지
    • /
    • 제14권4호
    • /
    • pp.37-42
    • /
    • 2007
  • 본 연구에서는 ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al의 구조를 갖는 고분자 유기발광다이오드를 제작하여 정공 주입층으로 사용되는 PEDOT:PSS의 두께 변화와 PVK 정공 수송층을 도입하여 ITO/PEDOT:PSS/PVK/PFO:MEH-PPV/LiF/Al 구조를 갖는 고분자 유기발광 다이오드를 제작하여 정공수송층이 유기발광다이오드의 전기 광학적 특성에 미치는 영향에 대하여 조사, 비교하였다. 실험에 사용된 모든 유기물은 플라즈마 처리된 ITO/glass 기판위에 스핀 코팅법으로 도포하였다. 정공 주입층인 PEDOT:PSS 두께를 약 80 nm에서 50 nm로 감소한 경우 PLED 소자의 휘도는 약 $220cd/m^2$ 에서 $450cd/m^2$으로 크게 증가하였다. 이러한 결과는 정공 주입층의 두께가 감소할수록 ITO 전극에서 발생한 정공이 보다 쉽게 발광막으로 전달되기 때문이다. 또한 PVK 정공 수송층을 도입한 PLED소자에서 최대 전류밀도와 휘도는 $268mA/cm^2$$540cd/m^2$ (at 12V)의 값을 각각 나타내었다. PVK 정공 수송층이 도입되지 않은 소자에 비해 전류밀도는 약 14%, 휘도는 약 22%의 특성개선을 나타내었다.

  • PDF

정공 주입층 CuPc 두께 변화에 따른 유기 발광 소자의 발광 특성 (Electroluminescent Properties of Organic Light-emitting Diodes Depending on the Thickness of CuPc Hole-injection Layer)

  • 이정복;김경환;김태완;이원재
    • 한국전기전자재료학회논문지
    • /
    • 제26권12호
    • /
    • pp.899-903
    • /
    • 2013
  • We investigated the luminescence properties of $Alq_3$ in the device structure of ITO/CuPc/TPD/$Alq_3$/Al. The CuPc as a hole-injection material and TPD as hole-transport material. Emission properties were measured by varying a layer thickness of CuPc (0 nm to 50 nm), which is the hole-injection layer. As a result, it was found that the hole injection occurs smoothly when the layer thickness was 20 nm among the thicknesses from 0 nm to 50 nm.

The Moving Photocarrier Grating (MPG) Technique for the Transport Properties of α-Se:As Films

  • Park, Chang-Hee;Lee, Kwang-Sei;Kim, Jeong-Bae;Kim, Jae-Hyung
    • Transactions on Electrical and Electronic Materials
    • /
    • 제6권6호
    • /
    • pp.280-283
    • /
    • 2005
  • The moving photocarrier grating (MPG) technique for the determination of the carrier mobilities and the recombination lifetime of $\alpha$-Se:As films has been studied. The electron and hole drift mobility and the recombination lifetime of $\alpha$-Se films with arsenic (As) additions have been obtained from measurement of the short circuit current density $j_{sc}$ as a function of grating velocity and spatial period. The hole mobility decreases due to defect density of hole traps when x exceeds 0.003, whereas the hole mobility increases for the case of low As addition (x$\le$0.003). We have found an increase in hole drift mobility and recombination lifetime, especially when As with (x = 0.003) is added into the $\alpha$-Se film.

신경회로망기법을 사용한 원통형 막냉각 홀의 최적설계 (Design Optimization of a Cylindrical Film-Cooling Hole Using Neural Network Techniques)

  • 이기돈;김광용
    • 대한기계학회논문집B
    • /
    • 제32권12호
    • /
    • pp.954-962
    • /
    • 2008
  • This study presents a numerical procedure to optimize the shape of cylindrical cooling hole to enhance film-cooling effectiveness. The RBNN method is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer with shear stress transport turbulent model. The hole length-to-diameter ratio and injection angle are chosen as design variables and film-cooling effectiveness is considered as objective function which is to be maximized. Twelve training points are obtained by Latin Hypercube Sampling for two design variables. In the sensitivity analysis, it is found that the objective function is more sensitive to the injection angle of hole than the hole length-to diameter ratio. Optimum shape gives considerable increase in film-cooling effectiveness.

Co-existence of Random Telegraph Noise and Single-Hole-Tunneling State in Gate-All-Around PMOS Silicon Nanowire Field-Effect-Transistors

  • Hong, Byoung-Hak;Lee, Seong-Joo;Hwang, Sung-Woo;Cho, Keun-Hwi;Yeo, Kyoung-Hwan;Kim, Dong-Won;Jin, Gyo-Young;Park, Dong-Gun
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • 제11권2호
    • /
    • pp.80-87
    • /
    • 2011
  • Low temperature hole transport characteristics of gate-all-around p-channel metal oxide semiconductor (PMOS) type silicon nanowire field-effect-transistors with the radius of 5 nm and lengths of 44-46 nm are presented. They show coexisting two single hole states randomly switching between each other. Analysis of Coulomb diamonds of these two switching states reveals a variety of electrostatic effects which is originated by the potential of a single hole captured in the trap near the nanowire.

Effect of Hole-Transporting Layer and Solvent in Solution Processed Highly-Efficient Small Molecule Organic Light-Emitting Diodes

  • Jo, Min-Jun;Hwang, Won-Tae;Chae, Hee-Yeop
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
    • /
    • pp.250-250
    • /
    • 2012
  • Organic light-emitting diodes (OLED) and polymer light emitting diodes (PLED) have been regarded as the candidate for the next generation light source and flat panel display. Currently, the most common OLED industrial fabrication technology used in producing real products utilizes a fine shadow mask during the thermal evaporation of small molecule materials. However, due to high potential including low cost, easy process and scalability, various researches about solution process are progressed. Since polymer has some disadvantages such as short lifetime and difficulty of purifying, small molecule OLED (SMOLED) can be a good alternative. In this work, we have demonstrated high efficient solution-processed OLED with small molecule. We use CBP (4,4'-N,N'-dicarbazolebiphenyl) as a host doped with green dye (Ir(ppy)3 (fac-tris(2-phenyl pyridine) iridium)). PBD (2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole) and TPD (N,N'diphenyl-N,N'-Bis (3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine) are employed as an electron transport material and a hole transport material. And TPBi (2,2',2''-(1,3,5-phenylene) tris (1-phenyl-1H-benzimidazole)) is used as an hole blocking layer for proper hole and electron balance. With adding evaporated TPBi layer, the current efficiency was very improved. Among various parameters, we observed the property of OLED device by changing the thickness of hole transporting layer and solvent which can dissolve organic material. We could make small molecule OLED device with finding proper conditions.

  • PDF