• Title/Summary/Keyword: higher order solution

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Effect of Extraction Solvents on Color of the Dyed Fabrics with Safflower Red Colorants (홍화의 홍색소 추출 용제의 종류에 따른 색상 변화)

  • Son, Kyung-Hee;Shin, Youn-Sook;Yoo, Dong-Il;Choi, Hee;Cho, A-Rang
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.3
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    • pp.486-493
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    • 2008
  • Safflower red colorants extracted by two solvents including the traditional ash solution and $K_{2}CO_{3}$ solution was used for dyeing cotton, ramie, viscose rayon, silk, wool, and nylon fabrics. The effects of extraction solvents on the reflectance, K/S value, and color properties of the dyed fabrics were investigated. Wash/dry cleaning and light colorfastness were evaluated. Reflectance curves of cotton, ramie, viscose rayon, and silk fabrics dyed with red colorants extracted by $K_{2}CO_{3}$ solution were similar, showing the maximum absorption at 520nm, to that of the dyed fabrics with red colorants extracted by ash solution. The reflectance curves of wool and nylon fabrics were different, showing the maximum absorption at 400nm. K/S values of dyed fabrics with red colorants extracted by $K_{2}CO_{3}$ solution were higher than that by ash solution with the exception of nylon. $L^{*},\;a^{*},\;b^{*}$, and $C^{*}$ of the dyed fabrics with red colorants extracted by $K_{2}CO_{3}$ solution were higher than that by ash solution except for $L^{*}$ of nylon and $b^{*}$ of viscose rayon. Color difference(${{\Delta}E}^*$) of the dyed fabrics between ash solution and $K_{2}CO_{3}$ solution increased in the order named as cotton, silk, ramie, viscose rayon, wool, and nylon. Regardless of extraction solvents, safflower red colorants produced RP color on cotton, ramie, and nylon, R color on viscose rayon and silk, and YR color on wool. Wash/dry cleaning fastness of the dyed fabrics was high above 3/4 rating but light fastness was very poor. It is considered that the use of $K_{2}CO_{3}$ solution instead of the traditional ash solution would be more effective in terms of color reproducibility and extraction process.

Adsorption of lisinopril and chlorpheniramine from aqueous solution on dehydrated and activated carbons

  • El-Shafey, El-Said I.;Al-Lawati, Haider A. J.;Al-Saidi, Wafa S. H.
    • Carbon letters
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    • v.19
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    • pp.12-22
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    • 2016
  • Date palm leaflets were used as a precursor to prepare dehydrated carbon (DC) via phosphoric acid treatment at 150℃. DC, acidified with H3PO4, was converted to activated carbon (AC) at 500℃ under a nitrogen atmosphere. DC shows very low surface area (6.1 m2/g) while AC possesses very high surface area (829 m2/g). The removal of lisinopril (LIS) and chlorpheniramine (CP) from an aqueous solution was tested at different pH, contact time, concentration, and temperature on both carbons. The optimal initial pH for LIS removal was 4.0 and 5.0 for DC and AC, respectively. However, for CP, initial pH 9.0 showed maximum adsorption on both carbons. Adsorption kinetics showed faster removal on AC than DC with adsorption data closely following the pseudo second order kinetic model. Adsorption increases with temperature (25℃–45℃) and activation energy (Ea) is in a range of 19–25 kJ mol/L. Equilibrium studies show higher adsorption on AC than DC. Thermodynamic parameters show that drug removal is endothermic and spontaneous with physical adsorption dominating the adsorption process. Column adsorption data show good fitting to the Thomas model. Despite its very low surface area, DC shows ~70% of AC drug adsorption capacity in addition of being inexpensive and easily prepared.

Approximation to the Probability of Downlink Blocking between cdma2000 1X and WCDMA in Urban Handover Areas (도심 핸드오프 지역에서의 cdma2000 1X와 WCDMA간의 다운링크 블록킹 확률 근사)

  • 박승근;조경록;박덕규
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.2
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    • pp.89-95
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    • 2003
  • This paper proposes downlink blocking model and approximation equation using lower bound approximation in order to determine the proper guard band between cdma2000 1X and WCDMA in handover areas. The frequency sharing conditions obtained by the model and approximation equation on blocking probability proposed in the paper, are co-site of base station and guard band higher than 1 MHz. Also, the proposed equation is in the form of Q-function. It is an analytical solution overcoming the drawback of recalculation, belonged to Monte-Carlo technique.

Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water (고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향)

  • Lee, Sun Gi;Han, Seung Woo;Kang, Lim Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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Preparation of$SnO_2$-based gas sensor by Sol-Gel process

  • Bui, Anh-Hoa;Baek, Won-Woo;Lee, Sang-Tae;Jun, Hee-Kwon;Lee, Duk-Dong;Huh, Jeung-Soo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.135-135
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    • 2003
  • This paper presents the preparation of SnO$_2$ films by Sol-Gel process and using spin coating method, and their sensing properties in CO gas. Experimental procedure consisted of following steps: (1) Tin chloride(SnCl$_4$) and Ammonium hydrogen carbonate (NH$_4$HCO$_3$) were used as precursors; (2) the Sol solution with concentration of about 10wt% SnO$_2$ was prepared from washed Gel-precipitate for spin coating step; (3) thereafter, the coating solution was dropped onto the alumina (Al$_2$O$_3$) substrate that was then spun, the spin coating was carried out with total 10 times; (4) finally, the films were calcined for 3 hours at 50$0^{\circ}C$ or higher temperature (600, 700, 800 or 90$0^{\circ}C$) in order to obtain various gram sizes. The average grain size was calculated by Scherrer's equation using main peaks in XRD spectra; meanwhile the thickness, microstructure and surface morphology of the films were observed by FE-SEM.

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Removal of Cd(II) and Pb(II) Ions in water by the Ulva pertusa and Sargassum horneri (Ulva pertusa 및 Sargassum horneri를 이용한 수중 Cd(II) 및 Pb(II) 이온의 제거)

  • 김영하;박미아;박수인;김택제;이기창
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.803-809
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    • 1998
  • Heavy metal ions in water were removed using algal biomass as adsorbents. Absorbents were dried for 3 days, ground them by 40~60 mesh and then were swelled in a buffer solution for 1hr. After being packed in the column, commercially available standard solution of Cd(II) and Pb(II) ions were diluted to get the suitable concentration and then it was eluted with the rate of 1mι/min. Heavy metals on the adsorbents were recovered with nitric acid. More amounts of Cd(II) or Pb(II) ions in green algae, Ulva pertusa, than in brown algae, Sargassum horneri, were adsorbed. Pb(II) ion was adsorbed more than Cd(II) ion in both algae. The pH effect of adsorbed amounts of Cd(II), Pb(II) ions on the biomass was shown the following order ; pH 10.5 > 8.5 > 7.0 > 5.5 > 3.5. Recovery ratio of metal ions front algae is shown higher in acidic or neutral conditions than it in alkalic ones. Pb(II) ion is recovered relatively more than Cd(II) ion in our system.

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A Study on Physical Properties and Adsorption Characteristics of Heavy Metal Ions of Loess (황토의 물리적 특성 및 수용액중의 중금속 이온의 흡착 특성에 관한 연구)

  • 정의덕;김호성;박경원;백우현
    • Journal of Environmental Science International
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    • v.8 no.4
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    • pp.491-496
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    • 1999
  • Removal of Cu(II), Cr(III) and Pb(II) ions from aqueous solutions using the adsorption process on the loesses has been investigated. Variations of contact time, pH, adsorption isotherms and selectivity of coexisting ions were experimental parameters. pH of KJ and YIK samples diluted to 1% solution, was rearly the same with each value of pH 5.58 and 5.49, and both samples showed weak acidic properties. From chemical analysis, both samples contain remarkably different amounts of ${SiO}_{2}$, ${Al}_{2}O_{3}$ and ${Fe}_{2}O_{3}$. From XRD measurement, quartz was mainly observed in both samples. Kaolinite was also observed, also in both samples, but Feldspar was only observed in KJ sample. Adsorption of metal ions on the loesses were reached at equilibrium by shaking for about 30min. The adsorption of Cr(III) ion was higher than that of Cu(II) oand Pb(II) ions. The order of amount adsorbed among the investigated ions was Cr(III)>Pb(II)>Cu(II). In acidic solution, the adsorptivity of loesses was increased as pH increased. The adsorption of Cr(III) ion on the loesses were fitted to the Freundlich isotherms. Freundlich constants(1/n) of KJ and YIK loesses were 0.54 and 0.55, respectively.

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A Novel on Optimal Growth Management System of Corp using Recirculation of Nutrient Solution based on IoT and Location Tracking Technology (IoT 및 위치 추적 기술 기반의 양액 순환 방식을 활용한 작물의 최적 생장 관리 시스템에 관한 연구)

  • Jung, Se Hoon;Park, Sung Kyun;Sim, Chun Bo
    • Journal of Korea Multimedia Society
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    • v.19 no.11
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    • pp.1891-1899
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    • 2016
  • Recently food problem and crop disaster have been increased continuously because of the meteorological changes. These cause rising cost for crops continuously and irregularly. Some researchers have studied straight structure of device for hydroponics and plant factory previously to solve a fundamental part of these problems. However, there are several problems such as limited crop cultivation space, providing irregular nutrients for crops, and lack of monitoring interfaces. For them, we propose an optimal growth and development crops management system using light source tracking and recirculation of nutrient solution method to supply nutrient continuously based on IoT. In order to evaluate the performance of our system, we compared and analyzed in terms of two viewpoints, the tracking analysis for natural light source measurement and the growth of crops through artificial light, LED, respectively. We confirmed that the higher the duty ratio of LED, the larger the crop's size, particularly. As well as, for about 1 month, we compared with the existing natural light growing environment and that of our system. It was confirmed that the size of the crops grown through our system is about three times larger than that of natural light natural crops.

Development of viscosity sensor using surface acoustic wave (탄성 표면파를 이용한 점도 센서의 개발)

  • Chong, Woo-Suk;Kim, Gi-Beum;Kang, Hyung-Sub;Hong, Chul-Un
    • Journal of Sensor Science and Technology
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    • v.17 no.4
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    • pp.289-294
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    • 2008
  • The purpose of this study is to materialize the viscosity sensor by using the SH-SAW sensor of which the center frequency is operated at higher than 50 MHz. In order to measure the viscosity, SAW sensor of which the center frequency is operated at 100 MHz is developed. By using the developed sensor, phase shift, delay time, insertion loss, and frequency variation are measured at different viscosity. The result shows that the phase shift difference between the viscosity variations is such that the difference between the distilled water and the 100 % glycerol solution is approximately $45^{\circ}$, the change of the insertion loss is approximately 9 dB, and the difference of frequency variation is approximately 5.9 MHz. Therefore, it is shown that viscosity of unknown solution can be measured with the surface acoustic wave sensor.

Free vibration analysis of FG plates resting on the elastic foundation and based on the neutral surface concept using higher order shear deformation theory

  • Benferhat, Rabia;Daouadji, Tahar Hassaine;Mansour, Mohamed Said;Hadji, Lazreg
    • Earthquakes and Structures
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    • v.10 no.5
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    • pp.1033-1048
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    • 2016
  • An analytical solution based on the neutral surface concept is developed to study the free vibration behavior of simply supported functionally graded plate reposed on the elastic foundation by taking into account the effect of transverse shear deformations. No transversal shear correction factors are needed because a correct representation of the transversal shearing strain obtained by using a new refined shear deformation theory. The foundation is described by the Winkler-Pasternak model. The Young's modulus of the plate is assumed to vary continuously through the thickness according to a power law formulation, and the Poisson ratio is held constant. The equation of motion for FG rectangular plates resting on elastic foundation is obtained through Hamilton's principle. Numerical examples are provided to show the effect of foundation stiffness parameters presented for thick to thin plates and for various values of the gradient index, aspect and side to thickness ratio. It was found that the proposed theory predicts the fundamental frequencies very well with the ones available in literature.