• Title/Summary/Keyword: high-density polyethylene (HDPE)

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Crystallization Behavior and Mechanical Properties of High Density Polyethylene/metallocene catalyzed Poly(ethylene-co-octene) Blends (고밀도 폴리에틸렌/폴리에틸렌-옥텐 공중합체 블렌드의 결정화 거동 및 기계적 물성에 관한 연구)

  • Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.6
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    • pp.3108-3113
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    • 2013
  • Compatibility between mLLDPE and HDPE was investigated by observing the crystallization behavior and mechanical properties of their blends. HDPE and mLLDPE blends were prepared by a melt-blending with compositions of 100/0, 80/20, 60/40, 40/60/ 20/80 and 0/100. Four different mLLDPEs containing various octene contents (4.1, 6.8, 9.8 및 12.5 mol.%) were investigated. The melting temperature and crystallization peak temperature of the blends were measured by DSC and the mechanical properties were measured in an universal testing machine. By observation that the melting and crystallization peak temperatures of one component were affected by its counterparts, it was revealed that HDPE and mLLDPE are miscible or at leat partially miscible at molten state. It was also found that the crystalline phase of mLLDPE contains HDPE crystals. However. it was not clear that mLLDPE was cocrystalized in the crystalline phase of HDPE. By various investigation with DSC and mechanical properties, it was concluded that the compatibility between mLLDPE and HDPE decreases with the octene content in the mLLDPE.

Effects of MA Storage with NaCl for Red Chili Pepper and Red Bell Pepper Fruits (NaCl을 이용한 홍고추 및 홍피망의 MA저장 효과)

  • 정천순;이귀현
    • Food Science and Preservation
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    • v.9 no.1
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    • pp.8-13
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    • 2002
  • The effects of modified atmosphere (MA) storage far fresh red pepper and red bell pepper fruits were investigated with storing in high and few density polyethylene films (HDPE, LDPE) with various NaCl contents(0 g, 15 g, 20 g, 25 g). During the storage of pepper fruits, the weight loss, color change, mold emergence, and firmness were evaluated. The weight loss of pepper fruits packaged in HDPE and LDPE without NaCl was 3∼5%, even though it was 6∼19% in pepper fruits packaged with NaCl. The lutes of mold emergence of red pepper and red bell pepper fruits were lowered to 20∼45% as stored in HDPE and LDPE with NaCl but those of fruits stored in films without NaCl were high as 55∼65%. The color and firmness of pepper fruits were not much changed in comparison with those of non-packaged fruits as stored in HDPE and LDPE with or without NaCl.

Investigation on the thermal butt fusion performance of the buried high density polyethylene piping in nuclear power plant

  • Kim, Jong-Sung;Oh, Young-Jin;Choi, Sun-Woong;Jang, Changheui
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1142-1153
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    • 2019
  • This paper presents the effect of fusion procedure on the fusion performance of the thermal butt fusion in the safety class III buried HDPE piping per various tests performed, including high speed tensile impact, free bend, blunt notched tensile, notched creep, and PENT tests. The suitability of fusion joints and qualification procedures was evaluated by comparing test results from the base material and buttfusion joints. From the notched tensile test result, it was found that the fused joints have much lower toughness than the base material. It was also identified that the notched tensile test is more desirable than the high speed tensile impact and free bend tests presented in the ASME Code Case N-755-3 as a fusion qualification test method. In addition, with regard to the single low-pressure fusion joint performances, the procedure given by the ISO 21307 was determined to be better that the one specified in the Code Case N-755-3.

Pigment Influence of High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌의 전계 세기의 영향)

  • Choi, Yong-Sung;Wee, Sung-Dong;Hwang, Jong-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.50-53
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    • 2008
  • In this work, the $TiO_2$ pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties. Formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The $\beta$ parameter could be using to insulator particles dispersion. The $TiO_2$ concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the $\beta$ parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% $TiO_2$ weight.

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Pigment Influence in High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌에 있어서 전계의 세기의 영향)

  • Yun, Ju-Ho;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.331-332
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    • 2007
  • In this work, the TiO2 pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties, formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The parameter could be using to insulator panicles dispersion. The TiO2 concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% TiO2 weight.

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Morphological Properties of Binary Blends of Polyolefins Synthesized by Metallocene and Ziegler-Natta Catalysts (Ziegler-Natta와 메탈로센 촉매로 합성된 폴리올레핀 2원 블렌드의 상 형태학)

  • Kwag, Hanjin;Kim, Hak Lim;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.944-948
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    • 1999
  • The morphological properties of four binary blends of polyethylene synthesized by metallocene catalyst(MCPE) and four polyolefins prepared by Ziegler-Natta catalyst have been investigated to interpret the effect of micro-molecular structure on the phase morphology and interfacial behavior; four binary blend systems studied are high density polyethylene(HDPE)-metallocene polyethylene (MCPE), polypropylene(PP)-MCPE, poly(propylene-co-ethylene) (CoPP)-MCPE, and poly(propylene-co-ethylene-co-1-butylene) (TerPP)-MCPE, and they are all phase separated. The HDPE-MCPE blend shows evenly growing homogeneous HDPE domain on the continuous MCPE phase, on the other hand, the rest of three blends show complex heterogeneous phase behavior. The PP-MCPE blend shows that PP and MCPE and completely phase separated and phase inversion takes place at 50% MCPE. The CoPP-MCPE and TerPP-MCPE show enhanced interface due to the same micro-molecular structure of ethylene, and phase inversion takes place at 40% MCPE. In particular, TerPP-MCPE blend shows improved phase morphology between interfaces, and this may be arisen from the comonomer contents in TerPP, which are 1-butene and ethylene having the same chemical structure as that of MCPE. The enhancement of the phase morphology in the TerPP-MCPE blend is correlated with the mechanical and morphological properties. Thus, although the four blend systems are phase separated, the phase morphology suggests that the order of interfacial adhesion strength be HDPE-MCPE > TerPP-MCPE > CoPP-MCPE > PP-MCPE and that micro-molecular structure between constituents be one of major factors giving enhanced interfacial adhesion.

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Microstructure and Properties of Mortar Containing Synthetic Resin using Image Analysis (이미지 분석을 활용한 합성수지 혼입 모르타르의 특성 및 미세구조 분석)

  • Lee, Binna;Min, Jiyoung;Lee, Jong-Suk;Lee, Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.28 no.1
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    • pp.59-65
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    • 2016
  • Commercial synthetic resins with great amount of hydrogen atoms were investigated for neutron shielding aggregates. Total three types of resins were considered in this study: high density polyethylene (HDPE), polypropylene (PP), and ultra molecular weight polyethylene (UPE). When these resins replaced 20, 40, 60 vol% of fine aggregates, mechanical properties were first evaluated including compressive and tensile strengths, and then image/microstructure analyses such as cross-section analysis, SEM, and X-ray CT were performed. The results showed that the compressive and tensile strengths decreased with the increase of replacement ratio of HDPE and PP, which was found through image analysis that it was closely related to the distribution of resins at the failure surface of test specimens. The strength reduction of UPE was quite small compared to HDPE and PP but it abruptly increased when the replacement level exceeded 60 vol%. The results of microstructure analyses indicated that the replacement level significantly affected the amount of air void so that it is critical to determine the reasonable amount of UPE to make cementitous materials for neutron shielding.

Effect of Packaging Method on the Quality of Strawberry, Tomato, and plum during Storage

  • Lee, Se-Hee;Lee, Myung-Suk;Lee, Yong-Woo;Sun, Nam-Kyu;Song, Kyung-Bin
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.187-187
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    • 2003
  • To examine the effect of packaging method on strawberry, tomato, and plum quality, the rate of weight loss, Hunter a value, decay rate, anthocyanin contents, and microbial (total bacterial counts, mold and yeast, and pseudomonas) changes were determined during storage. Strawberry was packaged with low density polyethylene (LDPE). Tomato and plum were packaged with high density polyethylene film (HDPE). Strawberries, tomatoes, and plums were then stored at 4$^{\circ}C$ and 20$^{\circ}C$, respectively. LDPE package was the most effective on the decrease of decay rate of strawberry and the rate of weight loss for packaged strawberry was lower than that of the non-packaged. HDPE package was the most effective on the rate of weight loss during storage of tomatoes and plums regardless of storage temperature. Hunter a value increased during storage. Anthocyanin contents of plums increased overall with increasing storage time, and plums stored without package were changed more than those with package. Microbial changes of strawberry, tomato, and plum stored at 4$^{\circ}C$ and 20$^{\circ}C$ were monitored during storage. Packaging method did not affect the microbial change, yet temperature did affect the microbial change significantly. These results indicate that storage of these commodities at 4$^{\circ}C$ should be recommended in terms ,of microbial safety as well as quality and shelf-life.

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Studies on the Development of Biodegradable Plastics and Their Safety and Degradability (생붕괴성 플라스틱 포장재의 제조 및 제조된 소재의 안전성과 분해성 연구)

  • You, Young-Sun;Han, Jung-gu;Lee, Han-na;Park, Su-il;Min, Sea-Cheol
    • Food Engineering Progress
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    • v.15 no.3
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    • pp.257-261
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    • 2011
  • Biodegradable plastics were developed using biodegradable pellets made of corn stalk and rice husk and their safety as food packages and their biodegradability against light (ultraviolet (UV)), heat, and fungi were evaluated. Four kinds of 50-${\mu}m$ biodegradable plastics were produced by extruding the mixtures of the biodegradable pellets, low-density polyethylene (LDPE), high-density polyethylene (HDPE), and linear low-density polyethylene (LLDPE) with different compositions. Developed biodegradable plastics were safe to be used as food packages. The initial tensile strength and percentage elongation of the plastics were similar to those of LDPE, but the values decreased with increased their exposure time to UV and heat. The fungal biodegradability of the biodegradable plastics was higher than that of LDPE. The biodegradability of the biodegradable plastics shows the potential for them to be used as sustainable food packages.

Comparison of Biomass Productivity of the Microalgae, Tetraselmis sp. KCTC12236BP, in Polyvinyl Chloride Marine Photobioreactor and High Density Polyethylene Marine Photobioreactor (폴리비닐클로라이드 해양광생물반응기와 고밀도 폴리에틸렌 해양광생물반응기에서 미세조류, Tetraselmis sp. KCTC12236BP의 생산성 비교)

  • Jung, Seung-Gyun;Kim, Su-Kwon;Bun, Moon-Sup;Cho, Yonghee;Shin, Dong-Woo;Kim, Z-Hun;Lim, Sang-Min;Lee, Choul-Gyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.8 no.1
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    • pp.18-23
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    • 2016
  • It is important to design photobioreactor by cheap material for economical microalgal biomass production. In this study, two types of marine photobioreactors (MPBR), made by either polyvinyl chloride (MPBR-PVC) or high density poly ethylene (MPBR-HDPE), are used and performance of these were compared. Tetraselmis sp. KCTC 12236BP is a green marine alga that isolated from Ganghwa Island, Korea, and the strain was used for marine cultivations using MPBR-PVC and MPBR-HDPE. The cultivations were performed three times in the spring season of 2012 using MPBR-PVC and of 2013 using MPBR-HDPE in the coastal area of Young Heung Island. As the results, MPBR-PVC shows higher biomass productivities than MPBR-HDPE, due to its high light transmittance. In the cultivations using MPBR-PVC, the average sea water temperature was $11.5^{\circ}C$ during the first experiment and $16.5^{\circ}C$ during the second and third experiments. Average light intensities during three times for experiments were 407.5, 268.1 and $273.0{\mu}{\cdot}E{\cdot}m^{-2}{\cdot}s^{-1}$, respectively. The maximum fresh cell weight and average biomass productivity were $1.2g{\cdot}L^{-1}$ and $0.12g{\cdot}L^{-1}{\cdot}day^{-1}$. These results showed that Tetraselmis sp. KCTC12236BP were adapted well with the environmental conditions from ocean, and grow in the MPBR-PVC and MPBR-HDPE.