• Title/Summary/Keyword: high vapor pressures

Search Result 53, Processing Time 0.025 seconds

Measurement of Equilibrium Moisture Content of Wood at High Temperatures and Vapor Pressures (고온고압에서의 목재 평형함수율 측정)

  • Lee, Weon-Hee;Abe, Hisashi;Kuroda, Naohiro
    • Journal of the Korean Wood Science and Technology
    • /
    • v.26 no.4
    • /
    • pp.1-5
    • /
    • 1998
  • In this study, it was examined the method to estimate equilibrium moisture content(EMC) at high vapor pressures and high temperatures above $100^{\circ}C$. The material used for the experiment was Sugi(Cryptomeria japonica). EMC was investigated at temperatures ranging from $100^{\circ}C$ to $160^{\circ}C$ and under saturated vapor pressures above 1 atm. The correlation between temperatures and vapor pressures have a good agreement with those observed by thermocouple and pressure gauge in the air state of autoclave, respectively. A sensitivity of quartz spring was 65mm/g. Moisture content(MC)s calculated from the quartz spring elongation by vapor sorption showed a good agreement with MCs by oven-dried method. Using this system, it was found that EMC at high vapor pressures and high temperatures above $100^{\circ}C$ were higher than EMC of wood in 1 atm pressure conditions. With this system, therefore, it was concluded that the EMCs of wood and wood-based materials at high temperatures were able to be evaluated.

  • PDF

Vaporization of Hydrocarbon Fuel Droplet in High Pressure Environments (고압 환경하에서 탄화수소 연료 액적의 기화특성 연구)

  • Kim, Sung-Yup;Yoon, Woong-Sup
    • Proceedings of the KSME Conference
    • /
    • 2003.11a
    • /
    • pp.127-132
    • /
    • 2003
  • A study of high-pressure n-heptane droplet vaporization is conducted with emphasis placed on equilibrium at vapor-liquid interface. General frame of previous rigorous model[1] is retained but tailored for flash equilibrium calculation of vapor-liquid interfacial thermodynamics. The model is based on complete time-dependent conservation equations with a full account of variable properties and vapor-liquid interfacial thermodynamics. The influences of high-pressure phenomena, including ambient gas solubility, thermodynamic non-ideality, and property variation on the droplet evaporation are investigated. The governing equations and associated moving interfacial boundary conditions are solved numerically using a implicit scheme with the preconditioning method and the dual time integration technique. And a parametric study of entire droplet vaporization history as a function of ambient pressure, temperature has been conducted. Some computational results are compared with Sato's experimental data for the validation of calculations. For low ambient temperatures, the droplet lifetime first increases with pressures, then decreases for high pressures. For higher ambient temperatures, the droplet lifetime increase with less amplitude than that of low ambient temperatures, which then decreases with more amplitude than that of low temperatures. The solubility of nitrogen can not be neglected in the high pressure and it becomes higher as the pressure goes up.

  • PDF

Measurement of Vapor Pressure of Molten ZnCl2 and FeCl2 by the Transpiration Method (유동법에 의한 용융 ZnCl2 및 FeCl2의 증기압 측정)

  • Lee, Woo-Sang;Kim, Won-Yong;Jung, Woo-Gwang
    • Korean Journal of Materials Research
    • /
    • v.20 no.3
    • /
    • pp.111-116
    • /
    • 2010
  • Chloride-based fluxes such as NaCl-KCl are used in the refining of Al melt. The vapor pressure of the chloride is one of the fundamental pieces of information required for such processes, and is generally high at elevated temperatures. In order to measure the vapor pressure for chlorides, the apparatus for the transpiration method was assembled in the present study. The vapor pressure of $ZnCl_2$ and $FeCl_2$, which is related with the process of aluminum refining and the recovery of useful elements from iron and steel industry by-products, was also measured. In the measurement of vapor pressure by the transpiration method, the powder of $ZnCl_2$ or $FeCl_2$ in a alumina boat was loaded in the uniform zone of the furnace with a stream of Ar. The weight loss of $ZnCl_2$ and $FeCl_2$ after holding was measured by changing the flow rate of Ar gas (10 sccm -230 sccm), and the partial pressures of $ZnCl_2$ and $FeCl_2$ were calculated. The partial pressures within a certain range were found to be independent of the flow rate of Ar at different temperatures. The vapor pressures were measured in the temperature range of 758-901K for $ZnCl_2$ and 963-983K for $FeCl_2$. The measured results agreed well with those in the literature.

Analyses of Thermodynamic Vaporization Behaviour and Voloxidaion Conditions for Metal Oxides (금속산화물의 열역학적 휘발 거동 및 휘발 산화 공정의 조건 분석)

  • Lee, Young Woo;Park, So Young;Park, Byung Heung
    • Journal of Institute of Convergence Technology
    • /
    • v.3 no.2
    • /
    • pp.7-10
    • /
    • 2013
  • Metal oxides are known as stable materials during a thermal treatment. However, some oxides are readily evaporated at high temperatures. A voloxidation process is a head-end process for a pyroprocessing dealing with spent nuclear fuels (SF). In SFs, fission productions are in the form of oxides and some of them would be evaporated during the voloxidation process. Therefore, it is of importance to analyse the vapor pressures of metal oxides so that the material flows throughout the pyroprocessing could be estimated. In this work, vapor pressures of relevant metal oxides were calculated and presented to draw a baseline on the material flow of the pyroprocessing.

  • PDF

Influence of Selenization Pressure on Properties of CIGS Absorber Layer Prepared by RF Sputtering

  • Jung, Sung Hee;Choi, Ji Hyun;Chung, Chee Won
    • Current Photovoltaic Research
    • /
    • v.4 no.3
    • /
    • pp.87-92
    • /
    • 2016
  • The effects of selenization pressure on the structural, optical and electrical properties of the CIGS thin films prepared by RF magnetron sputtering using a single quaternary target were investigated. At selenization pressures lower than atmospheric pressure, CIGS thin films formed non-stoichiometric compounds due to deficiencies of Se vapor. In contrast, when selenization process was conducted at above atmospheric pressure, the residence time of Se vapor inside the tube increased so that the Se element could be incorporated within vacant sites of the CIGS structure, resulting in the formation of stoichiometric CIGS thin films. High quality CIGS thin films could be obtained when the selenization process was performed at pressures greater than atmospheric and $550^{\circ}C$.

Characterization of Diamond-like Carbon Films Prepared by Magnetron Plasma Chemical Vapor Deposition

  • Soung Young Kim;Jai Sung Lee;Jin Seok Park
    • The Korean Journal of Ceramics
    • /
    • v.4 no.1
    • /
    • pp.20-24
    • /
    • 1998
  • Thin films of diamond-like carbon(DLC) can be successfully deposited by using a magnetron plasma chemical vapor deposition (CVD) method with an rf(13.56 MHz) plasma of $C_dH_8$. Plasma characteristics are analyzed as a function of the magnetic field. As the magnetic field increases, both electron temperature ($T_e$) and density ($n_e$)increase, but the negative dc self-bias voltage (-$V_{ab}$) decreases, irrespective of gas pressures in the range of 1~7 mTorr. High deposition rates have been obtained even at low gas pressures, which may be attributed to the increased mean free path of electrons in the magentron plasma. Effects of rf power and additive gas on the structural properties of DLC films aer also examined by using various technique namely, TED(transmissio electron diffraction) microanalysis, FTIR, and Raman spectroscopies.

  • PDF

Robust Design for Shape Parameters of High Pressure Thermal Vapor Compressor by Numerical Analysis (전산해석을 통한 고압열증기압축기 형상변수에 관한 강건 설계)

  • Park, Il-Seouk
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.32 no.12
    • /
    • pp.931-937
    • /
    • 2008
  • A high motive pressure thermal vapor compressor(TVC) for a commercial multi-effect desalination(MED) plant is designed to have a high entraining performance and its robustness is also considered in the respect of operating stability at the abrupt change of the operating pressures like the motive and suction steam pressure which can be easily fluctuated by the external disturbance. The TVC having a good entraining performance of more than entrainment ratio 6.0 is designed through the iterative CFD analysis for the various primary nozzle diameter, mixing tube diameter and mixing tube length. And then for a couple of TVC having a similar entrainment ratio, the changes of the entrainment ratio are checked along the motive and suction pressure change. The system stability is diagnosed through the analyzing the changing pattern of the entrainment ratio.

Development Behavior of Vaporizing Sprays from a High-Pressure Swirl Injector Using Exciplex Fluorescence Method

  • Choi, Dong-Seok;Kim, Duck-Jool;Hwang, Soon-Chul
    • Journal of Mechanical Science and Technology
    • /
    • v.14 no.10
    • /
    • pp.1143-1150
    • /
    • 2000
  • The effects of ambient conditions on vaporizing sprays from a high-pressure swirl injector were investigated by an exciplex fluorescence method. Dopants used were 2% fluorobenzene and 9% DEMA (diethyl-methyl-amine) in 89% solution of hexane by volume. In order to examine the behavior of liquid and vapor phases inside of vaporizing sprays, ambient temperatures and pressures similar to engine atmospheres were set. It was found that the ambient pressure had a significant effect on the axial growth of spray, while ambient temperature had a great influence on the radial growth. The spatial distribution of vapor phase at temperatures above 473K became wider than that of liquid phase after half of injection duration. From the analysis of the area ratio for each phase, the middle part (region II) in the divided region was the region which liquid and vapor phases intersect. For liquid phase, fluorescence-intensity ratio was greatly changed at lms after the start of injection. However, the ratio of vapor phase was nearly uniform in each divided region throughout the injection.

  • PDF

Characteristics of Spray Development from Vapor/Liquid Phase Distribution for GDI Spray (GDI 분무의 기.액상 분포를 통한 분무의 성장 특성)

  • 황순철;최동석;김덕줄
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.9 no.2
    • /
    • pp.50-58
    • /
    • 2001
  • The purpose of this research is to obtain the information of the development process of a vaporizing GDI spray using exciplex fluorecence method. Fluorobenzene/DEMA system was used as the exciplex-forming dopants. The 2-D spray images of liquid and vapor phases were acquired, and the behavior of both phases was analyzed by the image processing. The experiment was performed at the three different ambient perssures and the ambient temperature of 273K and 473K. As the result of this work, it was found that the development characteristics of GDI spray have stronger effect on the ambient pressure than on the ambient temperature. With an increase of ambient pressure, the distribution of vapor phase was decreased and the concentration of that was denser. Two regions, namely cone and mixing regions could be identified from those resulrs.

  • PDF

Breakdown Characteristics of Liquid Nitrogen in the Environment to Restrain Vapor Bubbles (비등 기포를 억제한 환경에서 액체 질소의 절연파괴 특성)

  • 백승명;정종만;김영석;곽동순;한철수;김상현
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
    • /
    • 2003.02a
    • /
    • pp.228-231
    • /
    • 2003
  • Experimental investigations of AC breakdown characteristics of liquid nitrogen in the environment to restrain boil bubbles are presented in this paper. The environment to restrain vapor bubble in the liquid nitrogen is both increasing pressure and decreasing temperature. Measurements of the breakdown voltage of liquid nitrogen in the environment to restrain vapor bubbles are investigated under AC high voltage in a quasi-uniform and non-uniform electrical field for pressures and temperatures ranging from 0 to 0.5 MPa and 77 K to 65 K respectively.

  • PDF