• Title/Summary/Keyword: high temperature retention time

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Retention Behaviors of Natural Gas Components on a Single Column by Gas Chromatography (기체 크로마토그래피에 의한 단일 컬럼상에서 천연가스 성분의 머무름 거동)

  • Choi, Yong-Wook;Choe, Kun-Hyung;Lee, Dai-Woon
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.329-338
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    • 1994
  • The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.

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A Study on the Effect of the Rhizobacterium, Bacillus sp. SH1RP8 and Potassium Family Polymers on the Crop Growth under Saline (염 환경 하에서 Bacillus sp. SH1RP8와 Polyacrylate Polymers가 작물 생장에 미치는 영향에 관한 연구)

  • Hong, Sun Hwa;Kim, Ji Seul;Park, Jang Woo;Lee, Eun Young
    • KSBB Journal
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    • v.30 no.3
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    • pp.97-102
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    • 2015
  • This study aimed to evaluate the potential plantgrowth promoting effects of potassium polyacrylate, a superabsorbent polymer, and Bacillus sp. SH1RP8, a family of plant-growth-promoting bacteria. Potassium polyacrylate was selected as the polymer for use due to its high molecular weight and its ability to retain and continuously supply moisture. Plant-growth-promoting rhizobacteria (PGPR) were isolated from the soil and applied to plants growing in dry environments, such as saline conditions. The moisture absorption and retention abilities of potassium polyacrylate were evaluated at a high temperature ($50^{\circ}C$) and in a dry condition, during which time the polymer showed a water retention potential of 19606.07% after 29 days. To overcome the reaming problem in the soil environment, natural polymers (such as cellulose) were mixed with the potassium acrylate. The shoot growths of Peucedanum japonicum Thunb and Arundo donax were significantly enhanced when treated with the mixture of the isolated rhizosphere bacterium SH1RP8 and potassium polyacrylate (63.5 and 124.3%, respectively).

Effect of Cooling Rate and Temperature on Intercritical Annealing of Medium-Carbon Cr-Mo Alloy for High Strength Cold Heading Quality Wire Rod (고강도 냉간압조용 중탄소 Cr-Mo 합금강의 임계간 어닐링시 냉각속도 및 온도의 영향)

  • JongHyeok Lee;ByoungLok Jang
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.4
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    • pp.230-236
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    • 2023
  • The current study deals with the effect of cooling rate and temperature for annealing on medium-carbon Cr-Mo alloy steel, especially for cold heading quality wire rod, to derive the optimum micro-structures for plastic deformation. This is to optimize the spheroidization heat treatment conditions for softening the material. Heat treatment was performed under seven different conditions at a temperature between Ac1 and Ac3, mostly within 720℃ to 760℃, and the main variables at this time were temperature, retention time and cooling rate. Microstructure and phase changes were observed for each test condition, and it was confirmed that they were greatly affected by the cooling rate. It was also confirmed that the cooling rate was changed in the range of 0.1℃/min to 5℃/min and affected by phase deformation and spheroidization fraction. The larger the spheroidization fraction, the lower the hardness, which is associated with the increasing connection of ferrite phases.

Evaluation of Nitritation of High Strength Ammonia with Variation of SRT and Temperature using Piggery Wastewater (SRT와 온도 변화를 통한 돈사폐수 내 고농도 암모니아의 아질산화 평가)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Korean Society on Water Environment
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    • v.27 no.5
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    • pp.563-571
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    • 2011
  • The purpose of this study is to investigate the high strength ammonia oxidation of piggery wastewater. Laboratory scale reactors was operated using influent of piggery wastewater and effluent of anaerobic digester from piggery wastewater at $35^{\circ}C$ and $20^{\circ}C$. Results of various operating conditions were compared and analyzed. After analyzing the results, effluent of anaerobic digester from piggery wastewater required shorter Solid retention time (SRT) than influent of piggery wastewater. In terms of the temperature, stable ammonia removal and denitrification was achieved on the both of the condition. At the temperature of $35^{\circ}C$, nitrite conversion rate was better than $20^{\circ}C$. It can be concluded that treating the piggery wastewater using anaerobic digester on the condition of the temperature at $35^{\circ}C$ is more efficient on the nitritation of the piggery wastewater.

Kinetic Study of the Anaerobic Digestion of Swine Manure at Mesophilic Temperature: A Lab Scale Batch Operation

  • Kafle, Gopi Krishna;Kim, Sang-Hun
    • Journal of Biosystems Engineering
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    • v.37 no.4
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    • pp.233-244
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    • 2012
  • Purpose: The kinetic evaluation was performed for swine manure (SM) degradation and biogas generation. Methods: The SM was anaerobically digested using batch digesters at feed to inoculum ratio (F/I) of 1.0 under mesophilic conditions ($36.5^{\circ}C$). The specific gas yield was expressed in terms of gram total chemical oxygen demand (mL/g TCOD added) and gram volatile solids added (mL/g VS added) and their effectiveness was discussed. The biogas and methane production were predicted using first order kinetic model and the modified Gompertz model. The critical hydraulic retention time for biomass washout was determined using Chen and Hashimoto model. Results: The biogas and methane yield from SM was 346 and 274 mL/ TCOD added, respectively after 100 days of digestion. The average methane content in the biogas produced from SM was 79% and $H_2S$ concentration was in the range of 3000-4108 ppm. It took around 32-47 days for 80-90% of biogas recovery and the TCOD removal from SM was calculated to be 85%. When the specific biogas and methane yield from SM (with very high TVFA concentration) was expressed in terms of oven dried volatile solids (VS) basis, the gas yield was found to be over estimated. The difference in the measured and predicted gas yield was in the range of 1.2-1.5% when using first order kinetic model and 0.1% when using modified Gompertz model. The effective time for biogas production ($T_{Ef}$) from SM was calculated to be in the range of 30-45 days and the critical hydraulic retention time ($HRT_{Critical}$) for biomass wash out was found to be 9.5 days. Conclusions: The modified Gompertz model could be better in predicting biogas and methane production from SM. The HRT greater than 10 days is recommended for continuous digesters using SM as feedstock.

Concentration of Persimmon Juice by Revers Osmosis System (역삼투 시스템을 이용한 감 과즙의 농축)

  • Kang, Hyun-Ah;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.279-283
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    • 1997
  • Membrane separation technology was applied to prepare high quality persimmon juice from persimmon, which is produced in large quantities in Korea. The influences of time, pressure, and temperature on permeate flux were studied during concentration by reverse osmosis. The chemical components of retentate were also analyzed. The permeate flux was higher as the operating temperature and pressure were increased, and was influenced more strongly by operating pressure than temperature. Maximum concentration by reverse osmosis employed in this study in the oBrix scale was about 30. Retention percentage of sugar in the persimmon juice which was concentrated by membrane separation system was more than 90% and was not influenced by operating conditions. Retention percentage of volatile components in the same process was more than 60%; it was increased as operating temperature was decreased and pressure was increased.

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The beating effect of high crystalized nonwood fibers treated with low-molecular weighted waste celulase in the papermaking processes (Cellulase생산공정중 발생되는 저분자량 분포도의 폐효소류 처리가 고결정화된 배목재 섬유소의 고해에 미치는 영향)

  • 김병현;신종순;강영립;박병권;이성구
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.121-139
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    • 2000
  • This study is to test the possibility of applying the low-molecular weighted waste cellulase, which is produced in the process of cellulase production, to paper making. After experimenting on high-crystallized non-wood fibers with beating catalyst. I got the result that the condition for the optimal effect is temperature 40~6$0^{\circ}C$, the time 90min to 120min, pH 5.0 to 6.0, the enzyme contents 0.3% and that the effect of beating such as slight reduction of fiver viscosity, increase of water retention value(WRV) and shortening of fiber length was increased with waste cellulase. Through this process, the density, folding endurance, tensile strength and burst strength of paper was remarkably increased, which is inferred to result from the increased flexibility of fiber by individual characteristics of non-wood fiber, which was high-crystallized by penetrated low-molecular weight cellulases in the fiber.

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Effect of Digestion Temperature on the Solid-Liquid Separation Characteristics of Anaerobically Digested Municipal Sewage Sludge (도시하수슬러지의 혐기성소화시 고액분리 특성에 미치는 소화온도의 영향)

  • Han, Jang Woon;Chang, Duk;Kim, Sung Soon
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.1
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    • pp.1-8
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    • 1994
  • Laboratory experiments were conducted to investigate the effect of digestion temperature on the settleability and dewaterability of anaerobically digested sludge. The digesters were operated at a hydraulic retention time of 20 days with a loading rate of 0.63~0.66kg volatile solids per cubic meter per day at the temperature of $35^{\circ}C$ and $55^{\circ}C$. A mixed primary and secondary municipal sludge was used as a feed. The interface height of the sludge during settling test was recorded to identify settleability. As a measure of dewaterability of the sludge, specific resistance and capillary suction time were also measured with and without chemical conditioning. Higher digestion efficiency was obtained at $55^{\circ}C$ than $35^{\circ}C$. However, the settleability and dewaterability of the sludge at $35^{\circ}C$ were quite higher than those of the sludge digested at $55^{\circ}C$. The optimum dosages of ferric chloride for sludge conditioning were 0.4% and 0.6% at $35^{\circ}C$ and $55^{\circ}C$, respectively. The filtrate COD of the sludge digested at $55^{\circ}C$ was higher than at $35^{\circ}C$, which means that poor dewaterability of the sludge result in high filtrate COD.

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DEVELOPMENT OF ELECTROREFINER WASTE SALT DISPOSAL PROCESS FOR THE EBR- II SPENT FUEL TREATMENT PROJECT

  • Simpson, Michael F.;Sachdev, Prateek
    • Nuclear Engineering and Technology
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    • v.40 no.3
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    • pp.175-182
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    • 2008
  • The results of process development for the blending of waste salt from the electrorefining of spent fuel with zeolite-A are presented. This blending is a key step in the ceramic waste process being used for treatment of EBR-II spent fuel and is accomplished using a high-temperature v-blender. A labscale system was used with non-radioactive surrogate salts to determine optimal particle size distributions and time at temperature. An engineering-scale system was then installed in the Hot Fuel Examination Facility hot cell and used to demonstrate blending of actual electrorefiner salt with zeolite. In those tests, it was shown that the results are still favorable with actinide-loaded salt and that batch size of this v-blender could be increased to a level consistent with efficient production operations for EBR-II spent fuel treatment. One technical challenge that remains for this technology is to mitigate the problem of material retention in the v-blender due to formation of caked patches of salt/zeolite on the inner v-blender walls.

Effect of Air Temperature Changes on Water Temperature and Hysteresis Phenomenon in Lake Paldang (기온 변화에 따른 팔당호 수온 영향 및 이력현상)

  • Yu, Soonju;Im, Jongkwon;Lee, Bomi
    • Journal of Environmental Impact Assessment
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    • v.29 no.5
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    • pp.323-337
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    • 2020
  • Long-term continuous data were used to investigate changes in air and water temperature and temperature hysteresis at Lake Paldang, the largest source of drinking water in South Korea. Based on the temperatures at Yangpyeong, near Lake Paldang, using a seasonal Mann-Kendall test, the rate of change of increase in temperature over the last 27 years (0.060℃/yr, 1993-2019) was higher than that of during 47 years (0.048℃/yr, 1973-2019). The air and water temperatures in Lake Paldang and its influent rivers had a high correlation (R > 0.9, p < 0.005); however, the water temperature increased at rate slower than the river water temperature, and the water temperature decreased slowly as the air temperature fell. The depth-averaged water temperature also changed more slowly than the surface water of the lake both when the air temperature was high and when it was low. This is likely because the lake has a larger area and a longer heat retention time than rivers, resulting in a greater hysteresis of water temperature at lake.