• 제목/요약/키워드: high temperature degradation

검색결과 862건 처리시간 0.028초

시베리아산 전나무 바이오매스의 열분해-액화반응 (Pyrolysis-Liquefaction of a Siberian Spruce Biomass)

  • 윤성욱
    • 한국수소및신에너지학회논문집
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    • 제19권5호
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    • pp.430-438
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    • 2008
  • Siberian spruce, found in the northern temperature and boreal regions of the earth, is usable biomass as fuels. In this study, parameters of thermochemical degradation by pyrolysis-liquefaction reaction of siberian spruce such as the effect of reaction temperature, reaction time and degradation products and energy yields were investigated. The liquid products from pyrolysis-liquefaction of siberian spruce contained various kinds of cyclicketones, cresols, dimethyl phenols and benzenediols. Combustion heating value of liquid products from pyrolysis-liquefaction conversion processes was in the range of $7,650{\sim}7,800cal/g$. The energy yield in pyrolysis-liquefaction of siberian spruce was as high as 69.5% after 40min of reaction at $400^{\circ}C$. The liquid products from the thermochemical conversion of siberian spruce could be used as high octane value fuels and fuel additives.

전기화학적 분극특성을 이용한 2.25Cr-lMo 강의 열화도 평가 (The Evaluation of 2-25Cr-lMo Steels Degradation by the Electrochemical Polarization Method)

  • 김지수;현양기;이재도;오세규
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2001년도 춘계학술대회 논문집
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    • pp.314-319
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    • 2001
  • Most parts of facilities in domestic petroleum plants and power plants are needed to be abandoned, repaired or replaced, because in Korea they were built in the 1960s and, they have been used under severe conditions and exposed corrosive environments. 2.25Cr- lMo steels have excellent high-temperature mechanical properties. Therefore, the material have been widely used as heat exchanger tubes, boiler headers and its tubes in such industries. But, those microstructural evolutions in high temperature such as precipitation and carbide coarsening give a reason to degrade the material. Especially, in case of this material, carbides induced embrittlement(CIE) is the primary reason for degrading mechanical properties at over 50$0^{\circ}C$. In this paper, we introduce a electrochemical polarization method for detecting CIE quantitatively.

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STS 304 강의 기계적 특성에 미치는 고온 열화 시간의 영향 (Effect of High Temperature Aging Time on Mechanical Characteristics Degradation of STS 304 Steel)

  • 정광후;김성종
    • 한국표면공학회지
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    • 제50권5호
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    • pp.380-385
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    • 2017
  • Mechanical characteristics of the STS 304 which is heat resistance steel were investigated after artificial aging at $650^{\circ}C$ with 1,000 hours. Tensile test specimens and small test pieces were done artificial aging up to 1,000 hours in the high temperature atmospheric environment. The results present that as the aging time increased, tensile properties were deteriorated. In the case of failure mechanism, the configuration of the fractography presented drastic change from ductile to brittle with aging time. $M_{23}C_6$ carbide leading to the change of the mechanical properties and fracture mode of the aged STS 304 steel continuously precipitated along the grain boundaries of austenite microstructure.

자외선 조사된 HTV 실리콘 고무의 표면열화 분석 (Analysis of the Surface Degradation in UV-irradiated High-Temperature Vulcanized Silicone Rubber)

  • 연복희;이태호;허창수;이종한
    • 한국전기전자재료학회논문지
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    • 제13권5호
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    • pp.411-419
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    • 2000
  • In this paper we have investigated the surface degradation by ultraviolet-irradiation in high-temperature vulcanized silicone rubber. Through the measurement of surface potential decay by corona-charging and of contact angle it is found that the change of surface electrostatic properties and the decrease of contact angle under UV-radiation. For the changes in micro-morphological and chemical structure of the UV-treated silicone rubber we utilized several analytical techniques such as SEM, ATR-FTIR,XPS. From this study it is shown that the chemical reactions(scissoring of side chain(S-$CH_3$) cross-linking and branching) occur on the surface of silicone rubber during the UV-irradiation. Also we obtained the results of the loss of low molecular weight chain by cross-linking and oxidation reaction.

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사용 환경조건에 따른 Epoxy/Glass Fiber 복합재료의 표면특성 (Surface properties of epoxy/glass Eber composites by environmental conditions)

  • 임경범;이백수;황명환;김윤선;유도현;이덕출
    • 한국진공학회지
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    • 제9권3호
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    • pp.279-284
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    • 2000
  • 본 연구는 옥외용 epoxy/glass fiber의 열화과정을 분석하기 위하여 FRP 적층판을 고온과 수에 노출시켰다. 열화과정은 접촉각, 표면전위감쇠, 표면저항률의 비교에 의해 평가하였다. 젖음성의 변화는 열처리 시료에서 $200^{\circ}C$까지 접촉각이 증가하였지만 수분처리 시료는 감소하였다. 표면전위감쇠 특성은 수분처리 시료에서는 감소하지만, 열처리 시료는 미 처리와 비교해서 증가하였다. 또한, 표면저항률은 접촉각의 변화와 같은 경향을 보이고 있다.

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SCC 분위기 하에서 장시간 인공열화된 304 스테인리스강 용접부의 파괴인성($J_{IC}$)평가 (Evaluation of Fracture Toughness($J_{IC}$) on 304 Stainless Steel Weldments Artificially Degraded under SCC Environment)

  • 김성우;배동호;조선영;김철한
    • Journal of Welding and Joining
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    • 제17권2호
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    • pp.76-83
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    • 1999
  • Fracture toughness({TEX}$J_{IC}${/TEX}) on 304 austenitic stainless steel weldments artificially degraded for long period under SCC environments were evaluated to investigate its reliability and environmental characteristics. Electro-chemical polarization tests were previously carried out to evaluate corrosion susceptiblility of weldment, and stress corrosion cracking was tested under various conditions of 3.5wt.% NaCl solution, the temperature of $25^{\circ}$C and $95^{\circ}$C, and oxygen concentration during 3000hours. From the results obtained, it was found that 304 stainless steel weldment was so susceptible under high temperature and high oxygen concentration of 3.5wt.% NaCl solution, and fracture toughness({TEX}$J_{IC}${/TEX}) was also considerably reduced by material degradation.

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고온초전도체의 DC 전압 - 전류 특성 (DC Voltage-Current Characteristics of a High Temperature Superconducting Conductor)

  • 류경우;이주영;마용호;최병주;박권배;오일성
    • 한국초전도ㆍ저온공학회논문지
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    • 제8권3호
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    • pp.49-53
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    • 2006
  • A high temperature superconductor (HTS) has been developed for power applications such as power cables, fault current limiters and superconducting magnetic energy storage devices. For such applications it is required to understand the DC voltage-current characteristic of the HTS. which is important in analyzing AC loss and flux flow loss quantitatively. In this work, we have experimentally investigated influence of several factors, e.g. critical current density. degradation and AC external magnetic field, on the DC voltage-current characteristic. The measured results have been discussed in engineering application point of view.

LaNi5의 intrinsic degradation 거동에 관한 연구 (A Study on the Intrinsic Degradation Behavior of LaNi5)

  • 안효준;이재영
    • 한국수소및신에너지학회논문집
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    • 제2권1호
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    • pp.77-82
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    • 1990
  • To investigate the effect of strains heat effect and thermal energy on the intrinsic degradation of $LaNi_5$, the changes of P-C-Isotherm curves under the condition of mainly applied one of the above factors were investigated. The revesible hydrogen storage capacity decreased by means of the hydrogenation at high temperature without cyclings or pressure induced cyclings with low thermal energy. The degree of degradation was more severe as the heat of hydrogenation reaction increased. Thus the intrinsic degradation of $LaNi_5$ depended upon lattice strain as well as thermal energy.

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등온열처리법에 의해 모의 열화된 1Cr-1Mo-0.25V 터빈케이싱 강의 재질열화 평가 (Evaluation of Material Degradation of 1Cr-1Mo-0.25V Turbine Casing Steel Aged Artificially by Isothermal Heat Treatment)

  • 마영화;김도형;윤기봉
    • 한국안전학회지
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    • 제25권1호
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    • pp.22-26
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    • 2010
  • Material degradation should be considered to assess integrity and residual life of high temperature equipments. However, the property data reflecting degradation are not sufficient for practical use. In this study, mechanical properties of 1Cr-1Mo-0.25V casting steel generally used for turbine casing were measured and variation of microstructure was observed. Degradation was simulated by isothermal heat treatment.

1Cr-1Mo-0.25V 강의 열화거동에 관한 연구 (A Study on Degradation Behavior of 1Cr-1Mo-0.25V Steel)

  • 석창성;구재민;김동중;안하늘;박은수
    • 한국안전학회지
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    • 제15권4호
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    • pp.8-14
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    • 2000
  • The remaining life estimation for the aged components in power plants as well as chemical plants are very important because mechanical properties of the components are degraded with time of service exposure in the high temperature. Since it is difficult to take specimens from the operating components to evaluate mechanical properties of components, accelerated aging technique are needed to estimate and analyse the material degradation. In the this study, test materials with 4 different degradation levels were prepared by isothermal aging heat treatment at $630^{\circ}C$. And tensile test, $k_{IC}$ test, hardness test and Scanning Electron Microscope analysis were performed in order to evaluate the degradation of 1Cr-1Mo-0.25V steels.

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