• 제목/요약/키워드: high pressure $CO_2$ processing

검색결과 47건 처리시간 0.025초

유기용제 함침법을 통한 알루미늄 다이캐스팅의 미세결함 및 기밀성 평가 (Evaluation of Micro-defects and Air Tightness of Al Die-casting by Impregnation of Organic Solvent)

  • 이진욱;조창현;김성계;고영건;김동주
    • 한국주조공학회지
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    • 제42권4호
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    • pp.218-225
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    • 2022
  • 본 연구에서는 고압 다이캐스팅 (High pressure die-casting, HPDC)을 통해 알루미늄 합금 (상업코드: ALDC12종)으로 수소 자동차용 부품 (Air pressure control valve housing, APCVH)을 제조하였으며 주조품의 기밀성을 향상시키기 위해 유기 함침액을 개발하였다. 개발된 2종류의 유기 함침액 (INNO-series, 한국)과 상용 합침액 (P601, 일본)을 사용하여 함침공정 조건 및 후 처리에 따른 미세결함과 기밀성을 비교 평가하였다. 컴퓨터 단층촬영 및 3차원 X-선 현미경 분석을 통해 함침된 알루미늄 주조품의 결함제어 및 성능 개선을 확인하였다. 또한, 함침 공정 후 기밀성 시험에서 INNO-01이 함침된 시료의 경우 성능 개선율이 70%인 것으로 확인하였다. 따라서, 개발된 유기 함침액은 상용 가능하며 다이캐스팅 제품의 기밀성 향상에 도움이 될 것으로 판단된다.

초임계 CO2를 이용한 Saw palmitto로부터 전립선 비대 유효 성분의 추출 조건 (Process conditions of valuable compound for benign prostatic hyperplasia(BPH) from saw palmitto by supercritical CO2)

  • 류병호;조경자
    • 생명과학회지
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    • 제13권5호
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    • pp.569-575
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    • 2003
  • 초임계 이산화탄소를 이용하여 saw palmitto로부터 전립선 비대증 치료를 위한 유효성분을 효율적으로 추출하기 위하여 초임계 유체의 압력(22, 30 Mpa), 온도 $(35^{\circ}C,\; 60^<\circ}C)$, 및 보조용매의 농도, 및 추출시간에 다른 효율을 조사하였다. 보조 용매로는 메탄올보다는 에탄올이 효과적이었고. 보조용매의 농도가 증가할수록 유효성의 추출 효율은 증가하였고 15% 에탄올 농도에서 효율이 가장 높았다. 15%에탄올 농도에서 초임계유체의 최적 추출조건은 압력은 30 Mpa, 온도는$60^<\circ}C$이였고, 추출시간에 따른 추출효율은 추출시간이 증가할수록 완만하게 증가하는 경향을 나타내었다. 초임계 이산화탄소의 추출조건으로 saw palmitto로부터 전립선 비대 치료를 위한 유효물질을 추출할 수 있다.

A Study on Touchless Panel based Interactive Contents Service using IrDA Matrix

  • Lee, Minwoo;Lee, Dongwoo;Kim, Daehyeon;Ann, Myungsuk;Lee, Junghoon;Lee, Seungyoun;Cho, Juphil;Shin, Jaekwon;Cha, Jaesang
    • International Journal of Internet, Broadcasting and Communication
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    • 제7권2호
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    • pp.73-78
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    • 2015
  • Touch panel is mainly applied to pressure type touch panel but it occur a low recognition rate and error during long-term use. So, it is partly applied to capacitive touch panel to compensate for these problems but it also can occur a same problems via pollutions. Touch technology has developed a various method but it is not used because of high costs and difficult installation process. So, in this paper, we proposed an input method of touchless panel using IrDA matrix. This method is conducted using an IrDA Matrix composed of depth sensor. It is possible to offer a various contents for multi user. The proposed technology need a development of a high sensitivity sensing method and high-speed processing method of position information for Seamless operation control. And, it is required high-precision drive technology. Also, we proposed a Seamless user recognition for interactive contents service through a touchless panel using IrDA matrix.

A7003 알루미늄 합금 압출공정의 MLCA 산정기술 (Material Life Cycle Assessment of Extrusion Process of A7003)

  • 조형호;조훈;김병민;김영직
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2002년도 제5회 압출 및 인발가공 심포지엄
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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방전플라즈마 소결 공정을 이용한 WC-Co-Mo2C 소재의 기계적 특성평가 (Mechanical Property Evaluation of WC-Co-Mo2C Hard Materials by a Spark Plasma Sintering Process)

  • 김주훈;박현국
    • 한국재료학회지
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    • 제31권7호
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    • pp.392-396
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    • 2021
  • Expensive PCBN or ceramic cutting tools are used for processing of difficult-to-cut materials such as Ti and Ni alloy materials. These tools have the problem of breaking easily due to their high hardness but low fracture toughness. To solve these problems, cutting tools that form various coating layers are used in low-cost WC-Co hard material tools, and research on various tool materials is being conducted. In this study, binderless-WC, WC-6 wt%Co, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are densified using horizontal ball milled WC-Co, WC-Co-Mo2C powders, and spark plasma sintering process (SPS process). Each SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are almost completely dense, with relative density of up to 99.5 % after the simultaneous application of pressure of 60 MPa and almost no significant change in grain size. The average grain sizes of WC for Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are about 0.37, 0.6, 0.54, and 0.43 ㎛, respectively. Mechanical properties, microstructure, and phase analysis of SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are investigated.

레이저 빔의 흡수 액체 내 침투에 의해 생성된 키홀 구조와 안정성 (Keyhole-structure and Stability in Laser-beam Penetration Into an Absorbing Liquid (Water))

  • 김동식;장덕석
    • 한국레이저가공학회지
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    • 제4권2호
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    • pp.13-19
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    • 2001
  • When a high-power laser beam is irradiated on the surface of material, it is well known that a cavity, called a keyhole induced by the pressure action of the vapor plume, is generated in the molten material. This paper describes the interaction between a pulsed CO$_2$ laser beam and water. The laser-beam is used to generate and maintain a conical depression in the water surface similar to the keyhole created during laser penetration welding. Experimental results show that the depth of laser-beam penetration is limited by hydrodynamic instability. The instability of the surface cavity can be understood by the capillary instability of a hollow jet. Theoretical computation of the steady keyhole shape has been performed. modifying the model suggested by Andrews et al. (1976). The model predicts the qualitative behavior of the keyhole but significantly underestimates the average diameter.

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1-(2-methoxyethyl)-3-methylimidazolium Methanesulfonate 이온성 액체 합성 및 CO2 흡수 특성 연구 (Study of CO2 Absorption Characteristic and Synthesis of 1-(2-methoxyethyl)-3-methylimidazoLium Methanesulfonate Ionic Liquid)

  • 진유란;정윤호;박소진;백일현
    • Korean Chemical Engineering Research
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    • 제50권1호
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    • pp.35-40
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    • 2012
  • 본 연구에서는 화석 연료 사용시 발생되는 이산화탄소를 분리할 수 있는 신 흡수제로써 활용 가능성을 파악하기 위하여, sulfonate계 이온성 액체인 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate 흡수제에 대하여 합성하고, 성상 분석 및 이산화탄소 흡수능을 측정하였다. 1단 방법을 이용하여 저렴하게 이온성 액체를 합성하였다. 합성된 시료의 열적, 화학적 안정성을 DSC 및 TGA를 사용하여 측정하였으며, 화학적 구조는 $^1H$-NMR spectrum으로 확인하였다. 또한, 가변부피투시창(Variable-volume view cell)이 장착된 고압용 상평형 장치를 사용하여 $CO_2$ 흡수능을 평가하였다. 실험 조건은 30, 50, $70^{\circ}C$ 온도에서 수행하였고, 압력 195 bar까지 측정하였다. 실험결과 압력이 증가하거나 온도가 감소할 때 $CO_2$ 흡수량이 증가하였으며, $30^{\circ}C$, 13 bar에서 27.6 $CO_2/IL$(g/kg)의 $CO_2$ 흡수능을 보였다.

Microstructure analysis of pressure resistance seal welding joint of zirconium alloy tube-plug structure

  • Gang Feng;Jian Lin;Shuai Yang;Boxuan Zhang;Jiangang Wang;Jia Yang;Zhongfeng Xu;Yongping Lei
    • Nuclear Engineering and Technology
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    • 제55권11호
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    • pp.4066-4076
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    • 2023
  • Pressure resistance welding is usually used to seal the connection between the cladding tube and the end plug made of zirconium alloy. The seal welded joint has a direct effect on the service performance of the fuel rod cladding structure. In this paper, the pressure resistance welded joints of zirconium alloy tube-plug structure were obtained by thermal-mechanical simulation experiments. The microstructure and microhardness of the joints were both analyzed. The effect of processing parameters on the microstructure was studied in detail. The results showed that there was no β-Zr phase observed in the joint, and no obvious element segregation. There were different types of Widmanstätten structure in the thermo-mechanically affected zone (TMAZ) and heat affected zone (HAZ) of the cladding tube and the end plug joint because of the low cooling rate. Some part of the grains in the joint grew up due to overheating. Its size was about 2.8 times that of the base metal grains. Due to the high dislocation density and texture evolution, the microhardnesses of TMAZ and HAZ were both significantly higher than that of the base metal, and the microhardness of the TMAZ was the highest. With the increasing of welding temperature, the proportion of recrystallization in TMAZ decreased, which was caused by the increasing of strain rate and dislocation annihilation.

가교도와 공정 조건에 따른 폴리프로필렌 발포체 구조 변화 (Structural Development of Polypropylene Foam by Crosslinking and Processing Conditions)

  • 황대영;한갑동;홍다윗;이규일;이기윤
    • 폴리머
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    • 제24권4호
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    • pp.529-537
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    • 2000
  • 본 연구에서는 압출된 PP sheets를 각기 다른 조사량으로 조사 가교시켜, 겔 분율 차이에 따른 세 종류의 샘플을 만든 다음, 회분식 공정을 통해 초임계 유체 (supercritical fluid) 상태의 $CO_2$를 발포제로 사용하여 발포시켰다. 이때, 겔 분율의 차이 및 고압 반응기 내에서 충진 압력과 충진 시간이 셀 구조에 미치는 영향을 관찰하였다. 다음으로, 발포조건에 따른 셀 구조 변화를 알아보기 위해 발포온도와 발포시간을 변화시키면서 실험하였다. 고분자 샘플 내로 침투한 가스의 양은 겔 분율의 차이에 의한 변화가 거의 없었으며, 충진 압력이 2000 psi 이상일 경우 충진 압력의 영향에도 큰 영향을 받지 않았다. 겔 분율이 낮은 샘플은 발포온도나, 발포시간이 증가함에 따라 셀 크기가 불균일하게 증가하였으나, 겔 분율이 높은 샘플은 높은 발포온도와 발포시간에서도 균일하게 셀 크기를 유지하며 안정한 구조를 나타내었다.

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Stereospecific anticancer effects of ginsenoside Rg3 epimers isolated from heat-processed American ginseng on human gastric cancer cell

  • Park, Eun-Hwa;Kim, Young-Joo;Yamabe, Noriko;Park, Soon-Hye;Kim, Ho-Kyong;Jang, Hyuk-Jai;Kim, Ji Hoon;Cheon, Gab Jin;Ham, Jungyeob;Kang, Ki Sung
    • Journal of Ginseng Research
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    • 제38권1호
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    • pp.22-27
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    • 2014
  • Background: Research has been conducted with regard to the development of methods for improving the pharmaceutical effect of ginseng by conversion of ginsenosides, which are the major active components of ginseng, via high temperature or high-pressure processing. Methods: The present study sought to investigate the anticancer effect of heat-processed American ginseng (HAG) in human gastric cancer AGS cells with a focus on assessing the role of apoptosis as an important mechanistic element in its anticancer actions. Results and Conclusion: HAG significantly reduced the cancer cell proliferation, and the contents of ginsenosides Rb1 and Re were markedly decreased, whereas the peaks of less-polar ginsenosides [20(S,R)-Rg3, Rk1, and Rg5] were newly detected. Based on the activity-guided fractionation of HAG, ginsenoside 20(S)-Rg3 played a key role in inducing apoptosis in human gastric cancer AGS cells, and it was generated mainly from ginsenoside Rb1. Ginsenoside 20(S)-Rg3 induced apoptosis through activation of caspase-3, caspase-8, and caspase-9, as well as regulation of Bcl-2 and Bax expression. Taken together, these findings suggest that heat-processing serves as an increase in the antitumor activity of American ginseng in AGS cells, and ginsenoside 20(S)-Rg3, the active component produced by heat-processing, induces the activation of caspase-3, caspase-8, and caspase-9, which contributes to the apoptotic cell death.