• Korean Chemical Engineering Research
• /
• 제44권5호
• /
• pp.435-443
• /
• 2006

이 논문은 화약연구 종사자는 물론 화학공학자들에게 고폭화약에 대한 기본적인 정보를 제공하는데 그 목적이 있다. 고폭화약 연구를 기술 분야별로 (1) 신규 에너지물질의 합성, (2) 기능성 화약 제조, (3) 복합화약 조성개발, (4) 무기체계 적용성 연구, (5) 군용 물질 해체 공정 등으로 대별하여, 고폭화약 연구의 이해를 위해 필요한 기본적인 기술분야에 대해 소개한다.

• 통합자연과학논문집
• /
• 제5권3호
• /
• pp.175-181
• /
• 2012

Oxepane high explosives substituted to explosive group such as azido, nitrato and hydrazino are investigated theoretically the acid catalyzed reaction using the semiempirical MINDO/3, MNDO and AM1 methods to use as the guidelines of high explosives. The nucleophilicity and basicity of oxepane high explosives can be explained by the value of negative charge on oxygen atom of oxepane and the reactivity in propagation step can be represented by the value of positive charge on carbon atom and low electrophile LUMO energy. It was known that carbenium ion was favorable due to the stable energy (19.507~32.101 Kcal/mol) between oxonium ion and carbenium ion in the process of cyclic oxonium ion of oxepane high explosives being converted to open carbenium ion in oxepane high explosives. The value of concentration of cyclic oxonium ion and open carbenium ion in equilibrium status was found to be a major determinant of mechanism, it was expected to react faster in the prepolymer propagation step in SN1 mechanism than in that of $S_N2$.

• 통합자연과학논문집
• /
• 제7권4호
• /
• pp.266-272
• /
• 2014

Oxocane high explosives substituted to explosive group such as azide (-CH2N3), nitrate (-CH2ONO2), and hydrazine (-CH2N2H3) are investigated theoretically the acid catalyzed reaction using the semiempirical MINDO/3, MNDO and AM1 methods to use as the guidelines of high explosives. The nucleophilicity and basicity of oxocane high explosives can be explained by the value of negative charge on oxygen atom of oxocane and the reactivity in propagation step can be represented by the value of positive charge on carbon atom and low electrophile LUMO energy. It was known that carbenium ion was favorable due to the stable energy (11.745~25.461 Kcal/mol) between oxonium ion and carbenium ion in the process of cyclic oxonium ion of oxocane high explosives being converted to open carbenium ion in oxocane high explosives. The value of concentration of cyclic oxonium ion and open carbenium ion in equilibrium status was found to be a major determinant of mechanism, it was expected to react faster in the prepolymer propagation step in SN1 mechanism than in that of SN2.

• 터널과지하공간
• /
• 제10권2호
• /
• pp.218-226
• /
• 2000

고성능 폭약의 성능을 결정하기 위해서는 폭발압력, 폭발속도, 열, 발생되는 가스 등이 정확히 기술될 수 있어야 한다. 본 연구에서는 실측하는데 어려움이 따르는 폭굉 시의 현상을 이해하기 위해 폭약이 폭발할 때 발생하는 압력, 부피팽창, 온도, 폭발속도 등을 이론적으로 계산하고자 하였다. 본 연구를 통해 폭발 현상을 표현하기 위한 계산 프로그램이 개발되었으며 이 프로그램을 이용하여 ANFO와 NG에 대해 폭약성능에 영향을 미치는 요소들을 이론적으로 계산하였다.

• 화약ㆍ발파
• /
• 제13권4호
• /
• pp.73-81
• /
• 1995

Explosives demolition mothod is allowed for more efficient time-saving and safer demolitioni operations as compared to conventional / mechanical demolition methods. CDI has to minimize the effects of noise, dust and various demolition hazards to the public areas, and residences that are located adjacent to the project site. CDI's explosives demolition work on the Nam san Foreigner's Apartment Complex and chosun trading Co's factory are backed by over 45 years of explosives experience in the demolition of over 6,000 structures worldwide, many of these structures are similar to the Nam san Foreigner's Apt. and Chosun trading's factory in construction and proximity to sensitive adjacent exposures. Recoginized worldwide as the founder of the leader in explosives demolitioni technology, CDI always will applied "State-of-the-Art" explosives techniques to safely and successfully achieve the desired demolition results on these project. CDI has never injured, much less caused any fatality, to either a worker on one of our sites or to a third party during the implosion of high-rise structure.

• 화약ㆍ발파
• /
• 제23권1호
• /
• pp.55-64
• /
• 2005

근래 건설$\cdot$토목 현장에서는 인가절감 덴 안전사고를 방지하기 위하여 보다 안전하고 저렴한 폭약인 Emulsion 폭약이 기존의 CD계열의 폭약을 상당부분 대체해 가고 있는 실정이다. 그러나 현실적으로 경암 이상의 암반에 건설되는 터널에서는 Emulsion폭약 적용시 발파위력 면에서 그 한계에 봉착하고 있다. 따라서 본 연구에서는 고성능 Emulsion 폭약인 MegaMEX를 국내 경암 이상의 암반에 적용하여 발파효율 및 시공성 등을 검증해 보고자 하였다. 적용결과 굴진율, 파쇄도 등 발파효율 면에서 기존 Emulsion 폭약의 한계를 뛰어넘어, GD(Gelatin dynamite)계 열의 폭약인 MegaMITE와 근접한 수준의 발파효율을 나타내었으며, 환경적인 측면에서도 유리한 것으로 나타났다.

• 화약ㆍ발파
• /
• 제13권3호
• /
• pp.73-77
• /
• 1995

• 화약ㆍ발파
• /
• 제17권2호
• /
• pp.65-71
• /
• 1999

• 화약ㆍ발파
• /
• 제17권3호
• /
• pp.35-59
• /
• 1999

• 화약ㆍ발파
• /
• 제13권2호
• /
• pp.20-34
• /
• 1995