• Title/Summary/Keyword: high energy physics

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1H NMR Kinetic Studies for Degradation of Nitramine Explosives Using PdO Nanoparticle (PdO 나노입자를 이용한 니트라민 폭발물 분해반응에 대한 1H NMR 반응속도연구)

  • Kye, Young-Sik;Kumbier, Mathew;Kim, Dongwook;Harbison, Gerard S.;Langell, Marjorie A.
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.302-308
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    • 2022
  • The PdO nanoparticle with large surface area was selected to solve the environmental pollution problem at fire range caused by high energy explosives research department explosive (RDX) and high melting explosive (HMX). By simulating water pollution, RDX and HMX nitramine explosives were dissolved in water, followed by the degradation reaction at 313 K by adding PdO. In order to measure the degradation reaction rate of explosives, 1H NMR was used, which can monitor the reaction rate without losing sample during reaction, and observe the progress of the reaction through the spectrum. The results showed that the degradation of RDX and HMX by PdO nanoparticles are pseudo-first order reaction. The degradation of explosives compounds were observed via the chemical shift and peak intensity analysis of NMR peaks. The measured rate constants for these reactions of RDX and HMX were 2.10 × 10-2 and 6.35 × 10-4 h-1, respectively. This study showed that the application of PdO nanoparticles for explosives degradation is a feasible option.

NUMERICAL ANALYSIS FOR PRANDTL NUMBER DEPENDENCY ON NATURAL CONVECTION IN AN ENCLOSURE HAVING A VERTICAL THERMAL GRADIENT WITH A SQUARE INSULATOR INSIDE

  • Lee, Jae-Ryong;Park, Il-Seouk
    • Nuclear Engineering and Technology
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    • v.44 no.3
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    • pp.283-296
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    • 2012
  • The natural convection in a horizontal enclosure heated from the bottom wall, cooled at the top wall, and having a square adiabatic body in the center is studied. Three different Prandtl numbers (0.01, 0.7 and 7) are considered for the investigation of the effect of the Prandtl number on natural convection. Adiabatic boundary conditions are employed for the side walls. A two-dimensional solution for unsteady natural convection is obtained, using an accurate and efficient Chebyshev spectral methodology for different Rayleigh numbers varying over the range of $10_3$ to $10_6$. It had been experimentally reported that the heat transfer mode becomes oscillatory when Pr is out of a specific Pr band beyond the critical Ra. In this study, we reproduced this phenomenon numerically. It was found that when Ra=$10_6$, only the case for intermediate Pr (=0.7) reached a non-changing steady state and the low and high Pr number cases (Pr=0.01 and 7) showed a periodically oscillatory fashion hydrodynamically and thermally. The variation of time- and surface-averaged Nusselt numbers on the hot and cold walls for different Rayleigh numbers and Prandtl numbers are presented to show the overall heat transfer characteristics in the system. Further, the isotherms and streamline distributions are presented in detail to compare the physics related to their thermal behavior.

Effects of shot peening stand-off distance on electrochemical properties for surface modification of ALBC3 alloy (ALBC3 합금의 표면 개질을 위한 쇼트피닝 분사거리가 전기화학적 특성에 미치는 영향)

  • Han, Min-Su;Hyun, Koang-Yong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.233-238
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    • 2013
  • In the case of casting materials or ductile materials for marine equipment, it is common to employ a surface modification for achieving cost reduction and improvement in strength. In particular, aluminium bronze ALBC3 exhibits excellent corrosion resistance, and thus widely used for marine application. However, application of the material under high-velocity seawater flow may induce electrochemical corrosion damage and physical damage such as cavitation erosion, leading to shorter service life of equipment. In this study, surface modification was carried out on ALBC3 alloy for different shot peening stand-off distances, and the physical hardness and electrochemical characteristics before and after modification were investigated. The results in each case showed the hardness increase in comparison with non-peened specimen, and the maximum hardness improvement(50 %) was found in 10 cm of shot-peening stand-off distance. It is observed that the electrochemical characteristics were irrelevant to application of shot peening.

Application to Stabilizing Control of Nonlinear Mobile Inverted Pendulum Using Sliding Mode Technique

  • Choi, Nak-Soon;Kang, Ming-Tao;Kim, Hak-Kyeong;Park, Sang-Yong;Kim, Sang-Bong
    • Journal of Ocean Engineering and Technology
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    • v.23 no.2
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    • pp.1-7
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    • 2009
  • This paper presents a sliding mode controller based on Ackermann's formula and applies it to stabilizing a two-wheeled mobile inverted pendulum in equilibrium. The mobile inverted pendulum is a system with an inverted pendulum on a mobile cart. The dynamic modeling of the mobile inverted pendulum was established under the assumptions of a cart with no slip and a pendulum with only planar motion. The proposed sliding mode controller was based upon a class of nonlinear systems whose nonlinear part of the modeling can be linearly parameterized. The sliding surface was obtained in an explicit form using Ackermann's formula, and then a control law was designed from reachability conditions and made the sliding surface attractive to the equilibrium state of the mobile inverted pendulum. The proposed controller was implemented in a Microchip PIC16F877 micro-controller. The developed overall control system is described. The simulation and experimental results are presented to show the effectiveness of the modeling and controller.

Characteristics of TiN Films by ion Beam Assisted Deposition (이온빔 보조 증착에 의한 TiN 박막의 특성)

  • Kim, Sang Hyun;Kim, Dae Hyeon
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.1
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    • pp.161-166
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    • 2004
  • In this research, TiN films has been grown to the stainless steel substrate by ion beam assisted deposition. TiN film was grown to the nitrogen atmosphere of around $10^{-15}$ Torr with Arion bombardment. The chemical composition, color and adhesion of TiN films were examined as a variation of En(ion energy per atom). The N/Ti ratio increased linearly as the increase of En and saturated around 1.2 at high En. As a results, the bright golden color was obtained when En reached a certain value of Ecn. As a results, the N/Ti ratio is about 0.9.

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Steady- and Transient-State Analyses of Fully Ceramic Microencapsulated Fuel with Randomly Dispersed Tristructural Isotropic Particles via Two-Temperature Homogenized Model-I: Theory and Method

  • Lee, Yoonhee;Cho, Bumhee;Cho, Nam Zin
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.650-659
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    • 2016
  • As a type of accident-tolerant fuel, fully ceramic microencapsulated (FCM) fuel was proposed after the Fukushima accident in Japan. The FCM fuel consists of tristructural isotropic particles randomly dispersed in a silicon carbide (SiC) matrix. For a fuel element with such high heterogeneity, we have proposed a two-temperature homogenized model using the particle transport Monte Carlo method for the heat conduction problem. This model distinguishes between fuel-kernel and SiC matrix temperatures. Moreover, the obtained temperature profiles are more realistic than those of other models. In Part I of the paper, homogenized parameters for the FCM fuel in which tristructural isotropic particles are randomly dispersed in the fine lattice stochastic structure are obtained by (1) matching steady-state analytic solutions of the model with the results of particle transport Monte Carlo method for heat conduction problems, and (2) preserving total enthalpies in fuel kernels and SiC matrix. The homogenized parameters have two desirable properties: (1) they are insensitive to boundary conditions such as coolant bulk temperatures and thickness of cladding, and (2) they are independent of operating power density. By performing the Monte Carlo calculations with the temperature-dependent thermal properties of the constituent materials of the FCM fuel, temperature-dependent homogenized parameters are obtained.

Interaction of Laser Beam with PZT - Target and Observation of Laser - Induced Plume and Particle Ejection (Laser와 PZT - Target간의 반응과 그에 따른 Plume 형성 및 입자 방출에 관한 연구)

  • Lee, Byeong-U
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.5
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    • pp.93-102
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    • 1996
  • Laser-induced plume and laser-target interaction during pulsed laser deposition are demonstrated for a lead zirconate titanate (PZT). A KrF excimer laser (wavelength 248nm) was used and the laser was pulsed at 20Hz, with nominal pulse width of 20ns. The laser fluence was~$16J/cm^2,$ with 100mJ per pulse. The laser-induced plasma plume for nanosecond laser irradiation on PZT target has been investigated by optical emission spectra using an optical multichannel analyzer(OMA) and by direct observation of the plume using an ICCD high speed photography. OMA analysis showed two distinct ionic species with different expansion velocities of fast or slow according to their ionization states. The ion velocity of the front surface of the developing plume was about $10^7$cm/sec and corresponding kinetic energy was about 100eV. ICCD photograph showed another kind of even slower moving particles ejected from the target. These particles considered expelled molten parts of the target. SEM morphologies of the laser irradiated targets showed drastic melting and material removal by the laser pulse, and also showed the evidence of the molten particle ejection. The physics of the plasma(plume) formation and particle ejection has been discussed.

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Variation of Catecholamine Content in Rat Vline under the Immo bilization Stress (흰쥐의 구속 stress 에 의한 catecholamine 의 변화)

  • 김형석
    • Journal of environmental and Sanitary engineering
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    • v.6 no.2
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    • pp.59-68
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    • 1991
  • The word of stress was wsed in the field of physics as a external force from 17th century, but the meaning of this stress had chafed to the internal and exteral demand fort the human body in medical area. All the stumulants which make stress was called as j stressor. When animals get stress blucose excreted from liver to adapt for the emergent state ant some related hormone secrete convert protein and lipid to glucose for the purpose of energy supply to muscle. As a results heart rate, blood pressure, respiration rate are increased and musclse are strengthed. These physiolgical reactions ate controlled by autonomic nerve system under the control of hyothalamus in brain. Autonomic nerve system and endocrinary system are react harmoiously to stress reaction. According to the stress reaction, adrenomedullary system are stimulated, and epinephrine, morepinephrine are exceted. Author experimented the effect of the immobilizational stress to rat by analyzing the variaition of catecholamine secrction, the Na concentration and the effect of the antistresf effect by Panax Ginseng which is a traditional Korean herb medicine. The concentration of the norepinephrine, epinephrin, and dopamin in normal rat are 1 578 ng/ml, 0.365 ng/ml, and 0.731 ng/ml respectively, but in the immobilyzed stress groIn the concentration were increased to 1.915 ng.ml, 0.854 ng/ml, and 2,361 ng/ml which she the high show the higher concentration of catecholamine to stressor.

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Comparison between quasi-linear theory and particle-in-cell simulation of solar wind instabilities

  • Hwang, Junga;Seough, Jungjoon;Yoon, Peter H.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.47.2-47.2
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    • 2016
  • The protons and helium ions in the solar wind are observed to possess anisotropic temperature profiles. The anisotropy appears to be limited by various marginal instability conditions. One of the efficient methods to investigate the global dynamics and distribution of various temperature anisotropies in the large-scale solar wind models may be that based upon the macroscopic quasi-linear approach. The present paper investigates the proton and helium ion anisotropy instabilities on the basis of comparison between the quasi-linear theory versus particle-in-cell simulation. It is found that the overall dynamical development of the particle temperatures is quite accurately reproduced by the macroscopic quasi-linear scheme. The wave energy development in time, however, shows somewhat less restrictive comparisons, indicating that while the quasi-linear method is acceptable for the particle dynamics, the wave analysis probably requires higher-order physics, such as wave-wave coupling or nonlinear wave-particle interaction. We carried out comparative studies of proton firehose instability, aperiodic ordinary mode instability, and helium ion anisotropy instability. It was found that the agreement between QL theory and PIC simulation is rather good. It means that the quasilinear approximation enjoys only a limited range of validity, especially for the wave dynamics and for the relatively high-beta regime.

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A study of the radioprotection effect of guarana (Paullinia cupana) on the fetuses of ICR mice THE RADIATION PROTECTION EFFECTS OF GUARANA

  • Gu, Yeun-Hwa;Hasegawa, Takeo;Suzuki, Ikukatsu;Yamamoto, Youichi;Yoon, Yeog-Byung;Rhee, Soo-Yong
    • Journal of Radiation Protection and Research
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    • v.26 no.4
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    • pp.347-356
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    • 2001
  • Guarana, a tropical plant is found in powdered for in health food and is very popular soft drink in Brazil as an energy feaster with its high caffeine contents. We examined its radioprotection effects during organogenesis stages of ICR mice by malformations rate and cellular lead 8 the embryo by radiation and analyzed the mechanism of the radioprotection effects in the fetal of ICR mice. The results of this study showed that Guarana reduced clearly the embryonic death rate and teratogenesis rate by radiation. Its radioprotection effect inject be related with its radioprotection effect might be related with its antioxidant effect or free radical scavenger. We need to exposure the Guarana as a potential radioprotection agent. Therefore, we investigated about radiation effects by Guarana using to mice experiments in this paper.

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