• Title/Summary/Keyword: high durability

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Development of Pore Filled Anion Exchange Membrane Using UV Polymerization Method for Anion Exchange Membrane Fuel Cell Application (음이온교환막 연료전지 응용을 위한 UV 중합법을 이용한 세공 충진 음이온교환막 개발)

  • Ga Jin Kwak;Do Hyeong Kim;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.2
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    • pp.77-86
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    • 2023
  • In this study, pore-filled ion exchange membranes with low membrane resistance and high hydroxide ion conductivity was developed. To improve alkali durability, a porous substrate made of polytetrafluoroethylene was used, and a copolymer was prepared using monomers 2-(dimethyl amino) ethyl methacrylate (DMAEMA) and vinyl benzyl chloride (VBC) for pores. divinyl benzene (DVB) was used as the cross-linker, and ion exchange membranes were prepared for each cross-linking agent content to study the effect of the cross-linker content on DMAEMA-DVB and VBC-DMAEMA-DVB copolymers. As a result, chemical stability is improved by using a PTFE material substrate, and productivity can be increased by enabling fast photo polymerization at a low temperature by using a low-pressure UV lamp. To confirm the physical and chemical stability of the ion exchange membrane required for an anion exchange membrane fuel cell, tensile strength, and alkali resistance tests were conducted. As a result, as the cross-linking degree increased, the tensile strength increased by approximately 40 MPa, and finally, through the silver conductivity and alkali resistance tests, it was confirmed that the alkaline stability increased as the cross-linking agent increased.

A Study on Tensile Property due to Stacking Structure by Fiber Design of CT Specimen Composed of CFRP (CFRP로 구성된 CT시험편의 섬유설계에 의한 적층구조에 따른 인장 특성 연구)

  • Hwang, Gue-Wan;Cho, Jae-Ung
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.11
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    • pp.447-455
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    • 2017
  • At the modern industry, the composite material has been widely used. Particularly, the material of carbon fiber reinforced plastic hardened with resin on the basis of fiber is excellent. As the specific strength and rigidity are also superior, it receives attention as the light material. Among these materials, the carbon fiber reinforced plastic using carbon fiber has the superior mechanical property different from another fiber. So, it is utilized in vehicle and airplane at which high strength and light weight are needed at the same time. In this paper, the tensile property due to the fiber design is investigated through the analysis study with CT specimen composed of carbon plastic reinforced plastic. At the stress analysis of CFRP composite material with hole, the fracture trend at the tensile environment is examined. Also, it is shown that the lowest stress value happens and the deformation energy of the pre-crack becomes lowest at the analysis model composed of the stacking angle of 60° through the result due to the stacking angle. On the basis of this study result, it is thought to apply the foundation data to anticipate the fracture configuration at the structure applied with the practical experiment.

Enhancement of Penetration by Using Mechenical Micro Needle in Textile Strain Sensor (텍스타일 스트레인 센서에 마이크로 니들을 이용한 전도성입자 침투력 향상)

  • Hayeong Yun;Wonjin Kim;Jooyong Kim
    • Science of Emotion and Sensibility
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    • v.25 no.4
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    • pp.45-52
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    • 2022
  • Recently, interest in and demand for sensors that recognize physical activity and their products are increasing. In particular, the development of wearable materials that are flexible, stretchable, and able to detect the user's biological signals is drawing attention. In this study, an experiment was conducted to improve the dip-coating efficiency of a single-walled carbon nanotube dispersion solution after fine holes were made in a hydrophobic material with a micro needle. In this study, dip-coating was performed with a material that was not penetrated, and comparative analysis was performed. The electrical conductivity of the sensor was measured when the sensor was stretched using a strain universal testing machine (Dacell Co. Ltd., Seoul, Korea) and a multimeter (Keysight Technologies, Santa Rosa, CA, USA) was used to measure resistance. It was found that the electrical conductivity of a sensor that was subjected to needling was at least 16 times better than that of a sensor that was not. In addition, the gauge factor was excellent, relative to the initial resistance of the sensor, so good performance as a sensor could be confirmed. Here, the dip-coating efficiency of hydrophobic materials, which have superior physical properties to hydrophilic materials but are not suitable due to their high surface tension, can be adopted to more effectively detect body movements and manufacture sensors with excellent durability and usability.

Stress-strain Relations of Concrete Confined with Tubes Having Varying GFRP Layers (수적층 및 필라멘트 와인딩을 이용한 GFRP튜브로 구속된 콘크리트의 압축 거동)

  • Lee, Sung Woo;Choi, Sokhwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6A
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    • pp.861-872
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    • 2008
  • Concrete-filled glass fiber reinforced polymer tubes are often used for marine structures with the benefit of good durability and high resistance against corrosion under severe chemical environment. Current research presents results of a comprehensive experimental investigation on the behavior of axially loaded circular concrete-filled glass fiber reinforced polymer tubes. This paper is intended to examine several aspects related to the usage of glass fiber fabrics and filament wound layers used for outer shell of piles subjected to axial compression. The objectives of the study are as follows: (1) to evaluate the effectiveness of filament winding angle of glass fiber layers (2) to evaluate the effect of number of GFRP layers on the ultimate load and ductility of confined concrete (3) to evaluate the effect of loading condition of specimens on the effectiveness of confinement and failure characteristics as well, and (4) to propose a analytical model which describes the stress-strain behavior of the confined concrete. Three different types of glass fiber layers were chosen; fabric layer, ${\pm}45^{\circ}$ filament winding layer, and ${\pm}85^{\circ}$ filament winding layer. They were put together or used independently in the fabrication of tubes. Specimens that have various L:D ratios and different diameters have also been tested. Totally 27 GFRP tube specimens to investigate the tension capacity, and 66 concrete-filled GFRP tube specimens for compression test were prepared and tested. The behavior of the specimens in the axial and transverse directions, failure types were investigated. Analytical model and parameters were suggested to describe the stress-strain behavior of concrete under confinement.

Fatigue Behavior of Steel-Concrete Composite Bridge Deck with Perfobond Rib Shear Connector (유공판재형 전단연결재를 갖는 강-콘크리트 합성바닥판의 피로거동에 관한 연구)

  • Kyung, Kab Soo;Lee, Seung Yong;Jeong, Youn Ju;Kwon, Soon Cheol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.1A
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    • pp.71-80
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    • 2010
  • Bridge deck is directly influenced by environment and vehicle load, it is easily damaged so that it requires an appropriate repair and retrofit. Therefore, developing a bridge deck with high durability is necessary in order to minimize the maintenance of bridge deck and use it to its design life. In this study, static test was carried out to evaluate a fatigue capacity of steel-concrete composite deck, which was newly developed by supplementing problems of existing reinforced concrete deck. Based on results from the static test, fatigue load was decided, and fatigue test was conducted under the constant amplitude repeated load. From the fatigue tests, the S-N curve regarding principle structural details of composite deck was made, and characteristics of fatigue behavior was estimated by comparing and evaluating it with fatigue design criteria. In addition, fatigue design guideline was presented. As a result, it is found that each structural details of composite deck proposed by this study, such as upper flange of corrugated steel plate and middle section of it, shear connector and lower flange of corrugated steel plate, is satisfying the fatigue strength.

A Study on the Calculation of Load Resistance Factor of over Tension Anchors by Optimization Design (최적화 설계를 통한 과긴장 앵커의 하중-저항계수 산정 연구)

  • Soung-Kyu Lee;Yeong-Jin Lee;Yong-Jae Song;Tae-Jun Cho;Kang-Il Lee
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.4
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    • pp.17-26
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    • 2023
  • To consider the risk of damage and fracture of P.C strands, the existing post-maintenance system alone has the limitations, hence it is necessary to quantitatively evaluate and predict the deterioration, durability and safety of facilities and establish a reasonable maintenance system considering the asset value of facilities. Therefore, it is worth considering a preventive maintenance plan that allows proactive measures to be taken before a major defect occurs in the temporary anchor. This study devised a preventive over tension method, reviewed its effectiveness through design and field tests, by calculating the resistance factors by performing a reliability-based optimization design. At this time, the over tension anchor method was evaluated using the ratio of the residual tension force after the fracture of P.C strands to the effective tension force before the fracture of P.C strand, followed by the resistance factor calculated by the optimal solution for each random variables using Excel solver and applying it to the limit state equations. As a result of the study, if the over tension ratio is 125% to 130%, the remaining strands showed a high resistance effect even after the fracture of P.C strand. As a result of the optimization design, it was found that it is appropriate to apply the load factor (γ) of 1.25, and the resistance factors of Φ1, Φ2, Φ3 as 0.7, 0.5, 0.6.

Fundamental Study for Extension of Application of Recycled Concrete Aggregate: Spun High Strength Concrete (순환골재의 사용성 확대를 위한 연구: 원심력콘크리트로의 적용)

  • Sim, Jong-Sung;Park, Cheol-Woo;Park, Sung-Jae;Kim, Hyun-Jung;Kim, Taeg-Wang;Lee, Man-Suk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.103-112
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    • 2006
  • Along with recent improvement of recycling technique, the quality of the recycled concrete aggregate have become very competitive to the natural concrete aggregate. Therefore, a practical use of the recycled concrete aggregate may be possible for structural members. Majority studies about the recycled concrete aggregate was emphasized a limitation of fundamental study concerned with a strength characteristics and durability of the recycled aggregate concrete, there is use for the structural members. Therefore, for the extension of application of recycled concrete aggregate, this investigation verifies the strength characteristics recycled concrete aggregate of the spun-concrete products with various coarse and fine recycled aggregate replacement ratio(coarse recycled aggregate: 0%, 20%, 40%, 60%, 100%; fine recycled aggregate: 0%, 30%, 60%, 100%) and with addition of cellulose fibers(0%, 0.01%, 0.03%, 0.05%, 0.08%). From the test results, The strength of spun concrete used with recycled aggregate [NR specimen], was measured as 72MPa, was found to be very approximately to the strength of spun concrete used with the natural aggregate(NN specimen), was measured as 74MPa, when only fine aggregate was replaced with the recycled. Therefore, the fine recycled concrete aggregate can be successfully used in the spun high strength concrete product. The compressive strength of all specimens used the specialty cellulose fiber were measured as about 70M Pa, however, the increasement of the specialty cellulose fiber content is showed to decrease compressive strength of spun concrete. Therefore, it is anticipated that the specialty cellulose fiber can be applied to the various spun concrete products.

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Effects of Encapsulation Layer on Center Crack and Fracture of Thin Silicon Chip using Numerical Analysis (봉지막이 박형 실리콘 칩의 파괴에 미치는 영향에 대한 수치해석 연구)

  • Choa, Sung-Hoon;Jang, Young-Moon;Lee, Haeng-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.1
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    • pp.1-10
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    • 2018
  • Recently, there has been rapid development in the field of flexible electronic devices, such as organic light emitting diodes (OLEDs), organic solar cells and flexible sensors. Encapsulation process is added to protect the flexible electronic devices from exposure to oxygen and moisture in the air. Using numerical simulation, we investigated the effects of the encapsulation layer on mechanical stability of the silicon chip, especially the fracture performance of center crack in multi-layer package for various loading condition. The multi-layer package is categorized in two type - a wide chip model in which the chip has a large width and encapsulation layer covers only the chip, and a narrow chip model in which the chip covers both the substrate and the chip with smaller width than the substrate. In the wide chip model where the external load acts directly on the chip, the encapsulation layer with high stiffness enhanced the crack resistance of the film chip as the thickness of the encapsulation layer increased regardless of loading conditions. In contrast, the encapsulation layer with high stiffness reduced the crack resistance of the film chip in the narrow chip model for the case of external tensile strain loading. This is because the external load is transferred to the chip through the encapsulation layer and the small load acts on the chip for the weak encapsulation layer in the narrow chip model. When the bending moment acts on the narrow model, thin encapsulation layer and thick encapsulation layer show the opposite results since the neutral axis is moving toward the chip with a crack and load acting on chip decreases consequently as the thickness of encapsulation layer increases. The present study is expected to provide practical design guidance to enhance the durability and fracture performance of the silicon chip in the multilayer package with encapsulation layer.

Prediction of field failure rate using data mining in the Automotive semiconductor (데이터 마이닝 기법을 이용한 차량용 반도체의 불량률 예측 연구)

  • Yun, Gyungsik;Jung, Hee-Won;Park, Seungbum
    • Journal of Technology Innovation
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    • v.26 no.3
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    • pp.37-68
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    • 2018
  • Since the 20th century, automobiles, which are the most common means of transportation, have been evolving as the use of electronic control devices and automotive semiconductors increases dramatically. Automotive semiconductors are a key component in automotive electronic control devices and are used to provide stability, efficiency of fuel use, and stability of operation to consumers. For example, automotive semiconductors include engines control, technologies for managing electric motors, transmission control units, hybrid vehicle control, start/stop systems, electronic motor control, automotive radar and LIDAR, smart head lamps, head-up displays, lane keeping systems. As such, semiconductors are being applied to almost all electronic control devices that make up an automobile, and they are creating more effects than simply combining mechanical devices. Since automotive semiconductors have a high data rate basically, a microprocessor unit is being used instead of a micro control unit. For example, semiconductors based on ARM processors are being used in telematics, audio/video multi-medias and navigation. Automotive semiconductors require characteristics such as high reliability, durability and long-term supply, considering the period of use of the automobile for more than 10 years. The reliability of automotive semiconductors is directly linked to the safety of automobiles. The semiconductor industry uses JEDEC and AEC standards to evaluate the reliability of automotive semiconductors. In addition, the life expectancy of the product is estimated at the early stage of development and at the early stage of mass production by using the reliability test method and results that are presented as standard in the automobile industry. However, there are limitations in predicting the failure rate caused by various parameters such as customer's various conditions of use and usage time. To overcome these limitations, much research has been done in academia and industry. Among them, researches using data mining techniques have been carried out in many semiconductor fields, but application and research on automotive semiconductors have not yet been studied. In this regard, this study investigates the relationship between data generated during semiconductor assembly and package test process by using data mining technique, and uses data mining technique suitable for predicting potential failure rate using customer bad data.

Consumer Intention to Purchase Domestic/Foreign Brand Jeans;Beliefs, Attitude, and Individual Characteristics. (국내 및 외국 상표 청바지의 구매의도에 따른 평가기준에 대한 신념과 추구이미지 및 의복태도의 차이연구)

  • 고애란
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.2
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    • pp.263-272
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    • 1994
  • The purpose of this study was to identify factors that might distinguish those who have a high level of Intention to purchase each of domestic, foreign designer and national brand jeans from those who have a low intention in terms of evaluative criteria belief, ideal jeans image and clothing altitude. The sample consisted of 198 male and 197 female students from five universities in Seoul. The questionnnaire consisted of 50 seven-point semantic differential scales dealing with evaluative criteria and ideal jeans image, beliefs about and intention to purchase domestic, foreign designer and foreign national brand jeans and 25 Likert type clothing attitude scales. Based on a series of t-tests the results showed that color and design were the most influencing factor among the evaluative criteria belief, regardless of brand type, while durability, accessory, sewing were the least. Sexy image, brand consciousnees and fashion interest were the important factor that distinguish high intention to purchase group fro)m low intention to purchase group.

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