• 제목/요약/키워드: high Tg

검색결과 894건 처리시간 0.036초

Fatty Acids Composition in Viscera and Muscle of the Philippines Pinkgray Goby, Amblvchaeturichthys hexanema

  • Choi Byeong-Dae;Kang Seok-Joong;Jeong Bo-Young;Mendoza Lonarda S.
    • Fisheries and Aquatic Sciences
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    • 제4권4호
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    • pp.265-267
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    • 2001
  • In this study, lipid classes and fatty acids composition in viscera and muscle of the philippines Pinkgray goby, Amblychaeturichtys hexanema were determined. The viscera contained high levels of total lipid $(TL,\;4.8\%)$, while the muscle contained less TL $(0.5\%)$. TL in the viscera consisted of triacylglycerol $(83.9\%)$, diacylglycerol $(7.9\%)$, polar lipid $(7.4\%)$, and cholesterol $(0.8\%)$. However, the muscle contained a small amount of TG $(3.0\%)$ and much more PL $(73.8\%)$. Principal fatty acids composition of PL and NL in the viscera and muscle were 16:0, 16:1n-7, 18:0, 18: 1n-9, 18:1n-7, l8:3n-3, 20:5n-3, 22:5n-3, and 22:6n-3.

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전력케이블용 절연재료의 캐리어 극성 및 공간전하 측정기술에 관한 연구-PE-EVA에서의 하전입자의 거동 (A Study on the Space Charge Measurement Technique and Carrier Polarity of Insulating Materials on Power Cable)

  • 국상훈;박중순;강용철;권영수
    • 대한전기학회논문지
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    • 제41권2호
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    • pp.185-191
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    • 1992
  • In this paper, it is attempted to distinguish the charged particles and to judge the polarity by the use of Thermally Stimulated Current(TSC) and Temperature Gradient Thermally Stimulated Surface Potential Measurement(TG-TSSP)with experimental insulation material XLPE-EVA for power cables which is made by blending cross-linked polyethylene(XLPE) and ethylene-vinylacetate copolymer(EVA). In addition, it is performed to investigate the effect of EVA blending. From the experimental results, it is known that for the case of XLPE-EVA blended experimental material, the generation of space charged electric field is not obtained in the high temperature region due to the obatruction of the injection of trapping carrier by the electron and the positive hole.

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CF$_4$ 플라즈마 처리로 불소를 첨가한 실록산 Spin-On-Glass 박막의 특성 (Properties of Spin-On-Glass Siloxane Thin Films Fluorine-doped by CF$_4$ Plasma)

  • 김현중;김기호
    • 한국표면공학회지
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    • 제34권3호
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    • pp.258-263
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    • 2001
  • Siloxane thin films were fabricated on a silicon wafer by spin-coating using a siloxane solution made by the sol-gel process. Fluorine was doped using$ CF_4$ plasma treatment. The film was then annealed in-situ state in the nitrogen atmosphere. In order to examine the influence of annealing and fluorine doping on the siloxane thin film, thermogravimetric-differential thermal analysis (TG-DTA), Fourier transform-infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) were used and the dielectric constant was determined by the high-frequency capacitance-voltage method. Stable siloxane films could be obtained by in-situ annealing in a nitrogen atmosphere after $CF_4$ plasma treatment, and the dielectric value of the film was $\varepsilon$ 2.5.

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Preparation and Nonlinear Optical Properties of Novel Polyesters with Enhanced Thermal Stability of Second Harmonic Generation

  • Kim, Jin-Hyang;Won, Dong-Seon;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • 제29권1호
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    • pp.181-186
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    • 2008
  • 2,5-Di-(2'-hydroxyethoxy)-4'-nitrostilbene (3) was prepared and polycondensed with terephthaloyl chloride, adipoyl chloride, and sebacoyl chloride to yield novel T-type polyesters (4-6) containing the NLO-chromophores dioxynitrostilbenyl groups, which constituted parts of the polymer backbones. Polymers 4-6 are soluble in common organic solvents such as acetone and N,N-dimethylformamide. They showed thermal stability up to 260 oC in thermogravimetric analysis with glass-transition temperatures obtained from differential scanning calorimetry in the range 90-95 oC. The second harmonic generation (SHG) coefficients (d33) of poled polymer films at the 1064 nm fundamental wavelength were around 1.42 ´ 10-9 esu. The dipole alignment exhibited high thermal stability up to 5 oC higher than glass-transition temperature (Tg), and there was no SHG decay below 100 oC due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

양생온도와 재령에 다른 콘크리트의 결합수량과 수산화칼슘의 변화 (A Variation of Non-Evaporable Water and Calcium Hydroxides of Concrete with Various Curing Temperatures and Ages)

  • 이창수;윤인석;이규동
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.273-276
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    • 2003
  • The non-evaporable water and calcium hydroxides were measured by TG/DTA for studying the temperature effect on hydration of concrete mixture. The experimental parameters introduced in this study were the curing temperatures, ages and W/C ratios. The mixing temperature was also controlled to improve the efficiency of experimental work. While the mixture cured at high temperature showed the large quantity of non-evaporable water and calcium hydroxides at early age, the production rate of these hydration products was decreased as increasing the curing age, and the quantity of hydration product became smaller than that of the corresponding mixture cured at lower temperature at later age.

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고분자 분자량 변화에 따른 핫 엠보싱 공정 연구 (The effect of melt flow index on polymer deformation in hot embossing process)

  • 윤근병;정명영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1025-1029
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    • 2003
  • We studied the cross-sectional profiles of deformed thermoplastics in hot embossing process and compared with melt flow index for various embossing conditions such as embossing temperature, embossing pressure and initial thickness of the thermoplastics. The fastest embossing times for complete penetration of the cavities were obtained at temperature greater than $60^{\circ}C$ above glass transition temperature (Tg). When the melt flow index of polymer is low, the penetration ratio does not become large even if the embossing pressure increases. The complete occupation of the cavities was easier obtained with high melt flow index polymer than low melt flow index polymer at the same process condition. We believe these results can be very useful for optimizing nanostructured hot embossing also known nanoimprinting process conditions.

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아크릴계 점착제의 박리강도와 점착부여제 (Peel Stength of the Acrylic Copolymer and Pressure Sensitive Adhesives)

  • 김현중
    • 펄프종이기술
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    • 제31권1호
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    • pp.79-88
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    • 1999
  • The stability and performance (peel strength) of the acrylic copolymer and various modified rosin systems were investigated. The peel strength was measured over a wide range of scaling rates, and the influence of the viscoelasticity of the PSA(pressure sensitive adhesive) was considered. In the case of miscible systems, the peak of peel strength (PSA performance) over wide peel rates was changed and modified systematically with increasing glass transition temperature of the blends. The peak of the peel strength for blended systems shifts toward the lower rate side as glass transition temperature ($T_g$) of the blend increased. The influence of esterification of the rosin on performance and stability against deterioration was greatly modified by blending with rosin of glycerol ester and rosin pentaerythritol ester. The failure mode of the blend varies with the combination with acrylic copolymer and modified rosin, and cohesive failure was found at a lower peel rate while interfacial failure was found at a high peel rate. A few systems where a single Tg could be measured, despite the fact that two phases were observed microscopically, were detected.

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졸-겔법에 의한 실리카 유리의 제조와 온도 의존성 및 활성화에너지 변화 (Silica Glass Preparation by the Sol-Gel Process and the Temperature Dependence on Changes of Apparent Activation Evergies)

  • 이경희;이병하;오부근;안광훈;김종옥
    • 한국세라믹학회지
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    • 제26권4호
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    • pp.471-478
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    • 1989
  • In this study we investigated the gelation time of sol which containing mixtures of TEOS with H2O, ethanol, HCl in the preparation of monolithic silica glass through Sol-Gel method. In this case apparent activation energies were observed by Arrhenius equation. We investigated the conversion from gel to glass in drying and heat treatment stages using DT-TG, FT-IR, XRD analysis and dried gel conversed to glass by heat treatment up to 85$0^{\circ}C$. The results of this experiment showed that the gelation time of solutions were promoted when increasing the amount of addition of H2O and HCl catalyst for TEOS and high reaction temperature of solution.

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무선 홈네트워크 실현을 위한 고속 UWB 기술 및 표준화 동향 (Introduction of High Data -Rate UWB Technology and IEEE802.15.3a Standardization Status for Wireless Home Network)

  • 최상성;신철호;강법주
    • 전자통신동향분석
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    • 제19권5호통권89호
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    • pp.87-94
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    • 2004
  • 기존의 통신 시스템에 비해 매우 넓은 대역폭을 사용하는 UWB 시스템은 기존의 유선장치를 무선장치로대치할 수 있는 유일한 고속 무선 전송기술로서 가정내 멀티미디어 데이터 전송을 위한 근거리 무선 홈네트워크 기술로 부각되고 있다. 현재 IEEE802.15의 TG3a에서는 UWB 기술을 이용한 고속 WPAN의 물리계층에 대한 표준화가 진행되고 있으며, MBOA에서 주도하고 있는 MB-OFDM 시스템과 Motorola에서 주도하고 있는 DS-UWB 시스템의 2가지 제안서로 압축되어 표준화가 진행되고 있다. 본 논문에서는 현재까지의 표준화 진행 상황 및 양측에서 제안된 UWB 물리계층 표준화 기술 동향에 관하여 살펴본다.

비구면 렌즈의 설계 및 제조를 위한 칼코게나이드계 유리의 물리적 화학적 특성 연구 (A study on physical and chemical properties of chalcogenides for an aspheric lens)

  • 고준빈;김정호
    • 한국생산제조학회지
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    • 제19권3호
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    • pp.388-393
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    • 2010
  • In recent years the research has been focused on the preparation of special glasses, i.e., chalcogenide and heavy metal oxide ones that can transmit optical radiation above 2 um and also other optical parameters exceed those of silica based glasses. The attention in this paper is focused on chalcogenide glasses, on preparation of high quality base glass, for an application in infrared optical product design and manufacture. The amorphous materials of As-Se and Ge-As-Se chalcogenides were prepared by a standard melt-quenching technique. The compositions were mesaured by ICP-AES and EPMA, and structural and thermal properties were studied through various annealing processes. Several anomalies of glass transition and crystallization were observed in the DSC/DTA/TG results of the chalcogenide glass.