Browse > Article
http://dx.doi.org/10.5012/bkcs.2008.29.1.181

Preparation and Nonlinear Optical Properties of Novel Polyesters with Enhanced Thermal Stability of Second Harmonic Generation  

Kim, Jin-Hyang (Institute of Functional Materials, Department of Chemistry, Inje University)
Won, Dong-Seon (Institute of Functional Materials, Department of Chemistry, Inje University)
Lee, Ju-Yeon (Institute of Functional Materials, Department of Chemistry, Inje University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.1, 2008 , pp. 181-186 More about this Journal
Abstract
2,5-Di-(2'-hydroxyethoxy)-4'-nitrostilbene (3) was prepared and polycondensed with terephthaloyl chloride, adipoyl chloride, and sebacoyl chloride to yield novel T-type polyesters (4-6) containing the NLO-chromophores dioxynitrostilbenyl groups, which constituted parts of the polymer backbones. Polymers 4-6 are soluble in common organic solvents such as acetone and N,N-dimethylformamide. They showed thermal stability up to 260 oC in thermogravimetric analysis with glass-transition temperatures obtained from differential scanning calorimetry in the range 90-95 oC. The second harmonic generation (SHG) coefficients (d33) of poled polymer films at the 1064 nm fundamental wavelength were around 1.42 ´ 10-9 esu. The dipole alignment exhibited high thermal stability up to 5 oC higher than glass-transition temperature (Tg), and there was no SHG decay below 100 oC due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.
Keywords
Citations & Related Records
Times Cited By KSCI : 8  (Citation Analysis)
Times Cited By Web Of Science : 6  (Related Records In Web of Science)
Times Cited By SCOPUS : 6
연도 인용수 순위
1 Kim, J.-H.; Lee, J.-Y.; Won, D.-S.; Rhee, B. K. Macromol. Res. 2007, 15, 506   과학기술학회마을   DOI   ScienceOn
2 Cullinane, N. M. J. Chem. Soc. 1923, 123, 2053   DOI
3 Cisneros, J. I. Appl. Opt. 1998, 37, 5262   DOI   ScienceOn
4 Herman, W. N.; Hayden, L. M. J. Opt. Soc. Am. B 1995, 12, 416   DOI   ScienceOn
5 Cho, M. J.; Kim, J. Y.; Kim, J. H.; Lee, S. H.; Dalton, L. R.; Choi, D. H. Bull. Korean Chem. Soc. 2005, 26, 77   DOI   ScienceOn
6 Moon, J. R.; Kim, B. S.; Kim, J.-H. Bull. Korean Chem. Soc. 2006, 27, 981   DOI   ScienceOn
7 Kim, M. H.; Jin, J.-I.; Lee, C. J.; Kim, N. J.; Park, C. H. Bull. Korean Chem. Soc. 2002, 23, 964   DOI   ScienceOn
8 Lee, J.-Y.; Kim, J.-H.; Won, D.-S.; Jang, H.-N. Bull. Korean Chem. Soc. 2007, 28, 1433   DOI   ScienceOn
9 Lee, J.-Y.; Kim, J.-H.; Jung, W.-T. Bull. Korean Chem. Soc. 2007, 28, 329   DOI   ScienceOn
10 Lee, J.-H.; Lee, K.-S. Bull. Korean Chem. Soc. 2000, 21, 847
11 Lee, S.-H.; Kim, Y.-K.; Won, Y.-H. Macromolecules 1999, 32, 342   DOI   ScienceOn
12 Renate, D.; Walter, M. F. F.; Dietmar, K.; Hans, J. Dyes and Pigments 1997, 34, 13   DOI   ScienceOn
13 Ambrosanio, P.; Centore, R.; Concilio, S.; Panunzi, B.; Sirigu, A.; Tirelli, N. Polymer 1999, 40, 4923   DOI   ScienceOn
14 Lee, J.-Y.; Jung, W.-T.; Lee, W.-J. Polym. Int. 2006, 55, 248   DOI   ScienceOn
15 Lee, C.; Park, S.-K.; Yang, M.; Lee, N.-S.; Kim, N. J. Bull. Korean Chem. Soc. 2007, 28, 447   DOI   ScienceOn
16 Han, K. S.; Park, S. K.; Shim, S. Y.; Jahng, W. S.; Kim, N. J. Bull. Korean Chem. Soc. 1998, 19, 1165
17 Han, K. S.; Park, S. K.; Shim, S. Y.; Lee, Y. S.; Jahng, W. S.; Kim, N. J. Bull. Korean Chem. Soc. 1998, 19, 1168
18 Cho, B. R.; Kim, Y. H.; Son, K. W.; Khalil, C.; Kim, Y. H.; Jeon, S.-J. Bull. Korean Chem. Soc. 2002, 23, 1253   DOI   ScienceOn
19 Marks, T. J.; Ratner, M. A. Angew. Chem. Int. Ed. Engl. 1995, 34, 155   DOI   ScienceOn