• Title/Summary/Keyword: hexagonal

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ZnO Nanoparticles with Hexagonal Cone, Hexagonal Plate, and Rod Shapes: Synthesis and Characterization

  • Kim, Sun-Young;Lee, In-Su;Yeon, Yun-Seon;Park, Seung-Min;Song, Jae-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.29 no.10
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    • pp.1960-1964
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    • 2008
  • The roles of coordinating ligands (TOPO, OA, HDA, and TDPA) for the synthesis of ZnO nanoparticles are investigated. Various shapes (hexagonal cone, hexagonal plate, and rod) and sizes (5-100 nm) of ZnO nanoparticles are prepared in relation to the coordinating ligands. The hexagonal shapes ($\leq$ 100 nm) are synthesized with TOPO and OA, while smaller size nanorods (5 ${\times}$ 30 nm) are with TOPO and TDPA. The relative intensities of two distinctive emission bands centered at 385 and 500 nm, which are related to the exciton and defect states, respectively, depend on the crystal qualities of ZnO nanoparticles affected by the coordinating ligands. The intense UV emissions with the reduced visible emissions are found in the monodisperse nanoparticles such as hexagonal cones and nanorods, suggesting that the monodispersity as well as the crystallinity is closely related to the coordinating ligands. The blue-shift of photoluminescence and absorption edge is observed in the nanorods, because the sizes of the nanorods are in the quantum confinement regime.

Relation between the Concentration of Hexagonal Boron Nitride Nano-Sheets Dispersed in Pure Water and Their Width and Height (초순수 용매 내 육방정 질화붕소 나노시트의 농도와 크기의 관계)

  • Cho, Dae-Hyun;Park, Miyoung;Ha, Seonghun
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.343-349
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    • 2019
  • According to a report in 2011, hexagonal boron nitride demonstrated good solubility in pure water, even without surfactants or organic functionalization. Hexagonal boron nitride nanosheets are an effective lubricant additive, and their solubility in pure water has motivated lubrication engineers to utilize aqueous solutions containing these nanosheets as water-based lubricants. In this study, we measure the width and height of the hexagonal boron nitride nanosheets dispersed in pure water by using the Zetasizer and atomic force microscopy. Without surfactants or functionalization, aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of hexagonal boron nitride nanosheets are synthesized via sonication-assisted hydrolysis. The Zetasizer provides only a one-dimensional size of approximately 410 nm, regardless of the concentration of the solution. Thus, it does not allow the estimation of the shape of the nanosheet. To acquire the three-dimensional size of the nanosheets, atomic force microscopy is employed. The aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of the hexagonal boron nitride nanosheets show average values of 740, 450, 700, and 610 nm in width, and 37, 26, 33, and 32 nm in thickness, respectively. No significant trend is observed between the concentration of the solution and size of the nanosheets. Therefore, when preparing a water-based lubricant, it may be appropriate to adjust conditions such as ultrasonication time rather than the concentration.

An Estimation of Shear Capacity of Hexagonal Masonry Walls Under Cyclic Loading (반복하중을 받는 육각형 블록 벽체 전단내력평가)

  • Chang, Gug-Kwan;Seo, Dae-Won;Han, Tae-Kyoung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.205-214
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    • 2010
  • Masonry structures have been used throughout the world for the construction of residential buildings. However, from a structural point of view, the masonry material is characterized by a very low tensile strength. Moreover, the bearing and shear capacity of masonry walls have been found to be vulnerable to earthquakes. In this study, to improve the seismic performance of masonry walls, hexagonal blocks were developed and six masonry walls made with hexagonal block were tested to failure under reversed cyclic lateral loading. This paper focuses on an experimental investigation of different types of wall with hexagonal blocks, i.e. walls with different hexagonal blocks and with different reinforcing bar arrangements, subjected to applied cyclic loads. The cracking, damage patterns and hysteretic feature were evaluated. Results from the hexagonal masonry wall were shown more damage reduction and less brittle failure in comparison to the existing rectangular masonry walls.

Parallel Processing Method for Generating Elemental Images from Hexagonal Lens Array (육각형 렌즈 어레이로부터 요소영상을 생성하기 위한 병렬 처리 기법)

  • Kim, Do-Hyeong;Park, Chan;Jung, Ji-Sung;Kwon, Ki-Chul;Kim, Nam;Yoo, Kwan-Hee
    • The Journal of the Korea Contents Association
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    • v.12 no.6
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    • pp.1-8
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    • 2012
  • According that most integral imaging techniques have used rectangular lens array, this integrated distribution of light is recorded in the form of a rectangular grid. However, hexagonal lens array gives a more accurate approximation of ideal circular lens and provides higher pickup/display density than rectangular lens array[4]. Using the parallel processing technique in order to generate the elemental imaging for hexagonal lens array, each pixel that compose the elemental imaging should be determined to belong to the hexagonal lens. This process is output to the screen for every pixel in progress, and many computations are required. In this paper, we have proposed parallel processing method using an OpenCL to generate the elemental imaging for hexagonal lens array in 3D volume date. In the experimental result of proposed method show speed of 20~60 fps for hexagonal lens array of $20{\times}20$ sizes and input data of Male[$128{\times}256{\times}256$] volume data.

THE ASSESSMENT OF ABUTMENT SCREW STABILITY BETWEEN THE EXTERNAL AND INTERNAL HEXAGONAL JOINT UNDER CYCLIC LOADING

  • Lee, Tae-Sik;Han, Jung-Suk;Yang, Jae-Ho;Lee, Jae-Bong;Kim, Sung-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.6
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    • pp.561-568
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    • 2008
  • STATEMENT OF PROBLEM: Currently, many implant systems are developed and divided into two types according to their joint connection: external or internal connection. Regardless of the connection type, screw loosening is the biggest problem in implant-supported restoration. PURPOSE: The purpose of this study is to assess the difference in stability of abutment screws between the external and internal hexagonal connection types under cyclic loading. MATERIAL AND METHODS: Each of the 15 samples of external implants and internal abutments were tightened to 30 N/cm with a digital torque gauge, and cemented with a hemispherical metal cap. Each unit was then mounted in a $30^{\circ}$ inclined jig. Then each group was divided into 2 sub-groups based on different periods of cyclic loading with the loading machine (30 N/ cm - 300 N/cm,14 Hz: first group $1{\times}10^6$, $5{\times}10^6$ cyclic loading; second group $3{\times}10^6$, $3{\times}10^6$ for a total cyclic loading of $6{\times}10^6$) The removal torque value of the screw before and after cyclic loading was checked. SPSS statistical software for Windows was used for statistical analysis. Group means were calculated and compared by ANOVA, independent t-test, and paired t-test with ${\alpha}$=0.05. RESULTS: In the external hexagonal connection, the difference between the removal torque value of the abutment screw before loading, the value after $1{\tims}10^6$ cyclic loading, and the value after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading was not significant. The difference between the removal torque value after $3{\times}10^6$ cyclic loading and after $3{\times}10^6$, and additional $3{\times}10^6$ cyclic loading was not significant. In the internal hexagonal connection, the difference between the removal torque value before loading and the value after $1{\times}10^6$ cyclic loading was not significant, but the value after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading was reduced and the difference was significant (P < .05). In addition, in the internal hexagonal connection, the difference between the removal torque value after $3{\times}10^6$ cyclic loading and the value after $3{\times}10^6$, and additional $3{\times}10^6$ cyclic loading was not significant. CONCLUSION: The external hexagonal connection was more stable than the internal hexagonal connection after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading (t = 10.834, P < .001). There was no significant difference between the two systems after $3{\times}10^6$, and additional $3{\times}10^6$ cycles.

The Analysis Study on Correlation between the Axis of Investigative·Enterprising(IE) in Holland Hexagonal Model and Job Value (Holland 6각형 모형의 탐구형·진취형(IE) 축과 직업가치와의 관계분석)

  • Choi, Seon-Hee;Cho, In-Soo;Seo, Seol-Hwa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.372-383
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    • 2017
  • This paper attempted to verify that Investigative Enterprising(IE) axis in the Holland hexagonal model can measure the internal and external job value. This study analyzed internal and external job values of 19 subjects who participated in the 150 Job cards classification test. The results of this study are as follows: First, the study group with Holland hexagonal model centered on the Investigative Enterprising type(IE) axis and artistic type(A) and social type(S) showed internal job value and supported the hypothesis. Second, the hypothesis that the group with the hexagonal model centered on the Investigative Enterprising(IE) axis and the bias toward the realistic type(R) and the conventional type(C) would pursue external job value was rejected. This is due to the Korean cultural context that pursues psycho-cultural value in Confucian culture. There is also a Holland hexagonal model that is not exactly distributed to the left of the Investigative Enterprising(IE) axis. Third, the group of amphibolic job value based on the Investigative Enterprising(IE) axis, and the Holland hexagonal model is expressed in artisic type(A), social type(S), realistic type(R), and conventional type(C) supported some hypotheses. This paper is the first to suggest that the Investigative Enterprising(IE) axis of the Holland hexagonal model can be used to measure job value, and the Holland hexagonal model can predict job value as well as career choice. This paper is intended to expand the foundation of the Holland theories, and to provide meaningful contribution to the basis for vocational studies.

Background Subtraction Algorithm by Using the Local Binary Pattern Based on Hexagonal Spatial Sampling (육각화소 기반의 지역적 이진패턴을 이용한 배경제거 알고리즘)

  • Choi, Young-Kyu
    • The KIPS Transactions:PartB
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    • v.15B no.6
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    • pp.533-542
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    • 2008
  • Background subtraction from video data is one of the most important task in various realtime machine vision applications. In this paper, a new scheme for background subtraction based on the hexagonal pixel sampling is proposed. Generally it has been found that hexagonal spatial sampling yields smaller quantization errors and remarkably improves the understanding of connectivity. We try to apply the hexagonally sampled image to the LBP based non-parametric background subtraction algorithm. Our scheme makes it possible to omit the bilinear pixel interpolation step during the local binary pattern generation process, and, consequently, can reduce the computation time. Experimental results revealed that our approach based on hexagonal spatial sampling is very efficient and can be utilized in various background subtraction applications.

Dependence of Ferroelectric Properties on the Crystalline Phases of HoMnO3 Thin Film (HoMnO3 박막의 강유전 특성의 결정상 의존성)

  • Kim, Eung-Soo;Kang, Dong-Ho
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.394-399
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    • 2006
  • Ferroelectric $HoMnO_3$ thin films were deposited on the Si(100) substrate at $700^{\circ}C$ for 2 hrs by metalorganic chemical vapor deposition (MOCVD) and post-annealed at 850oC by rapid thermal process (RTP). Electrical properties and crystalline phases of $HoMnO_3$ thin films were investigated as a function of postannealing time. Single phase of hexagonal symmetry with c-axis preferred orientation was obtained from $HoMnO_3$ thin films post-annealed at $850^{\circ}C$ for 5 min, while the c-axis preferred orientation was decreased with the increase of post-annealing time, and the thin films post-annealed at $850^{\circ}C$ for 15 min showed the mixture phases of hexagonal and orthorhombic symmetry. P-E (Polarization-Electric field) hysteresis loop of ferroelectric $HoMnO_3$ thin films was observed only for the single phase of hexagonal symmetry, but that was not observed for the mixture phases of the hexagonal and orthorhombic symmetry, which was discussed with the bond valence of Mn ion of crystalline phase. Leakage current density was dependent on the microstructure of thin films as well as the change of valence of Mn ion.

Surface Morphology Variation During Wet Etching of N-face GaN Using KOH (KOH를 이용한 N-face GaN의 습식 식각으로 인한 표면 변화)

  • Kim, Taek-Seung;Han, Seung-Cheol;Kim, Jae-Kwan;Lee, Ji-Myon
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.217-222
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    • 2008
  • Characteristics of etching and induced surface morphology variation by wet-etching of n-face n-type GaN were investigated using KOH solutions. It was observed that hexagonal pyramids were formed on the etched surface regardless of etching conditions. However, the size of the hexagonal pyramids was changed as the etching time and temperature increased, respectively. Initially, as the etching time and concentration of KOH solution increased, the hexagonal pyramid was observed to be dissociated into smaller pyramids. However, as the etching time increased further, the size of the hexagonal pyramids increased again, indicating that the etching of N-face n-type GaN by KOH solutions proceeded through the evolution of hexagonal pyramids, such as formation, dissociation and enlargement of pyramids. Furthermore, it was also observed that there is a correlation between the photoluminescence intensity of the etched surface and the value of root-mean-square roughness. The intensity of PL increased as the roughness value increased due to the enhancement of the extraction efficiency of the generated photons.