• The Korean Journal of Ecology
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• v.22 no.3
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• pp.139-144
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• 1999

In order to clarify ecological survival strategy of Rumex crispus community dominating under contaminated area of lower region of Kumho riverside including Chimsangyo (CS), Paldalgyo (PD), Talseochon (TS) and Kumhogyo (KH), we analyzed the content of heavy metals and inorganic matter and vegetative growth. R. crispus showed rapid formation of community by high growth rate, high T/R ratio and showed maximum T/R ratio at the contaminated area Talseochon. Nitrogen and phosphorus contents in R. crispus showed high value in shoot than that of root. T/R ratio of nitrogen and phosphorus showed 3.1∼3.6 and 1.5∼4.5 for the early growth stage, and 6.7∼17.3 and 3.9∼8.3 for the late one, respectively. The absorbed heavy metals by riot were translocated to shoot, the heavy metal content in shoot higher than those in root of Cu, Zn, Fe, and Pb for 3.6, 1.7, 1.5 and 4.8 times, respectively. Distribution ratio of the heavy metals in each organ showed 61∼85% and 15∼39% for shoot and root, respectively. R. crispus accumulated heavy metals in the order of Fe>Zn>Cu>Pb in shoot, and showed maximum values of Cu, Zn, Fe and Pb for 89.7, 376.6, 2946.1 and 13.2 ㎍/g dw, respectively at Talseochon in April. A physiological and morphological characteristics of R. crispus showed thickened leaf, increased water content above 80% and rapid growth of shoot. R. crispus showed ecological adaptation to the contaminated area by transportation of heavy metals and inorganic matter to shoot, and by accumulation of Ca ion in root.

• Korean Journal of Environmental Agriculture
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• v.37 no.2
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• pp.141-145
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• 2018

BACKGROUND: Agricultural soils are vulnerable from contamination of heavy metal derived from industrial waste. Monitoring on heavy metals on agricultural soils around industrial complexes and evaluation on distributional state on the concentrations of heavy metals in soil have been carried out for problem assessment on soil condition. METHODS AND RESULTS: Soil samples of 1,200, were collected from sixty site of industrial complexes located Gyounggi, Chungbuk, Cheonbuk, and Gyoungnam provinces. Total concentration of Cu, Pb, Zn, Ni, and As were analyzed. Heavy metal concentrations in most soil samples were below warning criteria, except 1 site of Pb, Ni, and As, separately. The comparison of mean values of heavy metal concentrations between soils around industrial complexes and paddy soils, showed similar levels of heavy metals, except Pb. The concentrations of lots of heavy metals were distributed between from warning criteria to one fifth level of warning criteria. However, in the case of Cu and Pb, more than 30% were distributed below one twenties level of warning criteria. These results were very similar with the distribution state of heavy metals in upland soils. The concentrations of heavy metals in surface soil and subsoil were similar among the heavy metals in soils around industrial complexes. CONCLUSION: The concentrations of heavy metals in soils around industrial complexes were distributed close to warning criteria. Long term and continous monitoring and evaluation on heavy metals in agricultural soils are required for food safety and sustainable soil management.

• Journal of Korea Soil Environment Society
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• v.2 no.3
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• pp.69-80
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• 1997

This investigation was conducted to provide information for characteristics of environmental pollution by the heavy metals from the abandoned gold mine in order to characterize the distribution patterns and environmental damages of the contaminants to the surrounding environment. Through analysis of CN, Cd, Cu, Pb, Zn, As, Cr, and Hg in a mine tailings, paddy soils, and stream sediments, the physico-chemical properties of the mine tailings and paddy soils were measured. The pH's were 5.4, 8.4 for the paddy soil and mine tailing, respectively. The maximum contents of CN, Pb, Cd, and As the in mine tailing were 99.98, 1,752.72, 31.88, and 298.50 mg/kg, respectively. The amounts of these ions were higher than the standard level of industrial area in Korea. The average content of CN and heavy metals in the paddy soils were higher than the background level of heavy metals in the unpolluted paddy soils around the mine. Especially, the contents of heavy metals in the paddy soils along the adjacent stream were higher compared to the paddy soil that was not influenced by the mine tailings. The contents of CN and heavy metals in the stream sediment close to the mine area were similar to those of the mine tailings, but decreased along the distance of the stream farther away from the tailings that was the source of these pollutants.

• Journal of Environmental Analysis, Health and Toxicology
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• v.21 no.4
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• pp.292-303
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• 2018

The particle sizes and heavy metal concentrations (Pb, Zn, Cu, Cd, Hg, As, Cr, Ni, Li, Al) of surface sediments of the Yeongsan River were analyzed to assess the distribution and pollution level of heavy metals. The distribution of particle sizes was dominated by sand in the upstream sites (MS1-MS7) and by silt loam in the downstream sites (MS8-ML3), but MS3 and MS6, located slightly upstream of the two weirs, were found to be loamy sand and silt loam, respectively. The concentrations of Pb, Zn, Cu, Cd and Hg were higher at the upstream sites, while As, Cr, Ni and Li were higher at the downstream sites. The heavy metals of crustal origin (As, Cr, Ni and Li) were strongly correlated with particle size, while the other heavy metals (Pb, Zn, Cu, Cd and Hg) were weakly correlated with particle size. Considering their concentrations, most of heavy metals were evaluated as having almost no toxic effects on benthic organisms, at all sites. In addition, anthropogenic contamination by the $I_{geo}$, EF and CF were found to have no impact at most sites, with only low levels of pollution at the others. Using the PLI method, the MS2 and MS3 sites, located upstream, were assessed to be affected by anthropogenic contamination. Most importantly, Zn, Cu and Hg were found to be the elements responsible for most pollution, and they were highest at the upstream sites, implying pollution by domestic sewage and urban discharge.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.239-244
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• 2014

BACKGROUND: Heavy metals contamination of soils in the vicinity of abandoned mines in South Korea has been investigated. However, PAHs contamination rarely has been studied. Both heavy metals and PAHs concentrations have been measured in this study. METHODS AND RESULTS: The samples of soil and sediment were collected from the vicinities of three abandoned coal mines and two abandoned metal mines for analysis of heavy metals contaminants and PAHs concentration from April to September 2012. After preparation of these samples following the Korean standard test method for soils, the concentrations of heavy metals contaminants and PAHs were measured using ICP-OES and GC-MS, respectively. It was observed that the concentration of Arsenic was above the concern level based on 'area 1' suggested by Korean soil conservation law, resulting that Arsenic is the main contaminant in these areas. Also Cd, Cu, Pb and Zn were observed as a partial contaminants. The concentrations of other investigated components including benzo(a)pyrene were less than the concern level. CONCLUSION: The correlation observed between Arsenic (as main contaminant) and PAHs concentrations suggested that the contaminant source and pathway are different for each other. The effect of mine activity on PAHs concentration was rarely observed.

• Journal of Korean Society on Water Environment
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• v.25 no.3
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• pp.404-410
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• 2009

In this study, research for physical and chemical characteristics were conducted through analysis of sediments, grading and heavy metals (e.g., Mn, Cu, Cd, Zn and Pb ) in sewers which are classified by drainage types. After that, cement solidification and yellow soil calcinations made heavy metals stabilized and then, ways of recycling it were examined. The grain size distribution of all sediments was relative graded. When evaluating heavy metal pollution through index of geoaccumulation (Igeo), Cu showed moderately pollution or strong pollution in forest and street site and Zn was assessed by moderately pollution in military, residential, and street site. Analysis of Pearson Correlation coefficient of heavy metal indicated that all items in street site have tight relationship respectively. Especially, Cd-Zn, Cu-Pb, Cu-Mn, and Pb-Mn have relationship at 99% confidence intervals in statistical analysis. Recycling it with cement solidification was satisfied with compressive strength standard under 55% deposit contents and Zn, Pb, Mn were stabilized effectively. If time and temperature plasticity and compressive strength would be standard, it is revealed that yellow soil calcinations is valuable aggregate when it has 50-60 Wt% contents. When considering economic feasibility and stabilization of heavy metals, cement solidification would be more appropriate than yellow soil calcinations as solution to recycling.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.2
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• pp.74-77
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• 2005

The injection of cement stabilizer is used as one of ways to stabilize soft sea-bottom. However, this method makes an argument for the possibility of releasing heavy metals from the cement stabilizer to the seawater. To investigate the effect of the cement stabilizer on the seawater, field measurements were carried out in Ocheon harbor of the Chunsoo Bay. Although the highest concentrations of dissolved heavy metals were found in the surface seawater of the injection point and the metal concentrations decreased with distances, the levels of heavy metals in all the seawater met the demand of environmental criteria of Korea, US and UK.

• Journal of the Korean earth science society
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• v.23 no.5
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• pp.406-415
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• 2002

Heavy metal concentrations (Cu(II), Zn(II), Pb(II) and Cd(II)) at field and upland soils were investigated with two extraction methods, 0.1mole L$^{-1}$ HCI extraction and HNO$_3$-HCIO$_4$ digestion, in order to estimate soil pollution and to understand their distribution and accumulation characteristics. Through an application of 0.1mole L$^{-1}$ HCI extraction method, the surface horizons of field soils were found to have higher concentrations of heavy metals (except Pb(II)) than those of upland soil. It was also seen that Cu(II), Zn(II) and Cd(II) were enriched in surface horizon of field soils, whereas upland soils did not show much difference across depth. When the method of HNO$_3$-HCIO$_4$ digestion was used, upland soils showed higher concentrations than those of other soils, and the distribution of heavy metals did not show much difference between horizons of all soils. From these results, it was recognized that, although total natural contents of heavy metals were the largest in upland soil, surface horizons of field soils became gradually polluted with heavy metals. Especially, Cd(II) is considered as a potential metallic pollutant in field soils because of its weak adsorption strength. Concentrations of heavy metals also seemed to be influenced by their adsorption characteristics. When we computed 0.1HCl$_{ext}$HNCL$_{dig}$ ratios to estimate the adsorption strengths of soil heavy metals, their adsorption strengths decreased on the order of Cu(II) > Zn(II)> Pb(II) > Cd(II). The distribution characteristics of heavy metals in field soil, especially Cd(II),are required more detail study because of its importance of land use and complicated mobilization characteristic.

• Environmental Engineering Research
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• v.18 no.3
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• pp.177-189
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• 2013

Studies were carried out on the speciation of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during rotary drum composting of water hyacinth (Eichhornia crassipes) for a period of 20 days. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for composting. This study concluded that, rotary drum was very efficient for the degradation of organic matter as well as for the reduction of mobility and bioavailability of heavy metals during water hyacinth composting. The results from the sequential extraction procedure of heavy metals shows that rotary drum composting changed the distribution of five fractions of Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr. The highest reduction in the bioavailability factors of Pb and Cd was observed during the process. The total concentration of Cu, Cr, and Cd was very low compared to the other metals (Zn, Mn, Fe, Ni, and Pb); however, the percentage of exchangeable and carbonate fractions of these metals was similar to other metals. These results confirmed that the bioavailability of metals does not depend on the total concentration of metals. From this study, it can be concluded that the addition of an appropriate proportion of cattle manure significantly reduced the mobile and easily available fractions (exchangeable and carbonate fractions) during water hyacinth composting in rotary drum.

• Resources Recycling
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• v.16 no.2 s.76
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• pp.32-39
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• 2007

The measurement of physicochemical properties of ASR incineration ash has been carried dot and the preparation of light-weight material has also been performed using ASR ash for recycling point of view as building or construction materials. For this aim, chemical composition, particle size distribution, and heavy metal leachability were examined for 2 bottom ashes and 4 fly ashes obtained from the domestic ASR incinerator. In the present work, attempt has been made to prepare the lightweight material using boiler ash as a raw material, which is prepared by forming the mixture of boiler ash, lightweisht filler and inorganic binder and followed by calcination at elevated temperature. As a result, the content of Cu in bottom ash was as high as about 3wt% so that the recovery of Cu from ash was required. The major compound of SDR #5 and Bag filter #6 was found to be $CaCl_2{\cdot}Ca(OH)_2{\cdot}H_2O\;and\;CaCl_2{\cdot}4H_2O$, respectively. It is thought that heavy metal teachability of lightweight material prepared with boiler ash was significantly decreased due to the encapsulation or stabilization of heavy metal compounds.