• Title/Summary/Keyword: heavy metal and As

Search Result 2,488, Processing Time 0.033 seconds

Heavy Metal Concentrations in Three Shorebird Species in Saemankeum Mudflat, Korea (대한민국 새만금 갯벌지역에 도래하는 도요류 3종의 중금속 농도)

  • Lee, Hwa-Su;Kim, Jung-Soo;Koo, Tae-Hoe
    • Korean Journal of Environment and Ecology
    • /
    • v.22 no.3
    • /
    • pp.241-248
    • /
    • 2008
  • We studied concentrations of trace elements such as iron, zinc, copper, lead and cadmium in three shorebird species from Saemankeum mudflat, Korea$(1999{\sim}2000)$, and also analysed correlations between elements in livers. Iron(ANOVA, p=0.018), copper(ANOVA, p=0.043), lead(ANOVA, p=<0.001) and cadmium (ANOVA, p=0.016) concentrations significantly differed among shorebird species, but zinc concentrations wasn't different among species. We suggested that iron, zinc, and copper concentrations were within a range for normal and are maintained by normal homeostatic mechanisms for wild birds. Lead concentrations in Great Knots Calidris tenuirostris$(5.76{\pm}2.14{\mu}g/dry\;g)$ were at the background level but Red-necked Stints Calidris ruficollis$(29.4{\pm}10.6{\mu}g/dry\;g)$ and Terek Sandpipers Xenus sinereus$(15.9{\pm}11.9{\mu}g/dry\;g)$ were within the exposed level for wild birds. In particular, Red-necked Stints were nearly poisoned level. Cadmium concentrations in Terek Sandpipers and Great Knots were at the background concentration, but Red-necked Stints were greater than the poisoned level$(3{\mu}g/dry\;g)$. We found significantly correlations between lead and cadmium concentrations, but other elements didn't find.

Adsorption of nitrate from contaminated sea water with activated dredged sediment (오연해수로부터 질산염의 제거를 위한 개질 퇴적물의 흡착특성)

  • Song, Young-Chae;Woo, Jung-Hui;Jung, Eun-Hye;Go, Sung-Jung;Kim, Dong-Geun;Park, In-Seok
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
    • /
    • v.29 no.1
    • /
    • pp.311-316
    • /
    • 2005
  • A laboratory study on the adsorption of nitrate contaminated in nearshore water using various materials including several types of dredged sediments(ST) and yellow clays(YC), which are activated by hear(HT), bioleaching for heavy metal removal(BL) and neutralization(NR) was performed. The equilibrium time of the adsorption for the sediment bioleached and treated by heat(BL-HT-ST) was only 17min. which was faster than the sediment bioleached, neutralized and treated by heat(BL-NR-HT-S) (25min) or the sediment treated by the bioleaching process(BL-ST)(27min), but longer equilibrium times for yellow clay(YC) or heat treated yello clay(HT-YC) were required. The adsorption processes of nitrate in sea water for tested material could be described by Freundlich isotherm, but were significantly affected by surface characteristics of the materials. The adsorption capacities for raw sediment and heat treated sediment were 2.12, 2.19mg $NO_{3}$-N/g, respectively, which were higher than others, indicating that the sediment activated by heat could be used as a material for the improvement of nearshore water quality.

  • PDF

Fish Farm Performance of Copper-alloy Net Cage: Biological Safety of Red Sea Bream Pagrus major Rearing the Copper-alloy Net Cage (동합금가두리망에서 사육한 참돔, Pagrus major의 생물학적 안전성)

  • Shin, Yun Kyung;Kim, Won-Jin;Jun, Je-Cheon;Cha, Bong-Jin;Kim, Myoung-Sug;Park, Jung Jun
    • Korean Journal of Ichthyology
    • /
    • v.29 no.1
    • /
    • pp.41-51
    • /
    • 2017
  • To understand the application in farm for the fish aquaculture, we investigated biological and pathological traits on red sea bream Pagrus major which were reared in each copper-alloy net cage and the synthetic fiber net cage for 9 months. Two groups of cage were made and set in Yokji-eup, Tongyoung, Gyeongsangnam-do in size of 25 m in diameter and 10 m of depth. Survival rate of the red sea bream in the rearing copper-alloy net cage and synthetic fiber cage showed 99.75% and 99.70% respectively, there was no significant difference. Daily weight growth rate in each net was shown to 2.13 g/day and 1.65 g/day. Health analysis by blood composition analysis showed a favorable result in the copper-alloy net cage rather than in the synthetic fiber net. Bioaccumulation of heavy metal such as Cu and Zn especially in gonad was higher than other organ. Bioaccumulation of Cu and Zn in the muscle was lower compared to the permitted standard for food safety. Pathogenic infection test discovered Microcotyle tai for parasite, V. alginolyticus and other five species for bacteria. But there was a little bit difference of bacteria infection in copper-alloy net cage and copper-alloy net cage is expected to be has antibacterial effect. Thus, copper-alloy net cage can be applied to farm considering its system stability, recycling, antibiosis and food safety.

Bacterial Productivity and Degradability of Organic Compounds in the Coastal Area of East Sea (동해 연안역의 박테리아 생산력과 유기물질의 분해능)

  • 이기성;고동규;김근호;이영근;최청일;최영길
    • Korean Journal of Environmental Biology
    • /
    • v.17 no.1
    • /
    • pp.59-69
    • /
    • 1999
  • Bacterial population, signal compounds of pollution, bacterial productivity, heterotrophic activity and the activities of extracellular enzymes were analyzed four times from July 1994 to April 1995 at Daejin, Galnam, Pohang, and Ulsan in the coastal area of Bast Sea in order to investigate the state of eutrophication. The population of heavy metal resistant bacteria in Pohang was the highest among all stations. The bacterial populations which could utilize C -P compounds (phosphonate) showed the highest at Pohang that was expected for the industrial and agricultural effluents to inpour. It could be useful as an index of expectation about the influx of industrial sewages and agricultural effluents. The activities of extracellular enzymes for the degradation of organic matter were the highest in the Ulsan Chuyongam, but low in Daejin. These results showed positive relationship with the population of heterotrophic bacteria and bacterial productivity The ratio of poly-P and DNA in Pohang was the highest, and that in Ulsan, Galnam, and Daejin consecutively, corresponding with the distribution of heterotrophic bacteria. In case of the heterotrophic activities, each of the stations gives difference of seasonal variation in heterotrophic activities. Bacterial productivity seemed to be dependent on seasons; the highest in summer and the lowest in fall and winter. These seasonal variations of bacterial productivity seems to be similar with those of heterotrophic bacteria. It is suggested that the state of eutrophication could be evaluated by the criteria of the population sizes and the productivities of microorganisms, the amount of poly-P, heterotrophic activity, the activities of extracellular enzymes, etc.

  • PDF

Adsorption of Pb(II) by Cherry (Prunus x yedoensis) Leaf-Derived Biochar (왕벚나무 잎으로 제조된 바이오차의 Pb(II) 흡착특성)

  • Lee, Myoung-Eun;Hwang, Kyu-Taek;Kim, Sun-Young;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.26 no.2
    • /
    • pp.33-41
    • /
    • 2018
  • Large amounts of leaves from street trees fall onto the streets annually and need to be cleaned and treated. Cherry trees are common street trees in Korea. The adsorption characteristics of Pb(II) by cherry leaf (CL) and cherry leaf-derived biochar (CB) were studied through a series of batch experiments. CB was produced through the carbonization of CL at $800^{\circ}C$ for 90 min. Carbonization increased the C content and pH value, while decreased H and O contents. Well developed pore structure was observed at the surface of CB. The pseudo-second order model better described the kinetics of Pb(II) adsorption onto CL and CB, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption. Fast adsorption rates and high adsorption capacities were obtained by the carbonization from CL to CB. Langmuir models better adequately described the Pb(II) adsorption onto CL and CB. Maximum adsorption capacities of Pb(II) expressed by Langmuir constant, $Q^0$ were 37.31 mg/g and 94.34 mg/g, when CL and CB were used as adsorbents, respectively.

Field Applicability Evaluation Using Effective Microorganism Brewing Cycle for Contaminated Soil in Water Retention Basin (복합발효미생물을 이용한 하천유수지 오염토의 현장적용성 평가)

  • Shin, Eunchul;Jung, Minkyo;Kim, Kyeongsig;Kang, Jeongku
    • Journal of the Korean GEO-environmental Society
    • /
    • v.17 no.11
    • /
    • pp.35-43
    • /
    • 2016
  • In this study, by using a Effective Microorganisms Brewing Cycle, it confirmed the purification effect of pollutants that are adsorbed on the basins stench removal and retarding soil. On the basis of on-site application test, a soil decontamination system will be suggested. Using a Effective Microorganisms Brewing Cycle, the odor concentration is reduced 2.5 times than that of natural purification treatment method. It was measured and found that the quality of the pore water discharged from the soil is improved. In addition, it was found that a composite of copper and lead with the fermentation microorganisms adsorbed on soil particles from the surface of the stirred experiments lagoon mixed soil is reduced to 65% and 66%, respectively, The TPH organic component was confirmed that the reduction effect of 85%. Restoration of reservoir contaminated soils using the effective microorganism brewing cycle needs to be more developed and implemented as a long-term purification system. This study may be a good reference of developing more complete microorganism brewing system which will efficiently reduce the odor and soil contamination based on optimal stirring and mixing ratio of the compound solutions and contaminated soils in reservoir.

Comparison of Soil Extractants for Estimation of Cadmium, Zinc and Lead in Brown Rice Collected from Paddy Soils near Old Zinc-Mining Sites II. A prediction Model for Cadmium, Zinc and Lead Contents in Brown Rice Based on Some Chemical Properties of Soils (현미중(玄米中) 중금속(重金屬) 함량예측(含量豫測)을 위한 토양침출액(土壤浸出液)의 비교(比較) II. 토양분석(土壤分析)에 의(依)한 현미중(玄米中) 중금속(重金屬) 함량(含量) 예측(豫測))

  • Yoo, Sun-Ho;Park, Moo-Eon
    • Korean Journal of Environmental Agriculture
    • /
    • v.4 no.1
    • /
    • pp.31-36
    • /
    • 1985
  • In order to choose a suitable soil extractant for the prediction model of heavy metal content in brown rice, four extractants-0.1 M HCl, 0.1 M $HNO_3$, 0.1 M $NH_4$-oxalate and 0.001 M 2Na-EDTA, were compared by analyzing 84 soil and 45 brown rice samples collected from paddy fields adj-acent to five old zinc-mining sites. Content of cadmium and zinc in brown rice had the highest correlation coefficient to 0.001 M 2Na-EDTA and 0.1 M HCl extractants, respectively. However, the lead content in brown rice was significantly correlated with only 0.1 M $NH_4$oxalate solution. For the simultaneous prediction of zinc, cadmium and lead in brown rice, 0.1 M $NH_4$-oxalate solution was the most effective. On the multiple analysis by using various chemical characteristics of soils, pH and calcium content of soils were effective variables for the estimation of cadmium content in brown rice, while CEC and magnesium content were more effective for the estimation of zinc content in brown rice. Furthermore, for the estimation of lead content in brown rice, factors such as pH, CEC, calcium, magnesium, potassium and organic matter content were important variables in the multiple regression equation.

  • PDF

Cellular Immune Responses of the Manila Clam, Ruditapes philippinarum, Exposed to Cadmium Chloride (카드뮴에 노출된 바지락 (Ruditapes philippinarum) 의 세포성 면역 반응)

  • Park, Kyung-Il;Choi, Min-Soon;Park, Sung-Woo;Park, Kwan-Ha;Choi, Sang-Hoon;Yoon, Jong-Man
    • The Korean Journal of Malacology
    • /
    • v.25 no.2
    • /
    • pp.135-143
    • /
    • 2009
  • The Manila clam, Ruditapes philippinarum, has been considered as a sentinel species due to dominant distribution along the coast of Korea and well developed regulatory system. In order to develop and understand immune responses of the Manila clams, clams were exposed to $50\;{\mu}g/L$ of cadmium chloride (Cd) for 8 days and monitored the cellular immune parameters of the hemocytes including blast cell composition, DNA damage, necrosis, apoptosis and hemocyte mortality using a flow cytometer. The results showed that all immune parameters analyzed in the present study increased remarkably compared to the controls and the increases were statistically significant. Apoptosis rate was higher than necrosis rate in the clams exposed to Cd suggesting that apoptosis was preferably induced by the concentration of Cd used in the present study. Our study indicates that the measurement of cellular immune responses of the Manila clam using flow cytometer will be a useful technique for assessment of heavy metal contamination in marine environment.

  • PDF

Optimization of Conditions for the Preparation of W/O Emulsion Containing Eugenolchitosan (Eugenolchitosan 함유 유중수적형 유화 형성 조건 최적화)

  • Kim, Je-Jung;Chang, Pahn-Shick;Jung, Byung-Ok;Park, Dong-Ki
    • Korean Journal of Food Science and Technology
    • /
    • v.35 no.3
    • /
    • pp.423-428
    • /
    • 2003
  • Stabilities of W/O emulsions containing eugenolchitosan (EuCs) prepared from chitosan and eugenol were compared to determine the optimal conditions for the ratio of water (core phase) to corn oil (continuous phase), the concentration of EuCs, storage temperature, and the extent of homo-mixing. The optimal ratio of water to corn oil was 2:3 (w/w). The effects of EuC concentrations, and singular vs. binary system of emulsifiers on the storage stability of the emulsion were investigated with EuCs and polyoxyethylene sorbitan monolaurate. The emulsion was stable, showing more than 95% emulsion stability index (ESI) value, when the concentration of EuCs was more than 0.18% (w/v). ESI value of binary emulsifier system was almost equal to that of singular emulsifier system at the concentration of 0.18% (w/v). At this singular emulsifier system, the W/O emulsion formed by EuCs had ESI value of 100%. The optimal concentration of EuCs was determined as 0.18% (w/v). The highest stability of the emulsion was obtained from the homo-mixing at 11,000 rpm for 10 sec and the storage temperature ranging $25{\sim}65^{\circ}C$. EuCs produced from this study was mutagenecity-negative on Ames test and contained no heavy metal ions.

The Treatment of Heavy Metal Hydroxides by Crossflow-Microfiltration (정밀여과에 의한 중금속수산화물의 처리)

  • Yoo, Kun-Woo;Seo, Hyung-Joon
    • Clean Technology
    • /
    • v.8 no.3
    • /
    • pp.151-165
    • /
    • 2002
  • In the treatment of the wastewater containing metals($Cu^{2+}$, $Zn^{2+}$, $Ni^{2+}$, $Cr^{3+}$) by using batch precipitation and flocculation followed by membrane filtration, permeate flux and removal efficiency were investigated according to by the effect of pH and coagulants, and the type of membranes used and pore size. It was found that it is most effective to use $0.45{\mu}m$-polysulfone membrane and coagulant(PAC) at the conditions of the pH of 10.0~10.5 for the case of copper containing wastewater, $0.1{\mu}m$-PVDF membrane and coagulant(PAC) at the conditions of the pH of 10.0~10.5 for the case of zinc containing wastewater, $0.1{\mu}m$-PVDF membrane and coagulant at the conditions of the pH of 11.0~11.5 for the case of nickel containing wastewater, $0.2{\mu}m$ membrane and coagulant at the conditions of the pH of 8.0~8.5 for the case of chromic containing wastewater, and $0.2{\mu}m{\sim}0.45{\mu}m$ membrane and coagulant at the conditions of the pH of 11.0~11.5 for the case mixture wastewater. The permeate flux could higher as to be used coagulants except for the case of copper containing wastewater.

  • PDF