• Korean Journal of Environmental Agriculture
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• v.5 no.1
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• pp.11-23
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• 1986

Soils and rice plants in wastewater irrigated area of the Mangyeong River receiving waster from the Jeonju Industrial Complex and municipal sewage were sampled at two depths to assess the nature and content of Cd, Cu, Pb and Zn, particularly with respect to distance from wastewater source. For metal levels of soils in these area, no difference in the heavy metal contents between the surface and the subsurface soils was found. Total contents of Cu, Pb and Zn in soils were negatively correlated with distance from the source. A positive correlation was found between contents of total and 0.1N-HCl extractable or $1N-CH_3COONH_4$ extractable heavy metals in surface soils of these area. Total contents of heavy metals in soils were positively correlated with clay, soil organic matter and cation exchange capacity. Heavy metal contents of brown rice sampled at the Jeon-ju Industrial Complex area ranged from 0.15 to 0.91 ppm for Cd, from 1.13 to 5.68 ppm for Cu, from 0.22 to 7.16 ppm for Pb and from 11.74 to 38.66 ppm for Zn. Negative correlation was found between the contents of Cd, Cu, Pb, and Zn in the brown rice and the distance from the source. The contents of Cd, Cu and Zn in rice straw were positively correlated with those in the brown rice.

• Korean Journal of Environmental Agriculture
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• v.16 no.1
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• pp.55-60
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• 1997

Heavy metal-tolerant microorganisms, such as Pseudomonas putida, P. aeruginosa, P. chlororaphis and P. stutzeri which possessed the ability to accumulate cadmium, lead, zinc and copper, respectively, were isolated from industrial wastewaters and mine wastewaters polluted with various heavy metals. The distribution of heavy metal in the cell components, and amino acid compositions, was investigated. The distribution of heavy metal in the cell fractions of each heavy metal-tolerant microorganism grown for 20 hours in the basal medium containing 100mg/l of each heavy metal was investigated. In the case of cadmium-tolerant P. putida, lead-tolerant P. aeruginosa and copper-tolerant P. stutzeri, approximately $50{\sim}60%,\;30{\sim}40%$ and $10{\sim}17%$ of each heavy metal absorbed were distributed to cell wall, cell membrane and cytoplasm fractions, respectively. In the case of zinc-tolerant P. chlororaphis, approximately 32%, 55% and 13% of zinc were distributed to cell wall, cell membrane and cytoplasm fractions, respectively. These results indicated that the cell wall was a major adsorbing fraction of cadmium, lead and copper, and the cell membrane was that of zinc. Total amino acid content per gram of the cell grown in the culture media with heavy metal was higher than that of the cell grown in the culture media without heavy metal, and the content of acidic amino acids, such as aspartic acid(Asp.+Asn.) and glutamic acid(Glu.+Gln.) was higher than that of basic amino acids, such as histidine, lysine and arginine.

• The Korean Journal of Ecology
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• v.25 no.6
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• pp.379-382
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• 2002

The present study was to investigate Pb and Cd concentrations in tissues of feral pigeons in urban areas. The Pb levels in bones and livers did not differ between Seoul and Kwangju areas. However, there were significant differences in kidney and liver Cd concentrations between the study sites. These are thought to be a reflection of the metal exposure conditions in the local environment. In particular, metal levels from Seoul were compared with those obtained in the same area between 1991 and 2000 in terms of the long-term biomonitoring approaches. The mean Pb concentrations in bones decreased from 59.1 $\mu$g/wet g in 1991 to 29.5 $\mu$g/wet g in 2000, totaling a reduction in concentrations of approximately 50 percent. However, there were no significant differences in the liver Pb concentrations. Concentrations of Cd in livers and kidneys did not differ between 1991 and 2000.

• Korean Journal of Environmental Agriculture
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• v.25 no.4
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• pp.316-322
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• 2006

Objective of this research was to assess the release characteristics of metals from the mine tailing to base the prediction of metal load potential from tailing to soils. Water-soluble concentrations of Cd, Cu, Pb and Zn released from mine tailing after 2 hrs were 2.31, 129.38, 17.17, and 287.53 mg/kg, respectively, as compared to 1.6, 128, 108, and 142 mg/kg that were extractable by 0.1 M HCl. Kinetics of metal releases followed the power function model significantly indicating that more of water soluble fractions of those metals released at the initial short time, followed by a slow increase. Concentrations of metals released from tailing by water and 0.1 M HCl were in the orders of Zn > Cu > Pb > Cd. The breakthrough curve from the column experiment showed that concentrations of Cd, Cu, and Zn reached at highest after one pore volume, but that of Pb reached highest after five pore volumes when 0.1 M HCl was used as eluent. The release rate of Cd from mine tailing was the fastest but Pb was the slowest. The cumulative mass of metal released by 0.1 M HCl was in the order of Zn > Cu > Pb > Cd after nine pore volume elution.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.21-33
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• 2004

The objective of this study is to review of environmental assessment of heavy metals derived from various metalliferous mines in Korea. As a results of national wide research for heavy metal contaminations in the vicinity of metalleferous mines, the main contaminants are mine waste materials including tailings. From the materials, toxic elements including As, Cd, Cu, Pb and Zn can be dispersed into downstream through wind and water. Thus, soils around the mines contain elevated levels of those elements, which are over the guide values for environmental regulation of soils in Korea. Arsenic is one of the most important elements contaminated by mining activities, to a less extent, Cd, Cu, Pb and Zn. In spite of remediation works for some metal mines by the government, there are still lots of abandoned mines which are necessary for reclamation of mining sites. This study also includes that metal concentrations in soils and tailings can be varied upon various decomposition methods including 0.1N HC1 and aqua regia and sequential extraction scheme, with differences in each element, too. This may be due to geochemical characteristics of the elements, such as solubility, mobility and chemical forms in the geochemical environment. Finally, it is suggested that a certain organization should be runned by Korean government for management of abandoned mines.

• Journal of Environmental Science International
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• v.23 no.8
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• pp.1419-1428
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• 2014

Electron beam-induced grafting polymerization was employed to prepare Acrylic acid-grafted bacterial cellulose (BC-g-AAc). BC-g-AAc as an adsorbent was applied to remove heavy metals (e.g., As, Pb, and Cd). This study examined followings; morphological change of surface, adsorptive behavior of BC-g-AAc, and interpretation of adsorptive kinetics. Specific surface areas of BC and BC-g-AAc were $0.9527m^2g^{-1}$ for BC and $0.2272m^2g^{-1}$ for BC-g-AAc, respectively as measured by BET nitrogen adsorption, revealing the morphological change of the surface of BC-g-AAc. Batch adsorption test was performed to investigate adsorptive behavior of BC-g-AAc in aqueous solution. The amounts of Pb and Cd adsorbed on BC-g-AAc were $69mg\;g^{-1}$ and $56mg\;g^{-1}$, respectively. However, As was not adsorbed on BC-g-AAc due to its neutral nature. Both the Benaissa model and the Kurniawan model were applied in the study to interpret adsorptive kinetics. From the value of correction coefficient ($R^2$), adsorptive kinetics of Pb and Cd were subjected to Kurniawan model referred to pseudo-second-order. Taken together, the results of this study show that BC-g-AAc has potential as a heavy metal (eg., Pb, Cd)-adsorbent made of an environmentally friendly material.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.6
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• pp.449-453
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• 2009

This study focused on the content characteristics of regulated hazardous substances in specific wastes. Regulated heavy metal such as Cu, Pb, Cd analyzed the 108 waste samples that it choice from the representative facilities. Analytical method used content test method, suggested on the basis of analytical method of developing country, and the results as compared with limited standard in Austria Petroleum, primary metalworking and electronic industry had high content of Cu more than 100 mg/kg of Austria limited standard. Pb detected high level concentration the sample that dust producted at Primary metalworking industry. In case of total Cr was show that high content at KSIC 18, 19, 23 etc but result analyzed Cr(VI), it was shown that high level at dust producted from sewing clothes and fur industry.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.3
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• pp.225-232
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• 1998

In order to monitor the degree of heavy metal distribution in upland cultivations in Korea, both the cultivated soils and crops were collected from the 854 and 140 sites, respectively. The contents of cadmium (Cd), copper(Cu), lead(Pb), and zinc(Zn) in each sample were measured by Inductively Coupled Plasma(ICP) technique after 1N-HCl extraction. The content of Arsenic(As) was also measured with the same technique after 1N-HCl extraction. The average contents of heavy metal in surface soils(0~15 cm depth) were $0.135mg\;kg^{-1}$ for Cd, $2.77mg\;kg^{-1}$ for Cu, $3.47mg\;kg^{-1}$ for Pb, $10.7mg\;kg^{-1}$ for Zn, and $0.57mg\;kg^{-1}$ for As. Heavy metal contents of soil were similar to those values measured for upland soils in 1989, lower than soils under plastic film house in 1996. However, these contents were lower than "Countermeasure values for soil contamination"(Cd: 4, Cu: 125, Pb: 300, and As: $15mg\;kg^{-1}$ in soil) describled in Soil Environmental Conservation Act in Korea(1996). The contents of heavy metal in fresh vegetable, and root and tuber crops ranged $0.005{\sim}0.019mg\;kg^{-1}$ for Cd, $0.20{\sim}1.03mg\;kg^{-1}$ for Cu, $0.042{\sim}0.104mg\;kg^{-1}$ for Pb, and $2.0{\sim}4.0mg\;kg^{-1}$ for Zn, respectively.

• Korean Journal of Environmental Agriculture
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• v.29 no.1
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• pp.61-65
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• 2010

Phytoextraction is a method of phytoremediation using plants to remediate metal-contaminated soils. Recently, various chelating agents were used in this method to increase the bioavailability of metals in soils. Even though phytoextraction is an economic and environment-friendly method, this cannot be applied in highly metal-contaminated areas because plants will not normally grow in such conditions. This research focuses on identifying chelating agents which are biodegradable and applicable to highly metal-contaminated areas. Lead (Pb) as a target metal and cysteine (Cys), histidine (His), citrate, malate, oxalate, succinate, and ethylenediamine (EDA) as biodegradable chelating agents were selected. Ethylenediamine tetraacetic acid (EDTA) was used as a comparative standard. Plants were grown on agar media containing various chelating agents with Pb to analyze the effect on root growth. Cys strongly increased the inhibitory effect of Pb on root growth of plants, while, His did not affect on it significantly. The inhibitory effect of oxalate is weak, and malate, citrate, and succinate did not show significant effects. Both EDTA and EDA diminished the inhibitory effect of Pb on root growth. The effect of EDA is correlated with decreased Pb uptake into the plants. In conclusion, as biodegradable chelating agents, EDA is a good candidate for highly Pb-contaminated area.

• Fashion & Textile Research Journal
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• v.8 no.4
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• pp.458-464
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• 2006

The adsorption ability of heavy metal ions from the aqueous solution by chitosan, which it is well known natural biopolymer, has been investigated. The fundamental study in this research is focusing on the physicochemical adsorption utilizing the chitosan as a organic chelating adsorbent, adsorb especially heavy metal ions from the waste liquid solution. The adsorption ability of the chitosan between metal ions, having different characteristics with Mw of 188,600, 297,200, and 504,200 g/mol and degree of deacetylation (DD) of 86.92% and 100% were investigated targeting on the $Ni^{2+}$, $Co^{2+}$, $Zn^{2+}$, and $Pb^{2+}$ ions, respectively. The uptake of heavy metal ions with chitosan was performed by atomic absorption flame emission spectrophotometer (AAS) as conducted residual metal ions. It was found that chitosan has an strong adsorption capacity for some metals under certain conditions. Chitosan, which have 100% degree of deacetylation showed high adsorption recovery ratio and have an affinity for all kinds of heavy metals. In contrast, the molecular weight of chitosan was not completely affected on metal ion adsorption.