• 한국산림과학회지
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• 제88권4호
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• pp.429-437
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• 1999

대기오염지역에서 중금속오염의 영향을 파악하기 위해서 온산공단 주변에서 생육하고 있는 해송을 원판으로 채취하여 연륜 속의 중금속함량을 3년씩 나누어 분석하였다. 온산공단지역에서 연륜폭의 변화는 공장이 가동된 이후부터 감소하기 시작하였으며, 1991년 이후에는 급격한 감소현상이 나타나 해송의 가시적인 쇠퇴현상과 일치하였다. 온산공단지역 해송 연륜 속의 카드뮴 함량은 119.4ppb에서 867ppb로 나타났으며 1992년 이후에 급격히 증가하였다. 구리 함량은 최저 309.5ppb에서 최고 3686.8ppb로 나타났다. 납의 함량은 911.33ppb에서 7997.1ppb로 나타냈으며, 1970년 이후부터 증가하기 시작하여 공장가동 이후인 1980년 이후에는 증가폭이 컸다. 아연의 함량은 3528.7ppb에서 23826.7ppb로 나타났으며, 1960년 이후부터 큰 폭으로 상승하였고 1992년 이후에는 급 상승하는 경향이었다. 한편 비오염지역인 고성지역 해송 연륜 속의 중금속 함량은 모두 온산공단 지역보다는 많이 낮았으며, 특히 1990년 이후에는 차이가 컸다. 온산과 고성지역 해송의 수피에 축적되어 있는 중금속을 분석한 결과, 카드뮴 함량에서는 10배, 구리 함량에서는 1000배, 납 함량은 285배, 아연 함량에서는 133배의 차이를 나타내었다. 원판과 core의 분석에서는 일반적으로 core속의 중금속 함량이 높게 나타났으며, 특히 납에서는 차이가 컸다. 그러나 연륜별 증감의 패턴은 비슷한 경향을 나타내었다.

• 환경위생공학
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• 제9권2호
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• pp.110-119
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• 1994

The objective of the this study was to evaluate the effects of heavy metals on the sewage treatment process designed to remove organic material and nutrients using Water- hyacinth ( Eichhornia crassipes ). Batch experiments were carried out using domestic sewage spiked with different level of heavy metal mixtures ( Cd, Pb and Cu ). The specific growth rates of Water- hyacinth ranged from 0.0008 to 0.0015 1/day( operated at water temperatures of 22 ∼30$\circ $c ) and increased as the concentration of heavy metals decreased. The test result showed that the permissible maximum concentrations Cd, Pb and Cu for the growth of Water- hyacinth were 0.5, 1, and 6 mg/ℓ respectively. Under these maximum permissible heavy metal loads, removal rate of organic material, nitrogen and phosphorus were 85%,75% and 75% , respectively, during 40days of the test period.

• 한국식품영양과학회지
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• 제28권1호
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• pp.22-27
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• 1999

This study was performed to investigated the contamination levels of harmful heavy metals were sampled from Aug. 1 to Aug. 31, 1997, at 9 areas in Cheonbuk area. The heavy metal contents were determinated by ICPS(Inductively Coupled Plasma Spectrometer) method. The levels of total lead, cadmium, aluminum, iron and copper were determined and the results were summarized as follows: The minimum and maximum values(ppm) of 9 areas of Carassius auratus were Pb: 2.03~6.19, Cd: 0.06~ 0.76, Al: 8.84~23.5, Zn: 10.68~48.71, Cu: 0.60~1.51ppm. Among the five heavy metals contents, the highest was zinc and the lowest was cadmium. The results showed that the contents of Pb, Cd, Al, Zn and Cu in Carassius auratus were lower than the FAO/WHO maximum allowance.

• Journal of the Korean Wood Science and Technology
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• 제24권3호
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• pp.51-56
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• 1996

The Bark lignin(alkali- and acid lignin), bark extractives(hot water-and $Na_2SO_3$ extractives) of Quercus acutissima and Pinus densiflora, and flavonoids were used to detect heavy metal adsorption. The adsorption ratio of heavy metals by lignin was assigned for 40 to 50%, but was not dependent on lignin kinds. However, in case of the addition of light metals such as $Ca^{++}$ and $Mg^{++}$ to lignin the adsorption ratio was increased by 20 to 40%, and $Pb^{++}$ was almost completely adsorbed. On hot water extractives, the adsorption ratio was very low because the substrate was water-soluble, so the substrate should be water-insoluble to adsorb the heavy metals. However, the adsorption ratios of $Cd^{++}$ and $Pb^{++}$ on $Na_2SO_3$ extractives were significantly increased, while those of $Zn^{++}$ and $Cu^{++}$, were similar to lignin. When four kinds of heavy metals were treated to $Na_2SO_3$ extractives together, more than 97% of $Pb^{++}$ and $Cu^{++}$ was adsorbed_ and $Zn^{++}$ was more adsorbed by 40%, and $Cd^{++}$ was not changed, comparing with the case that on kind of heavy metal was treated. There were differences between adsorption ratio of the kinds of flavonoids and heavy metals, and the adsorption ratio of heavy metals was assigned to 20 to 45% per 0.1g flavonoid.

• 한국지하수토양환경학회지:지하수토양환경
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• 제18권1호
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• pp.85-93
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• 2013

This study is conducted to evaluate the leaching of contaminants from mine tailing by natural water and finally to estimate the leaching and transportation of heavy metal contaminants by rainfall. In order to identify contaminated heavy metal of soil, 17 soil, 2 tailing and 2 waste dump and 2 control samples were taken at mine area and analyzed total metal contents. The leaching experiments were conducted using distilled water. Cu, Pb, Zn was extracted from the reddish mine tailing in a short period time, especially the extraction rate of Cu (45.0%) was highest. The contaminants were leached from the yellowish mine tailing within an hour and the leaching rate of Cd (42.0%) and Zn (17.2%) were relatively high. The reddish soil from the waste dump showed leaching of Cu (5.1%), Pb (4.0%) and Zn (3.3%), however the leaching rate was low except Mi (14.2%). From the yellowish soil sampled from the dumping site, the leaching of Cu (8.2%) and Ni (9.7%) was high while the leaching of Zn (0.2%) were relatively low.

• Environmental Engineering Research
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• 제25권2호
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• pp.258-265
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• 2020

Heavy metal removal by using porous mineral adsorbents bears a great potential to decontaminate sludge compost, and natural zeolite (NZ), artificial zeolite (AZ), and expanded perlite (EP) seem to be possible candidates for this purpose. A composting experiment was conducted to compare the efficiency of those adsorbents for removal of iron (Fe), manganese (Mn), chromium (Cr), copper (Cu), zinc (Zn), nickel (Ni), and lead (Pb) from sewage sludge compost with no adsorbent amendment. For this purpose, 10 g of NZ and AZ and 5 g of EP was filled in a small bag made from non-biodegradable synthetic textile and was separately mixed in composting piles. The bags were separated from compost samples at the end of the experiment. AZ and NZ exhibited different reduction potentials depending on the type of heavy metal. AZ significantly reduced Cr (43.7%), Mn (35.8%), and Fe (29.9%), while NZ more efficiently reduced Cu (24.5%), Ni (22.2%), Zn (22.1%), and Pb (21.2%). The removal efficiency of EP was smaller than both AZ and NZ. The results of this simultaneous composting and metal removing study suggest that AZ and NZ can efficiently bind metal during composting process.

• 한국식품과학회지
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• 제37권4호
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• pp.519-524
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• 2005

국내산 소금과 수입산 소금의 무기질 및 중금속 함량의 차이와 이들 소금이 새우젓의 무기질 및 중금속 함량에 미치는 영향을 파악하였으며, 실제 시판되고 있는 새우젓을 산지별로 구입하여 무기질 및 중금속 함량을 분석하였다. 국산 천일염과 그것으로 제조한 새우젓은 중국산에 비해 Cu, K, Mg의 함량이 많았으며, 중국산 천일염과 그것으로 제조한 새우젓은 Mn, Na함량이 높은 것으로 나타났다. 그러나 시판새우젓에서는 산지에 따른 무기질의 차이가 나타나지 않았다. 중금속을 분석한 결과 시판 소금은 Pb, Hg 및 As는 검출되지 않았으나, Cd는 식품공전의 규정(<0.5ppm) 이하인 0.07-0.30ppm의 함량으로 검출되었다. 20 종의 시판 새우젓의 경우, Cd가 0.1 ppm(ND-0.5 ppm)의 함량으로 검출되었으며, 실험실 제조 새우젓의 경우, Pb이 0.3ppm(ND-0.8ppm)의 함량으로 검출되었으며, 다른 중금속(As, Hg, and Ni)은 검출되지 않았다.

• 한국환경농학회지
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• 제37권3호
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• pp.179-188
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• 2018

BACKGROUND: Reclamation of heavy metal-contaminated agricultural fields has intensively been done to ensure the soil quality and food security. This study evaluated the efficiency and longevity of current physical and chemical approaches for heavy metal-contaminated soils. METHODS AND RESULTS: Concentrations of 0.1 N HCl-leachable trace metals of Cd, Pb, and As from the stabilizing agents-treated soils decreased by 50%, 70%, and 40%, respectively, compared to the control. Among the stabilizing agents, the $CaCO_3$ was the best for stabilization. For physical stabilization, the soil dressing reduced the concentrations of Cd, Pb, and As by 88%, 94%,and 88%, respectively, compared to the control. Moreover, the dilution of the contaminated soils decreased the metals by an average of 25.3% when compared with the control. The longevity of each stabilization method was determined by using the availability assessment of heavy metals in the soils. Results showed that the leaching methods using HCl and $NH_4NO_3$ had 120 and 32 weeks longevity, respectively. Interestingly, any stabilization efficacy was not found over the time for Cd and Pb (i.e., cation metals), whereas the stabilization efficacy of As was sharply decreased under 50% after 32 weeks. However, the change of metal concentration was not significant with the physical stabilization compared to the chemical stabilization. CONCLUSION: The stabilization methods should carefully be selected based on long-term monitoring under climate conditions.

• 한국해양학회지
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• 제19권2호
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• pp.111-117
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• 1984

동해안의 임원, 새해안의 반월, 그리고 남해안의 진해만과 여수 등지에서 진주담치 시료를 채취하여 생체에 함유되어 있는 중금속함량을 1981∼82년에 걸쳐 조사하였다. 조사한 중금속은 Cd, Cr, Cu, Pb, Zn, Mn, Fe 등 7가지 였다. 시료채취시 시료는 깨끗한 해수에 담가 청장(depuration) 시키는 것이 좋으며 시간은 48시간 정도가 적당하였다. 진주담치 중의 중금속함량은 임원 해역의 자연산이 Cd, Cr, Cu 등이 특히 높았으나 Mn과 Fe 등은 조사 지역 중에서 가장 낮았다. 반면에 여수는 Pb, Mn, Fe 등의 함량이 높은 것으로 나타났다. 진해만 에서는 마산만 입구의 양식 진주담치도 중금속함량이 비교적 낮은 것으로 조사되었다. 그리고 중금속들은 Cu를 제외하고는 진주담치가 성장해 감에 따라 건증량 농도가 감소하는 것으로 나타났다.

• 한국해양학회지
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• 제14권1호
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• pp.1-5
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• 1979

최근에 들어 우리나라는 공업의 급속한 발달과 도시로의 인구집중 및 농약의 남용등으로 하천 및 연안오염이 크게 우려되고 있다. 특히 중금속은 지속성이 커서 일단 자연에 버려지면 바다로 들어가고, 또한 먹이사슬을 통해 생물농축 (Bioaccumulation)되어 결국에는 인간에게 돌아오기 때문에 연안의 중금속 오염현황 조사와 오염방지대책수립은 시급한 업무라 하겠다. 따라서 본 연구실에서는 우리나라의 연안오염 현황파악과 앞으로의 보다 조직적이고 체계적인 조사계획수립을 위해, 1977년 여름철에 주요연안인 묵호 삼척, 울산, 여수 광양, 목포, 군산, 인천해역 해수의 일반수질지수, 영양염류 그리고 중금속(Cd, Cu, Fe, Pb, Zn)의 농도를 조사하였다. 이중에 일반수질지수와 영양염류의 농도조사결과는 전보(이광우외, 1978) 에 발표하였고, 본보에는 중금속의 조사결과를 보고한다.