• Title/Summary/Keyword: heavy hydrocarbon

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Introduction of Fire Protection Technology and Its Design Method of Offshore Facilities (해양플랜트의 방화대책 및 설계기술 소개)

  • Koo, Myeong Jun;Choi, Jae Woong;Yoon, Ho Byung
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.49-57
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    • 2013
  • The dimensioning accidental loads have been selected through suitable quantitative risk assessment and generally utilized important factors for offshore facility design. The fire hazard can be quantified with dimensioning fire loads. The main purposes of fire protection are to maintain the functionality of safety systems within evacuation period and to prevent the escalation from initial fire to uncontrolled catastrophic fire. This paper introduces the applications and the design methods of active and passive fire protections as representative measures of fire protection of offshore facilities. The passive fire protection requires the high initial installation cost and much difficulty on the operation of facilities and their maintenance. The oil major clients have asked the design contractors of offshore facilities to optimize the amount of passive fire protection with relevant engineering technology recently.

Composition and Structure of Marine Benthic Community Regarding Conditions of Chronic Barbour Pollution

  • Fadeeva, N.P.;Bezverbnaja, I.P.;Tazaki, Kazue;Watanabe, Hiroaki;Fadeev, V.I.
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.21-30
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    • 2003
  • Seasonal fluctuations of physico-chemical and biological aspects of the environment were studied in Vladivostok harbour (Golden Horn Bay, the East Sea/Sea of Japan). The benthic community structure was described with a focus on size-spectra (bacteria, meio- and macrofauna) related with the chemical environment and chemical fluxes in sediment and to reveal their possible ecological role in the process of bioremediation of the environment. Samples from two sites with different concentrations of heavy metals (Fe, Zn, Cu, Pb, Mn, Cr, Ni Cd, Co) and petroleum hydrocarbon were assessed by a number of methods. These included plate counts of culturable bacteria, observation through a scanning electron (SEM) and transmission electron microscope (TEM). These approaches were complemented with microscopic assessments of the diversity of the benthic community. The specific communities had a limited number of species, tolerant to abnormally high levels of toxic compounds. The dominant species were presented by several sho.1-lived small polychaetes (Capitella capitata) and nematodes (Oncholaimium ramosum). The highest population density was recorded in microbenthos, in various diatoms, various physiological groups of bacteria which participate in biomineralization: marine heterotrophic bacteria, which oxidized oil, black oil in addition to groups resistant to heavy metals. They have the entire set of mechanisms for neutralizing the negative effect of those compounds, forming the detrital food web and biogeochemical circulation of material in sediments, which results in the biological self-recycling of sea basins. Macro- and meiobenthic organisms were more sensitive to a greater extent of $H_2S$ and petroleum hydrocarbons than to metal content, but the within-site rankings were the same as those achieved for microbiological analyses.

Study of the Performance of a Dry Cleaning Method for Polluted Ballast Gravel of Railroad Fields (철도부지 오염도상자갈의 건식 정화 기술 성능 연구)

  • Cho, Youngmin;Park, Duckshin;Kwon, Tae-Soon;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.552-557
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    • 2015
  • Ballast gravel in a railroad field is often polluted by grease and heavy metals. In this paper, the performances of a dry cleaning method for polluted ballast gravel in which pollutants on the gravel surface can be physically removed was extensively studied. A polluted ballast cleaning device able to shoot emery blasting media onto the surface using compressed air was prepared. Polluted ballast gravel was put into this device for cleaning, with the treatment time varied from 1 to 10 min. The cleaning efficiency of the total petroleum hydrocarbons and heavy metals were studied. The total petroleum hydrocarbon removal efficiency was 70-80% for gravels sampled from a locomotive waiting line, while it was 40-60% for gravels sampled from a turnout area. The heavy metal removal efficiency exceeded 90% for copper and lead, while it was 65-80% for nickel and zinc. This system was found to be effective for the remediation of polluted ballast gravels.

Applicability of Resistivity/Capacitance Measurement on CPT Module for Investigation of Subsurface Contamination (지반 오염도 조사를 위한 전기비저항/정전용량 측정콘의 적용성 평가)

  • Oh, Myoung-Hak;Kim, Yong-Sung;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.22 no.7
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    • pp.45-54
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    • 2006
  • Resistivity cone penetrometer test (RCPT) can be employed at a relatively low cost for in-situ delineation of subsurface contamination. While the resistivity measurement has a potential to investigate the subsurface contamination, resistivity measurements alone will lead to some degree of ambiguity in the results. In this study, capacitance measurement was incorporated into the RCPT to overcome the ambiguity inherent in electrical resistivity measurements. This study is focused on verifying the applicability of resistivity and capacitance measurements of CPT module to provide information on subsurface contaminated by heavy metal and petroleum hydrocarbon. Laboratory model tests were performed to evaluate the sensitivity of the measured resistivity and relative capacitance on the water content and different types of contaminants. Test results show that simultaneous measurement of electrical resistivity and capacitance can give more reliable information on subsurface contamination. Electrical measurements of the CPT module showed high applicability to be used in detecting saturated soils contaminated by heavy metal and diesel plume floating above the groundwater table.

A Study on Emission Reductions of Diesel Engine Using Plasmatron Fuel Converter (플라즈마트론을 이용한 디젤 엔진의 매연저감에 관한 연구)

  • Ki, Ho-Beom;Kim, Bong-Soo;Kwak, Yong-Hwan;Kim, Woo-Hyung;Lim, Won-Kyung;Chae, Jae-Ou
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.104-109
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    • 2006
  • Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.

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A Study on Experiment of CNG as a Clean Fuel for Automobiles in Korea

  • Chauhan, Bhupendra Singh;Cho, Haeng-Muk
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.469-474
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    • 2010
  • Gasoline engines have proven their utility in light, medium and heavy duty vehicles. Concern about long term availability of petroleum and the environment norms by the increased vehicular emission have mandated the search for safe fuel. CNG is an environmentally clean alternative to the existing spark ignition engines with the advantages of minimum change. A higher octane number and a higher self ignition temperature make it an attractive gaseous fuel. The thermal efficiency is better than gasoline for the same engine. The reduced carbon mono oxide, carbon di-oxide, hydrocarbon emissions is a favorable outcome along with a slight increase in $NO_x$ emission when compared with gasoline fuel to a dual fuel mode in the existing spark ignition engines. The result from the experiment shows that CNG could be a potential substitute fuel that maintains performance and emissions characteristics in gasoline engines.

An Experimental Study on the Emission Reduction of Duel-Fuel Engine by CNG (디젤기관에서 CNG혼소에 의한 배출가스 저감에 관한 실험적 연구)

  • 한영출;엄명도;오용석;이성욱
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.5
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    • pp.213-218
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    • 1997
  • CNG dual fuel engine for heavy duty diesel engine has been equipped to a Korean bus engine and tested to compare th engine performance and the emission characteristics with the existing diesel fueled engine. The results are summarized as follows. Diesel fueled engine has the fuel injection timing of BTDC17°. The injection timing of CNG modified engine is retarded to BTDC14° for reduction of NOx. Performance optimization has been carried out to have engine power equivalent to or better than the diesel fueled engine. Smoke is decreased by 85% by Korean smoke 3 mode test. By 6 mode test CO is increased by 313% and THC is increased by 1407%. NOx is decreased by 27%. Even though THC is increased very much, it's not too serious problem since CO and THC emission of diesel engine are very little compared to gasoline engine and THC don't give bad effect on human health. But the reduction technologies of CO and THC need to be considered.

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Changes on the Nature of Crude Oil and Heavy Fuel Oil exposed on the Sea Surface (해상에서 원유 및 중유의 경시변화 특성연구)

  • 김영희;이창섭
    • 한국해양학회지
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    • v.20 no.1
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    • pp.74-82
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    • 1985
  • Exposed on the sea, the oils are affected by the combined effects of evaporation, solution, chemical oxidation, and biological decomposition. Therefore the samples were taken after artificial weathering, and they were analyzed by gas chromatography for sulfur and hydrocarbons. The measurement results of gas chromatography have shown characteristic patterns. The peaks of the lower hydrocarbons in pollutant oil decreased with time. But the chromatograms for sulfur compound analysed by FPD showed little changes with lapse of time. The hydrocarbon and sulfur compound analysis by gas chromatography can be effectively used for analyzing oils for comparative identification.

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Physical remediation of ballast gravels contaminated by oil pollutants (도상자갈 표면 유류 오염물질의 물리적 제거방안 연구)

  • Cho, Young-Min;Lee, Jae-Young;Jung, Woo-Sung;Park, Duck-Shin;Kang, Hae-Sook;Kim, Hee-Man;Lim, Jong-Il
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.1386-1391
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    • 2007
  • The ballast gravels are often contaminated by various pollutants, like diesel fuel, lubricants, and heavy metals. Especially, the gravels near the switching are apt to be polluted by the lubricant. Because this lubricant can pollute the soil of track, the contaminated ballast gravels should be cleaned immediately. In this study, a physical desorption method was used to remove the oil contaminants from the surface of the ballast gravels. Thermosetting resin was used as a media for physical remediation of ballast gravels. The total petroleum hydrocarbon of the gravels was monitored over time. In addition, scanning electron microscopic images were obtained to observe the removal of the oily pollutants from the surface of the gravels.

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Carbon Containing Compositions

  • Mansurova, R.M.;Mansurov, Z.A.
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.2
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    • pp.5-15
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    • 2001
  • The experiment established optimal conditions for over-carbonization. With the use of the electron microscopy and X-ray phase analysis the regularities of carbon deposit formation in process of methane and propane pyrolysis on the zeolites, Kazakhstan natural clays, chrome and bauxite sludge containing metal oxides of iron subgroup, have been studied. In process of over-carbonization the trivalent iron was reduced to metal form. In addition, the carbon tubes of divers morphology had been impregnated with ultra-dispersed metal particles. The kinetic parameters of carbon formation in process of methane decomposition on the zeolite - CoO mixture surface were investigated by method of thermo-gravimetric analysis. The morphology and structure of formed carbon fibrils, with the metal particles fixed at their ends, have been investigated, the formation of branched carbon fibrils pattern, so called octopus, being found. Also, the walnut shells and grape kernel carbonization, their immobilization by the cells of selective absorption of heavy metal and sulfur dioxide ions have been studied. The example of metal-carbon composites used as adsorbents for wastewater purification, C$_3$- C$_4$ hydrocarbon cracking catalysts and refractory materials with improved properties have been considered.

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