• Journal of the Korean Ceramic Society
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• v.38 no.10
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• pp.928-935
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• 2001

In this study, two kinds of activated carbon fibers were prepared from PAN-based stabilized fibers by physical activation with steam. The variations in specific surface area, amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. The activated carbon fibers were prepared by two different methods, namely a 1- and 2-step method. For the 2-step method, carbonization of fibers in $N_2$ atmosphere was carried out to make carbon fibers and then activated by steam. In normal two step steam activation, BET surface area of about $1019m^2/g$ was obtained in the study. In the 1-step steam activation process, the carbonization and activation were simultaneously carried out. In the one step steam activation, BET surface area of $1635m^2/g$ was obtained after heat-treatment at $990^{\circ}C$. However, nitrogen adsorption isotherms for oxidized PAN based activated carbon fibers that were prepared by both methods were type I in the Brunauer-Deming-Deming-Teller (BDDT) classification even though they have different BET surface areas, amounts of iodine adsorption and pore size distributions.

• Corrosion Science and Technology
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• v.7 no.1
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• pp.50-60
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• 2008

The majority of the described experimental results deal with relatively pure aluminium. Variations were made in the pretreatment of the aluminum substrates and an investigation was performed on the resulting changes in oxide layer composition and chemistry. Subsequently, the bonding behavior of the surfaces was investigated by using model adhesion molecules. These molecules were chosen to represent the bonding functionality of an organic polymer. They were applied onto the pretreated surfaces as a monolayer and the bonding behavior was studied using infrared reflection absorption spectroscopy. A direct and clear relation was found between the hydroxyl fraction on the oxide surfaces and the amount of molecules that subsequently bonded to the surface. Moreover, it was found that most bonds between the oxide surface and organic functional groups are not stable in the presence of water. The best performance was obtained using molecules, which are capable of chemisorption with the oxide surface. Finally, it was found that freshly prepared relatively pure aluminum substrates, which are left in air, rapidly lose their bonding capacity towards organic functional groups. This can be attributed to the adsorption of contamination and water to the oxide surface. In addition the adhesion of a typical epoxy-coated aluminum system was investigated during exposure to water at different temperatures. The coating was found to quite rapidly lose its adhesion upon exposure to water. This rapid loss of adhesion corresponds well with the data where it was demonstrated that the studied epoxy coating only bonds through physisorptive hydrogen bonding, these bonds not being stable in the presence of water. After the initial loss the adhesion of the coating was however found to recover again and even exceeded the adhesion prior to exposure. The improvement could be ascribed to the growth of a thin oxyhydroxide layer on the aluminum substrate, which forms a new, water-stable and stronger bond with the epoxy coating. Two routes for improvement of adhesion are finally decribed including an interphasial polymeric thin layer and a treatment in boiling water of the substrate before coating takes place. The adhesion properties were finely also studied as a function of the Mg content of the alloys. It was shown that an enrichment of Mg in the oxide could take place when Mg containing alloys are heat-treated. It is expected that for these alloys the (hydr)oxide fraction also depends on the pre-treatment and on the distribution of magnesium as compared to the aluminium hydroxides, with a direct impact on adhesive properties.

• Journal of Conservation Science
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• v.32 no.4
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• pp.521-534
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• 2016

Ancient tombs are typically comprised of confined rooms, which have different spatial characteristics than the external environment because they are covered by heavy layers of soil. In this study, we examined the thermal energy flow from the outside to inside of Songsan-ri tomb No. 6. External heat flows slowly to the inside because of heavy soil layer, and the presence of several rooms and entrances. For this reason, it takes about two months for the air temperature to travel from the outside to the inside of the tomb. Interestingly, the gradational inflow of thermal energy from outside the tomb leads to delicate horizontal and vertical variations in the wall temperature. These micro-environmental differences occur in the inner tomb every year, so we can expect them to cause condensation with regularity. In addition, we show that the previously installed forced circulation air conditioning system risks fatal damage to the mural wall painting. The results of this research suggest an optimal air conditioning system and optimized space planning to conserve Songsan-ri tomb No. 6 and its mural painting.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.477-477
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• 2008

For more than three decades, the gate dielectrics in CMOS devices are $SiO_2$ because of its blocking properties of current in insulated gate FET channels. As the dimensions of feature size have been scaled down (width and the thickness is reduced down to 50 urn and 2 urn or less), gate leakage current is increased and reliability of $SiO_2$ is reduced. Many metal oxides such as $TiO_2$, $Ta_2O_4$, $SrTiO_3$, $Al_2O_3$, $HfO_2$ and $ZrO_2$ have been challenged for memory devices. These materials posses relatively high dielectric constant, but $HfO_2$ and $Al_2O_3$ did not provide sufficient advantages over $SiO_2$ or $Si_3N_4$ because of reaction with Si substrate. Recently, $HfO_2$ have been attracted attention because Hf forms the most stable oxide with the highest heat of formation. In addition, Hf can reduce the native oxide layer by creating $HfO_2$. However, new gate oxide candidates must satisfy a standard CMOS process. In order to fabricate high density memories with small feature size, the plasma etch process should be developed by well understanding and optimizing plasma behaviors. Therefore, it is necessary that the etch behavior of $HfO_2$ and plasma parameters are systematically investigated as functions of process parameters including gas mixing ratio, rf power, pressure and temperature to determine the mechanism of plasma induced damage. However, there is few studies on the the etch mechanism and the surface reactions in $BCl_3$ based plasma to etch $HfO_2$ thin films. In this work, the samples of $HfO_2$ were prepared on Si wafer with using atomic layer deposition. In our previous work, the maximum etch rate of $BCl_3$/Ar were obtained 20% $BCl_3$/ 80% Ar. Over 20% $BCl_3$ addition, the etch rate of $HfO_2$ decreased. The etching rate of $HfO_2$ and selectivity of $HfO_2$ to Si were investigated with using in inductively coupled plasma etching system (ICP) and $BCl_3/Cl_2$/Ar plasma. The change of volume densities of radical and atoms were monitored with using optical emission spectroscopy analysis (OES). The variations of components of etched surfaces for $HfO_2$ was investigated with using x-ray photo electron spectroscopy (XPS). In order to investigate the accumulation of etch by products during etch process, the exposed surface of $HfO_2$ in $BCl_3/Cl_2$/Ar plasma was compared with surface of as-doped $HfO_2$ and all the surfaces of samples were examined with field emission scanning electron microscopy and atomic force microscope (AFM).

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.11
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• pp.1145-1151
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• 2015

High pressure components of a gas turbine engine must operate for a long life under severe conditions in order to maximize the performance and minimize the maintenance cost. Enhanced cooling design, thermal barrier coating techniques, and nickel-base superalloys have been applied for overcoming them and furthermore, material modeling, finite element analysis, statistical techniques, and etc. in design stage have been utilized widely. This article aims to evaluate the effects on the low cycle fatigue life of the high pressure turbine nozzle caused by different turbine inlet temperature profiles and installation conditions and to investigate the most favorable operating condition to the turbine nozzle. To achieve it, the structural analysis, which utilized the results of conjugate heat transfer analysis as loading boundary conditions, was performed and its results were the input for the assessment of low cycle fatigue life at several critical zones.

• Korean Journal of Materials Research
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• v.10 no.11
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• pp.760-769
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• 2000

Mechanical properties of HSLA cast steels alloyed with 0.15% Nb, Ti or V were tested as variations of austenizing temperatures and tempering times. The test results are as follows. The hardness of HSLA cast steels austenized for 2hrs at 115$0^{\circ}C$ was shown the highest value regardless of alloying elements and then decreased as the temperature decreased below 110$0^{\circ}C$. The hardness of HSLA cast steels with 0.15% Ti austenized for 2 hrs at $1150^{\circ}C$ was higher than that of any other HSLA cast steels, and chich was mainly attributed to the relatively high amount of bainite, and solid solution hardening. Charpy impact energy of HSLA cast steels was comparable to the C-Mn cast steel except HSLA cast steels with 0.15% Ti austenized at 115$0^{\circ}C$. The hardness of HSLA cast steels austenized for 2 hrs at $1150^{\circ}C$ increased at a ten-minute tempering, and after that, the hardness kept almost sililar level except HSLA cast steels with 0.15% V.

• Journal of Environmental Science International
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• v.3 no.2
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• pp.111-128
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• 1994

The distributions of sea surface temperature across the Cheju Strait and the Korea Strait have been measured by using a thermometer installed on board No.1 Cheju, a ferry that operates regularly between Pusan and Seogwipo. The data from 14 October 1991 to 15 August 1992 were analyzed in this paper. A clear temperature front is wormed at the adjacent sea of Geomundo, and its position is not fixed and moves north and south. The slow northward movement of the front can easily be traced, but the southward movement from March to October is obscure. The temperature contrast in the Cheju Soait and the Korea Strait is very we in this period. Some periodical fluctuations with a period of several tens of days are observed in the region of the temperature front from November to February. This fluctuation seems to be caused by winter heat flux exchange and the strong southeastward wind force. The result shows that continous observation of the sea surface temperature distribution across the Cheju Strait and the Korea Strait yields a good method for monitoring the presence of Tsushima Warm Current and the fluctuations of South Korea Coastal Water. The formation and structure of shelf front in the Cheju Strait and the Korea Strait was analysed based on the detailed oceanographic data observed during the period of 1990-1992. The analysis shows that well-defined fronts were formed through yearly around the Chuja Island, particularly, in summer. In nature, its structure and formation position can be changed easily from year % year and by season. But, in region of the Korea Strait this front is relatively weak.

• Journal of the Microelectronics and Packaging Society
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• v.16 no.2
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• pp.43-50
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• 2009

Although thin PCBs(Printed Circuit Boards) have recently been required for high density interconnection, high electrical performance, and low manufacturing cost, the utilization of thin PCBs is severely limited by warpage and reliability issues. Warpage of the thin PCB leads to failure in solder-joints and chip. The $B^2it$(Buried Bump Interconnection Technology) for PCB has been developed to achieve a competitive manufacturing price. In this study, chip temperature, package warpage, chip stress and solder-joints stress characteristics of the PCB prepared with $B^2it$ process have been calculated using thermo-mechanical coupled analysis by the FEM(Finite Element Method). FEM computation was carried out with the variations in bump shapes and kinds of materials under 1.5W power of chip and constant convection heat transfer. The results show that chip temperature distribution reached more quickly steady-state status with PCB prepared with $B^2it$ process than PCB prepared with conventional via interconnection structure. Although $B^2it$ structures are effective on low package warpage and chip stress, with high strength bump materials arc disadvantage for low stress of solder-joints. Therefore, it is recommended that optimized bump shapes and materials in PCB design should be considered in terms of reliability characteristics in the packaging level.

• Korean Journal of Materials Research
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• v.11 no.2
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• pp.94-103
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• 2001

SiO$_2$ and PDMS/SiO$_2$ xerogels which are derived PDMS into TEOS have been synthesized by sol-gel process and controlled pore size and distribution through 2 step acid/base catalyzed processes using HCI and NH$_4$OH as a catalyst. In HCl catalyzed SiO$_2$ and PDMS/SiO$_2$ xerogels, pH and gellation time of xerogel were 2.3~2.5 and 12~13 days, respectively, and the shape of xerogel was identified to pellet type and column type. Under acidic condition of final reaction solution, the hydrolysis rate is accelerating, resulting in long gel times. The shape of xerogel is pellet type. In contrast, under less acidic condition, the condensation rate is accelerating, resulting in shorter gel times and the shape of xerogel is column type. The surface area and average Pore size were changed 400$\rightarrow$600($\m^2$/g) and 15$\rightarrow$28$\AA$, respectively, depending to the increase of the mole ratio of HCl/NH$_4$OH, and represented uniform pore size distribution. It is that all the alkoxide groups are hydrolyzed by HCl after the first step and the condensation rate is enhanced by NH$_4$OH. The regular backbone structures of silica are formed at low temperature and the uniform pores are produced by heat treatment.

• Journal of the Korea Convergence Society
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• v.12 no.12
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• pp.145-151
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• 2021

This study aimed to investigate the efficient conduct of HA coating on Ti Gr4 for the practical use of medical device. Ti Gr4 alloy specimens measuring 𝜱 25mm × 1mm were sprayed with hydroxyapatite using thermal spray according to ASTM F1185-88. The surface was evaluated at #120, #400, #1,000 sandpaper and barrel finishing. Each coating properties was analyzed using SEM, UTS 20,000psi cap. and in vitro cytotoxicity. Surface morphology consists of well molten particles with very little resolidified or unmolten areas. The average Ca/P ratio is 1.74 which is in good agreement with theoretical value of 1.67. The average roughness Ra is very representative of roughness of specimen. The coatings are dense and well adhered to the substrate. The average bond strength was 61.74 MPa with a standard deviation of 4.06 which indicates fairly reliable results for ASTM 633 type tests. Variations in results from jig design, epoxy used, crosshead speeds etc. in vitro cytotoxicity result had a Grade 3. The results of the study are expected to be helpful in osseointegration and plasma-spray HA coated Ti Gr4 are more satisfactory in HA coating thickness elevation which is preferable to any other system.