• Title/Summary/Keyword: heat of hydration heat

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Hydration Reaction Properties of Concrete With Binders and Admixtures (결합재와 혼화재 종류에 따른 콘크리트의 수화반응 특성)

  • Cho, Il-Ho;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.2
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    • pp.27-34
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    • 2008
  • Recently, owing to the development of industry and improvement of building techniques, concrete structures are becoming larger and higher. This study was performed to analyze hydration reation properties of concrete with binders and admixtures, such as OPC, low heat cement, belite rich cement, slag powder, lime powder and fly ash. To investigate effects of PC type superplasticizer on the hydration, experiments involving FT-IR, XRD, DSC, SEM were analyzed at the curing age 1day, 3days and 28days. The hydration reaction rate of OPC concrete slightly delayed at the curing age 1day, blast furnace slag powder and fly ash were more effective. BRC and LHC concretes can be used for concrete structures in winter season.

Early Hydration of Tricalcium Silicate(III) (Tricalcium Silicate의 초기수화반응(III))

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.385-391
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    • 1987
  • Zeta potential according to the hydration time was studied during the early hydration of C3S with and without CO2 atmosphere. Zeta potential was low as a level of 20mV at the first and second exothermic peaks of heat evolution, but it was rapidly increased up to a level of 300mV. In the CO2 atmosphere, zeta potential was level of 60mV at 10 minutes hydration and it's value became a low gradually according to the hydration time. Zeta potential was also proportioned to the Ca2+ concentration in the liquid phase, i.e., there was positive correlation between zeta potential and Ca2+ concentration. The existence of silicate layer was not found out on the hydrated C3S in the CO2 atmosphere by SEM-EDAX.

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Analytical Estimation of the Performance of Marine Concrete with Mineral Admixture (광물질 혼화재를 혼합한 해양 콘크리트의 해석적 성능 평가)

  • Lee, Bang-Yeon;Kwon, Seung-Jun;Kang, Su-Tae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.301-306
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    • 2015
  • For the purpose of developing high performance marine concrete with improved crack resistance and durability, this analytical study aimed to estimate strength, hydration heat characteristics, and chloride attack resistance of concrete with mineral admixture. Ground granulated furnace slag and fly ash were considered for mineral admixture. The replacement of ground granulated furnace slag and fly ash considered in the analysis was in the range of 0~70% and 0~40 %, respectively. The analysis results indicated that both ground granulated furnace slag and fly ash decreased compressive strength, and the effect of adding ground granulated furnace slag on mitigation of hydration heat was limited whereas fly ash had an noticeable influence on it. It was also found that the replacement with ground granulated furnace slag enhanced the chloride attack resistance but fly ash deteriorated the resistance. From the analytical studies, It could be expected that a ternary blended cement composition with proper amount of ground granulated furnace slag and fly ash might be effective to control crack resistance as well as chloride attack resistance of marine concrete.

A Study for Control of Thermal Cracking by Heat of Hydration in Subway Concrete Box Structure (지하철 콘크리트 BOX 구조물의 수화열에 의한 온도균열 제어 방안 연구)

  • Song, Suk-Jun;Yoo, Sang-Geon;Park, Ji-Woong;Kim, Eun-Kyum
    • Journal of the Korean Society for Railway
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    • v.12 no.6
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    • pp.1024-1029
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    • 2009
  • According to increase of massive concrete structures, Thermal crack done by heat of hydration have been increased in a process of the execution. In case of a subway concrete box structure, thickness of structures are almost over 1 meter, and penetrating crack by external restraint takes a bad effect on the durability with a water leakage and deterioration in especially concrete wall. A try of shortening a constructing period often occurs as subway is generally constructed according to a road to decrease a traffic jam. The research proposes executing method by skipping one block as a plan of shortening a constructing period and investigate an influence on thermal cracking control. Additionally, sensitivity analysis is accomplished by changing a height of a concrete wall, and concrete placing and air temperature met with a field condition.

Innovative Transient Thermal Gradient Control to Prevent Early Aged Cracking of Massive Concrete (매스콘크리트의 열경사 조절에 의한 수화열과 온도균열의 방지)

  • Kim, Seong-Soo;Cho, Tae-Jun;Lee, Jeong-Bae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.164-172
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    • 2008
  • The heat of hydration for early aged mass concrete induces high temperature with the hydration. Control of the temperature difference across a section is an effective strategy to minimize the hydration heat induced cracks for the structures where internal restraint is dominant. The current prevention methods for hydration cracking show some limitations for the control of thermal gradients, and these limitations could make micro and macro cracks in surface and core of concrete. Especially cooling methods can decrease the increasing hydration temperature, but it can not prevent the problem while decreasing temperature. Consequently heating pipes are added simultaneously with the cooling pipes in order to control the temperature gradients between core and surface of the concrete, followed by the finite element analysis (FEA). Based on the FEA, the proposed method using cooling pipe and heating pipes together has been found to be an effective alternative in thermal gradient control, in terms of controlling temperature induced cracks significantly.

Properties of the Super Flowing Concrete Using Crushed Stone Fines (쇄석분을 사용한 초유동콘크리트의 특성에 관한 연구)

  • 이승한;정용욱
    • Journal of the Korea Concrete Institute
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    • v.13 no.5
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    • pp.476-483
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    • 2001
  • 초유동콘크리트는 유동성 증진 및 충전성 향상을 위해 단위분체량을 크게하기 때문에 콘크리트의 고강도화와 수화발열량을 증가시키는 문제점을 가지고 있다. 이에 본 연구는 초유동콘크리트의 강도조절과 수화열 저감을 위해 쇄석분을 이용하여 초유동콘크리트의 강도, 유동성, 내구성능 및 건조수축 특성을 검토하였다. 실험결과 쇄석분은 치환율 10% 증가시마다 무치환시의 압축강도를 약 10~15%씩 감소시키며, 변형계수와 물구속비를 감소시켜 초유동콘크리트의 유동성 향상에 효과적이다. 또한 초유동콘크리트에서 쇄석분 10%치환시 마다 단위시멘트량 감소에 따른 최고 단열온도상승량을 약 4$^{\circ}C$씩 감소시켰다. 반면 건조수축량은 10%치환시 마다 약 5%증가시켰다. 한편 초유동콘크리트의 내구성능은 단위분체량과 유동성향상에 따른 조직의 치밀화로 쇄석분 치환에 관계없이 상대동탄성계수 90%이상으로 우수하게 나타났다. 이와 같이 분체로서 쇄석분 사용은 치환량에 따른 초유동콘크리트의 강도조절이 가능하며 수화발열량을 저감시킬 수 있다. ^ x Super flowing concrete causes high strength and the increase of heat of hydration because of the big unit powder content of concrete to increase flowability and to improve compact of concrete. Therefore, this study investigates the characteristic properties of strength, flowability, durability and drying shrinkage to control strength and to reduce heat of hydration of super flowing concrete using crushed stone fines. According to the experimental results, when crushed stone fines are increased every 10%, 10~15% of compressive strength is decreased and flowability of super flowing concrete is effectively improved due to the decrease of modulus of deformation and confined water ratio. When crushed stone fines are replaced every 10%, 4$^{\circ}C$ of the highest adiabatic temperature rise is decreased by reducing the unit cement. However, 5% of drying shrinkage is increased in the same condition. In the meantime, durability of super flowing concrete is excellent, having over 90 % of good relative dynamic modulus of elasticity due to fineness of formation caused by the increase of the unit powder content and the improvement of flowability, without regard to the replacement of crushed stone fines. Therefore, it can be said that the usage of crushed stone fines can control the strength of super flowing concrete by replacement and reduce heat of hydration.

A Study on the Thermal Crack Control of Foundation for Large Turbine (대형 터빈 기초 구조물의 온도균열 제어에 관한 연구)

  • Ha, Ju-Hyung;Cho, Yun-Gu;Lee, Kewn-Chu;Lim, Chang-Keun
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.287-297
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    • 2014
  • Heat of hydration of mass concrete is one of the most important factors that significantly affect structural quality and construction period. Therefore, appropriate methods to control heat of hydration are essential technologies for mass concrete construction. In this study, probability of thermal cracking was checked by thermal analysis prior to the construction of a turbine foundation in a domestic power plant. Subsequently, changes of concrete mix proportion and an effective curing method were proposed to control heat of hydration of mass concrete structures. Concrete manufactured by slag cement was proposed instead of concrete produced by ordinary Portland cement, and an automated curing method was proposed to improve the curing method using typical moist curing with blanket. The automated curing method maintains the temperature difference between center and surface of concrete below a setting value by temperature monitoring. Concrete with slag cement was used for actual construction. One of two identical turbine foundations was cured by an insulated curing method, and the other was cured by the automated curing method to compare the curing methods. And then, the effects of control of heat of hydration were evaluated based on temperature/strain monitoring and crack investigations.

Effect of Hardening Accelerators on the Adiabatic Temperature property Properties of Precast Concrete and FEM analysis for Evaluating the Crack Performance (경화촉진제를 사용한 프리캐스트 콘크리트의 단열온도특성 및 FEM해석에 의한 균열성능 평가에 관한 연구)

  • Min, Tae-Beom;Cho, In-Sung;Mun, Young-Bum;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.1
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    • pp.25-33
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    • 2015
  • In this study, initial crack index was evaluated by FEM analysis to find the crack propagation from hydration heat in precast concrete. As results, as the usage of hardening accelerator increased, initial compressive strength increased and setting time was shortened. Additionally, as amounts of hardening accelerators increased, the central temperature of concrete increased and the time to reach the highest temperature was shortened. It was demonstrated that the hardening accelerators accelerated the hydration reaction of cement, and caused the increase of hydration heat within the short period of time. Furthermore, the crack index for evaluating the heat level was performed by FEM. As results, there was no problem about the cracks, despite of the growth of initial high hydration heat. This is because of the increased tensile strength that is large enough to sustain the thermally induced-stress.

Influences of Sodium Gluconate on the Physical Properties of Portland Cement Pastes and Mortars (포틀랜드 시멘트 페이스트 및 몰탈의 물성에 미치는 글루콘산 나트륨의 영향)

  • 김창은;이승헌;김원기;이경원
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.289-295
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    • 1987
  • The changes of physical properties of portland cement pastes and mortars were investigated by addition of sodium gluconate. Flow table experiment and viscosity measurement were took in order to find dispersing effect, and time-dependent changesof viscosity and rates of hydration heat evolution were carried out for the sake of finding retardation effect of hydration. And changes of physical properties of cement pastes and mortars were discussed by setting time, compressive strength and porosity.

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The Properties of Roller-Compacted Concrete (롤러다짐 콘크리트의 물리적 특성)

  • Jang, Bong-Seok;Lim, Jeong-Yeul;Kim, Wan-Young;Jung, Woo-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.525-528
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    • 2006
  • This study performed an experimental test to derive the characteristics of compressive strength, het of hydration and creep of roller compacted concrete. The main variable of strength test are cement content and fly ash content. The heat of hydration test was performed using MARUTO CH-50-CA and dreep test was carried out according to KS F 2453.

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