• Title/Summary/Keyword: heat of formation

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Investigation of Al Back Contact and BSF Formation by In-situ TEM for Silicon Solar Cells

  • 박성은;송주용;탁성주;김영도;최철종;권순우;윤세왕;김동환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.38.1-38.1
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    • 2010
  • The trend to thinner crystalline silicon solar wafers in production of solar cells investigates re-evolution of back surface field (BSF) formation. We have studied mechanisms of back contact formation in Al evaporation and screen printed Al paste for Si solar cells by TEM analysis. We observed that Si diffuse into Al during heat up. The Si diffusion process made vacancies in Si wafer. The Al began to seep into the Si wafer (Al spike). During heat down, the Al spike were shrink which causes the doped region (BSF).

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층류 CH4/Air 예혼합화염의 하류영역에서 NO 농도 예측을 위한 열손실 모델의 검토 (An Investigation of the Heat Loss Model for Predicting NO Concentration in the Downstream Region of Laminar CH4/Air Premixed Flames)

  • 황철홍;이창언;금성민;이기만;신명철;김세원
    • 대한기계학회논문집B
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    • 제33권7호
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    • pp.486-494
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    • 2009
  • One-dimensional modeling of $CH_4$/air premixed flame was conducted to validate the heat loss model and investigate NOx formation characteristics in the postflame region. The predicted temperature and NO concentration were compared to experimental data and previous heat loss model results using a constant gradient of temperature (100 K/cm). The following conclusions were drawn. In the heat loss model using steady-state heat transfer equation, the numerical results using the effective heat loss coefficient ($h_{eff}$) of $1.0\;W/m^2K$ were in very good agreement with the experiments in terms of temperature and NO concentration. On the other hand, the calculated values using the constant gradient of temperature (100 K/cm) were lower than that in the experiments. Although the effects of heat loss suppress NO production near the flame region, a significant difference in NO concentration was not found compared to that under adiabatic conditions. In the postflame region, however, there were considerable differences in NO emission index as well as the contribution of NO formation mechanisms. In particular, in the range of ${\phi}\;{\geq}\;0.8$, the prompt NO mechanism plays an important role in the NO reduction under the adiabatic condition. On the other hand, the mechanism contributes to the NO production under the heat loss conditions.

열교환장치의 구조 및 재질에 따른 열회수율과 파울링의 발생 특성 (Characteristics of Heat Recovery Rate and Fouling according to Structures and Materials in Heat Exchangers)

  • 김현상;김용구;봉춘근;이명화
    • 자원리싸이클링
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    • 제24권2호
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    • pp.3-12
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    • 2015
  • 본 연구에서는 급수예열기 및 공기예열기 등의 열교환장치의 구조 및 재질에 따른 열회수율 및 파울링 발생량 특성에 대해 조사하였다. 열교환기는 석탄화력발전소에서 일반적으로 구성된 급수예열기와 공기예열기를 대상으로 하였고, 소형소각로를 제작하여 모사실험을 수행하였다. 24시간동안 미분탄을 연소하면서 파울링 발생 및 열회수율의 변화를 관찰하였는데, 급수예열기의 구조에 따른 파울링 발생량은 핀(FIN) 튜브형 > 튜브 연결형 > 파이프형 > 자동세정형의 순서로 발생량이 많았으며, 그에 따른 열회수율은 핀튜브형 > 자동세정형 > 파이프형 > 튜브연결형 순으로 높게 나타났다. 공기예열기의 경우에는 구조에 따라 핀(FIN)튜브형 > 핀(FIN)판형 > 파이프형 > 테프론 파이프형 > 세라믹 파이프형 순으로 파울링 발생량이 많았으며, 열회수율도 같은 순서로 높게 나타났다. 재질의 내구성, 내산성, 내열성 등을 고려하여 세라믹이나 테플론 코팅을 할 경우에는 파울링량을 감소시킬 수는 있으나, 열회수율이 낮게 나타나 비효율적이었다.

Cu-Al 마찰용접 접합부 계면에서 열처리에 따른 금속간화합물 성장 (Growth of Intermetallic Compounds by Heat Treatment at Interface of Friction Welded Al-Cu System)

  • 김기영;최인철;;오명훈
    • 열처리공학회지
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    • 제32권2호
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    • pp.79-85
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    • 2019
  • To investigate the influence of heat treatment on the growth intermetallic compounds (IMCs) at the joint interface of friction-welded Cu-Al, several heat treatments are performed at three different temperature with different times. The experiments reveal three different IMCs layers which are significantly influenced by atomic diffusion of Cu and Al with heat treatment conditions. Since the formation of these IMCs layers can affect mechanical properties of friction-welded Cu-Al interfaces, the relationship between the microstructure of IMCs layers and the tensile strength is analyzed according to heat treatment temperature and times.

고온 평면변형된 AZ91 마그네슘 합금의 미세조직 및 집합조직의 형성거동 (Effects of Deformation Conditions on Microstructure Formation Behaviors in High Temperature Plane Strain Compressed AZ91 Magnesium Alloys)

  • 홍민호;지예빈;윤지민;김권후
    • 열처리공학회지
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    • 제37권2호
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    • pp.66-72
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    • 2024
  • To investigate the effect of deformation condition on microstructure and texture formation behaviors of AZ91 magnesium alloy with three kinds of initial texure during high-temperature deformation, plane strain compression tests were carried out at high-temperature deformation conditions - temperature of 673 K~723 K, strain rate of 5 × 10-3s-1, up to a strain of -1.0. To clarify the texture formation behavior and crystal orientaion distribution, X-ray diffraction and EBSD measurement were conducted on mid-plane section of the specimens after electroltytic polishing. As a result of this study, it is found that the main component and the accumulation of pole density vary depending on initial texture and deformation caondition, and the formation and development basal texture components ({0001} <$10\bar{1}0$>) were observed regardless of the initial texure in all case of specimens.

Numerical Modeling for the $H_2/CO$ Bluff-Body Stabilized Flames

  • Kim, Seong-Ku;Kim, Yong-Mo;Ahn, Kook-Young;Oh, Koon-Sup
    • Journal of Mechanical Science and Technology
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    • 제14권8호
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    • pp.879-890
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    • 2000
  • This study investigates the nonpremixed $H_2/CO$-air turbulent flames numerically. The turbulent combustion process is represented by a reaction progress variable model coupled with the presumed joint probability function. In the present study, the turbulent combustion model is applied to analyze the nonadiabatic flames by introducing additional variable in the transport equation of enthalpy and the radiative heat loss is calculated using a local, geometry independent model. Calculations are compared with experimental data in terms of temperature, and mass fraction of major species, radical, and NO. Numerical results indicate that the lower and higher fuel-jet velocity flames have the distinctly different flame structures and NO formation characteristics in the proximity of the outer core vortex zone. The present model correctly predicts the essential features of flame structure and the characteristics of NO formation in the bluff-body stabilized flames. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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층류확산화염의 불안정성에 대한 매연생성 특성의 역할 (Soot Formation Characteristics on the Instability of Laminar Diffusion Flames)

  • 남연우;이원남
    • 한국연소학회지
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    • 제15권3호
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    • pp.74-81
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    • 2010
  • In this study, soot formation characteristics on the instability of laminar diffusion flames were investigated experimentally using a concentric co-flow burner. When a small amount of air was supplied through an inner nozzle, a stable propane laminar diffusion flame became unstable and began to oscillate mainly due to the dilution effect. The increase of air flow rate transformed an oscillating non-sooting flame into a stable nonsooting flame. When the air flow rate was continuously increased an inner flame was formed and the flame was changed to an oscillating sooting flame, an oscillating non-sooting flame and finally a stable non-sooting hollow flame. When the air flow rate was decreased, a non-sooting hollow flame was eventually changed back to a stable non-sooting flame. The presence of an inner flame, however, altered the soot formation characteristics of a flame. More soot production was observed with the presence of an inner flame. The increased or decreased soot formation/oxidation rates, the radiation heat loss, and the heating effect of inner flames are most likely to be responsible for the observed instability of laminar diffusion flames.

기계적 합금화에 의한 비정질 Cu-Ta 분말의 제조 및 전자물성 (Formation and Electronic Properties of the Amorphous Cu-Ta Alloy Powders Subjected to Mechanical Alloying)

  • 이충효
    • 한국재료학회지
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    • 제4권6호
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    • pp.620-625
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    • 1994
  • 자자들은 최근 비고용 Cu-Ta계의 기계적 합금화(Mechanical Alloying) 방법을 이용하여 이계에 있어서 비정질상의 형성에 대한 구조적 확인을 중성자 회절과 EXAFS(Extended X-ray Absorption Fine Structure)의 실험결과로 부터 얻었다. Cu-Ta계와 같이 혼합 엔탈피(Heat of Mixing: $\Delta$ Hmix)가 정인계에 있어서 비정질상 형성에 대한 연구는 구조적인 측면 뿐만 아니라. 시료의 전자물성에 대해서도 많은 연구가 되어야만 할 것으로 사료된다. 따라서 본 논문에서는 120시간 MA방법으로 제작한 시료에 대하여 초전도 천이온도 및 X선 광전자분광 실험에서 얻은 가전자대 구조의 전자물성을 측정하고, 그 결과로부터 이종원자 Cu와 Ta간의 결합은 화하결합에 의한 생성임을 확인하였는데, 이들 결과로부터 120시간 MA를 행하여 얻어진 시료는 확실하게 비정질 합금임을 알 수 있었다.

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해수용 재료의 TIG용접후 열처리에 따른 특성 평가 (Evaluation of the Properties of Seawater Materials by Heat Treatment after TIG Welding)

  • 배동수;이진경
    • 한국산업융합학회 논문집
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    • 제24권5호
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    • pp.517-523
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    • 2021
  • In this study, in the selection of materials for the elements of a small plant, those with high resistance to corrosion are selected and the material properties of coatings for corrosion prevention are evaluated. In addition, corrosion characteristics and material analysis were performed on the welded part, and the hardness characteristics of the welded part, heat-affected part, and the base metal were evaluated. In the case of the post-weld-heat-treated(PWHT) specimen, the corrosion resistance of STS 316 was lower than that of the specimen without the PWHT due to the formation of intergranular carbide. As a result of evaluating the distribution of the hardness of the weld before and after the PWHT, the hardness of the specimen after the PWHT increased by about 20 Hv. As a result of the corrosion test on the welded specimen, the weight loss tended to increase as the time increased. In the case of the PWHT specimen, the corrosion resistance tended to be significantly lower than that of the specimen without PWHT due to the formation of intergranular carbide.