• 제목/요약/키워드: heat evolution amount

검색결과 34건 처리시간 0.024초

VC의 첨가에 따른 Fe-TiC계의 미세조직변화 (Effect of VC Addition on the Microstructural Evolution of Fe-TiC Cermet)

  • 채기웅
    • 한국세라믹학회지
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    • 제36권4호
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    • pp.366-371
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    • 1999
  • The effect of VC addition on the microstructural evolution of Fe-TiC cermet has been investigated. The microstructures of the Fe-TiC varied with the amount of VC addition. The addition of 1wt% VC enhanced the instability of liquid-solid interface ; the dissolving interface showed round shape instead of facetted one which was ascribed to the increase of lattice mismatch between TiC and solid-solution carbide. in the speci-men with 10wt% VC the new set of solid-solution carbide grains of uniform and small size was formed in-side coarse TiC particles by diffusion induced recrystallizatin (DIR). With increasing the heat-treatment time fine recrystallized grains were dispersed homogeneously in the matrix and resulted in the increase in fracture strength.

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고강도용 콘크리트의 온도상승 억제를 위한 고로슬래그 미분말의 효과 (The Effect of Ground Granulated Blast-Furnace Slag on the Control of Temperature Rising in High Strength Concrete)

  • 문한영;최연왕
    • 콘크리트학회지
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    • 제10권4호
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    • pp.195-204
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    • 1998
  • 콘크리트가 고강도를 확보하기 위해서는 일반적으로 큰 단위시멘트량 및 낮은 물-시멘트비를 유지해야 하므로 콘크리트 타설후 내부온도 상승은 필연적이며, 구조물의 위치와 온도응력차에 의하여 콘크리트 구조물에 균열이 발생하게 된다. 그러므로 고강도용 콘크리트의온도상승 억제대책의 한 방안으로 고로슬래그미분말 3종류와 혼합률 4단계로 변화시킨 콘크리트를 제조하여 온도상승량과 최고온도 도달시간 및 강도를 측정하였으며, 고로슬래그미분말을 5단계로 혼합한 페이스트의 수화발열량 및 수화속도를 측정한 값에 대하여 고찰하였다. 본 연구결과 고로슬래그미분말의 분말도 6,000$\textrm{cm}^2$/g, 혼합률 50% 정도인 고강도용 콘크리트가 온도상승 억제효과 뿐만 아니라 조기재령에서의 강도도 비교적 잘 만족하였다.

$YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$ 및 Ba-Cu-O계 화합물의 수분과의 반응에 의한 열방출에 관한 연구 (Heat Liberation in the Reaction of $YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$, and Binary Compounds in the Ba-Cu-O System with Water)

  • 김배연
    • 한국세라믹학회지
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    • 제32권1호
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    • pp.83-89
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    • 1995
  • YBa2Cu3O7-$\delta$, Y2BaCuO5, and binary compounds in the Ba-Cu-O system with the nominal composition of Ba2CuO3, BaCuO2, Ba3Cu4O7, Ba3Cu5O8 were synthesized to investigate the heat evolutions and crystalline phases in the hydration reaction of orthorhombic YBa2Cu3O7-$\delta$ phase. The observed crystalline phases were YBa2Cu3O7-$\delta$, Y2BaCuO5, and BaCuO2, or Ba2Cu3O5+x, and some amount of noncrystalline phase in the Ba-Cu system comounds. In contact with distilled water, YBa2Cu3O7-$\delta$ and Y2BaCuO5 did not have considerable heat liberation, but in the binary compounds of the Ba-Cu-O system, the amount of total heat liberation was increased with respect to the Cu content. It might be that the reaction of high temperature superconductor YBa2Cu3O7-$\delta$ with water and/or moisture originated from the unusual oxidation state of Cu ion and the presence of amorphous Ba-Cu oxide compound. The degradation of high Tc superconductor by moisture and water could be controlled by restricting the heterogeneous distribution of Tc comlposition and the formation of second phase, such as stable Y2BaCuO5, and the resulting unstable Ba-Cu oxide compound.

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Energy and Mass Balance of Snowpack - Rapid snowmelt during Fohn events in the Takada plain -

  • 김선주
    • 한국농공학회지
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    • 제32권E호
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    • pp.88-94
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    • 1990
  • Several models physically based to predict the evolution of the snowpack have been proposed. Validity of these models for hourly estimation is, however, questionable, since they have been tested only on a daily basis. A computational model to predict the amount of snowpack on an hourly basis in terms of snowload from a set of meterological measurements was developed and investigated the rapid snowmelt conditions during Fohn events in the Takada plain.

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Sr 개량처리된 사형주조 Al-7Si-0.35Mg 합금의 열처리에 따른 공정 Si상 변화거동 및 특성평가 (Behavior of Eutectic Si and Mechanical Properties of Sr Modified Al-7Si-0.35Mg alloy with Solid Solution Treatment for Sand Casting)

  • 김명균;황석민
    • 한국주조공학회지
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    • 제38권1호
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    • pp.1-8
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    • 2018
  • In this study, we focused on the correlation between the solidification structure, heat treatment and mechanical properties of the A356 alloy according to the conditions of Sr modification. The microstructural evolution of the eutectic Si and ${\alpha}-Al$ phase in the A356 alloy castings depending on the amount of Sr were investigated during solid solution heat treatment using an optical microscope, a scanning electron microscope and an image analyzer. In addition, tensile tests on the heat treated materials examined the relationship between the microstructure and the fracture surface. The as-cast A356 alloys under 40 ppm Sr showed an undermodified microstructure, but that of the added 60-80 ppm Sr had well modified structure of fine fibrous silicon. After solid solution treatment, the microstructure of the undermodified A356 alloy exhibited a partially spheroidized morphology, but the remainder showed the fragmentation of fibrous shaped silicon. The spheroidization of the eutectic silicon in the modified A356 alloys was completed during heat treatment, which was very effective in increasing the elongation. This is supported by the fracture surface in the tensile test.

고강도 수중불분리성콘크리트의 기초물성에 대한 연구 (Fundamental Properties High-Strength Antiwashout Underwater Concrete)

  • 문한영;김성수;송용규;전중규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.195-198
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    • 2000
  • Recently, the anriwashout underwater concrete has been increasingly used for underwater structures such as vary high diaphrame walls of high strength massive concrete structures. In this study, experiments were made on the fundamental properties of antiwashout underwater concrete replaced with Fly Ash from 10% to 30% to improve its properties. Resultant to the test, we got the results as follows; the value of slump flow wasi ncreased, the setting, time was very delayed, and the heat evolution amount decreased, whereas the amount of suspended solids became high, and pH value became low as to increasing the replacement ratio of Fly Ash. Also the ratios of compressive strength (in water compared to in air) at 28day were obtained over 90%, and these values were satisfied with 70% of a criterion.

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Sol-Gel법을 이용한 (0.8PPV+0.2DMPPV)/Silica Glass, Borosilicate Glass 복합체의 합성과 그 특성 (Synthesis and Their Properties of (0.8PPV+0.2DMPPV)/Silica Glass, Borosilicate Glass Composites by Sol-Gel Process)

  • 이병우;김병호;윤영권;한원택
    • 한국세라믹학회지
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    • 제34권9호
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    • pp.993-1001
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    • 1997
  • The (0.8PPV+0.2DMPPV) copolymer and silica/borosilicate composites were synthesized by sol-gel process. The organic-inorganic hybrid solution was prepared by using of (0.8PPV+0.2DMPPV) copolymer precursor solution as a raw material for organic components and TEOS and TMB for glass components. Then by drying the solution in vacuum at 5$0^{\circ}C$ for 7days and subsequent heat treatment in vacuum at 15$0^{\circ}C$~30$0^{\circ}C$ for 2h~72h with heating rate of 0.2$^{\circ}C$/min and 1.8$^{\circ}C$/min, the organic-inorganic composites were synthesized. Microstructural evolution of the composites was characterized by DSC, IR spectrocopy, UV/VIS spectroscopy, and TEM. Elimination of the polymer precursor and degradation of the polymer were observed by DSC and Si-O and trans C=C absorption peaks were identified by IR spectra. The polymer was found to be successfully incorporated into the glass matrix and it was confirmed by the absorption peaks from the polymer in the UV/VIS spectra and the TEM results. The absorption peak of the composites was found to shift toward short wavelength side compared to that of the pure polymer and the amount of the blue shift increased with increasing the heat treatment temperature and heat treatment time and with decreasing the heating rate.

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고유동 자기충전 콘크리트의 압축강도 수준에 따른 수화발열 특성 (Properties of Hydration Heat with Compressive Strength Level of High Flowing Self-Compacting Concrete)

  • 최연왕;정재권;이재남;김병권
    • 대한토목학회논문집
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    • 제29권5A호
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    • pp.531-541
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    • 2009
  • 본 연구에서는 강도수준(30, 50 및 70 MPa)에 따른 고유동 자기충전 콘크리트의 수화발열 특성을 알아보기 위하여 2성분계 및 3성분계 고유동 자기충전 콘크리트를 제조하여 일반콘크리트와 수화열, 응결 및 역학적 특성을 분석 고찰 하였으며, 콘크리트에 사용된 분체에 대한 미소수화열량을 측정하여 얻은 분체의 열특성값, 간이단열온도실험을 실시하여 얻은 콘크리트의 열특성값 및 콘크리트에 사용된 재료의 일반적인 열특성값을 간편한 방법의 추정식을 이용하여 콘크리트 단열온도를 추정하였다. 또한, 온도해석에 의하여 얻어진 수화열 및 단열온도 특성값을 MIDAS CIVIL 06 프로그램을 이용하여 3차원 온도응력 해석을 실시하여 고유동 자기충전 콘크리트의 수화발열 특성 및 수화열에 의한 온도응력을 분석 고찰하였다.

화강암의 실내 가열실험에 대한 수치해석적 검토 (Numerical Analysis of Laboratory Heating Experiment on Granite Specimen)

  • 윤동준;손장윤;장리
    • 터널과지하공간
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    • 제32권6호
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    • pp.558-567
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    • 2022
  • 고준위방사성폐기물의 지중저장 안정성 평가의 일환으로 가열 중인 화강암의 온도변화와 열응력 발생 양상을 파악하기 위하여 가열실험을 실시하였다. 폐기물의 붕괴열 발생조건을 가정하고 정육면체 형태의 화강암 시편에 적용하여 온도와 변위의 분포를 측정하였다. 시편의 온도는 가열봉에서 발생하는 전도로 인하여 즉각적으로 상승하지만 동시에 외기에 노출되거나 하중재하장치에 접촉되어 있는 표면을 통하여 상당한 양의 열에너지가 소산되었다. 해당 실험에 대한 분석과 이해를 위해 실험조건을 삼차원 유한요소 수치해석으로 재구현하였다. 실험에서 관찰된 열-역학 연계 현상과 주변조건의 변화를 해석에 적용하고 이를 실내실험 결과와 비교하여 검증하였다. 이를 통해 가열실험에 영향을 주는 인자들을 분석하고 향후 관련 연구에서 고려되어야 할 부분을 요약하였다.

시멘트의 특성과 사용 온도가 모르터의 물성에 미치는 영향 (Effects of Portland Cement Characters and Working Temperature on the Physical Properties of Cement Mortars)

  • 김원기;김창은
    • 한국세라믹학회지
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    • 제37권5호
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    • pp.410-417
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    • 2000
  • In this study the effects of specifics surface area of cement, addition amount of gypsum and substitution ratio of gypsum anhydrite ont he physical properties of cement mortars were investigated by measruements of setting time, flow, compressive strength and hydration heat evolution rate. The results showed that fluidity of mortars was increased by 40 wt.% of maximum flow change with the decreasing specific surface area of cement from 3,500$\textrm{cm}^2$/g to 3,300${\pm}$50$\textrm{cm}^2$/g and affected by the relationship between the cement and balancing between the chemical activityof cement and solubility of calcium sulfate are desirable to prevent the fluidity of concrete from decreasing by high temperature in summer season.

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