• Title/Summary/Keyword: hazardous substances

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Research on the Actual State of Environmental Disease and Health Education at Middle and High School Students (일 지역 중.고등학생들의 환경성 질환 및 보건교육 실태 조사)

  • Jung, Jong-Hyeon;Moon, Ki-Nai;Seo, Bo-Soon;Kim, Chang-Tae;Lee, Jae-Hong
    • The Journal of Korean Society for School & Community Health Education
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    • v.12 no.3
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    • pp.65-87
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    • 2011
  • Objectives: The purpose of this study was to perform basic study on environmental and respiratory diseases in Ulsan and vicinities. Also, this study evaluated the actual state of environmental disease and health education at middle and high schools in Ulsan and surroundings. Methods: For this study, we conducted a survey on the health of the general public, environmental effects, and investigated the characteristics of environmental disease, health and hygiene education, etc. The populations of this study were middle and high school students in Ulsan, Korea. This study investigated the knowledge of environmental disease and health education at schools in Ulsan and vicinities from November 2009 to December 2009. All statistical calculations were performed with Statistical Package for Social Sciences (SPSS) for Windows, and gained the following results by implementing Frequency Analysis, Cross-tabulation Analysis and ANOVA. Results: As more and more environmental diseases are increased, the interest of the people has been increasing on this. The incidence rates of asthma and atopy were represented the top 25% of the country in Korea. The source of heavy metal, PAHs and VOCs in Ulsan includes the Petrochemical Complex at Nam-gu and Ulju-gun, the Nonferrous Metal Industrial Complex at Onsan-eup, Ulju-gun, and the Heavy Industrial Complex at Dong-gu and Buk-gu. Especially, there are a number of fossil fuel combustion facilities such as waste incineration plants and boilers at Nam-gu and the Onsan Industrial Complex. It may help greatly to investigate the characteristics of environmental pollutants such as environmental air pollutant and indoor contaminant to better manage the local student's health. Conclusions: It has been revealed that the hazardous chemicals and environmental contaminants are main substances of cause for asthma, atopy, dermatitis, and allergy disease. Therefore, through with collecting basic data such as environmental disease of inhabitants, health education, conscious and knowledgeable level in parents of students and students, We have to exert to improve knowledge and prevention with health life in school through development of health education program systematically for preventing of environmental disease.

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Analysis on Response System in US for Chemicals Driven Marine Pollution Accidents and Korean Response Policy Plan (화학물질 해양오염사고에 대한 미국의 방제체제 분석과 국내의 방제정책 방안)

  • Choi, Jong-Wook;Lee, Seung-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.3
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    • pp.205-212
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    • 2009
  • With an entry into force of OPRC-HNS on June 14th 2007, response system against any large scale accidents related to HNS is required to respond rapidly and effectively in a national scale, US national response system and national contingency plan for any chemicals in operation were analyzed to understand the characteristics of management system and response system for any HNS driven accidents in the Us. Main characteristics of the US system were well described as an unified information window and an integrated incident command system supported by response facilities, manpower and technical support from other response organizations through good cooperation. In general, response activities are conducted by private sectors, however, the government will take over response activities in case large scale accidents occur in the Us. Expected expenses for response activities are covered by a type of Superfund in the Us. Several applicable ways are proposed to enable NGO to participate in and reorganize response system in ROK, and are feasible in collaboration with other response organizations and private sectors in the aspects of equipment, technology and manpower, Based upon the above activities, it is desirable to reorganize domestic rules and/or regulations related to response measures in ROK.

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Determination of Heavy Metals in Sanitary Products of Women (여성용 위생용품의 유해중금속 분석)

  • Shin, Jeoung-Hwa;Lee, Kyu-Keon;Chung, Myung-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.6
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    • pp.853-859
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    • 2009
  • Endometriosis becomes the most common cause of pelvic pain and infertility women. The cause of endometriosis has ever been entirely proven. However, an increased use of commercial feminine hygiene products such as tampons and sanitary napkins was considered one of the major affect. Harmful substances in feminine hygiene products was analyzed and evaluated. Samples of commercial products obtained from Korea, Japan, America, Germany, and China were analyzed for six hazardous inorganic elements (chromium, cobalt, nickel, copper, cadmium and lead). In the extractable heavy metals of napkins, Cr, Ni and Cu were found in all of the samples, while Cd was detected only in two samples. In the tampons, Cr, Ni and Cu were found in all of the samples. The presence of Co and Cd was not detected in all samples The concentrations of extractable heavy metals in the tampons were lower than those in the sanitary napkins. The content of extractable heavy metals in the sanitary products was compared with the criteria of the 100 $\ddot{O}KO$ TEX Standard. It was confirmed that the level of heavy metals in the sanitary products posed no serious risk to health, based on the human-ecological criteria defined by the 100 $\ddot{O}KO$ TEX Standard.

Photolysis of the insecticide imidacloprid in water and water-paddy soil systems (살충제 imidacloprid의 물 및 물-토양계 중 광분해)

  • Ihm, Yang-Bin;Kyung, Kee-Sung;Kim, Chan-Sub;Choi, Byeong-Ryeol;Hong, Soo-Myung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.8 no.1
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    • pp.38-45
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    • 2004
  • To elucidate the photolysis characteristics of the insecticide imidacloprid in the environment, $[^{14}C]$imidacloprid was treated into water and paddy soil-water system. In water system, the amount of $^{14}C$-radioactivity distributed in aqueous phase was rapidly increased up to 80% of total $^{14}C$ in water during 7 days of exposure to sunlight. Also, the amounts of imidacloprid in water at day 0 and 3 days after treatment were 1.2461 and 0.8594 mg/kg, respectively, not being detected 7 days after treatment, indicating rapid degradation of imidacloprid in water by sunlight. One photodegradation product, imidacloprid urea, in which the $N-NO_2$ moiety of imidacloprid was replaced by oxygen, was detected from water in water and water-paddy systems. The amount of the metabolite detected from water in water system was 0.0112 mg/kg 1 day after treatment and reached the top concentration of 0.0391 mg/kg 7 days after treatment. In case of water-paddy system, its amount was 0.0117 mg/kg 1 day after treatment and reached the highest concentration of 0.0259 mg/kg 3 days after treatment. Rapid transformation of imidacloprid into polar compounds continued until 7 days after treatment, considering that 80% of $^{14}C$ in water distributed in aqueous phase 7 days after treatment, amount of imidacloprid was 1.6538 mg/kg at day 0 and 0.8785 mg/kg 1 day after treatment, not being detected after 15 days, indicating rapid degradation of imidacloprid in water-paddy soil system by sunlight. The direct degradation of imidacloprid to imidacloprid urea would be a major photodegradation pathway in water and water-paddy soil systems.

Hazard Assessment of Combustion Gases from Interior Materials (주요 건축 내장재의 연소가스 유해성 평가)

  • Seo, Hyun Jeong;Son, Dong Won
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.49-56
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    • 2015
  • Toxic gases from five types of interior building materials were investigated according to Naval Engineering Standard (NES) 713. The materials were plywood, indoor wall coverings (wood wall plate members and pine wood), reinforced Styrofoam insulation, laminate flooring, and PVC. Specimens were measured using an NES 713 toxicity test apparatus to analyze the hazardous substances in combustion gas from the materials. We used the US Department of Defense standard (MIL-DTL, Military Standard) to calculate the toxicity index of the combustion gas. Emissions of $CO_2$ from all specimens did not exceed the NES 713 limit of 100,000 ppm. The amount of CO gas emissions from reinforced Styrofoam insulation was 6,098 ppm. 25 ppm and 49 ppm of formaldehyde were released from the reinforced Styrofoam insulation and PVC flooring, respectively. These values were less than the limit of 400 ppm. The highest emissions were from $NO_X$ emitted by plywood and were above the limit of 250 ppm. The toxicity index of the specimens were calculated as 5.19 for plywood, 4.13 for PVC flooring, 2.35 for reinforced Styrofoam insulation, 2.34 for laminate flooring, and 1.22 for indoor wall coverings (pine wood). Our research helps us to understand the properties of these five interior materials by analyzing the combustion gas and explaining the toxicity of constituents and the toxicity index. Also, it would be useful for giving fundamentals to guide the safe use of interior materials for applications.

Effect of Work Intensity on Fit Factor and Affecive Quality of Dustproof Mask (작업 강도가 방진 마스크의 밀착도와 감성품질에 미치는 영향)

  • Lee, Jinsil;Cho, Sunhee;Yun, Jungmin;Kim, Min-Sun;Park, Jaekyu;Choe, Jaeho
    • Journal of Korean Society for Quality Management
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    • v.46 no.2
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    • pp.301-310
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    • 2018
  • Purpose: The purpose of this study is to investigate the effect of work intensity on fit factor and affective quality of the dustproof Background: Among the victims who suffer pneumoconiosis due to the inhalation of toxic substances or the lack of oxygen during the work, the proportion of the victims is larger than the other causes. Wearing a respirator may prevent pneumoconiosis, but it can be hazardous to workers because of the leakage through filters, cartridges, exhaust valves, broken parts, and face-to-face contact. Despite leakage through the contact area between the mask and the face has various causes such as the wearer's activity, sweat accumulation, facial shape, etc., There is a lack of relevant research and regulation compared to developed countries that have already institutionalized the law 30 years ago and give the right to sell through a test Method: The work intensity was adjusted by walking or running at 6km/h and 11km/h on the treadmill, and tasks were defined with reference to the test procedure and the exercise sequence applied in the face leakage test of the dustproof mask. And fit factor was measured objectively using 'Respirator Fit Tester 8038' which measures fit factor calculated by dividing the number of dust present outside the mask by inside the mask. In addition, affective quality was classified by the ease of use, ease of breathing, and ease of wearing, and was measured using the 5-point likert scale questionnaire. Results: There was a significant difference in fit factor, ease of breathing, and wearing convenience according to work intensity and no significant difference in ease of use(${\alpha}=0.01$). And when the work intensity was high, fit factor, ease of breathing, and wearing convenience were all lower than when the work intensity was low. Conclusion: In Korea, it is necessary to consider consideration of the work intensity when testing the leakage rate of the face part for safety certification of the respiratory protective equipment, When developing a mask, it should be possible to maintain high adhesion even under intense, active situation and high temperature conditions by selecting materials, improving the wearing style, and expanding the adjustable range.

Case Study of Cost Effect Analysis for Toxic Compounds to Developing Effluent Limitation Standards : Focus on 1,4-Dichlorobenzene (수질유해물질 배출허용기준 설정에 따른 배출시설 비용영향 분석사례 연구: 1,4-Dichlorobenzene을 중심으로)

  • Kim, Kyeongjin;Kim, Wongi;Heo, Jin;Kim, Kwangin;Kim, Jaehoon;Kim, Sanghun;Yeom, Icktae
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.557-565
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    • 2010
  • Recently, regulations on toxic compounds in aquatic environment have been strengthened in korea due to the increasing public awareness of the water quality. Typically, these regulations include introduction of emerging toxic compounds and stricter effluent limitations for the already regulated compounds. However, too strict regulations may cause excessive burden on the industry. Therefore it is also important to assess the economic impacts when the new effluent limitation guidelines are introduced. The estimation of the additional cost for the wastewater dischargers to meet the new guidelines are based on the selected treatment technology to handle the hazardous substances and the regulatory levels for effluent limitations. To explore the procedures for cost estimation in enforcing new effluent limitations, a case study was performed specially for 1,4-dichlorobenzene. The pollutants of concern are surveyed for different industrial categories and various treatment technologies. For a given pollutant, the general performances of the treatment technologies are surveyed and a representative technology is selected. For a given technology, the capital cost and annual Operation and Maintenance (O&M) cost was calculated. The calculation of baseline costs to operate ordinary treatment technologies is also important. The ratio between the cost for introducing new treatment process and the baseline cost required for conventional technology was used to evaluate the economic impact on the industry. For 1,4-dichlorobenzene, steam stripping and activated carbon processes were selected as the specific treatment technologies. The cost effects to the regulation of the compound were found to be 6.4% and 14.5% increase in capital cost and O&M cost, respectively, at the flow rate over $2,000m^3/d$ for the categories of synthetic resin and other plastics manufacturing industry. For the case of petrochemical basic compounds manufacturing industry, the cost increases were 5.8% and 12.4%, respectively. It was suggested that cost effect analysis to evaluate the economic impacts of new effluent limitations on the industry is crucial to establish more balanced and reasonable effluent limitations to manage the industrial wastewater containing emerging toxic compounds in the wastewater.

Determination of Heterocyclic Amines and Acrylamide in Agricultural Products with Liquid Chromatography-Tandem Mass Spectrometry

  • Lee, Kyung-Jun;Lee, Gae-Ho;Kim, HaeSol;Oh, Min-Seok;Chu, Seok;Hwang, In Ju;Lee, Jee-yeon;Choi, Ari;Kim, Cho-il;Park, Hyun-Mee
    • Toxicological Research
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    • v.31 no.3
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    • pp.255-264
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    • 2015
  • Heterocyclic amines (HCAs) and acrylamide are unintended hazardous substances generated by heating or processing of foods and are known as carcinogenic and mutagenic agents by the animal experiments. A simple method was established for a rapid and accurate determination of 12 types of HCAs (IQ, MeIQ, Glu-P-1, Glu-P-2, MeIQx, Trp-P-1, Trp-P-2, PhIP, $A{\alpha}C$, $MeA{\alpha}C$, Harman and Norharman) and acrylamide in three food matrices (non-fat liquid, non-fat solid and fat solid) by isotope dilution liquid chromatography-tandem mass spectrometry (LC-MS/MS). In every sample, a mixture of internal standards including $IQ-d_3$, $MeIQx-d_3$, $PhIP-d_3$, $Trp-P-2-^{13}C_2-^{15}N$ and $MeA{\alpha}C-d_3$ was spiked for quantification of HCAs and $^{13}C_3$-acrylamide was also spiked for the analysis of acrylamide. HCAs and acrylamide in sample were extracted with acetonitrile and water, respectively, and then two solid-phase extraction cartridges, ChemElut: HLB for HCAs and Accucat: HLB for acrylamide, were used for efficiently removing interferences such as pigment, lipid, polar, nonpolar and ionic compounds. Established method was validated in terms of recovery, accuracy, precision, limit of detection, limit of quantitation, and linearity. This method showed good precision (RSD < 20%), accuracy (71.8~119.1%) and recovery (66.0~118.9%). The detection limits were < 3.1 ng/g for all analytes. The correlation coefficients for all the HCAs and acrylamide were > 0.995, showing excellent linearity. These methods for the detection of HCAs and acrylamide by LC-MS/MS were applied to real samples and were successfully used for quantitative monitoring in the total diet study and this can be applied to risk assessment in various food matrices.

Evaluation of the Feasibility of Oyster-Shell and Eggshell Wastes for Stabilization of Arsenic-Contaminated Soil (농축수산 폐기물(굴껍질 및 달걀껍질)을 이용한 비소 오염토양의 안정화 효율 평가)

  • Lim, Jung-Eun;Moon, Deok-Hyun;Kim, Dong-Jin;Kwon, Oh-Kyung;Yang, Jae-E.;Ok, Yong-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1095-1104
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    • 2009
  • The objective of this research was to evaluate the feasibility of using oyster-shell and eggshell wastes for the stabilization of arsenic-contaminated soil. Artificial As(V) contaminated soil was mixed with 0~5% oyster-shell and eggshell wastes and each sample was incubated for 30 days in a controlled environment. The efficiency of each treatment was evaluated using various single extractants (1 N HCl, 0.1 N NaOH and 0.5 N $H_2SO_4$). The concentration of As(V) was reduced by 10% upon a 5% oyster-shell or eggshell waste treatments based on the Korea Standard Test method (1 N HCl extraction). Analogous trends were observed in the 0.1 N NaOH or 0.5 N $H_2SO_4$ extractions. In addition, the oyster-shell and eggshell waste treatments increased the pH of each soil from 6.54 (Control) to 7.62~7.94. The exchangeable Ca in each soil also sharply increased from 6.87 cmol(+)/kg (Control) to 12.77~20.18 cmol(+)/kg. Further research is needed to increase the effectiveness of the oyster-shell and eggshell waste for the stabilization of As(V) in the contaminated soil.

Physico-chemical stability of pesticide formulations under different storage conditions (저장조건별 농약제품의 물리.화학적 안정성)

  • Lee, Hee-Dong;Kim, Kwang-Ho;Rhi, Ja-Hyeun;Shin, Wook-Cheol;Park, Hyeon-Ju;Lee, Soo-Hyung;Park, Seung-Soon
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.103-106
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    • 2004
  • To confirm physico-chemical stability of formulated products, this study was conducted under different storage conditions; room temperature and accelerated temperature of $54^{\circ}C$. The tested pesticide formulations were dichlorvos 50% EC, acephate 50% WP, hymexazol 4% DP, thiram 80% WP and isoprothiolane 12% GR. The selected formulations were stored for 10 weeks and 5 years under the given temperature in maximum and contents of active ingredients were also analyzed by GLC or HPLC after each time of storage. The degradation rates of 5 active ingredients under the two conditions showed a similar trend except acephate. Acephate was rapidly decomposed at $54^{\circ}C$ but slowly decomposed at room temperature, and the degradation rate under the accelerated condition was 2.4 to 5-fold higher than that under the room temperature. Consequently, the stability test on active ingredients in pesticide formulations was able to recommend to be carried out under the accelerated condition except acephate. And the physical properties of all formulations tested under two storage conditions were good.