• Title/Summary/Keyword: hazardous heavy metals

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A Study on Hazardous Heavy Metal Contents of Lip Cosmetics (립메이크업 제품의 유해 중금속 함량 조사연구)

  • Choi, Chae Man;Kim, Su Un;Park, Ae Suk;Kim, Ji-Young;Kim, Yun Hee;Lee, Myung Sook;Kim, Uk Hee;Hwang, In Sook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.2
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    • pp.147-155
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    • 2022
  • From March to August 2021, a total of 66 lip makeup products were collected from Seoul to measure the contents of lead, arsenic, cadmium, antimony, and nickel, and compared by product type (lip gloss, lip balm and lip tint), production area (domestic and imported), and user (for adults and children). The average metal contents were as follows; 0.284 ㎍/g for lead, 0.020 ㎍/g for arsenic, 0.003 ㎍/g for cadmium, 0.004 ㎍/g for antimony and 0.415 ㎍/g for nickel. The results of lip cosmetics were below the recommended maximums in regulations on safety standards for cosmetics of Ministry of Food and Drug Safety.

Monitoring of Heavy Metals Migrated from Polylactide (PLA) Food Contact Materials in Korea (국내 유통 폴리락타이드(PLA) 식품용 기구 및 용기·포장의 중금속 이행량 모니터링)

  • Kim, Hyeonuk;Park, So-Yeon;Jo, Ye-Eun;Park, Yongchjun;Park, Se-Jong;Kim, Meehye
    • Journal of Food Hygiene and Safety
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    • v.33 no.2
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    • pp.102-109
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    • 2018
  • In the present study, a variety of polylactide (PLA) articles (n = 211) were tested for migration of lead (Pb), cadmium (Cd) and arsenic (As) into the food simulant (4% v/v acetic acid). Pb, Cd, and As were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Migration tests were performed at $70^{\circ}C$ and $100^{\circ}C$ for 30 min. The amounts of Pb, Cd, and As increased at $100^{\circ}C$ for 30 min compared with levels at $70^{\circ}C$. However, the migration at both conditions was very low. The maximum level of Pb at $100^{\circ}C$ for 30 min corresponded to 1% of the migration limit. The estimated daily intakes (EDI) based on safety evaluation ranged from $2.5{\times}10^{-5}$ to $2.0{\times}10^{-3}{\mu}g/kg\;bw/day$ for Pb, Cd, and As. The EDI calculated from migration of Pb at $100^{\circ}C$ for 30 min in PLA was the maximum value, $2.0{\times}10^{-3}{\mu}g/kg\;bw/day$, which corresponded to 0.055% of provisional tolerable weekly intake (PTWI, $25{\mu}g/kg\;bw/week$). The data from this study represent a valuable source for science-based safety control and management of hazardous heavy metals migrating from polylactide food contact materials.

Investigation of Unintentionally Hazardous Substance in Commercial Herbs for Food and Medicine (유통 식약공용농산물 중 비의도적 유해물질 오염도 조사)

  • Seo, Mi-Young;Kim, Myung-Gil;Kim, Jae-Kwan;Jang, Mi-Kyung;Lee, Yu-Na;Ku, Eun-Jung;Park, Kwang-Hee;Yoon, Mi-Hye
    • Journal of Food Hygiene and Safety
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    • v.33 no.6
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    • pp.453-459
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    • 2018
  • This study was performed to investigate the contamination levels of heavy metals (such as lead, cadmium, arsenic and mercury) and aflatoxin (such as $B_1$, $B_2$, $G_1$ and $G_2$) in commercial herbs for food and medicine. The concentrations of the heavy metals were measured by the ICP-MS and a mercury analyzer. The aflatoxins were analyzed by a HPLC-florescence coupled with photochemical derivatization. The detection ranges of the lead, cadmium, arsenic and mercury were found to be 0.006~4.088 mg/kg, 0.002~2.150 mg/kg, ND~0.610 mg/kg and ND~0.0139 mg/kg respectively. Among the total samples, the 3 samples (2.6%) were not suitable for the specification of cadmium by the MFDS (Ministry of Food and Drug Safety). The 13 samples of the total 117 samples were aflatoxin positive (11.1%). The amount of aflatoxin $G_1$ was $0.7834{\mu}g/kg$ in the Puerariae Radix and aflatoxin $G_2$ were $0.3517{\mu}g/kg$, $0.4881{\mu}g/kg$ in two samples of the Glycyrrhizae Radix et Rhizoma, respectively. The aflatoxins $B_2$ and $G_1$ were simultaneously detected in the 10 Angelicae Gigantis Radix. The detection ranges of aflatoxins $B_2$ and $G_1$ were $0.2324{\sim}1.0358{\mu}g/kg$ and $0.7552{\sim}1.6545{\mu}g/kg$ respectively in Angelicae Gigantis Radix. The results of the current study suggest that continuous monitoring is needed for the proactive management of commercial herbs for food and medicine safety.

Evaluation on the adsorption and desorption capabilities of filter media applied to the nonpoint source pollutant management facilities (비점오염 저감시설에 적용되는 여재의 흡착 및 탈착 능력 평가)

  • Moon, Soyeon;Hong, Jungsun;Choi, Jiyeon;Yu, Gigyung;Kim, Lee Hyung
    • Journal of Wetlands Research
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    • v.17 no.3
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    • pp.228-236
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    • 2015
  • Urbanization causes many environmental, hydrological and ecological problems such as distortion of the natural water circulation system, increase in nonpoint source pollutants in stormwater runoff, degradation of surface water quality, and damage to the ecosystem. Due to the increase in impervious surface by urbanization, developed countries apply low impact development (LID) techniques as important alternatives to reduce the impacts of urbanization. In Korea, LID techniques were employed since 2012 in order to manage nonpoint source pollutants. LID technology is a technique for removing pollutants using a variety of physical, chemical and biological mechanisms in plants, microorganisms and filter media with the reduced effluence of stormwater runoff by mimicking natural water circulation system. These LID facilities are used in a variety of filter media, but an assessment has not been carried out for the comprehensive comparison evaluation of adsorption and desorption characteristics for the pollutant removal capacity. Therefore, this study was conducted to analyze the adsorption and desorption characteristics of various filter media used in the LID facilities such as sand, gravel, bioceramic, wood chips and bottom ash etc. in reducing heavy metals(Pb, Cu). In this study, the adsorption affinity for Pb in all filter media was higher than Cu. Pseudo second order equation and Langmuir-3 isotherm are more applicable in the adsorption kinetic model and adsorption isotherm model, respectively. As a result of the desorption experiment, the filter media does not exceed KSLT which is the hazardous substance leaching limit, showing the capability of the filter media in LID. The bioceramic and woodchip as filter medias were evaluated and exhibited excellent adsorption capacity for Pb.

A Survey on the Content and Safety of Red Ginseng Products (홍삼음료의 함량 및 안전성 실태조사)

  • Kim, Jong-Pil;Kim, Jin-Hee;Gang, Gyung-Lee;Yang, Yong-Shik;Hong, Sam-Jai;Kim, Eun-Sun;Moon, Yong-Woon;Lee, Jeong-Chi;Song, Hyeon-Je;Chung, Jae-Keun
    • Korean Journal of Food Science and Technology
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    • v.43 no.4
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    • pp.413-418
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    • 2011
  • This survey was conducted to monitor the safety of red ginseng products in Gwangju, in 2010. Among 100 samples, 37 were beverages, 5 were functional health foods on the market, and 58 were beverages from a tailor-made shop. All samples were negative for coliform bacteria. Aerobic plate counts were detected from 13 samples in the 58 tailor-made products but not detected in the other types of products. Benzoic acid was detected in 5 samples (range, 19.2-543.0 mg/kg). Among heavy metals, lead was detected, ranging from 28.8-62.3 ${\mu}g/kg$, cadmium, from 1.15-4.18 ${\mu}g/kg$, and mercury from 0.10-0.18 ${\mu}g/kg$. Benzopyrene was not detected in any samples. Ginsenoside Rg1 and Rb1 were detected in 0.1-23.4 mg/90 mL of beverages and 12.1-66.8 mg/90 mL of functional health foods. These results indicate that red ginseng products are safe in terms of microbial contaminants and hazardous chemical compounds such as heavy metals and benzopyrene.

Characteristics of Trace Element Concentrations in Dust by Facilities and Areas in Daegu, Korea (대구지역 축적먼지 중 미량원소성분의 시설별 및 지역별 농도분포)

  • Song, Hee-Bong;Do, Hwa-Seok;Kwak, Jin-Hee;Kim, Jong-Woo;Kang, Jae-Hyoung;Phee, Young-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.287-295
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    • 2010
  • Dust samples have been collected from streets, schools, subway stations and households in Daegu metropolitan city. Samples were sieved through a 100 ${\mu}m$ mesh and the concentration of 14 elements have been determined using by ICP after acid extraction. Results showed that Ca, Fe, K, Mg, Mn, Na and V were influenced by natural sources while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources. The measured values were remarkably higher in components from natural sources than in components from anthropogenic sources. In particular, school dust had higher levels of Ca and Pb and subway station dust had higher levels of Cu and Zn. The percentage composition of chemicals from subway stations, households, and schools were remarkably higher in components from anthropogenic sources than that from streets. It is well recognized that anthropogenic sources were affected by indoor dust. Results of pollution index of hazardous heavy metals indicated that schools, households, and subway stations were more contaminated than streets and urban areas typically had higher pollution index than rural areas. The correlation analysis among trace elements seem to suggest that there were correlations between components of soil/road dust resuspension, and components of waste incineration and fuel combustion.

Characterization of Leaching Behaviour of Recycled Concrete for Environmental Assessment (용출특성규명을 통한 재생골재 환경성 평가)

  • Kang, S.H.;Lee, S.H.;Kwak, K.S.;Lee, J.Y.;Chung, M.K.
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.293-301
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    • 2005
  • We conducted several different leaching experiments for assessing the potential environmental risk when utilizing recycled concrete for stabilizing bridge pier. The methods include continuous batch leaching test (DIN 38414-S4), availability test (NEN 7341), pH-stat test (CEN/TC 292/WG6) and tank diffusion test (NEN 7345). The concentration ranges vary depending on the testing method. Nearly all the trace elements were low, some elements recording under detection limit. The maximum concentrations for trace elements leached throughout the whole tests are (as mg/L); Cd (0.029), Cu (0.437), Pb (0.14), Ni, Zn (0.95), Hg (0.005). Although the testing methods we used in this study are much more rigorous than other commonly adapted method including TCLP and domestic testing method for solid waste, the trace elemental concentrations are under the criteria for hazardous material set by the TCLP and domestic method. The result seems to suggest that applying the recycled concrete on stream water will be accepatable practice as for as trace elements are concerned. However, the influence of inorganics such as Ca, Mg, Ni and $SO_4^{2-}$ on aquatic ecology should be further examined.

A Survey on Parent's Recognition and Utilization Patterns of Oriental Medical Care of Preschool Students in Seong-Dong district (성동구내 어린이집 원아 부모의 소아 한방치료에 대한 인식 및 이용에 관한 조사 연구)

  • Park, You-Jin;Lee, Seul-Ji;Yoon, Ji-Yeon;Myoung, Sung-Min
    • The Journal of Pediatrics of Korean Medicine
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    • v.25 no.1
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    • pp.90-110
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    • 2011
  • Objectives: The purpose of this study is to examine the parental recognition and utilizing patterns of oriental medical care in children who live in Seong-Dong district. Methods 802 day-care center children's parents participated in the survey on recognition and utilizing patterns of oriental medical care, and 702 of the surveys were analyzed. Results: 1. 38.33% has received previous oriental medical treatments and most were received at the children's age under 12-24 months. Majority of the treatments took place in the clinical settings. By recommendation, some also received their treatment at the medical centers. One of the reasons why they receive oriental medical treatments was that they prefer to balance their treatment with the orental medical treatments along with the western's. 2. 53.85% of those who received oriental medical treatments were satisfied with their treatments. The effective treatment results were the major reason for the satisfaction. 3. 49.56% of those who had oriental medical treatments chose specific oriental medical facilities for the children's ailment. Most specific oriental medical facilities were local oriental medical clinics. Reputation fame were the main reason in choosing the clinics. 4. In 2009, 55.26% had received care in the specific oriental medical clinics for the diseases, such as respiratory symptoms, systemic symptoms, gastrointestinal symptoms, skin problems, neurological and psychiatric disease for infants, and respiratory symptoms, gastrointestinal symptoms, systemic symptoms, skin problems, neurological and psychiatric symptoms, urinary symptoms and musculoskeletal symptoms for toddlers. 5. The average duration of herbal treatment were 7-14 days, preferably 4-6 days, and preferred number of medical visits were once a week on Saturdays and preferred day for night cares were on Friday nights. Average treatment fee per treatment was less than 10,000 won which coincided with the preferred treatment fee per visit. 6. The very first medical institutions chosen by parents once their children are ill are the following; Western medical institutions, western medical clinics, pharmacies, oriental medical clinics, health centers, and lastly, oriental medical institutions. The major concerns in receiving oriental medical cares include pesticides in herbs and hazardous substances in heavy metals. Preferred form of oriental medicine was decoction, the negative feedback of oriental medicine was mostly due to the bitter taste of the oriental herbal decoctions. Preferred frequency of intake was twice a day with less than 10cc~20cc per single intake. Conclusions: Taken all together, we conclude that the growing recognition of Oriental Pediatric medicine is needed among parents.

Distribution of Chromium in Radish and Soil by Successive Leather Processing Sludge Treatment (피혁폐기물 연용에 따른 토양 및 식물체내 크롬분포)

  • Kwon, Soon-Ik;Jung, Kwang-Yong;Jung, Goo-Bok;Park, Baeg-Gyoon
    • Korean Journal of Environmental Agriculture
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    • v.19 no.1
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    • pp.20-25
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    • 2000
  • Leather processing sludge were amended in sandy loam soil successively to investigate effects on soil properties and radish crop. Total nitrogen concentration of the sludge was $60\;g\;kg^{-1}$, and chromium was $9,048\;mg\;kg^{-1}$. Sludges were treated twice each year for 4 year, and the soils were mixed with sludge to give mixtures equivalent to sludge application rates of 12.5, 25 and $50\;Mg\;ha^{-1}\;yr^{-1}$ in dry matter. Chemical fertilizers $(N-P-K\;:\;280-59-154\;kg\;ha^{-1})$ used as a control. All treated soils were croped to altari and kimjang radish in spring and fall respectively. Organic matter and Cr content in soils were increased with input rate and years of successive application of leather processing sludge, while phosphorous and potassium contents were decreased. Yields of the first harvested altari grown in sludge treated pots were less than control. In the other hand, yields of the first kimjang radish were more than control in proportion with sludge input rates until third year fall. But in fourth year, all sludge treated pot was much less than control in radish yield. Chromium contents of radish in treated soil increased and Cr contents in leaves of radish were higher than roots. Leather processing sludge was considered a potential hazardous resource to soil and crops when it use continuously, because it has high Cr concentration.

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Total content characteristics of inorganic and organic substances from wastes from thermal processes (열처리 공정에서 발생하는 무기·유기물질류의 함량특성)

  • Yeon, Jin-Mo;Kim, Woo-Il;Kang, Young-Yeul;Jeon, Tae-Wan;Jeong, Seong-Kyeong;Cho, Yoon-A;Kim, Min-Sun;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.27 no.5
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    • pp.254-260
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    • 2014
  • In this study, heavy metals, PCDD/PCDFs, PAHs in wastes generated from thermal processes were analyzed. Waste from lead thermal metalurgy (EWC 10 04) inorganic metal substances in the regulation were detected in the highest concentrations of Pb. EWC 10 04 seems to be a result of the dust. Waste from zinc thermal metalurgy (EWC 10 05) inorganic metal substances in the regulation were detected in high concentration of Zn. EWC 10 05 seems to be a result of the dust. Waste from copper thermal metalurgy (EWC 10 06) Cu in the 651,77 mg/kg to 651 times higher than regulation standard appeared in the copper thermal metallurgy process seems to be a result of dust. The concentrations of PCDD/PCDFs ranged from 0.0005~11.748 ng-TEQ/g in dust, 0.0027 ng-TEQ/g in fly ash. PCDD/PCDFs content was not detected in excessive value in regulation standard. PAHs concentration was in the range of ND~118.9 mg/kg in Naphthalene, ND~9.6 mg/kg in Phenanthrene, ND~48.4 mg/kg in Benzo[b]fluoranthene, ND~62.6 mg/kg in Benzo[a]pyrene, ND~10.7 mg/kg in Fluoranthene, ND~11.5 mg/kg in Benzo[a]anthracene.