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A Study on Selecting Personal Protective Equipment for Listed Hazardous Chemicals (1): Analysis of Hazard Ranks and Workplace Exposure Risks (사고대비물질 개인보호구 선정에 관한 연구(1): 물질유해성 및 작업위해성 분석)

  • Han, Don-Hee;Chung, Sang-Tae;Kim, Jong-Il;Cho, Yong-Sung;Lee, Chung-Soo
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.419-429
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    • 2016
  • Objectives: According to the new Chemical Control Act from the Korean Ministry of Environment (2014-259), workers handling hazardous chemicals should wear personal protective equipment (PPE). However the act simply states in basic phrases that every worker handling one or more of the 69 listed chemicals should wear PPE and does not consider the unique hazard characteristics of chemicals and work types. The main purpose of this study is to provide basic data to revise the act to suit particular work processes and situations. Methods: The hazard rank of the substances was classified based on hazardous characteristics such as LC50 and vapor pressure using matrix analysis. The workplace exposure risk of the substances was also determined through a matrix analysis based on the previously determined hazard ranks and the demands of manual handling together with the likelihood of accident frequency of the operation combined with the exposure of workers during spill accidents. Results: To meet the demands for developing subsequent guidelines for the risk-based application of PPE in hazardous workplaces, this study sorted the 69 listed chemicals into five hazardous categories based on their LC50 and vapor pressures, and also assigned exposure categories according to exposure vulnerability for various types of work which are frequently performed throughout the life cycle of the chemicals. Conclusion: In the next study, an exposure risk matrix will be produced using the hazard rank of chemicals and workplace exposure risk, and then PPE will be selected to suit the categories of the exposure risk matrix.

FT-NMR as an analytical tool for identification of inert materials in crop protection products (농약제품분석의 정성분석도구로서 FT-NMR)

  • Choi, Dal-Soon;Kyung, Suk-Hun;Hong, Su-Myeong;Jin, Yong-Duk;Lee, Hea-Keun;Kim, Jin-Hwa;Ryu, Gab-Hee
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.88-94
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    • 2004
  • In order to evaluate NMR spectrometer as the analytical tool for identification of individual adjuvant in crop protection products, the standard sample of individual adjuvant was analyzed by NMR spectrometer and then the formulation of crop protection products was also analyzed. Almost polymer system of surfactant was a co-polymer and there was an excess of ethylene. The most intense signal comes from long polyethylene blocks, 70.5 ppm. The carbonyl groups of ester group resonate at 173.5 ppm. Analytical sample was prepared in NMR tube without extraction, cleanup, concentration, or chromatographic separation. Identification of individual adjuvant in crop protection products was conducted by comparison of sample and reference spectra. NMR spectrometer was useful to analyze adjuvant in crop protection products without preparation process.

Hazardous Area Identification Model using Automated Data Collection(ADC) based on BIM (BIM기반 자동화 데이터 수집기술을 활용한 위험지역 식별 모델)

  • Kim, Hyun-Soo;Lee, Hyun-Soo;Park, Moon-Seo;Lee, Kwang-Pyo;Pyeon, Jae-Ho
    • Korean Journal of Construction Engineering and Management
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    • v.11 no.6
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    • pp.14-23
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    • 2010
  • A considerable number of construction disasters occurs on pathway. A safety management in construction sites is usually performed to prevent accidents in activity areas. This means that safety management level of hazards on pathway is relatively minified. Many researchers have introduced that a hazard identification is fundamental of safety management. Thus, algorithms for helping safety managers' hazardous area identification is developed using automated data collection technology. These algorithms primarily search potential hazardous area by comparing workers' location logs based on real-time locating system and optimal routes based on BIM. And potential hazardous areas is filtered by identified hazardous areas and activity areas. After that, safety managers are provided with information about potential hazardous areas and can establish proper safety countermeasures. This can help improving safety in construction sites.

A Study on the Convergence Safety Management Improvement of Hazardous Material Facilities (위험물시설의 융합형 안전관리 개선방안에 관한 연구)

  • Ku, Jae-Hyun
    • Journal of the Korea Convergence Society
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    • v.9 no.7
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    • pp.47-53
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    • 2018
  • The actual condition of safety management and problems for hazardous material facilities in national industrial complex are investigated and analyzed in fields of hazardous material facilities safety, fire fighting equipment safety, building safety, space safety. In most cases, the failure to comply with legal requirements and the maintenance of fire safety have been pointed out. As a result, the total number of problems identified was 466 and problems in the field of hazardous material facilities safety have been pointed out the most. Also, it was analyzed that the number of problems identified in the manufacturing facilities and general handling centers among the hazardous materials facilities was the highest. Therefore, it will contribute to strengthening the safety management capability of the national industrial complex in the future by suggesting the convergence direction of the safety diagnosis system and the systematic introduction of the precise safety diagnosis.

Future Challenges for Risk-Based Management of 135 Environmental Hazardous Substances in Children's Products (위해성에 근거한 어린이용품 함유가능 환경유해인자 135종의 관리를 위한 향후 과제)

  • Kim, Jungkon;Seo, Jung-Kwan;Kim, Taksoo;Park, Gun-Ho
    • Journal of Environmental Science International
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    • v.23 no.7
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    • pp.1277-1287
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    • 2014
  • As concerns have been raised about health effects of children's products containing hazardous chemicals on children, the Korea Ministry of Environment announced 135 environmental hazardous substances in children's products (EHSCP) which were subject to risk assessment. Therefore, it is necessary to identify the current status of EHSCP for management due to their various exposure routes and types. In this study, we investigated the exposure assessment of EHSCP as well as relevant policies implemented in domestic and foreign countries. Domestic and foreign cases of detection of EHSCP were reviewed in the literature and websites of related agencies. Due to the lack of reference values for child-specific toxicity of EHSCP, those for adults and regulatory status of EHSCP were also investigated and reviewed with literature. The related agencies of foreign countries provided 13 child-specific reference doses (RfDs), 76 RfDs, and 42 reference concentrations as toxicity reference values of the EHSCP. Among substances investigated in the studies to assess exposure of hazardous substances in children's products by the Korea Ministry of Environment, 23 substances were included in 135 EHSCP. The same studies identified 9 substances which were excluded from the 135 EHSCP. For regulatory status for hazardous substances in children's products, 44 substances (32.6 %) and 84 substances (62.2 %) of 135 EHSCP were under regulation in Korea and foreign countries, respectively. In the present study, we found that a list of 135 EHSCP should be revised to ensure children's safety.

Factors Influencing Hazardous Drinking of Women who Experienced Intimate Partner Violence (아내폭력 피해여성의 위험 음주 실태와 영향요인에 관한 연구)

  • Kim, Jae-Yop;Lee, Ji-Hyeon;Song, Hyang-Ju;Han, Saem
    • Korean Journal of Social Welfare
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    • v.62 no.4
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    • pp.275-296
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    • 2010
  • This study analyzed the state of battered women who drink at a dangerously high level and the factors that influence their hazardous drinking in order to promote their safety and their healthy adjustments. The researchers utilized the data from "Analysis of the Effectiveness of Intimate Partner Violence Offenders Correction and Treatment Program" funded by Ministry of Gender Equality, and thereby, sampled 124 battered women for interview over phone. The results of applying the WHO's standard for hazardous drinking based on frequency and quantity calculations showed that 15.7% of survey participants were classified as hazardous drinkers, either currently experiencing or having the risk of experiencing problems related to drinking. The result of carrying out a logistic regression analysis to identify the factors that influence hazardous drinking showed that household income and self-blame were factors that exerted statistically significant influence. Based on these results, clinical and practical intervention plans for helping battered women who drink hazardously were discussed.

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A Study on Predictive Models based on the Machine Learning for Evaluating the Extent of Hazardous Zone of Explosive Gases (기계학습 기반의 가스폭발위험범위 예측모델에 관한 연구)

  • Jung, Yong Jae;Lee, Chang Jun
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.248-256
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    • 2020
  • In this study, predictive models based on machine learning for evaluating the extent of hazardous zone of explosive gases are developed. They are able to provide important guidelines for installing the explosion proof apparatus. 1,200 research data sets including 12 combustible gases and their extents of hazardous zone are generated to train predictive models. The extent of hazardous zone is set to an output variable and 12 variables affecting an output are set as input variables. Multiple linear regression, principal component regression, and artificial neural network are employed to train predictive models. Mean absolute percentage errors of multiple linear regression, principal component regression, and artificial neural network are 44.2%, 49.3%, and 5.7% and root mean square errors are 1.389m, 1.602m, and 0.203 m respectively. Therefore, it can be concluded that the artificial neural network shows the best performance. This model can be easily used to evaluate the extent of hazardous zone for explosive gases.

Short-term Effect of Phosphogypsum on Soil Chemical Properties

  • Chung, Jong-Bae;Kang, Sun-Chul;Park, Shin
    • Korean Journal of Environmental Agriculture
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    • v.20 no.5
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    • pp.317-324
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    • 2001
  • Short-term effect of phosphogypsum on soil properties including acidification, salinity and metal availability were investigated under laboratory and field conditions. Phosphogypsum and mixtures of phosphogypsum and compost were added to soil and incubated in a laboratory condition with 15% moisture content. Phosphogypsum treatments were 2.5 and 5.0 g/kg soil and in the treatments of phosphogypsum and compost mixture 10 g of compost was added additionally. After the 30 days of incubation, an additional phosphogypsum and/or compost were added to the remaining soils at the same rates of the first treatments. pH, electrical conductivity, and available hazardous elements were measured periodically during the incubation. Field experiment was conducted in a plastic film house of mellon with four treatments of phosphogypsum and compost mixtures - 25+125, 50+125, 50+250 and 100+250 kg/165 $m^2$. pH, electrical conductivity, and hazardous elements in soil and total hazardous elements in leaf were measured. In the laboratory experiment, after 30 days of the first phosphogypsum application, soil pHs were lowered by 0.7-0.8 units. After the second treatment of phosphogypsum 0.2 units of additional acidification occurred. However, acidification was not observed in the soils treated with mixtures of phosphogypsum and compost. In the laboratory experiment, phosphogypsum treatments increased electrical conductivity very significantly. In field experiment, pH and electrical conductivity of soils treated with phosphogypsum were nearly the same as those of soil not treated with phosphogypsum. Since soil condition in the field study was an open system, the free acids and salts derived from phosphogypsum could be diffused down with water leaching through the soil profile and then any significant acidification or salt accumulation in the topsoil could not be observed. In both laboratory and field experiments, levels of available hazardous elements in soils treated with phosphogypsum were quite low and not different from the levels found in the control soil. Results obtained from this study suggest that application of phosphogypsum at appropriate rates on agricultural land appears of no concern in terms of acidity, salinity and hazardous element content of soil.

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A Study on Analysis of Causes for Fatal Accidents (사망재해의 원인분석에 관한 연구)

  • 백종배;민경일;이영섭
    • Journal of the Korean Society of Safety
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    • v.5 no.3
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    • pp.56-62
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    • 1990
  • This study is conducted to analyze exact causes of occupational fatalities and results are as follows : 1) The number of fatalities in establislment which employed less than 50 workers is 605(40.1% ). Age of sixties and seventies is occupied by 10 percent with there being old-aged trend. Fatal workers who were employed less than 3 months are 39.5 percent and fatal workers who were employed more than 10 years are 11.9 percent. Safety training is necessary for newly recruited and long employed workers. 2) Accident type is, in sequence, fall from elevation, traffic accident, disease, contact with electric current, and hazardous condition is, in order, inadequate guard, hazardous method or procedure, public hazard, and agency of accident is, in sequence, temporary structure/building/structure, powered transport vehicle, passenger vehicle, hoisting or lifting apparatus, and unsafe act is, in order, driving error, failure to secure or warn. 3) The results of cross-tabulation for hazardous condition and accident type is, in sequence, traffic accident by public hazard, fall from elevation by hazardous method or procedure, fall from elevation as well as contact with elctric current by inadequate guard. The result of cross-tabulation for agency of accident and accident type is, in order, fall from elevation by temporary structure/building/structure, traffic accident of passenger vehicle and powered transport vehicle, contact with electric apparatus. The result of cross-tabulation for agency of accident and hazardous condition is, in sequence, public hazard of passenger vehicle, hazardous method or procedure of temporary structure/building/structure, publit hazard of powered transport vehicle, inadequate guard of temporary structure/building/structure. The result of cross-tabulation for unsafe act and accident type is, in sequence, traffic accident by driving error, fall from elevation by inattention to footing or surrounding, contact with electric current by secure or warn.

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Development of Hazardous Materials Management Standard for Decoction Type of Personalized Herbal Medicine

  • Jeong, Hye-In;Kim, Kyeong-Han;Won, Jae-Hee;Sung, Gi-Un;Kim, Ji-Won;Han, Ji-eun;Sung, Angela Dong-Min;Park, Eun-Jung;Sung, Soo-Hyun
    • Journal of Pharmacopuncture
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    • v.23 no.2
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    • pp.71-78
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    • 2020
  • Objectives: This study was conducted to development of hazardous materials management standards for the decoction type of personalized herbal medicines (PHMs). Methods: This study was conducted in two stages. We searched documents about criteria to use words such as 'Herb', 'Herbal medicine', and 'Botanical Drug' and summarized the results. We organized the committee consisted of seven experts, and held two meetings to reach an agreement on hazardous management standards of the decoction type of PHMs. Results: The seven documents were presented in the literature review and six items related to hazardous management standards of decoction were identified. The second expert meeting brought that a total of six items, including heavy metal, pesticide residues, sulfur dioxide, benzopyrene, mycotoxin, and micro-organism limits, were selected for safety management of decoction type of PHMs. Also, the criteria and test methods for each standard were suggested for monitoring the decoction type of PHMs. Conclusion: The study suggested hazardous material management standards and criteria for the decoction types of PHMs. In the future, it would be necessary to conduct a pilot test to ensure the validity and credibility of the safety management standard and criteria. Furthermore, the government level safety management system should be introduced to verify the safety of decoction medicines.