• Title/Summary/Keyword: harmful components

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Study on the performance characteristics of a new CO2 auto-cascade heat pump system (새로운 CO2 오토 캐스케이드 열펌프 시스템의 성능특성 연구)

  • Yun, Sang-Kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.191-196
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    • 2017
  • Owing to the harmful environmental effects of HCFC and CFC refrigerants discovered in the late 20th century, the need for environmentally friendly refrigerants such as $CO_2$ in cooling systems has increased. Air-source $CO_2$ heat pumps that utilize ambient heat in cold winter are less efficient because of a higher evaporation temperature, and it is difficult to manufacture the components of the heat pump owing to a super critical pressure of over 130 bar. This research aims to overcome these disadvantages and improve energy efficiency by introducing a new lower-pressure $CO_2$ auto-cascade heat pump system. $CO_2$-R32 zeotropic refrigerants were considered for two-stage expansion and effective cooling heat exchanging system configurations of the new auto-cascade heat pump. The results indicated that the efficiency of the two-stage expansion system was higher than that of the original one-stage expansion system. Furthermore, the two-stage expansion system showed significant performance improvements when the two-stage expansion stage from highest pressure of 70bar, intermediate expansion pressure of 25bar, and final low pressure of 10bar is applied. The COP of the new two-stage auto-cascade system (2.332) was 43.15% higher than that of the present simple auto-cascade system (1.629). Refrigerants having an evaporation temperature of $-10^{\circ}C$ or lower can be obtained that can be easily evaporated in an evaporator even at a low temperature.

AN EXPERIMENTAL STUDY OF THE DEGREE OF CONVERSION AND CYTOTOXICITY OF DUAL CURE RESIN CEMENTS (수종 이원중합 레진 씨멘트의 중합률 및 세포 독성에 관한 실험적 연구)

  • Roh, Byoung-Duck;Park, Seong-Ho;Lee, Chung-Suck
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.33-54
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    • 1995
  • The degree of conversion of composite resin was known to have influence on the mechanical properties of composite materials such as hardness, strength, wear resisitance, dimensional and color stability. Also unreacted monomer was reported to be harmful to the pulp. So the degree of conversion was a very important factor in the success of composite resin restorations. In recent, the dual cure resin cement was developed with the advocations that it could increase the curing rates in the sites where the curing ligt could not reach. Moreover many manufactors added some adhesive components in the resin cement. This study was undertaken to observe the effects of curing depth and light curing times on the degree of conversion of dual cure resin cements. CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND, by the Fourier transform Infrared analysis, changing the curing depth 1mm, 2mm and 3mm, and varying the light curing time 20 seconds, 40 seconds and 80 seconds at each depth. The cytotoxicity of dual cure resin cements was tested by the in vitro MTT method using L929 cell. The results was evaluated and compared statistically. The results were obtained as follows : 1. The dual cure resin cements reavealed various degree of conversion, CR INLAY CEMENT and DUAL CEMENT had a tendency to be more reactive to the light cure and OPTEC BOND was a more chemical one. 2. CR INLAY CEMENT and DUAL CEMENT showed the lowest degree of conversion in 2 mm depth, and in 3mm depth the degree of conversion increased, which were due to the chemical cure of dual cures, but OPTEC BOND showed decreasing degree of conversion with increasing curing dept h and all experimental groups showed lower degree of conversion than CHEMICAL group which cured in dark room with no light, so the weak light-curing of dual cure resin cement prevented the chemical cure. (P<0.05) 3. CR INLAY CEMENT and DUAL CEMENT showed increasing degree of conversion in 1 mm and 3 mm, according to the increasing cure times, but in 2 mm depth the degree of conversion decreased with increasing light-curing times and OPTEC BOND showed contrary tendency, but there was no ststistical importance in the differences among the experimental group.(P>0.05) 4. The optical density by MTT assay of extractions of CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND revealed no statitically important differences comparing with optical density of negative control.(P>0.05) 5. CR INLAY CEMENT showed a tendency of increaing cytotoxicity with days and DUAL CEMENT and OPTEC BOND showed higher cytotoxicity in 2 days than in 4 days, but there was no statistical importance in the differences.(P>0.05).

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Isolation and Characterization of Wild Yeasts for Improving Liquor Flavor and Quality (주류의 풍미 및 품질 향상을 위한 야생 효모의 분리 및 특성분석)

  • Baek, Seong Yeol;Lee, You Jung;Kim, Jae Hyun;Yeo, Soo-Hwan
    • Microbiology and Biotechnology Letters
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    • v.43 no.1
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    • pp.56-64
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    • 2015
  • It has been known for some time to the wine industry that non-Saccharomyces yeasts play an important role in increasing volatile components through the secretion of extracellular enzymes. The objective of this study was to investigate what types of enzymes are produced by 1,007 non-Saccharomyces yeast strains isolated from Korean fermented foods. Among 1,007 yeast strains, the 566, 45 and 401 strains displayed β-glucosidase, glucanase and protease activity, respectively. In addition, the 563 and 610 strains possessed tolerances against cerulenin and TFL, and the 307 strain was tolerant to 15% ethanol. Yeasts producing harmful biogenic amines and hydrogen sulfide were excluded from further study, and eventually 12 yeast strains belonging to the genera Wickerhamomyces, Hanseniaspora, Pichia, Saccharomyces were identified, based on the 26S rRNA gene sequences. Among the 12 strains, the 9 and 5 strains possessed glucose and ethanol tolerance, respectively. Yeasts belonging to the genus Saccharomyces produced more than 8% alcohol, but non-Saccharomyces yeasts produced only 3% alcohol.

Manufacturing of Organic Composts from Shiitake Bedlogs (표고버섯 재배폐골목의 유기질 비료화)

  • Cho, Nam-Seok;Oh, Byung-Ik;Kim, Dok-Sik;Min, Du-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.2
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    • pp.62-69
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    • 1999
  • With increased utilization of chemical fertilizer, soil fertility is getting serious problem. As a result, using organic soil conditioner (woody wastes or sawdust compost) would be only solution to recover soil vitality. In this study, manufacturing and characteristics of organic soil conditioner from Shiitake bedlogs (woody wastes) were studied. Also, to investigate the effect of continuous application of this bedlog compost on growth of plants, growth tests for radish and tree seedlings were done. The results are as follows ; Analytical results of decayed and fresh wood materials showed almost same as its wood components. The mixing ratio of raw materials with the other filling materials is essential for the manufacturing as well as good quality of its compost during composting process. In this experiment, mixing 12kg of urea, 25kg of lime, 40kg of chicken shit, and small amount of fermentation aids corresponding to I ton of sawdust resulted in good composts. Their moisture contents were adjusted to about 55%. Temperature of pile, in composting process, rose after I week and kept about above $60^{\circ}C$ for certain period. They were turned two times, 30th and 59th day, respectively, after piling. This bedlog compost contained 81.7% of high organic matter, 1.4% of a little nitrogen, 6.75 of pH and 25 - 30 of C/N ratio. There were no harmful effect on germination and growth of plants, such as radish and softwood and hardwood seedlings. Concerned to the effect of bedlog compost on soil temperature, the compost did not affect plant growth by changing soil temperature abruptly, but compensated the soil temperature such as a little increasing on the early morning, a little decreasing on the mid-day or afternoon (pm 2:00), and increasing on the early evening (pm 6:00).

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Spatial and Vertical Distribution of Polycyclic Aromatic Hydrocarbons in Sediment of the Shipyard Area in Gohyeon Bay (고현만 조선소 주변해역 퇴적물내 다환방향족탄화수소의 시공간적 분포특성)

  • Park, Pan-Soo;Kim, Nam-Sook;Yim, Un-Hyuk;Shim, Won-Joon;Kim, Gi-Beum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.2
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    • pp.68-74
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    • 2009
  • Polycyclic aromatic hydrocarbons (PAHs), one of ubiquitous organic pollutants in marine environments, are major toxic components of petroleum and are produced during the incomplete combustion of organic materials. As shipyards are located inside of natural or artificial semi-enclosed bay, even a relatively weak environmental disturbance by ship-building activity can cause severe damage to marine ecosystem in the bay. Many studies of pollution in shipyard area have been focused on the antifouling agent, like tributyltin. This study aimed to investigate the effect of ship-building activity on PAH contamination. Total PAHs concentration was higher nearby and inside shipyard area than outside, implying that shipyard could be one of major source area of PAH contamination to pose harmful effects to surrounding environments. Through PAH profile and source recognition index, the source of PAHs inputs in this area was estimated to originate from both petrogenic and pyrogenic origin. PAH levels showed a significant correlation with total butyltins, indicating that ship-building activity influenced PAH concentration and distribution. Vertical distribution of PAHs historically confirmed the correlation between shipbuilding activity and PAHs contamination.

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Study on the Correlation between Air Emission Gas and Alternative Fuels Used in Cement Sintering Process (시멘트 소성공정에 사용된 대체연료와 대기배출가스간 상관관계 연구)

  • Choi, Jaewon;Baek, Ju-Ik;Kwon, Sang-Jin;Won, Pil-Sung;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.286-293
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    • 2020
  • In this study, we tried to verify the correlation of the amount of combustible industrial by-products, household waste used as fuels on cement sintering process and the amount of NOx, and CO, harmful components in the exhaust gas. The analysis uses coal as natural fuel, soft plastics (plastics with properties that tend to be scattered by wind, such as vinyls), hard plastics (plastics with properties that are not scattered by wind, such as PETs, wate rubbers), and reclaimed oils as alternative fuels. Utilizing the response surface analysis (RSM) technique using the process data of 2019, such as the fuel input and combustion temperature of a domestic A cement manufacturer's sintering facilities as independent variables, and the NOx, and CO emissions to the stack as dependent variables. Correlation was analyzed. As a result, it was confirmed that the impact on the emission material differs for each waste. In particular, it was analyzed that the hard plastics increase the CO emission but have an excellent effect of reducing NOx.

Chemical Changes of the Deep Fat Frying Oils Used Commercially (일반시장에서 튀김식품에 사용된 기름의 화학적 변화)

  • Joo, Kwang-Jee;Ha, Gy-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.3
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    • pp.247-254
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    • 1989
  • In deep-fat frying, the fats and oils are used over and over again, and moisture and air are mixed in to the hot oil. Many reports related to these fats and oils have been established that thermal and oxidative decomposition products and polymers formed under the conditions of deep fat frying are harmful to health. This work was carried out with 3 domestic frying oils and 6 used oils commercially, and that there were difficulties in finding a good definition between fresh oil and used oil with adding unheated oil. As starting materials, commercially used soybean oil and rapeseed oil already passed over induction period in the lipids oxidation standard. From the qualitative point of view, they were inferior to domestic frying oils. Free fatty acid and peroxide value of heated oils were increased gradually by the time pass whereas iodine value were decreased. After adding unheated oil to the heated oil, these values were restored to that of initial levels. On the other hand, content of polar components in the heated oil were directly related to the heating time. This result showed that polar compounds may be a clear indicator of used oils. Fatty acid composition in the used oils, unsaturated fatty acids such as linoleic and linolenic acid decreased while saturated fatty acid content increased with heating.

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On the Harzadous Components of Paper Mill Sludge and Sludge Treated Soil (제지(製紙)슬러지와 슬러지 시용토양중(施用土壤中)의 유해성분(有害性分)에 관하여)

  • Lee, Kyu Seung;Choi, Jong Woo;Jo, Jeong Rye;Kim, Moon Kyu
    • Korean Journal of Agricultural Science
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    • v.19 no.2
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    • pp.194-200
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    • 1992
  • In order to use organic resource like a compost 44 samples of paper mill sludge were collected from each paper manufacturer. Some metal and PCBs(polychlorinated biphenyls) contents in/on sludge were investigated and metal contents of soil treated with kraft and paper board sludge were checked in contrast io the non-treated soil. The staple results were the same as followings. 1. Average contents of Pb in sludge ranged 14.5-25.7 ppm, and Al, Cd, Cu, Fe, Zn were similar concentration to unpolluted soil. Also, Cr and Hg were not detected from any sludge sample. 2. PCBs contents in sludge of kraft, paper board and news print paper were determined. Less than 10 ppb of $PCB_s$ contents were detected from kraft and paper board sludges, but a little more was found in sludge of news print paper. 3. Some metal contents in sludge treated soil were much similar to non-treated soil and the concentration also were ranged under the average of unpolluted natural soil. 4. From these results paper mill sludge seemed to be no harmful effects to soil.

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Resource of Food Waste using Indigenous Bacteria Isolated from Soils (토양으로부터 분리한 토착유효미생물을 이용한 음식물쓰레기의 자원화)

  • Lee, Sang-Woo;Ham, Sun Nyeoo;Shin, Taek-Soo;Kim, Hye-Kyung;Yeon, Ik-Jun;Kim, Kawng-Yul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.35-41
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    • 2009
  • This study was conducted to investigate feasibility of feedstuff for animal using food waste by fermentation mechanism of indigenous microorganism. To achieve this purpose, indigenous bacteria was isolated from soils to use as an inoculant. Enzyme test was performed to verify activity of amylase, protease and lipase using isolated bacteria. Bacteria(H1, D1), which vigorously express the enzyme activity, was selected and used in the fermentation experiments of food waste. From the analysis of 16s rDNA sequencing, H1 and D1 were identified as Bacillus subtilis and Paenibacillus polymyxa, respectively. In the fermentation experiment, food waste was mixed with rice bran and popped rice to control moisture and nutrient content. Isolated bacteria(B. subtilis and P. polymyxa) was used as an inoculant. From the measured data such as temperature, pH and ORP, it can be verified that food waste adding the indigenous bacteria was effectively fermented. From the nutritional analysis of manufactured feedstuff, it showed that the contents of crude protein, crude fat and crude fiber were enough to use as feedstuff for animal. In addition, harmful components such as Pb, Hg, Cd, aflatoxin and salmonella concentration were not exceeded permitted standards. Therefore, fermented food waste using indigenous bacteria can be used as feedstuff.

Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region (강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구)

  • Ahn, Joong-Bae;Hur, Ji-Na;Jung, Hae-Gon;Park, Jong-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.71-78
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    • 2012
  • Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.