• 제목/요약/키워드: hard carbon

검색결과 220건 처리시간 0.027초

Microstructure and Flexural Strength of Hardmetals

  • Hayashi, Koji
    • 한국분말재료학회지
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    • 제1권2호
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    • pp.119-198
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    • 1994
  • The characteristics of various important microstructural factors of WC-base hard- metals (cemented carbides) such as the amount of Co metal binder phase, the carbide grain size, the microstructural defects acting as a fracture source, the solid solubility of tungsten in the binder phase affected by the carbon content, the precipitation of $Co_3W$, the domain size of binder phase, the formation of ${\beta}-free$ layer or Co-rich layer and CVD or PVD coated layer, and the effects of these factors on the flexural strength of the hardmetals are reviewed.

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연탄재를 충전제(充塡劑)로한 고무배합(配合)에 있어서의 특성변화(特性變化) 및 그 응용(應用)에 관한 연구(硏究) (A study on the physical properties and application in rubber compounds which is used the ash of holed briquette coal as fillers)

  • 김병국;김종숭
    • Elastomers and Composites
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    • 제18권1호
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    • pp.8-12
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    • 1983
  • The purpose of this study is to apply in various fields of products economically and practically using the characteristic of ash of holed briquette coal in maximum. According to the test results, the cure rate of ash of holed briquette coal is comparatively late. But it has shown nearly same level of physical properities compared with other fillers except hard clay and grey carbon.

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High aspect ratio wrinkled patterns on polymers by glancing angle deposition

  • Ko, Tae-Jun;Ahmed, Sk. Faruque;Lee, Kwang-Ryeol;Oh, Kyu-Hwan;Moon, Myoung-Woon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.335-335
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    • 2011
  • Instability of a thin film attached to a compliant substrate often leads to emergence of exquisite wrinkle patterns with length scales that depend on the system geometry and applied stresses. However, the patterns that are created using the current techniques in polymer surface engineering, generally have low aspect ratio of undulation amplitude to wavelength, thus, limiting their application. Here, we present a novel and effective method that enables us to create wrinkles with a desired wavelength and high aspect ratio of amplitude over wavelength as large as to 2.5:1. First, we create buckle patterns with high aspect ratio of amplitude to wavelength by deposition of an amorphous carbon film on a surface of a soft polymer poly(dimethylsiloxane) (PDMS). Amorphous carbon films are used as a protective layer in structural systems and biomedical components, due to their low friction coefficient, strong wear resistance against, and high elastic modulus and hardness. The deposited carbon layer is generally under high residual compressive stresses (~1 GPa), making it susceptible to buckle delamination on a hard substrate (e.g. silicon or glass) and to wrinkle on a flexible or soft substrate. Then, we employ glancing angle deposition (GLAD) for deposition of a high aspect ratio patterns with amorphous carbon coating on a PDMS surface. Using this method, pattern amplitudes of several nm to submicron size can be achieved by varying the carbon deposition time, allowing us to harness patterned polymers substrates for variety of application. Specifically, we demonstrate a potential application of the high aspect wrinkles for changing the surface structures with low surface energy materials of amorphous carbon coatings, increasing the water wettability.

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전도성 카본블랙이 충진된 도전성 고분자 복합재료(II) -가공성을 중심으로 - (Conductive Carbon Block Filled Composites( II ) - Concentrated on Processabilily -)

  • 김진국
    • Elastomers and Composites
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    • 제34권2호
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    • pp.113-120
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    • 1999
  • 기능성고분자의 가장 대표적인 것으로 전도성 고분자를 꼽을 수 있다. 상업화된 전도성 고분자 제조법으로서 전도성 물질의 충진에 의한 방법이 널리 사용되고 있지만 전도성 기능이 강하게 나타나지 않아 연구 개발 중이다. 이러한 이유중의 하나로 카본블랙과 고분자수지의 컴파운딩에 대한 이해 부족이 지적되고 있어, 본문은 전도성 카본블랙을 이용한 컴파운딩에 대한 기술 개발을 중심으로 이루어졌다. 연구 결과 섬유모양의 카본블랙이 고무가공 면에서 쉽지가 않았으나 전도성 면에서는 구 모양과 막대모양의 카본블랙 보다 우수한 결과를 나타내었다. 따라서 섬유모양 카본블랙과의 가공성을 높이기 위하여 oil을 첨가하여 가공한 결과, 물성면에서는 약간 뒤떨어지나 가공성이 향상되었으며 전도성 면에서도 우수한 결과를 나타났다. 또한 용액가공에 대한 연구를 용융가공과 비교하면서 수행하였다.

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도로시설물 운영 및 유지관리단계의 탄소배출원단위 구축 (Calculation of Basic Unit of Carbon Emissions in Operation and Maintenance Stage of Road Infrastructure)

  • 곽인호;김건호;위대형;박광호;황용우
    • 대한교통학회지
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    • 제33권3호
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    • pp.237-246
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    • 2015
  • 도로시설물의 운영 및 유지관리는 기능을 유지하기 위해 반복적으로 이루어지는 온실가스 배출 활동이며, 도로를 계획 및 시공, 운영, 유지보수의 전과정 측면에서 봤을 때 이미 건설된 도로시설물과 신규로 건설하고자 하는 도로시설물에 대해 탄소배출을 줄이기 위한 접근이 용이한 활동이기 때문에 운영 및 유지관리 단계에서 탄소배출량의 정량화는 매우 중요하다. 하지만 도로시설물의 운영 및 유지관리 단계에서의 정량적인 탄소배출량 산정은 분산되어 있는 활동 자료의 수집의 어려움과 탄소배출량 산정 과정의 복잡성을 이유로 정량적인 탄소배출량 산정은 이루어지지 않고 있다. 이에 본 연구에서는 도로시설물의 운영 및 유지보수 단계에서 탄소배출원단위를 산정하였고, 이를 활용해 2012년 기준으로 국내에 건설되어 운영중인 고속국도 및 일반국도에 대해 탄소배출량을 산정하였다.

Analysis of Amorphous Carbon Hard Mask and Trench Etching Using Hybrid Coupled Plasma Source

  • Park, Kun-Joo;Lee, Kwang-Min;Kim, Min-Sik;Kim, Kee-Hyun;Lee, Weon-Mook
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.74-74
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    • 2009
  • The ArF PR mask was. developed to overcome the limit. of sub 40nm patterning technology with KrF PR. But ArF PR difficult to meet the required PR selectivity by thin PR thickness. So need to the multi-stack mask such as amorphous carbon layer (ACL). Generally capacitively coupled plasma (CCP) etcher difficult to make the high density plasma and inductively coupled plasma (ICP) type etcher is more suitable for multi stack mask etching. Hybrid Coupled Plasma source (HCPs) etcher using the 13.56MHz RF power for ICP source and 2MHz and 27.12MHz for bias power was adopted to improve the process capability and controllability of ion density and energy independently. In the study, the oxide trench which has the multi stack layer process was investigated with the HCPs etcher (iGeminus-600 model DMS Corporation). The results were analyzed by scanning electron microscope (SEM) and it was found that etching characteristic of oxide trench profile depend on the multi-stack mask.

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유한요소해석에 의한 DLC 코팅면의 마멸기구에 대한 연구 (A Study on Wear Mechanism in Diamond-like Carbon Coated Surface by Finite Element Analysis)

  • 이준혁;박태조
    • Tribology and Lubricants
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    • 제29권6호
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    • pp.366-371
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    • 2013
  • Various heat treatment and surface coating methods have been applied to machine parts. Nowadays, diamond-like carbon (DLC) coatings are widely used because of their excellent tribological characteristics. Despite the numerous studies on DLC-coated engineering surfaces, the exact wear mechanisms related to the coating thickness and elastic modulus have not been fully examined. In this study, a sliding contact problem between a small spherical hard particle and a DLC-coated steel surface is analyzed using a nonlinear finite element code, MARC. The maximum principal stress distributions and deformed surfaces are compared for different coating thicknesses and Young's modulus values. Plastically deformed surface shapes such as a groove and torus indicate that the most dominant wear mechanism for a DLC-coated surface is abrasive wear. Fatigue wear can also play a role in a case where the coating thickness is relatively large and the elastic modulus is high.

Electrochemical Properties of Lithium Sulfur Battery with Silicon Anodes Lithiated by Direct Contact Method

  • Kim, Hyung Sun;Jeong, Tae-Gyung;Kim, Yong-Tae
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.228-233
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    • 2016
  • It is hard to employ the carbon materials or the lithium metal foil for the anode of lithium sulfur batteries because of the poor passivation in ether-based electrolytes and the formation of lithium dendrites, respectively. Herein, we investigated the electrochemical characteristics of lithium sulfur batteries with lithiated silicon anode in the liquid electrolytes based on ether solvents. The silicon anodes were lithiated by direct contact with lithium foil in a 1M lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) solution in 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL) at a volume ratio of 1:1. They were readily lithiated up to ~40% of their theoretical capacity with a 30 min contact time. In particular, the carbon mesh reported in our previous work was employed in order to maximize the performance by capturing the dissolved polysulfide in sulfur cathode. The reversible specific capacity of the lithiated silicon-sulfur batteries with carbon mesh was 1,129 mAh/g during the first cycle, and was maintained at 297 mAh/g even after 50 cycles at 0.2 C, without any problems of poor passivation or lithium dendrite formation.

無煙炭의 反應成에 關한 硏究 (第1報) 反應成 試驗藏置의 試作 (Studies on the Reactivity of Korean Anthracites. (Part 1) Setting-Up of an Apparatus for Testing the Reactivity of Korean Anthracites)

  • 한태희;이재성;신성식
    • 대한화학회지
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    • 제6권1호
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    • pp.47-53
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    • 1962
  • The "reactivity" of coal is one of the important characteristics of a coal used as a process raw material as well as a fuel. In this study, the reactivity was measured in terms of the magnitude of the reaction rate constant in the reduction of carbon dioxide with coal. A reactivity-testing apparatus was designed and constructed, and its performance characteristics were investigated by using Korean anthracite and hard-wood charcoal. Experiments were carried out at temperatures ranging from 750 to 1100$^{\circ}C$ with pulverized Korean anthracite whose sizes range from 1 to 10mm in diameter. Results showed that the reaction rate constant was not appreciably affected by the particle size investigated, and the reactivities of the anthracite and the charcoal were found to be a function of reaction temperature alone. It was also found that a straight line was produced when the logarithm of the rate constant is plotted against the reciprocal of the absolute temperature. The reactivities of the charcoal were found to be 2 to 10 times higher than those of the anthracite at a temperature ranging from 750 to 1100$^{\circ}C$, and 90% of carbon dioxide was reduced to carbon monoxide by the anthracite at a temperature above 1050$^{\circ}C$.

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카본 세라믹 복합재 디스크의 벤트 구조 최적화를 통한 냉각성능 향상에 관한 연구 (A Study on Improvement of Cooling Performance through Vent Structure Optimization of Carbon Ceramic Composite Disc)

  • 심재훈;신웅희;이중희;전갑배;김병철;곽정후;임동원;현은재;전태형;이재만
    • 자동차안전학회지
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    • 제11권1호
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    • pp.23-29
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    • 2019
  • Recently, use of composite materials has been increasing for body structures and chassis parts in the car industry because of weight reduction effect and excellent mechanical thermal characteristics. However, application of composite materials in brake system is very difficult because it is hard to obtain enough brake performance due to low heat storage capacity of the composite materials. In this paper, we will present new carbon ceramic composite disc with high flow characteristic. To obtain this characteristic, new vent structures were designed by using ARIZ method and substance-field model analysis. The flow effect of these vent structures on the brake performance was verified by pugh matrix and cooling test. The test results show improvement of cooling performance up to $30^{\circ}C$. Finally, These results will improve brake the reliability of the brake performance for the high performance vehicles and electric vehicles.