• Title/Summary/Keyword: hard carbon

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Investigation of Amorphous Carbon Film Deposition by Molecular Dynamic Simulation (분자 동역학 전산모사에 의한 비정질 탄소 필름의 합성거동 연구)

  • 이승협;이승철;이규환;이광렬
    • Journal of the Korean Vacuum Society
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    • v.12 no.1
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    • pp.25-34
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    • 2003
  • Deposition behavior of hard amorphous carbon film was investigated by molecular dynamic simulation using Tersoff potential which was suggested for the interaction potential between carbon atoms. When high energy carbon atoms were collided on diamond (100) surface, dense amorphous carbon film could be obtained. Physical properties of the simulated carbon film were compared with those of the film deposited by filtered cathodic arc process. As in the experimental result, the most diamond-like film was obtained at an optimum kinetic energy of the incident carbon atoms. The optimum kinetic energy was 50 eV, which is comparable to the experimental observation. The simulated film was amorphous with short range order of diamond lattice. At the optimum kinetic energy condition, we found that significant amount of carbon atom were placed at a metastable site of distance 2.1 $\AA$. By melting and quenching simulation of diamond lattice, it was shown that this metastatic peak is Proportional to the quenching rate. These results show that the hard and dense diamond-like film could be obtained when the localized thermal spike due to the collision of high energy carbon atom can be effectively dissipated to the lattice.

Relationship between Hard Disk Surface Damage and Data Loss (하드디스크의 표면파손과 데이터 손실과의 관계)

  • 이성창;박용식;전규찬;김대은
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.2
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    • pp.35-42
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    • 2000
  • In recent years the recording density of hard disks has increased significantly largely due to the decreasing flying height. As a result of decreased flying height, the reliability issue become more critical. In this work the relationship between hard disk surface damage and data loss was investigated by using an actual hard disk drive. The purpose of this research was to identify the key factor which leads to data loss. It was shown that data loss is directly related to the physical damage of the Co-magnetic layer and there was no data loss when only carbon protective coating was damaged by the diamond tip.

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Development of Polygonal Model for Shape-Deformation Analysis of Amorphous Carbon Hard Mask in High-Density Etching Plasma (고밀도 식각 플라즈마에서 비정질 탄소 하드 마스크의 형상 변형 해석을 위한 다각형 모델 개발)

  • Song, Jaemin;Bae, Namjae;Park, Jihoon;Ryu, Sangwon;Kwon, Ji-Won;Park, Taejun;Lee, Ingyu;Kim, Dae-Chul;Kim, Jong-Sik;Kim, Gon-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.53-58
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    • 2022
  • Shape changes of hard mask play a key role in the aspect ratio dependent etch (ARDE). For etch process using high density and energy ions, deformation of hard mask shape becomes more severe, and high aspect ratio (HAR) etch profile is distorted. In this study, polygonal geometric model for shape-deformation of amorphous carbon layered hard mask is suggested to control etch profile during the process. Mask shape is modeled with polygonal geometry consisting of trapezoids and rectangles, and it provides dynamic information about angles of facets and etched width and height of remained mask shape, providing important features for real-time HAR etch profiling.

Impact of Carbon Costs on Wholesale Electricity Market (탄소비용이 CBP전력시장에 미치는 영향)

  • Kim, Wook;Park, Jong-Bae;Lee, Joo-Won
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.4
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    • pp.700-706
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    • 2010
  • Carbon costs, either in the form of a carbon tax or through permit prices in an emissions trading scheme, would ultimately be reflected in higher electricity prices. This price "pass-through" is very critical to the effective design of new policies to curb the amount of carbon emissions. This paper sets out in a structured way the factors that determine price pass-through and how carbon costs would impact on the electricity market and the existing coal-fired power plants. It is shown that pass-through can vary drastically if the underlying dispatch potential of generators varies significantly across alternative emissions reduction scenarios. It can also vary depending on the availability of competing cleaner forms of generation. Pass-through as a measure of business performance is therefore hard to generalize across different circumstances and should be interpreted carefully.

Preparation of Carbon Solid from Dormant Mesophase Pitch without using a Binder (잠재적 이방성 핏치를 이용한 탄소성형체 제조)

  • 김제영;이성영;최재훈;박양덕
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.396-402
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    • 1992
  • Carbon solid was prepared from dormant mesophase pitch (DMPP) without using a binder and its properties were characterized. DMPP powder was stabilized with air or nitric acid in pretreatment stage so that it might not soften in later heat ttreatment stage. Optimum sintering properties were obtained from carbon powder with 2.36∼2.38 of C/H atomic ratio and 1.27∼1.40 of C/O atomic ration in air stabilization. In nitric acid stabilization, optimum sintering properties were obtained when 20∼40 vol.% of nitric acid solution was used. Compressive strength increased up to 1200$^{\circ}C$ of heat treatment temperature, and the highest compressive strength and bulk density of carbon solid from DMPP were 3000 kgf/㎤, respectively. The optical properties of carbon solid obtained was fine mosaic structure. Carbon solid after graphitization showed the properties of hard carbon due to stabilization and its shore hardness was 120.

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The Compound Refractive Lens for Hard X-ray Focusing

  • Choi, J.;Jung, J.;Park, S.;Kwon, T.
    • Journal of the Optical Society of Korea
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    • v.11 no.2
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    • pp.76-81
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    • 2007
  • The compound refractive X-ray lens (CRL) for focusing hard X-rays is investigated to determine the parameters such as the focal length, the focal spot size, and spatial distribution at the focal spot using a simple theoretical calculations and CRLs fabricated by the self-assembly method. The number of individual compound lenses are defined for the given focal length of 1 m. The X-ray energy of 1 to 40 keV is used in the calculations. The CRL for focusing hard X-rays which generated from the X-ray tube is fabricated by nanoparticle-polymer composite in the form of circular concaves. The self-assembly method is applied to form the nanoaluminum-poly (methly meth-acrylate) composite and carbon-polymer composite CRL lenses. Aluminum nanoparticles of 100 nm and carbon microparticles are diffused in the polymer solution then the high gravity up to 6000G is applied in it to form the concave lens shape. X-ray energy at 8 keV is used for characterization of the composite CRLs. The FWHM of intensity for the fabricated nanoaluminium composite CRL system, N=10 is measured as 1.8 mm, which would give about $70{\mu}m$ in FWHM at 1 m of the focal length.

Deposition of hard coatings on polycarbonate substrate by high frequency ion beam

  • Kim, Sung-Ryong;Song, Jun-Seob;Choi, Young-Joon;Kim, Jong-Hun
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.101-106
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    • 1998
  • The poor wear and scratch properties of polycarbonate have limited its application in many fields. In order to improve the wear and scratch properties of polycarbonate we have deposited diamond like carbon (DLC) coatings. The diamond like carbon coatings were made using a high frequency ion beam gun by introducing H2 and CH4 gases. The coatings were characterized with Raman spectroscopy, scanning electron microscope, ellipsometer, microscratch tester and hazemeter. Polymeric hard coating was applied onto the polycarbonate substrate before depositing a DLC coating to investigate the effect of interlayer on the system's failure mode.

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Investigation of Some Hard Coatings Synthesized by Ion Beam Assisted Deposition

  • He, Jian-Li;Li, Wen-Zhi;He, Xial-Ming;Liu, Chang-Hong
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.163-169
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    • 1995
  • Ion beam assisted deposition(IBAD) technique was used to synthesize hard coatings including diamond-like carbon(DLC), carbon nitride(CN) and metal-ceramic multilayered films. It was found that DLC films formed at low energy ion bombardment possess more $Sp^3$ bonds and much higher hardness. The films exhibited an excellent wear resistance. Nanometer multialyered Fe/TiC films was deposited by ion beam sputtering. The structure and properties were strongly dependent on the thickness of the individual layers and modulation wave length. It was disclosed that both hardness and toughness of the films could be enhanced by adjusting the deposition parameters. The CN films synthesized by IBAD method consisted of tiny crystallites dispersed in amorphous matrix, which were identified by electron diffraction pattern to be $\beta -C_3N_4$.

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Spectroscopic Studies on Cu$^{2+}$ and Ca$^{2+}$ Binding with Glycosaminoglycans$^*$

  • Lee, Ik-Choon;Yang, Ki-Yul
    • Bulletin of the Korean Chemical Society
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    • v.1 no.3
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    • pp.83-87
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    • 1980
  • The Murrell-Fueno type of the intermolecular perturbation approach was applied to the acid-catalyzed hydrolysis of diformamide. The results show that: (1) the attack of a water molecule on the protonated carbonyl carbon is favored over that on the unprotonated carbonyl carbon; (2) the ${\sigma}$-approach model of water is preferred to the ${\pi}$-approach model; (3) the major contributing term to the total energy is the Coulomb energy, $E_q$, especially in the ${\sigma}$-approach, while the contribution of $E_{ct}$ (and $E_k$) increases moderately in the ${\pi}$-approach; (4) the reaction is a charge-controlled one, a hard-hard type in the language of the HSAB principle.