• 제목/요약/키워드: hard Coating

검색결과 270건 처리시간 0.026초

국내 구리 함유 폐자원의 재활용 상용화 기술 및 연구동향 분석 (Analysis of Commercial Recycling Technology and Research Trend for Waste Cu Scrap in Korea)

  • 강이승;안혜란;강홍윤;이찬기
    • 자원리싸이클링
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    • 제28권1호
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    • pp.3-14
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    • 2019
  • 구리는 뛰어난 전기전도성 및 열전달 특성으로 인해 많은 전자기기 및 건축 부품에 활용되고 있고 니켈 등 다른 도금의 밑 도금으로 사용되는 등 현대 산업에서 필수적으로 사용되는 소재이다. 뿐만 아니라 차세대 산업군에서 배선, 센서, 데이터 장비의 사용량과 중요도가 더욱 커지면서 그 활용도가 더욱 커질 것으로 예상됨에도 불구하고 유럽발 경제위기, 중국 경제 저성장 기조, 트럼프 대통령의 공공 산업설비 투자 공약 등에 따라 가격이 급동하는 추세를 보여 안정적인 수급 확보 및 자원관리에 어려움을 겪는 실정이다. 국내 구리 사용량의 거의 대부분을 전기동을 이용하여 사용하기 때문에 본 연구에서는 상용화 되고 있는 구리 재활용 기술과 연구 단계에 머물고 있는 구리 재활용 기술을 구분하여 각각의 기술적 수준을 파악하였다. 이를 통해 각 공정별 특징과 향후 기술개발이 요구되는 분야를 고찰해 보고자 하였다.

스핀코팅 하드마스크용 유-무기 하이브리드 소재에 관한 연구 (Organic-inorganic Hybrid Materials for Spin Coating Hardmask)

  • 유제정;황석호;김상범
    • 공업화학
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    • 제22권2호
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    • pp.230-234
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    • 2011
  • 반도체산업은 고집적화된 회로를 요구하면서 미세 패턴을 형성하기 위해 계속해서 발전해가고 있다. 이에 반도체 산업에서 미세 패턴을 형성하기 위하여 하드마스크를 도입하여 사용되고 있다. 일반적으로 하드마스크는 화학증기증착법(CVD) 공정을 이용하여 다층구조로 제작된다. 이에 본 연구에서는 스핀공정이 가능하고 단층의 하드마스크용 조성물을 제조하기 위하여 유-무기 하이브리드 중합체를 이용하여 그 특성에 대하여 연구하였다. Silanol로 처리된 siloxane 화합물과 acetonide 그룹을 가지는 propionic acid를 에스터화 반응을 통하여 얻은 유-무기 하이브리드 중합체에 가교제 및 첨가제들의 첨가로 광학적, 열적, 그리고 표면 특성이 조절된 하드마스크 막을 제조하였다. 또한 하드마스크 막과 감광층의 식각비를 비교하여 유-무기 소재의 하이브리드 중합체에 대해 미세패턴을 형성시킬 수 있는 하드마스크 막으로써의 유용성을 확인하였다.

Effect of sowing italian ryegrass using unmanned helicopter under the established rice field on labour saving and rice growth

  • Kim, Young-Gwang;Seong, Deok-Gyeong;Nam, Jin-Woo;Choi, Young-Jo;Hong, Kwang-Pyo
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2017년도 9th Asian Crop Science Association conference
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    • pp.268-268
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    • 2017
  • Common sowing method of italian ryegrass (IRG) has been using the backpack seed sprayer (BSS) in Korea. It has weak point including a hard work and a little sowing area. This study was conducted to find out the effects of sowing IRG using unmanned helicopter (UH) under the established rice field. We checked the labour saving of sowing IRG and the growth and yield of rice after using IRG as forage crop. Two sowing implements(using by UH and backpack seed sprayer (BSS)) were tested for the ability of sowing IRG. For proper pretreatment of IRG seeds for aerial sowing using with UH, we tested one-day soaking seeds, iron-coated seeds, coated seeds sold in stores and untreated seeds. Aerial sowing of IRG seeds using UH was tested under the speed 10 km/h and flying altitude 3~4m. We tried to confirm the effects on rice growth in a paddy field after IRG had been used as forage in mid May. In 6 hours of seeding per day, UH had a seeding area of 21.8 hectares, three times wider than BSS. UH had a decrease of about 63 percent of sowing-seed cost in comparison with BSS. In the IRG aerial sowing using UH, coating seeds had the wider sowing width of 5~6 meter than 3~4 meter untreated seeds. Residual dry matter of IRG after using forage had 4.5 ton per hectare and 20 percent of top dry matter. The amount of nitrogen remaining in residual IRG in the soil was 12 kg per hectare, and the other nutrients such as calcium and potassium was incorporated into the soil with less than 10 kg/ha. The rice yield after the harvesting IRG was 5 percent higher than that of rice single cropping. Consequently, IRG sowing using UH was effective in reducing sowing time and sowing cost compared with conventional methods and, it is considered that there is a positive effect on the rice cultivation compared to rice single cropping.

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PEMOCVD of Ti(C,N) Thin Films on D2 Steel and Si(100) Substrates at Low Growth Temperatures

  • Kim, Myung-Chan;Heo, Cheol-Ho;Boo, Jin-Hyo;Cho,Yong-Ki;Han, Jeon-Geon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.211-211
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    • 1999
  • Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

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HIPIMS Arc-Free Reactive Deposition of Non-conductive Films Using the Applied Material ENDURA 200 mm Cluster Tool

  • Chistyakov, Roman
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.96-97
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    • 2012
  • In nitride and oxide film deposition, sputtered metals react with nitrogen or oxygen gas in a vacuum chamber to form metal nitride or oxide films on a substrate. The physical properties of sputtered films (metals, oxides, and nitrides) are strongly influenced by magnetron plasma density during the deposition process. Typical target power densities on the magnetron during the deposition process are ~ (5-30) W/cm2, which gives a relatively low plasma density. The main challenge in reactive sputtering is the ability to generate a stable, arc free discharge at high plasma densities. Arcs occur due to formation of an insulating layer on the target surface caused by the re-deposition effect. One current method of generating an arc free discharge is to use the commercially available Pinnacle Plus+ Pulsed DC plasma generator manufactured by Advanced Energy Inc. This plasma generator uses a positive voltage pulse between negative pulses to attract electrons and discharge the target surface, thus preventing arc formation. However, this method can only generate low density plasma and therefore cannot allow full control of film properties. Also, after long runs ~ (1-3) hours, depends on duty cycle the stability of the reactive process is reduced due to increased probability of arc formation. Between 1995 and 1999, a new way of magnetron sputtering called HIPIMS (highly ionized pulse impulse magnetron sputtering) was developed. The main idea of this approach is to apply short ${\sim}(50-100){\mu}s$ high power pulses with a target power densities during the pulse between ~ (1-3) kW/cm2. These high power pulses generate high-density magnetron plasma that can significantly improve and control film properties. From the beginning, HIPIMS method has been applied to reactive sputtering processes for deposition of conductive and nonconductive films. However, commercially available HIPIMS plasma generators have not been able to create a stable, arc-free discharge in most reactive magnetron sputtering processes. HIPIMS plasma generators have been successfully used in reactive sputtering of nitrides for hard coating applications and for Al2O3 films. But until now there has been no HIPIMS data presented on reactive sputtering in cluster tools for semiconductors and MEMs applications. In this presentation, a new method of generating an arc free discharge for reactive HIPIMS using the new Cyprium plasma generator from Zpulser LLC will be introduced. Data (or evidence) will be presented showing that arc formation in reactive HIPIMS can be controlled without applying a positive voltage pulse between high power pulses. Arc-free reactive HIPIMS processes for sputtering AlN, TiO2, TiN and Si3N4 on the Applied Materials ENDURA 200 mm cluster tool will be presented. A direct comparison of the properties of films sputtered with the Advanced Energy Pinnacle Plus + plasma generator and the Zpulser Cyprium plasma generator will be presented.

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자동차 구조용 접착제를 이용한 자동차용 Pre-primed 도료의 비용접식 접합공정 적용 (Automotive Pre-primed Coatings with Automotive Structural Adhesive for Non-weldable Binding Process)

  • 문제익;이용희;김현중;노승만;남준현;김민수;김준기;김종훈
    • 접착 및 계면
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    • 제12권3호
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    • pp.99-104
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    • 2011
  • 21세기 들어 자동차 도료산업은 엄격한 환경규제 및 생산 효율성 향상 및 더 낮은 생산비용으로 자동차용 도료를 생산하기 위하여 세정 및 전처리 과정을 삭제한 pre-primed 도장 시스템이 연구되고 있다. 이러한 pre-primed 도료 시스템의 경우, 차체 조립 전 단계에 강판이 유기 도막으로 도장되어있기 때문에 기존의 용접을 통한 조립이 힘들어 용접공정을 대체할 수 있는 새로운 비용접식 접합기술의 개발이 필요한 실정이다. 본 연구에서 비용접식 pre-primed 시스템에 적용하기 위하여 유연성과 성형성이 향상된 polyester계의 primer 1과 polyurethane계의 primer 2를 개발하였다. 개발된 도료의 물리적인 물성과 도장면의 부착력 평가 결과, primer 1이 primer 2에 비하여 연필경도, 내용제성, 유연성 및 접착제와의 부착력이 뛰어남을 알 수 있었으며, 용접공정을 대신한 비용접식 pre-primed 시스템의 가능성을 확인할 수 있었다.

메탄올 작업장 노출 평가에의 EU REACH 프로토콜 적용: Targeted Risk Assessment (The Application of an EU REACH Protocol to the Occupational Exposure Assessment of Methanol: Targeted Risk Assessment)

  • 나진성;송문환;최은경
    • 한국환경보건학회지
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    • 제47권5호
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    • pp.432-445
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    • 2021
  • Background: The European Centre for Ecotoxicology and Toxicology of Chemicals' Targeted Risk Assessment (ECETOC TRA) tool has been recognized by EU REACH as a preferred approach for calculating worker health risks from chemicals. Objectives: The applicability of the ECETOC TRA to occupational exposure estimation from industrial uses of methanol was studied by inputting surveyed and varied parameters for TRA estimation as well as through comparison with measured data. Methods: Information on uses of methanol was collected from seven working environment monitoring reports along with the measured exposure data. Input parameters for TRA estimation such as operating conditions (OCs), risk management measures (RMMs) and process categories (PROCs) were surveyed. To compare with measured exposures, parameters from the surveyed conditions of ventilation but no use of respiratory protection were applied. Results: PROCs 4, 5, 8a, 10, and 15 were assigned to ten uses of methanol. The uses include as a solvent for manufacturing sun cream, surfactants, dyestuffs, films and adhesives. Methanol was also used as a component in a release agent, hardening media and mold wash for cast products as well as a component of hard-coating solution and a viscosity-controlling agent for manufacturing glass lenses. PROC 8a and PROC 10 of a cast product manufacturer without LEV (local exhaust ventilation) and general ventilation as well as no respiratory protection resulted in the highest exposure to methanol. Assuming the identical worst OCs and RMMs for all uses, exposures from PROC 5, 8a, and 10 were the same and the highest followed by PROC 4 and 15. The estimation resulted in higher exposures in nine uses except one use where measured exposure approximated exposures without RMMs. Conclusions: The role of ECETOC TRA as a conservative exposure assessment tool was confirmed by comparison with measured data. Moreover, it can guide which RMMs should be applied for the safe use of methanol.

노인 대상 스마트폰 앱 콘텐츠를 이용한 구강 근력 강화 훈련의 기능 개선 효과 (Effects of smartphone app-based oral muscle strength training on functional improvement in the elderly)

  • Kyeong-Hee Lee;Yoon-Young Choi;Eun-Seo Jung;Hyun-Young Moon;Mi-Sook Yoon;Kyeong-Jin Lee
    • 한국치위생학회지
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    • 제24권3호
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    • pp.209-218
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    • 2024
  • 연구목적: 본 연구는 스마트폰 앱을 이용한 구강근력 강화훈련 교육 콘텐츠를 개발하고 노인들에게 적용한 후 효과를 살펴보고자 하였다. 연구방법: 훈련은 2023년 8월 말부터 10월 초까지 6주 동안 총12회를 적용하였다. 수행 장소는 참여 대상자의 소속기관이며, 1회당 소요시간은 약60분이었다. 연구결과: 구강건강 증진 효과는 치면세균막(p<0.05), 치은염(p<0.001), 설태(p<0.01), 타액분비량(p<0.001)에서 유의한 차이를 보였다. 프로그램 실시 전에 비해 치면세균막은 0.69 감소, 치은염은 0.99 감소, 설태는 1.11 감소, 타액 분비량은 0.73 증가하였다. 사후 두 그룹간의 비교에서도 치면세균막(p<0.001), 치은염(p<0.001), 설태(p<0.05)는 유의한 차이를 보였다. 구강근력 강화 효과는 전방부 혀 근력(p<0.001)과 후방부 혀 근력(p<0.01)에서 유의한 차이를 보였다. 전방부 혀 근력은 5.25 증가, 후방부 혀 근력은 6.82 증가하였다. 결론: 본 연구에서 개발한 스마트폰 앱 콘텐츠는 일상생활에서 노인의 구강건강 증진에 유용하게 활용될 수 있을 것으로 생각되며, 이를 위해서는 개발된 콘텐츠를 알리고 노인들이 잘 활용할 수 있도록 훈련하는 과정이 필요하다.

이중경화법을 이용한 열개시제 및 광개시제가 배합된 황칠도료의 경화속도 촉진 및 물성향상 연구 (Improving Curing Rate and Physical Properties of Korean Dendropanax Lacquer with Thermal and Photo Initiator by Dual Curing)

  • 황현득;문제익;박초희;김현중;황백
    • Journal of the Korean Wood Science and Technology
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    • 제38권4호
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    • pp.333-340
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    • 2010
  • 한반도 남부 일대에서 자생하는 황칠나무(Dendropanax morbifera Lev.) 수액으로부터 추출한 천연 도료인 황칠도료(Korean Dendropanax lacquer)는 예로부터 귀중한 예술품이나 투구, 화살, 활 등의 전쟁도구를 찬란한 황금색으로 도장하는데 사용되어 왔다. 경화 후 황금색의 투명한 도막을 형성하여 우수한 색상특성을 지니고 있을 뿐만 아니라 내후성, 내수성, 내식성 등이 우수하여, 보호도장으로써도 훌륭한 가치를 지니고 있다. 그러나 이러한 많은 장점에도 불구하고, 현대적인 여러 적용분야에 사용되지 못하고 있는 이유는 황칠도료의 생산량이 적고, 이로 인하여 가격이 매우 고가이고, 장시간의 경화시간이 소요되는 문제도 큰 원인으로 작용하고 있다. 한편 황칠 내에 광중합이 가능한 conjugated diene을 포함한 모노머가 있으며, 이러한 모노머는 일광 조사 조건등에 의하여 짧은 시간에 단단하고 황금색을 띠는 도막을 형성할 수 있음이 보고된 바가 있다. 따라서 본 연구에 서는 전통적인 황칠도료의 경화방법을 개선하고 경화속도를 촉진하기 위하여, 열개시제를 도입하여 열경화를 촉진하는 방법과 열개시제 및 광개시제를 동시에 도입하고 이중경화(dual curing)에 의해서 경화속도를 촉진하고자 하였다. 이러한 경화 속도 및 경화 거동은 적외선분광분석기(FT-IR)을 이용하여 -C=C- 이중결합 특성피크의 변화를 관찰하거나, 진자경도계(pendulum hardness tester)를 이용하여 표면 경도의 변화를 관찰함으로써 평가하였다. 또한 강체진자물성측정기(RPT)에 spot UV curing 장비를 도입하여 이중경화에 의한 경화 속도 진을 평가하였다. 본 연구의 결과 열개시제에 의하여 열경화가 촉진될 수 있을 뿐만 아니라, 이중경화에 의하여 경화속도를 향상시킬 수 있음을 확인하였다. 또한 이러한 황칠도료 경화 속도 촉진 방법을 활용하여 전통적인 역에만 사용되어온 황칠도료를 현대적인 여러 적용분야에도 확대하여 사용할 수 있는 가능성을 제시하였다.

역사기록물(Archives)의 항구적인 보존화 이용 : 보존전략과 디지털정보화 (Permanent Preservation and Use of Historical Archives : Preservation Issues Digitization of Historical Collection)

  • 이상민
    • 기록학연구
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    • 제1호
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    • pp.23-76
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    • 2000
  • In this paper, I examined what have been researched and determined about preservation strategy and selection of preservation media in the western archival community. Archivists have primarily been concerned with 'preservation' and 'use' of archival materials worth of being preserved permanently. In the new information era, preservation and use of archival materials were faced with new challenge. Life expectancy of paper records was shortened due to acidification and brittleness of the modem papers. Also emergence of information technology affects the traditional way of preservation and use of archival materials. User expectations are becoming so high technology-oriented and so complicated as to make archivists act like information managers using computer technology rather than traditional archival handicraft. Preservation strategy plays an important role in archival management as well as information management. For a cost-effective management of archives and archival institutions, preservation strategy is a must. The preservation strategy encompasses all aspects of archival preservation process and practices, from selection of archives, appraisal, inventorying, arrangement, description, conservation, microfilming or digitization, archival buildings, and access service. Those archival functions should be considered in their relations to each other to ensure proper preservation of archival materials. In the integrated preservation strategy, 'preservation' and 'use' should be combined and fulfilled without sacrificing the other. Preservation strategy planning is essential to determine the policies of archives to preserve their holdings safe and provide people with a maximum access in most effective ways. Preservation microfilming is to ensure permanent preservation of information held in important archival materials. To do this, a detailed standardization has been developed to guarantee the permanence of microfilm as well as its product quality. Silver gelatin film can last up to 500 years in the optimum storage environment and the most viable option for permanent preservation media. ISO and ANIS developed such standards for the quality of microfilms and microfilming technology. Preservation microfilming guidelines was also developed to ensure effective archival management and picture quality of microfilms. It is essential to assess the need of preservation microfilming. Limit in resources always put a restraint on preservation management. Appraisal (and selection) of what to be preserved was the most important part of preservation microfilming. In addition, microfilms with standard quality can be scanned to produce quality digital images for instant use through internet. As information technology develops, archivists began to utilize information technology to make preservation easier and more economical, and to promote use of archival materials through computer communication network. Digitization was introduced to provide easy and universal access to unique archives, and its large capacity of preserving archival data seems very promising. However, digitization, i.e., transferring images of records to electronic codes, still, needs to be standardized. Digitized data are electronic records, and st present electronic records are very unstable and not to be preserved permanently. Digital media including optical disks materials have not been proved as reliable media for permanent preservation. Due to their chemical coating and physical character using light, they are not stable and can be preserved at best 100 years in the optimum storage environment. Most CD-R can last only 20 years. Furthermore, obsolescence of hardware and software makes hard to reproduce digital images made from earlier versions. Even if when reformatting is possible, the cost of refreshing or upgrading of digital images is very expensive and the very process has to be done at least every five to ten years. No standard for this obsolescence of hardware and software has come into being yet. In short, digital permanence is not a fact, but remains to be uncertain possibility. Archivists must consider in their preservation planning both risk of introducing new technology and promising possibility of new technology at the same time. In planning digitization of historical materials, archivists should incorporate planning for maintaining digitized images and reformatting them in the coming generations of new applications. Without the comprehensive planning, future use of the expensive digital images will become unavailable. And that is a loss of information, and a final failure of both 'preservation' and 'use' of archival materials. As peter Adelstein said, it is wise to be conservative when considerations of conservations are involved.