• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.05a
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• pp.88-89
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• 2017

• Bulletin of the Korean Chemical Society
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• v.7 no.4
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• pp.296-298
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• 1986

Carboxylic acid anhydrides are rapidly reduced with borane-lithium chloride (1:0.1) system to give corresponding alcohols (diols in the case of cyclic anhydride) quantitatively in tetrahydrofuran at room temperature. This reagent tolerates aromatic acid ester, nitro, and halide functional groups, however competitively reduces aliphatic ester and nitrile groups.

• Journal of the Korean Chemical Society
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• v.13 no.2
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• pp.109-114
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• 1969

Halogen exchange reactions of benzyl halides have been studied in absolute acetone. Rate constants were calculated using an integrated rate expression derived for the reaction involving ion-pair association. The order of nucleophilicity of halide ions in acetone was found to be a reverse of the order in 90% aqueous enthanol solvent. This was interpreted by means of HSAB principle and solvation of halide ions. Net increase in rate of reaction in acetone compared with the rate in protic solvent resulted from large increase in ${\Delta}S^\neq$ rather than decrease in ${\Delta}H^\neq$. The solvation of the transition state also contribute to the net increase in rate.

• The Transactions of the Korean Institute of Power Electronics
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• v.4 no.5
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• pp.405-412
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• 1999

Meta! Halide Discharge(]\1HD) Iamps have good color rendition, long life and good focusing capability but h have flickers bv acoustic resonances. We have designed the electronic ballast for reducing acoustic resonances in high pressure discharge tube. The ballast consists of main two parts, the first part is a half-bridge inverter to make a square wave form a and the st'Cond part is a flyback converter to combine the low frequency and high frequency component. As a r result of this study, we conclude that MHD lamps of 70 watt 따c very well light(D without acoustic resonance p phenomena by the elestronic ballast.

• Journal of Power Electronics
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• v.10 no.5
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• pp.451-460
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• 2010

This paper presents a new kind of digital control metal halide lamp electronic ballast. A zero-voltage-switch quasi-square-wave (ZVS-QSW) dual Buck converter is adopted here. In this paper, a digital control method is proposed to achieve ZVS for the converter. This ZVS can be realized during the whole working condition. Single-cycle-peak-current control is proposed to solve the problem of excessive inductor current during a low-frequency reversal transient. Power loop control is also realized and its consistency for different lamps is good. An AVR special microcontroller for a HID ballast is used to raise the control performance, and the low-frequency square-wave control method is adopted to avoid acoustic resonance. A 70W prototype was built in the laboratory. Experimental results show that the electronic ballast works reliably. Furthermore, the efficiency of the ballast can be higher than 92%.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.16 no.2
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• pp.1-8
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• 2002

The electronic ballast have much more shaking of arc than magnetic ballast because of acoustic resonance phenomenon. but it has used mare than before. In this paper, we made metal halide lamp modeling by modifying modeling of mercury lamp. To avoid acoustic resonance phenomenon, We calculated acoustic resonance frequency band. We proposed design of LCC circuit. Also, electronic ballast simulator for metal halide lamp was developed by simulink LCC parameters of inverter was decided on the basis of simulation results. After development of prototype ballast, it was verified the characteristics of simulator.

• Journal of Korean Institute of Fire Investigation
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• v.11 no.1
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• pp.31-36
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• 2008

This paper carried out a variety of analysis for a finding out the causes of fire on the street lamp. The glass bulb of 250W metal-halide(MH) lamps attached with the impurities rose the temperature by at $410.4^{\circ}$ in normal condition. Therefore, a lamp apparatus is needed the improvement for ventilation and the protection against dust. The heat of MH lamps is diffused through out the luminous tube, a glass bulb, and apparatus by degrees. The accident cause of the lamp is presumed that the accumulated heat by deposits of the inner part. It will be recommended the improvement of the structure that aren't the external impurity and accumulated heat in the MH lamps set.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.18 no.3
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• pp.7-14
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• 2004

The metal halide lamps are now widely used in the application and commercial lighting due to their attracting properties such as good color rendering and high efficiency. But, they have a serious problem of acoustic resonance using high frequency operation and they need a high voltage to ignite. So, they have not been applied to indoors. Over the past few years, a considerable number of studies have been conducted on the electronic ballast with hot restarting and resonance phenomenon. But, Very few attempts have been made at adaptive ignition method according to lamp state. In this paper is proposed electronicballast for metal halide lamps with an igniter for adaptive ignition. The proposed electronic bllast can generate a different ignition voltage according to the arc tube state.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2008.05a
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• pp.121-125
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• 2008

최근들어 메탈핼라이드램프의 아크튜브에 사용되던 석영관을 내열성 및 내식성이 우수한 alumina ceramic 재질의 아크튜브에 교체한 세라믹 메탈핼라이드램프가 개발되었다. 이러한 세라믹 메탈핼라이드램프는 기존 석영관 메탈핼라이드램프에 비해 고효율, 고연색성 및 장수명 등 우수한 특성을 가지고 있어 램프의 compact화를 통해 150W이하의 옥내 상업용 조명시설에 급속한 보급이 이루어지고 있으며 국내에서도 이러한 세라믹 메탈핼라이드램프 개발을 위한 연구가 진행 중이다. 이에 본 논문에서는 국내 세라믹 메탈핼라이트램프(Ceramic Metal Halide lamp)의 개발에 필요한 국외 선진 제품에 대한 특성 DB구축을 위하여 150W급 세라믹 메탈핼라이드램프의 아크튜브 구조 및 치수를 측정하고 weibull++6을 이용한 성능열화데이터 분석을 통해 세라믹 메탈핼라이드램프의 수명을 예측해 보았다.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.7
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• pp.1187-1194
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• 2008

This paper presents a high-power electronic ballast for a metal-hallide lamp(MHL) that employs frequency modulation(FM) technique to eliminate acoustic resonance(AR). The proposed ballast consists of a full-bridge rectifier, a power factor correction(PFC) circuit, a full-bridge(FB) inverter, an ignitor using LC resonance and an FM control circuit. Whereas a manual PFC provides advantages in terms of high reliability and low cost for constructing the circuit, it is difficult to supply a stable voltage because of the output voltage ripple that occurs with a period of 120Hz. Although the ballast can be designed with a small size and a light weight if it is driven at a switching frequency between 1 and 100 kHz, AR will occur if the eigen-value frequency of the lamp coincides with the inverter's operation frequency. The operation frequency was modulated in real time according to the output voltage ripple to compensate for the variation in power supplied to the lamp and eliminate AR. Performance of the proposed technique was validated through numerical analysis, computer simulation using PSPICE and by applying it to an electronic ballast for a prototype 1kW MHL.