• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.181-181
• /
• 2012

Direct synthesis of graphene using a chemical vapor deposition (CVD) has been considered a facile way to produce large-area and uniform graphene film, which is an accessible method from an application standpoint. Hence, their fundamental understanding is highly required. Unfortunately, the CVD growth mechanism of graphene on Cu remains elusive and controversial. Here, we present the evidences for two different growth modes of graphene on Cu investigated by varying carbon feedstock (C2H2 and CH4) and working pressure. The number of uniform graphene layer grown by C2H2 increased with increasing its injection time. A combined secondary ion mass spectrometry (SIMS) and X-ray diffraction (XRD) study revealed a carbon-diffused Cu layer created below surface region of Cu substrate with the expansion of Cu lattice. The graphene on Cu was grown by the diffusion and precipitation mode not by the surface adsorption mode, because similar results were observed in graphene/Ni system. The carbon-diffused Cu layer was also observed after graphene growth under high CH4 pressure. Based on various previous results and ours, we have successfully found that there are two selective growth modes for graphene on Cu substrate, and a desired mode can be chosen by tuning working pressure corresponding to the kind of carbon feedstock. We believe that this finding will shed light on high quality graphene growth and its multifaceted applications.

• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.302-307
• /
• 2004

This paper reviewed characteristics of fatigue crack behavior observed by changing various shapes of initial crack and magnitudes of loading in compact tension shear(CTS) specimen subjected to shear loading. In the high-loading condition, fatigue crack under shear loading propagated branching from the pre-crack tip. Meanwhile, the secondary fatigue crack in the low-loading condition which was created in the notch root due to friction on the pre-crack face grew to a main crack. Influenced by the mode II loading condition, fatigue crack propagation retardation appeared in the initial propagation region due to the reduction of crack driving force and friction on crack face. In both cases, however, fatigue cracks grew in tensile mode type. Propagation path of fatigue crack under the shear loading was 70 degree angle from the initial crack regardless of its shape and load magnitude.

• Journal of Advanced Marine Engineering and Technology
• /
• v.35 no.7
• /
• pp.899-906
• /
• 2011

Generally, load conditions of machine or structure in fatigue destruction is occurred not under single load conditions but under mixed load conditions. However, the experiment under mixing mode is insufficient because of no having test standard to the behavior of crack under mixing mode and variety of test methods, and many tests are required. In this paper measured crack direction path by created figure capture system when a experiment. Also, we studied by comparison the behavior of crack giving the change of stress ratio and inserting beach mark. Through the test under mixing mode, advancing path of crack is indicated that advancing inclined angle ${\Theta}$ (direction of specimen length) has increased depending on the increase of mixed mode impaction. It is indicated that according to the increase of mixed mode loading condition impaction under mixing mode, advancing speed of crack gets slow. Also, we found that inner crack(cross section of specimen) is progressed more rapidly than outer crack based on data through beach mark.

• Proceedings of the KSR Conference
• /
• 2003.10c
• /
• pp.79-84
• /
• 2003

A fictitious crack model was used to analyze fatigue crack growth under the influence of residual stress. In the fictitious crack model, crack is represented in terms of the separation of two adjacent interfaces and the constitutive equation between the separation and traction is assumed. The effect of fatigue loading was included in the constitutive equation by considering damage accumulation in the cohesive zone. To investigate the effect of the residual stress on the fatigue crack growth, we calculated the residual stress distribution due to transient heat flux to the specimen by finite element method. Fatigue crack growth was simulated by the fictitious crack model with repeated loading. The mode-I crack growth rates were compared for the cases with and without the compressive residual stress around the crack tip. It was observed that the mode-I crack growth can be suppressed by compressive residual stress.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.66-69
• /
• 2001

Effect of $N_2$ flow rate on properties of GaN thin films grown by plasma-enhanced molecular beam epitaxy(PEMBE) was discussed to optimize the quality of thin films. It was found that at low $N_2$ flow rate indicating high III/V flux ratio, the growth rate of GaN thin films was controlled by $N_2$ flux, and at high $N_2$ flow rate the growth rate was not controlled by $N_2$ flux any longer. It was also found that III/V flux ratio affected film quality. The film grown at higher $N_2$ flow rate showed low background carrier concentration, higher carrier mobility, and narrow FWHM in band-edge emission of low temperature PL. It is thought that the film in more Ga flux region was grown by 2-dimensional layer-by-layer growth mode, and the film in more nitrogen region was grown by 3-D island growth mode. All samples exhibited a good crystallinity.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.29 no.9 s.240
• /
• pp.1225-1234
• /
• 2005

Mode I stress intensity factor $(K_I)$ of Notched Ring Test(NRT) specimen for measuring slow crack growth resistance was found using finite-element method. The theoretical $K_I$ value of NRT was not available in any references and could not be solved analytically. At first, in order to verify the accuracy of the finite-element approach, published $K_I$ values of several cracks were calculated and compared with finite-element results. The results were in good agreement within inherent errors of theoretical $K_I$. Finally the mode I stress intensity factor of NRT was found using 2- and 3-dimensional finite-element methods and expressed as a function of the applied load. This enabled direct comparison of resistance to slow crack growth between NRT and Notched Pipe Test(NPT), which employ different loading regime.

• International Journal of Railway
• /
• v.5 no.2
• /
• pp.71-76
• /
• 2012

Recently, axle load, operating speed and traffic density on railroads have had a tendency to increase and thereby cause additional pressure applied on used track. These operating conditions frequently result in service failure due to wear caused by wheel-rail contact and fatigue damage under cyclic loading. Among rail defects, the transverse crack, which has been the most dangerous type of fatigue damages, is developed from the subsurface crack near the rail running face and grows perpendicular to the rail surface. Therefore, it is necessary to investigate systematically the growth behavior of transverse crack for rail steel under mixed mode. In this study, the fatigue crack growth behavior of the transverse crack in rail steel was experimentally investigated under mixed-mode variable amplitude loadings.

• Journal of the Korean Institute of Rural Architecture
• /
• v.14 no.2
• /
• pp.11-18
• /
• 2012

Carlos Jimenez's 'House and Studio' was self-designed to fully function as both a home and workplace. Since its establishment in 1983, the installation has been continuously updated for almost 30 years solely under the guidance of the owner's life occurrences and routine needs. The additions and alterations succeeding the building's erection were executed to incorporate small yet symbolic fragments of the resident's memories and life episodes. The particularity of the 'House and Studio' can be compared with other residential remodeling and expansion projects in regards to certain key aspects. These means of comparison include, but are not limited to, building strictly under the direction of a master plan of development vs. allowing natural adaptations that comply with the resident's needs, rapid development vs. gradual advancement, the ornamenting by exposing showy features vs. the enhancing by addition of modest natural components, sustainability vs. sustenance, systematic room divisions vs. ambiguous spatial organization, possession as a materialized asset vs. preservation as a recollection of memories, and finally the recognition as one example of signature architecture vs. the witnessing of a maturing animated shelter. The given propositions can be further explained with the comprehension of Erich Fromm's theory of the 'Having' mode and 'Being' mode, two mechanisms that categorize the essence of human life. The 'Having' mode is described by the human greed for wealth, power, and influence, whereas the 'Being' mode is comprised of compassion, joy, and productivity. Fromm's thesis applies to the general sense of human life, but the ideas can be narrowed to accommodate the architectural standpoint. In architecture, the 'Having' mode can be translated to be the conspicuous form-oriented and self-contained object. The 'Being' mode, on the other hand, is transposed as the more natural form, incorporating the needs of the owner before commercialization. The growth of Jimenez's 'House and Studio' can be perceived as an architectural suggestion to the overcoming of human indifference caused by fixation on the 'Having' mode.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.12
• /
• pp.4371-4376
• /
• 2011

In this work, we investigate the growth behavior of silicon oxide nanowires via a solid-liquid-solid process. Silicon oxide nanowires were synthesized at $1000^{\circ}C$ in an Ar and $H_2$ mixed gas. A pre-oxidized silicon wafer and a nickel film are used as the substrate and catalyst, respectively. We propose two distinctive growth modes for the silicon oxide nanowires that both act as a unique solid-liquid-solid growth process. We named the two growth mechanisms "grounded-growth" and "branched-growth" modes to characterize their unique solid-liquid-solid growth behavior. The two growth modes were classified by the generation site of the nanowires. The grounded-growth mode in which the grown nanowires are generated from the substrate and the branchedgrowth mode where the nanowires are grown from the side of the previously grown nanowires or at the metal catalyst drop attached at the tip of the nanowire stem.

• Proceedings of the Korea Association of Crystal Growth Conference
• /
• 1999.06a
• /
• pp.81-114
• /
• 1999

The strain, surface and inerfacial energies of III-V ternary systems were calculated for three kinds of structure modes: the Frank-van der Merwe (FM) mode, the Stranski-Krastanov (SK) mode an the Volmer-Wever (VW) mode. The free energy for each mode was estimated as functions of the thickness and composition or lattice misfit. Through comparison of the free energy of each mode, it was found that the thickness-composition phase diagrams of III-V ternary systems can be determined only by considering the balance of the free energy and three kinds of structure modes appear in the phase diagrams. The SK mode appears only when the lattice misfit is large and/or the lattice layer is thick. The most stable structure of the SK mode is a cluster with four lattice layers or minimum thickness on a wetting layer of increasing lattice layers. The VW mode appears when the lattice misfit is large and the lattice layer is thin and only in the InPSb/InP and GaPSb/GaP systems which have the largest lattice misfit of III-V ternary systems. The stable region of the SK mode in the GaPSb/GaP and InPSb/InP phase diagrams is largest of all because the composition dependence of the strain energy of these systems is stronger than that of the other systems. The critical number of lattice layers below which tow-dimensional (2D) layers precede the three-dimensional (3D) nucleation in the SK mode at x=1.0 depnds on the lattice misfit.