• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2738-2742
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• 2014

Geometry relaxation effects on the formation of benzene excimer were investigated by means of ab initio calculation at SOS-CIS($D_0$)/aug-cc-pVDZ level. In the case of T-shaped dimer configuration, intermolecular interactions in the excited states are found to be nearly the same as those in the ground state and structural deformations are limited within a single molecule; the geometry relaxation effects are then negligible and singlet-triplet energy gap remains constant. As for face-to-face eclipsed dimer, on the other hand, both molecules undergo structural change. As a result, intermolecular interactions in the excited states are significantly different than those in the ground state. Although the intermolecular distances obtained from potential energy curve calculation with frozen molecular structures are in qualitative agreement, the excited-state binding energies are notably overestimated with respect to those at optimized structures. In particular, the effects are calculated to be larger in $T_1$ state and hence singlet-triplet energy gap, which reduces markedly in this configuration, is underestimated without relaxation.

• Journal of Korean Society of Disaster and Security
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• v.10 no.1
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• pp.47-53
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• 2017

Accurate exploration of the risk factors of the ground subsidence is needed to predict and evaluate the subsidence of the surrounding ground due to the excavation of the ground. In this study, we analyzed the distribution of soil relaxation area by analyzing the behavior around the ground excavation site and simulated the GPR exploration under various conditions. As a result, Although there are some differences according to the water content, distribution of the strata and the distribution of the relaxation region were confirmed in the unsaturated soil, and it was found that there was a difficulty in the GPR exploration in the saturated soil.

• Journal of the Korean Geosynthetics Society
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• v.16 no.2
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• pp.11-21
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• 2017

Ground subsidence mainly occurs due to the soil wash-away caused by cracked sewer pipes. It is necessary to understand the behavior surrounding soils with the formation of cavity and relaxation zone to set up counterplan. In this paper, a series of laboratory model tests and numerical analyses (Discrete Element Method) were performed to investigate the ground subsidence mechanism due to sewer pipe damage. For model tests, aluminum rod and trap door were used to simulate the behavior of model ground. Test results were compared with the numerical analyses conducted under the same boundary conditions with model tests. From this study, it was investigated the shape and size of cavity and relaxation zone due to the soil wash-away and a void ratio distribution of surrounding soils with relaxation properties.

• Journal of the Korean Geosynthetics Society
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• v.16 no.4
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• pp.67-74
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• 2017

In order to prevent the ground subsidence accidents caused by the occurrence of underground cavity, it is necessary to evaluate the mechanical characteristics in the relaxation zone of the underground cavity. Also, the relaxation zone including underground cavity be appropriately reinforced. This paper described analysis results based on finite element method that was conducted to analyze the mechanism for occurrence of the relaxation zone around the underground cavity. The finite element analysis applied in forced displacement was carried out to simulate the underground cavity and relaxation zone, and then there were compared with previous research results. The analysis results showed that the void distribution of soil around the underground cavity has figured out. As a result, the area of the relaxation zone could be quantitatively presented by reduction characteristics of the shear stress.

• Journal of the Society of Disaster Information
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• v.14 no.4
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• pp.399-408
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• 2018

Purpose: Recently, the ground subsidence has caused social problem, because it occurred life and economic damage. Method: Ground subsidence is different from a sink hole. Ground subsidence occurred cavities from loss of by groundwater flow, surface layer is collapsed due to relaxation and expansion. Results: According to the survey, the caused of ground subsidence are classified as ground cavities, surrounding ground relaxation and pipe joint failure. Conclution: Cavities of ground is mainly caused by cavities formed by rainfall induced infiltration of the heavy rainfall, loss of soil due to rise and fall of ground water level and repeated sewage runoff.

• Journal of the Korean Geosynthetics Society
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• v.16 no.4
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• pp.231-240
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• 2017

Recently, there have been frequent occurrences of ground sink in the urban area, which have resulted in human and material damage and are accompanied by economic losses. This is caused by artificial factors such as soil loss, poor compaction, horizontal excavation due to the breakage of the aged sewage pipe, and lack of water proof at vertical excavation. The ground sink can be prevented by preliminary restoration and reinforcement through exploration, but it can be considered that it is not suitable for urgent restoration by the existing method. In this study, a model experiment was carried out to simulate the in-ground cavities caused by groundwater flow for developing non-excavation urgent restoration in underground cavity and the range of the relaxation zone was estimated by detecting the around the cavity using a relaxation zone detector. In addition, disturbance region and relaxation region were separated by injecting gypsum into cavity formed in simulated ground. The shape of the underground cavity due to the groundwater flow was similar to that of the failure mode III formed in the dense relative density ground due to water pipe breakage in the previous study. It was confirmed that the relaxed region detected using the relaxation zone detector is formed in an arch shape in the cavity top. The length ratio of the relaxation region to the disturbance region in the upper part of the cavity center is 2: 1, and it can be distinguished by the difference in the decrease of the shear resistance against the external force. In other words, it was confirmed that the secondary damage should not occur in consideration of the expandability of the material used as the injecting material in the pre-repair and reinforcement, and various ground deformation states will be additionally performed through additional experiments.

• Journal of the Korean Geotechnical Society
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• v.35 no.1
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• pp.43-53
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• 2019

This paper described a result of finite element analysis considering sewerage damage scale and soil depth, in order to analyze quantitatively for cavity and relaxation zone of underground due to sewerage damage. The mechanical model, which was verified by previous studies, was applied to the finite element analysis. In addition, the mechanical behavior of the soil around the sewerage damage due to the soil loss was simulated by using the forced displacement. Based on finite element analysis results, characteristics of the void ratio distribution, ground subsidence, and shear stress distribution according to sewerage damage scale and soil depth were analyzed. And then, The boundaries of the underground cavity and relaxation zone were determined by using the shear stress reduction characteristics of the ground. Also, an occurrence scope of the cavity and relaxation zone was quantitatively evaluated by the change of sewerage damage scale and soil depth.

• Bulletin of the Korean Chemical Society
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• v.15 no.9
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• pp.762-765
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• 1994

Picosecond time-resolved resonance Raman spectroscopy has been used to study the photochemistry of Cr(CO$)_6$ in cyclohexane following photoexcitation at 266 nm. Photodissociative loss of CO is found to occur within our pulse width of ${\leq}$5 ps by probing the 533 c$m^{-1}$ vibrational mode of ground state Cr(CO$)_6$. The subsequent dynamics after photodissociation are interpreted in terms of solvation, vibrational and electronic relaxations. The vibrational relaxation time of 100 ps and 83 ps are observed by monitoring v=O and v=l of the 381 c$m^{-1}$ transient mode, respectively. No evidence was found for solvation and electronic relaxation occurring on a time scale of ${\leq}$5 ps.

• Bulletin of the Korean Chemical Society
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• v.16 no.12
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• pp.1184-1189
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• 1995

The rapid quenching dynamics of F center excitation by OH- defects in KCl crystals are investigated by monitoring ground state absorption bleach recovery, using a picosecond streak camera absorption spectrometer. F center absorption bleach in OH--doped crystals shows three distinguishable recovery components with the current temporal resolution, designated as slow, medium and fast components. The slow one is due to the normal relaxation process of F* centers as found in OH--free crystals. The others are consequent on energy transfer from electronically excited F centers to OH--vibrational levels. The fast component is a minor energy transfer process and resulting from the relaxation of somewhat distant, not the closest, associated pairs of F* and OH- defects. The energy transfer between widely separated F* and OH- defects opens up a recovery process via the medium component which is assisted by OH- librations, lattice vibrations and OH- dipole reorientations. The quenching behaviors of F* luminescence and photoionization by OH- are explained well by the relaxation process of the medium component.

• Journal of the Korean Institute of Landscape Architecture
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• v.22 no.3
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• pp.151-162
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• 1994

This is a comparative study on the use pattern and satisfaction of skiers between the suburban skiing ground and the resort one. The purpose of this study is to provide basic data for the planning and the management of skiing ground. The sites of case study are Yong Pyung Ski Resort (Resort type) and Bears Town(Suburban type). Data were collected from questionaire. A total of 420 questionaires were completed. And data were subjected to following analysis: First, the descriptive statistics(mean, chi-square analysis etc.) were used to compare the characteristics of the users and the use pattern of two sites. Second, factor analysis was utilized to reduce 22 satisfaction items into the smaller number of factors. Third, regression analysis was used to find the factors affecting users' overall satisfaction in each skiing ground. The findings of this study are as follows: First, it was proved that the characteristics of users between tow sites were different in terms of age, income, and skill level. Second, it was proved that the use pattern between two sites were different in terms of travel distance from home, traffic mode, length of stay, accommodation type, and the money spent per day. Third, By a principal component factor analysis several factors of satisfaction are found: In physical terms, they are 'slope and life facilities', 'recreation and lodge facilities', 'accessibility', 'crowding', and 'landscape'. In psychological terms, they are 'skiing skills and thrills', and 'relaxation and freedom'. Forth, As the result of the stepwise regression analysis, it was yielded that 'relaxation/and freedom' was most important factor to predict the overall satisfaction in both skiing ground. And it was proved that not only physical factors but also phychological(need gratifying) factors were important sources of the satisfaction.