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Characteristic of Flotation for Recovery of Copper from Copper Slag in Kazakhstan (카자흐스탄 구리제련소 슬래그 내 구리회수를 위한 선별 특성)

  • Park, Jayhyun;Choi, Uikyu;Choe, Hongil;Shin, Shunghan
    • Resources Recycling
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    • v.24 no.4
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    • pp.12-21
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    • 2015
  • Almost all copper slags contain a considerable amount of Cu (0.5 - 3.7%) close to or even higher than copper ores. A number of methods for metal recovery from copper slag were reported These methods can be classified into three categories, flotation, leaching and roasting. Sulfide flotation method for the recovery of copper from Kazahstan copper furnace slag is discussed in this investigation. 50% of copper from the slag was recovered by sulfide flotation at pH 4. meanwhile 67% of copper from the slag was recovered at pH 11. Higher copper recovery result at pH 11 rather than that at pH 4 was caused by the fact that copper sulfides were floated in particle size fraction over $100{\mu}m$ in concentrates at pH 11. When the slag were ground below $74{\mu}m$by ball milling, the recovery of copper by floation in slag improved to 78 - 83% because of copper liberation effect.

Physicochemical and Structural Characteristics of Waxy Rice Flours and Starches during Soaking Time (수침기간에 따른 찹쌀가루와 찹쌀전분의 이화학적 및 구조적 특성)

  • Park, Sara;No, Junhee;Shin, Malshick
    • Journal of the East Asian Society of Dietary Life
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    • v.26 no.5
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    • pp.457-465
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    • 2016
  • Effects of soaking time on the physicochemical and structural characteristics of waxy rice flours and starches purified from flours using the alkaline steeping method were investigated. Korean cultivar Sinseonchal waxy rice was washed and soaked in tap water (1:2 w/w) and stored at room temperature for 15 days. On each day of soaking for 0, 1,2 3, 5, 10, and 15 days, pH of soaking water was measured and rice grains were dried, ground, and passed through 100 mesh sieve. The pH was reduced to 3.90 by day 5 and increased to 4.60 by day 15. The protein and ash contents, swelling powers and solubilities of flours and starches decreased with increasing soaking time. The water-binding capacities increased while trends were not similar to soaking time. The flour particle size distribution ranged from two to four peaks with increasing soaking times. Starch granule size decreased with increasing soaking time. The peak, trough, and final viscosities of flours and starches showed similar trends until 10 days and 15 days, respectively. The starches presented higher viscosities than the flours. The branch chain length distributions of amylopectin of starches showed an increaseed DP6~12 portion and decreased DP13~24 portion with increasing soaking time of waxy rice grains.

A study on the Beneficiation of Muscovite Ore (백운모광의 품위향상에 관한 연구)

  • Lee, Jae-Jang;Choi, Soo-Yong
    • Journal of Industrial Technology
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    • v.9
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    • pp.29-41
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    • 1989
  • A general study on the upgrading of mica minerals which are mainly found in pegmatite deposits was carried out for the purpose of developing a technique for recovering mica in form of comercial grade products. By the way the grade one of about 5~6% $K_2O$ still is not developed. The target of this research work is to be establish a process for the efficient concentration of muscovite, containing more than 10% $K_2O$. The tests are applied to incraese the recovery and grade of concentrates in term of variations of conditions. The test sample consists of mainly muscovite and gangue mineral such as quartz, pyrite and chlorite. Decantation and shaking table tests were ineffective to up-grade this low grade one, but flotation method gave satisfactory result. By means of grade one, but flotation method gave satisfactory result. By means of grindability tests, an optimum result could be obtained from the sample ground to -48mesh feed size. The flotation result indicates that the dodecyl ammonium chloride used as a cationic collector is effective on the negatively charged surface, while the sodium dodecyl sulfate as an anionic collector is effective on the positively charged surface. Muscovite was floated by petroleum sulfonate as well as amine type collector, it also floated by MIBC as well as pine oil frother under well condition. Fine muscovite concentrates of about 10.68% $K_2O$ was obtained with 22.4% yield, by decantation, the muscovite concentrates of 10.10% $K_2O$ was obtained with 23.54% yield, by table concentration, the muscovite concentrates of 11.51% $K_2O$ was obtained with 23.0% yield by flotation.

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Development of Ozone Generation Technology Using Gaseous Electrical Discharge for Environment Improvement (환경개선용 기체전기방전을 이용한 오존발생기술 개발)

  • 이동헌;송현직;구건효
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.3
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    • pp.25-34
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    • 2001
  • In this paper, discharge lamp ozonizer(DLO) of a new discharge type using superposition of gaseous electrical discharge for environment improvement was designed and manufactured. DLO is equipped with 3 electrodes(central ground electrode of discharge lamp type internal high voltage electrode of mesh type and external high voltage electrode of spiral type), and it is composed of double gap(gap between discharge lamp and internal electrode, gap between discharge lamp and external electrode). Internal and external electrodes are respectively applied AC high voltage which has 180[$^{\circ}$] phase difference. Ozone is generated by overlaying of each silent discharge which is respectively came from two gaps. At the moment discharge characteristics and ozone generation characteristics of DLO were investigated in accordance with quantity of supplied gas, discharge power and the number of DLO. When ozone generated by DLO was in contact with NO gas, removal characteristics was excellent, so it confirmed that DLO could be used as air environment improvement facility.

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Effects of Properties of Binder between Electrode and Dielectric Barrier on Ozone Generation Characteristics (전극과 유전체장벽간의 접착물질의 물성변화가 오존발생특성에 미치는 영향)

  • 박승록;김진규;김형표
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.6
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    • pp.119-125
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    • 2002
  • The temperature decrease of discharge space was very important to generate the high concentration of ozone in silent discharge type ozone generator. At this time, binding materials and methods between dielectric barrier and ground electrode affected to the discharge importantly in electrical and thermal point of view. So, above two factors become very important parameters should be considered before designing the ozone generator. In this study, binders of silicone compound, electroconductive resin and charcoal were used for variations of binders properties. Resultantly, when the binding materials were used, better ozone generation characteristics were shown(maximum ozone generation 28044[ppmV] at 6.0[kV]) in comparison with the non-used case (maximum ozone generation 15944[ppmV] at 4.0[kV]). In addition, when the binding materials were used, the case of pure silicone compound showed better characteristics(maximum ozone generation 28044[ppmV] at 6.0[kV]) than the cases of conductive binding materials(maximum ozone generation 25842[ppmV] at 5.5[kV] and including the charcoal 5%).

Effect of addition of As-received IGCC slag in making geopolymer

  • Kim, Yootaek;Chae, Taesung
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.378-382
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    • 2018
  • It is a known fact that the cement production is responsible for almost 5% of total worldwide $CO_2$ emission, the primary factor affecting global warming. Geopolymers are valuable as ordinary Portland cement (OPC) substitutes because geopolymers release 80% less $CO_2$ than OPC and have mechanical properties sufficiently similar to those of OPC. Therefore, geopolymers have proven attractive to eco-friendly construction industries. Geopolymers can be fabricated from aluminum silicate materials with alkali activators such as fly ash, blast furnace slag, and so on. Integrated gasification combined cycle (IGCC) slag has been used for fabricating geopolymers. In general, IGCC slag geopolymers are fabricated with finely ground and sieved (<128 mesh) IGCC slag. The grinding process of as-received IGCC slag is one of the main costs in geopolymer production. Therefore, the idea of using as-received IGCC slag (before grinding the IGCC slag) as aggregates in the geopolymer matrix was introduced to reduce production cost as well as to enhance compressive strength. As-received IGCC slag (0, 10, 20, 30, 40 wt%) was added in the geopolymer mixing process and the mixtures were compared. The compressive strength of geopolymers with an addition of 10 wt% as-received IGCC slag increased by 19.84% compared to that with no additional as-received IGCC slag and reached up to 41.20 MPa. The enhancement of compressive strength is caused by as-received IGCC slag acting as aggregates in the geopolymer matrix like aggregates in concrete. The density of geopolymers slightly increased to $2.1-2.2g/cm^3$ with increasing slag addition. Therefore, it is concluded that a small addition of as-received IGCC slag into the geopolymer can increase compressive strength and decrease the total cost of the product. Moreover, the direct use of as-received IGCC slag may contribute to environment protection by reducing process time and $CO_2$ emission.

Development of Engine Clutch Female Flange for Tank Using SNCM439 Material (SNCM439재질의 전차용 엔진클러치 암플랜지 개발)

  • Kim, Joong-Seon;Kwon, Dae-Kyu;Ahn, Seok-Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.11
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    • pp.67-73
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    • 2021
  • Tanks are key weapons of ground combat that are equipped with powerful weapons and have strong protective bodies. One tank component, the engine clutch flange, is located in the part of the tank where the engine and transmission are installed, and it is a key part of the power transfer and shutoff. The engine clutch flange transmits high power to secure the mobility of the tank; thus, it must have high strength and hardness. In addition, high durability and safety must be ensured because tank operations must exclude concerns about damage. In this study, an engine clutch female flange for tanks made of SNCM439 was developed. The 2D design used AutoCAD programs, and the 3D shape design used CATIA programs. The structural analysis was conducted using ANSYS. The mesh grid has a tetrahedron shape and is created by adding a mid-side node. After the mechanical properties and constraints of SNCM439 were entered, the changes in the safety factor, total deformation, and Von-Mises stress were identified according to the increase in torque. Prototype processing was performed to verify the engine clutch female flange for the tank. To determine the productivity of the product, the cutting processing time was measured when processing the prototypes. Based on the results of measuring the cutting processing time, it is concluded that research is needed to improve productivity because MCT slot cutting processing is time consuming.

A Study on the Recovery of Lithium from Secondary Resources of Ceramic Glass Containing Li-Al-Si by Ca-based Salt Roasting and Water Leaching Process (Li-Al-Si 함유 유리세라믹 순환자원으로부터 Ca계열 염배소법 및 이에 따른 수침출 공정에 의한 리튬의 회수 연구)

  • Sung-Ho Joo;Dong Ju Shin;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.42-49
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    • 2023
  • The glass ceramic secondary resource containing Li-Al-Si is used in inductor, fireproof glass, and transparent cookware and accounts for 14% of the total consumption of Li, which is the second most widely used after Li-ion batteries. Therefore, new Li resources should be explored when the demand for Li is exploding, and extensive research on Li recovery is needed. Herein, we recovered Li from fireproof Li-Al-Si glass ceramic, which is a new secondary resource containing Li. The fireproof glass among all Li-Al-Si glass ceramics was used as raw material that contained 1.5% Li, 9.4% Al, and 28.9% Si. The process for recovering Li from the fireproof glass was divided into two parts: (1) calcium salt roasting and (2) water leaching. In calcium salt roasting, a sample of fireproof glass was crushed and ground below 325 mesh. The leaching efficiency was compared based on the presence or absence of heat treatment of the fireproof glass. Moreover, the leaching rates based on the input ratios of calcium salt, Li-Al-Si glass, and ceramics and the leaching process based on calcium salt roasting temperatures were compared. In water leaching, the leaching and recovery rates of Li based on different temperatures, times, solid-liquid ratios, and number of continuous leaching stages were compared. The results revealed that fireproof glass ceramics containing Li-Al-Si should be heat treated to change phase to beta-type spodumene. CaCO3 salt should be added at a ratio of 6:1 with glass ceramics containing Li-Al-Si, and then leached 4 times or more to achieve a recovery efficiency of Li over 98% from a solution containing 200 mg/L of Li.

Mapping Man-Made Levee Line Using LiDAR Data and Aerial Orthoimage (라이다 데이터와 항공 정사영상을 활용한 인공 제방선 지도화)

  • Choung, Yun-Jae;Park, Hyen-Cheol;Chung, Youn-In;Jo, Myung-Hee
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.1
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    • pp.84-93
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    • 2011
  • Levee line mapping is critical to the protection of environments in river zones, the prevention of river flood and the development of river zones. Use of the remote sensing data such as LiDAR and aerial orthoimage is efficient for river mapping due to their accessibility and higher accuracy in horizontal and vertical direction. Airborne laser scanning (LiDAR) has been used for river zone mapping due to its ability to penetrate shallow water and its high vertical accuracy. Use of image source is also efficient for extraction of features by analysis of its image source. Therefore, aerial orthoimage also have been used for river zone mapping tasks due to its image source and its higher accuracy in horizontal direction. Due to these advantages, in this paper, research on three dimensional levee line mapping is implemented using LiDAR and aerial orthoimage separately. Accuracy measurement is implemented for both extracted lines generated by each data using the ground truths and statistical comparison is implemented between two measurement results. Statistical results show that the generated 3D levee line using LiDAR data has higher accuracy than the generated 3D levee line using aerial orthoimage in horizontal direction and vertical direction.

Varietal Difference in Feed Value of Rice Straw and Its Relationship with Agronomic Traits (볏짚 사료가치의 품종간 차이 및 생육형질과의 관련성)

  • Kim Chang-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.6
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    • pp.516-521
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    • 2004
  • The straw of thirty one rice varieties were evaluated for their feed value and related agronomic traits. The rice straw were hand-harvested, dried to constant weight at $75^{\circ}C$ and ground through a 20 mesh seive in a Wiley mill, analyzed with crude protein (CP), acid detergent fiber (ADF) and neutral detergent fiber (NDF). Relative feed value (RFV) was calculated from NDF and ADF. The sum of standardized score was estimated by dry weight of rice straw, content of CP, ADF and NDF. The straw yield of Daeanbyeo was 725.9 kg/10a, showed heighest value among the varieties and remainder was in the order of Keumnambyeo, Donginbyeo #1 and Chucheongbyeo. Crude protein (CP) content in a Dasanbyeo was higher than those in other varieties. The content of ADF in a Junghwabyeo and NDF in a Sobaegbyeo were $34.3\%$ and $63.8\%$, respectively, showed lowest value among the varieties. The rice straw of Dunnaebyeo, Obongbyeo, Seoanbyeo, Keumobyeo, Hwaseongbyeo, Noganbyeo and Gyehwabyeo belonged to the high feed value varieties by estimation of cluster analysis, sum of standardized score and RFV. The content of CP was found to be positively related with dry weight of leaf and grain, but negatively related with heading days after seeding, culm length, specific leaf weight (SLW) and dry weight of stem. ADF and NDF were found to be positively related with heading days after seeding, culm length, SLW and dry weight of leaf, but negatively related with dry weight of stem. The sum of standardized score and RFV were the only positive relationship with dry weight of stem and negative relationship with other traits.