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Development of Equipment and Process on Dry Ice Blasting (드라이아이스 펠렛 세정 장치 및 공정개발)

  • Park, Jong Soo;Kim, Hotae;Kim, Sun-Geon
    • Clean Technology
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    • v.10 no.3
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    • pp.121-130
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    • 2004
  • Pelletizer of dry ice snow produced by adiabatic expansion of liquid carbon dioxide and their blaster were designed and manufactured. The blaster had a high cleaning power against various contaminants on the surface such as stain, oily dirt, lacquer film and paints with low blasting pressure and low consumption of blasting air. The capacity of hopper for dry ice pellet supply was 12 kg and the mass rate of pellet blasting was controlled in 0 to 1.2 kg/min. The impact of the pellets was independent of standoff distance within a certain limiting distance, and dependent on the impact stress, angle and mass rate of dry ice pellet blasting. On the other hand the cleaning power was influenced by thermal properties and surface roughness of the substrates and decreased in the order of glass, copper, brass, steel and acryl. The power was also affected by hardness and adhesion of the contaminant on the substrate, and decreased in the order of grease, epoxy and paint. The noise was detected during blasting in the range of 85 to 100dBA.

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Material Integrity Assessment for a Ni Electrodeposit inside a Tube

  • Kim, Dong-Jin;Kim, Myong Jin;Kim, Joung Soo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.233-238
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    • 2007
  • Due to the occasional occurrence of a localizedcorrosion such as a SCC and pitting in steam generator tubing(Alloy 600), leading to a significant economical loss, an effective repair technology is needed. For a successful electrodeposition inside a tube, many processes should be developed. Among these processes, an anode to be installed inside a tube, a degreasing condition to remove any dirt and grease, an activation condition for a surface oxide elimination, a strike layer forming condition which needs to be adhered tightly between an electroforming layer and a parent tube and a condition for an electroforming layer should be established. Through a combination of these various process condition parameters, the desired material properties can be acquired. Among these process parameters, various material properties including a mechanical property and its variation along with the height of the electrodeposit inside a tube as well as its thermal stability and SCC resistance should be assessed for an application in a plant. This work deals with the material properties of the Ni electrodeposits formed inside a tube by using the anode developed in this study such as the current efficiency, hardness, tensile property, thermal stability and SCC behavior of the electrodeposit in a 40wt% NaOH solution at $315^{\circ}C$. It was found that a variation of the material properties within the entire length of the electrodeposit was quite acceptable and the Ni electrodeposit showed an excellent SCC resistance.

MATERIAL RELIABILITY OF Ni ALLOY ELECTRODEPOSITION FOR STEAM GENERATOR TUBE REPAIR

  • Kim, Dong-Jin;Kim, Myong-Jin;Kim, Joung-Soo;Kim, Hong-Pyo
    • Nuclear Engineering and Technology
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    • v.39 no.3
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    • pp.231-236
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    • 2007
  • Due to the occasional occurrences of stress corrosion cracking(SCC) in steam generator tubing(Alloy 600), degraded tubes are removed from service by plugging or are repaired for re-use. Since electrodeposition inside a tube does not entail parent tube deformation, residual stress in the tube can be minimized. In this work, tube restoration via electrodeposition inside a steam generator tubing was performed after developing the following: an anode probe to be installed inside a tube, a degreasing condition to remove dirt and grease, an activation condition for surface oxide elimination, a tightly adhered strike layer forming condition between the electro forming layer and the Alloy 600 tube, and the condition for an electroforming layer. The reliability of the electrodeposited material, with a variation of material properties, was evaluated as a function of the electrodeposit position in the vertical direction of a tube using the developed anode. It has been noted that the variation of the material properties along the electrodeposit length was acceptable in a process margin. To improve the reliability of a material property, the causes of the variation occurrence were presumed, and an attempt to minimize the variation has been made. A Ni alloy electrodeposition process is suggested as a primary water stress corrosion cracking(PWSCC) mitigation method for various components, including steam generator tubes. The Ni alloy electrodeposit formed inside a tube by using the installed assembly shows proper material properties as well as an excellent SCC resistance.

High-Pressure Finger Injection Injury Caused by Paint Thinner: Case Report (페인트 신나에 의한 수지 고압 손상의 경험)

  • Song, Jin Woo;Choi, Hwan Jun;Kim, Mi Sun
    • Archives of Plastic Surgery
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    • v.34 no.2
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    • pp.269-273
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    • 2007
  • Purpose: High-pressure injection(HPI) injury is an injury caused by accidental injection of substances by industrial equipment. HPI injury of the hand is a serious injury that can be potentially devastating. There have been a number of publications on the results of its treatment and its functional outcome of these hands. Unfortunately, the clinical outcomes were unsatisfactory following an initial treatment approach of digital expression of the injection material, elevation, soaks, dressing changes, and antibiotics. Methods: A 43-year-old right handed man sustained a high pressure injection injury to the tip of the left index finger. The injected material was industrial paint thinner. Tissue necrosis was noted at the pulp of the finger. Several debridements and irrigation were required. A pedicled chest flap transfer was performed on the eighteenth day after injury as the dorsal nail complex remained viable. This is a retrospective review of our experience with high-pressure finger injection injury caused by paint. A literature review, retrospective chart and radiologic review were presented. Results: Follow-up length was about 1 year. The injuried hand was left nondominant hand, the index. Patient complaints were cold intolerance, paresthesia, contact pain, and impairment of activities of daily living. Conclusion: The outcome of high-pressure injection injuries of the hand is affected by many factors. The time between injury and operative treatment has been regarded as a key determinant by a number of authors. The nature of the injected material is probably more important. It has been noted by many authors that injuries with paints have a worse outcome than those with oil or grease. This study confirms the fact that high-pressure injection injury caused by paint thinner to the hand is a significant problem. Virtually a patient suffers sequelae of this injury. The injury has significant repercussions for future function and reintegration into the work force.

Characteristics of Washed-off Pollutants and Dynamic EMCs in a Parking Lot and a Bridge during Storms (주차장 및 교량지역의 강우유출수내 비점오염물질의 특성 비교 및 동적 EMCs)

  • Kim, Lee-Hyung;Lee, Seonha
    • Journal of Korean Society on Water Environment
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    • v.21 no.3
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    • pp.248-255
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    • 2005
  • Since the water quality of drinking water sources has been recognized as a big issue, the ministry of Environment in Korea is designing the total maximum daily load (TMDL) program for 4 major large rivers. The TMDL program can be successfully performed as controling the nonpoint pollutants from watershed area near the river. Of the various landuses in nonpoint pollution, parking lots and bridges are stormwater intensive landuses because of high imperviousness and high pollutant mass emissions from vehicular activities. Vehicle emissions from those areas include different pollutants such as heavy metals, oil and grease and particulates from sources such as fuels, brake pad and tire wear, etc. Especially the pollutant washed-off from the landuses are directly affecting to the river water quality. Therefore this research was conducted to understand the magnitude and nature of the stormwater emissions with the goal of quantifying stormwater pollutant concentrations and mass emission rates of pollutants from parking lot and bridges in Korea. In Kongju city areas, two monitoring sites were equipped with an automatic rainfall gages and an automatic flow meter for accumulating the useful data such as rainfall, water quality and runoff flow. This manuscripts will show the concentration changes during storm duration and EMCs to characterize the concentration profiles in different land uses. Also the first flush criteria will be suggested using dynamic EMCs. The definition of dynamic EMC is a new approach explaining the relationship of EMC and first flush effect.

Drag Torque Prediction for Automotive Wheel Bearing Seals Considering Viscoelastic as Well as Hyperelastic Material Properties (초탄성 및 점탄성 물성을 고려한 자동차용 휠 베어링 실의 드래그 토크 예측)

  • Lee, Seungpyo
    • Tribology and Lubricants
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    • v.35 no.5
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    • pp.267-273
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    • 2019
  • Wheel bearings are important automotive parts that bear the vehicle weight and translate rotation motion; in addition, their seals are components that prevent grease leakage and foreign material from entering from the outside of the bearings. Recently, as the need for electric vehicles and eco-friendly vehicles has been emerging, the reduction in fuel consumption and $CO_2$ emissions are becoming the most important issues for automobile manufacturers. In the case of wheel bearings, seals are a key part of drag torque. In this study, we investigate the prediction of the drag torque taking into consideration the hyperelastic and viscoelastic material properties of automotive wheel bearing seals. Numerical analysis based on the finite element method is conducted for the deformation analyses of the seals. To improve the reliability of the rubber seal analysis, three types of rubber material properties are considered, and analysis is conducted using the hyperelastic material properties. Viscoelastic material property tests are also conducted. Deformation analysis considering the hyperelastic and viscoelastic material properties is performed, and the effects of the viscoelastic material properties are compared with the results obtained by the consideration of the hyperelastic material properties. As a result of these analyses, the drag torque is 0.29 Nm when the hyperelastic characteristics are taken into account, and the drag torque is 0.27 Nm when both the hyperelastic and viscoelastic characteristics are taken into account. Therefore, it is determined that the analysis considering both hyperelastic and viscoelastic characteristics must be performed because of its reliability in predicting the drag torque of the rubber seals.

Study of the Performance of a Dry Cleaning Method for Polluted Ballast Gravel of Railroad Fields (철도부지 오염도상자갈의 건식 정화 기술 성능 연구)

  • Cho, Youngmin;Park, Duckshin;Kwon, Tae-Soon;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.552-557
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    • 2015
  • Ballast gravel in a railroad field is often polluted by grease and heavy metals. In this paper, the performances of a dry cleaning method for polluted ballast gravel in which pollutants on the gravel surface can be physically removed was extensively studied. A polluted ballast cleaning device able to shoot emery blasting media onto the surface using compressed air was prepared. Polluted ballast gravel was put into this device for cleaning, with the treatment time varied from 1 to 10 min. The cleaning efficiency of the total petroleum hydrocarbons and heavy metals were studied. The total petroleum hydrocarbon removal efficiency was 70-80% for gravels sampled from a locomotive waiting line, while it was 40-60% for gravels sampled from a turnout area. The heavy metal removal efficiency exceeded 90% for copper and lead, while it was 65-80% for nickel and zinc. This system was found to be effective for the remediation of polluted ballast gravels.

Development of Solid Lubricants for Oil-less Bush (오일리스 부시용 고체윤활제 개발)

  • Kong, Hosung;Han, Hung-Gu;Kim, Jin Uk;Kim, Kyoung Seok;Park, Jong Sik
    • Tribology and Lubricants
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    • v.35 no.2
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    • pp.87-93
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    • 2019
  • This work aims to develop a dry lubricant for oilless bush, especially a solid lubricant, thereby creating a coating method with improved properties of anti-friction and load-carrying capacity without oil lubrication. In this work, spherical-shaped powders of thermosetting resin such as polyimide (PI) are mixed with a binder matrix obtained by mixing a fluorocarbon compound resin such as Polytetrafluoroethylene (PTFE) or Ethylene tetra fluoro ethylene (ETFE) with itself or with a non-fluorocarbon thermoplastic resin such as Polyether ether ketone (PEEK). And these dry lubricant mixtures are thickly coated (200-300 mm in the thickness) on the inner surface of the bush by using a wet-typed air-spray deposition method. It was found that the load-carrying capacity of the solid lubricant for excavator bush (60 mm in diameter) that operates under a high load condition (at 40 MPa) is greatly improved owing to the spherical-shaped powders of thermosetting resin. In addition, the coefficient of friction at the sliding surface is also reduced less than 0.1. Thick coating also lowers the contact stress at the edge of a bush that results in better tribological performances. The result suggests that the lubrication performance and durability life of the bush can be remarkably improved even without lubrication (oil or grease).

The Evaluation of the Packaging Properties and Recyclability with Modified Acrylic Emulsion for Flexible Food Paper Coating (유연 종이 식품 포장재의 개질 아크릴 에멀젼 코팅 특성 및 재활용성 평가)

  • Myungho Lee;In Seok Cho;Dong Cheol Lee;Youn Suk Lee
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.153-161
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    • 2023
  • The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.

Study on Pre-treatment of Tropical Crop Oil for Bio-diesel Production (열대작물 오일로부터 바이오디젤 생산을 위한 전처리 공정 연구)

  • Kim, Deogkeun;Park, Jiyeon;Lee, Joonpyo;Park, Soonchul;Lee, Jinsuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.249.2-249.2
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    • 2010
  • 최근의 고유가와 환경오염에 대한 대응 수단으로 수송용 바이오연료의 보급에 대한 관심이 세계적으로 높아지고 있다. 이 중 바이오디젤은 동식물성 기름으로부터 메탄올과의 전이에스테르화 반응에 의해 생산되는 경유대체 연료로서 환경 친화성과 지속가능성이 인정됨에 따라 그 생산량이 급격히 증가하고 있다. 바이오디젤의 생산량이 증가함에 따라 대두유, 유채유, 팜유 등의 원료유 가격 상승 및 수급 불안정 문제가 대두되고 있으며 식량자원과의 충돌 문제도 발생되고 있다. 이를 해결하기 위한 방안으로 유리지방산 함량이 높은 저가유지 자원(폐식용유, 폐돈지, 폐우지, soapstock, trapped grease)을 이용한 공정 개발 연구가 활발히 진행되고 있다. 본 연구에서는 비활용되고 있는 해외 열대작물 열매씨앗에서 착유한 식물성 오일의 바이오디젤 원료유로서의 사용 가능성을 검토하였다. 열대작물 오일의 물성 분석 결과 고형물, 수분, 인, 유리지방산 함량이 대두원유보다 매우 높게 나타났다. 오일 중의 인지질은 바이오디젤 제조 반응후 에스테르와 글리세린의 층분리를 방해하여 공정 효율을 감소시키고 유리지방산은 염기촉매와 결합하여 지방산염을 생성해 생산수율을 감소시키는 문제를 일으킨다. 고형물과 수분은 여과와 감압증발에 의해 쉽게 제거가 가능하였다. 15~20%의 유리지방산 함유 열대작물 오일의 전처리를 위해 균질계 산촉매와 비균질 고체 산촉매를 이용해 에스테르화 반응 효율을 조사한 결과 황산이 가장 높은 효율을 보였다. 반응표면분석법(Response Surface Method, RSM)을 적용해 메탄올과 촉매량의 2변수 에스테르화반응 최적화를 수행한 결과 메탄올 26%, 촉매 0.98%로 최적 조건이 도출되었으며 초기 산가 33mgKOH/g에서 0.98mgKOH/g으로 감소됨을 확인하였다. 전처리 정제한 오일의 물성분석 결과 고형물 0.1%, 수분 0.10%, 산가 1.0mgKOH/g, 인함량 20ppm 이하로 바람직한 원료유가 생산됨을 알 수 있었다. 제조된 원료유를 이용해 전이에스테르화 반응 최적화 실험을 RSM에 근거하여 진행한 결과 KOH 0.8%, 메탄올:오일 몰비 6.2:1, 반응온도 $60^{\circ}C$, 교반속도 200rpm, 반응시간 30분으로 나타났으며 증류 정제전 97.3%, 증류후 100.0%의 바이오디젤을 생산 할 수 있었다. 열대작물 오일의 전처리 공정은 메탄올을 과잉양으로 사용함으로 효과적인 알콜 회수 공정이 중요하다. 전처리 후 층분리를 통해 회수되는 메탄올 중의 수분함량은 2%~7%로서 이를 전처리 반응에 재사용하기 위해서는 0.3%이하의 수분함량으로 정제가 필요하다. 본 연구에서는 고가의 증류탑 형태가 아닌 단증류방식으로 2단계 내지 3단계로 0.3% 수분의 메탄올 회수 조건을 도출하였으며 파일롯 공정 설계를 진행하고 있다. 이로서 본 연구의 열대작물 오일은 저가로 충분한 물량의 확보가 가능하다면 바이오디젤 원료 자원으로서 큰 활용가치가 있는 것으로 판단된다.

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