• 제목/요약/키워드: graphite oxide

검색결과 160건 처리시간 0.023초

Direct Comparison of Optical Properties from Graphene Oxide Quantum Dots and Graphene Oxide

  • Jang, Min-Ho;Ha, Hyun Dong;Seo, Tae Seok;Cho, Yong-Hoon
    • Applied Science and Convergence Technology
    • /
    • 제24권4호
    • /
    • pp.111-116
    • /
    • 2015
  • The graphene oxide (GO) and graphene oxide quantum dots (GOQDs), which have gained research interest as new types of light-emitting materials, were synthesized by the modified Hummers method for oxidation of graphite flake and graphite nanoparticle. The optical properties of GO and GOQDs have been compared by mean of photoluminescence (PL), PL excitation (PLE), UV-vis absorbance, and time-resolved PL. The GO have an absorption peak at 229 nm and shoulder part at 310 nm, whereas the GOQDs show broad absorption with a gradual change up without any absorption peaks. The PL emission of GOQDs and GO showed the green color at 520 nm and the red color at 690 nm, respectively. The red emission of GO showed faster PL decay time than the green emission of GOQDs. In particular, the temporal PL profile of the GO showed redshift from 560 nm to 660 nm after the pump event.

전해질 첨가제가 리튬 바나듐 옥사이드 전극의 성능에 미치는 영향 (Effect of Electrolyte Additive on the Electrochemical Characteristics of Lithium Vanadium Oxide Anode)

  • 이제남
    • 전기화학회지
    • /
    • 제21권3호
    • /
    • pp.55-60
    • /
    • 2018
  • 최근 휴대용 기기의 급속한 발전이 이뤄지고, 다양한 전자제품에서 높은 성능의 이차 전지가 요구됨에 따라 고에너지밀도 특성을 가능케 하는 전극 재료의 연구가 주목받고 있다. 음극의 경우, 기존에 사용하고 있는 흑연재료를 대체하기 위하여 실리콘, 주석 등의 소재와 전이금속 산화물을 새로운 음극재료로 사용하려고 한다. 리튬 바나듐 옥사이드는 리튬 전이금속 산화물 기반의 음극 소재로서 흑연 대비 1.5배의 부피당 용량을 나타낼 수 있다는 장점을 가지고 있으나, 낮은 전기전도도와 입자 파쇄현상으로 인하여 전해질의 분해가 가속화되어 성능이 열화되는 문제점을 가지고 있다. 본 연구에서는 이러한 문제를 개선시키기 위하여 전해질 첨가제를 도입하여 전극/전해질 계면의 개질에 따른 리튬 바나듐 옥사이드의 전기화학적 거동 특성을 보고자 하였다.

확산 접합에 의해 제조된 텅스텐-레늄 합금/티타늄/그래파이트 접합체의 미세구조 및 고온 안정성 (Interfacial Microstructure of Diffusion-Bonded W-25Re/Ti/Graphite Joint and Its High-Temperature Stability)

  • 김주형;백창연;김동석;임성택;김도경
    • 한국재료학회지
    • /
    • 제26권12호
    • /
    • pp.751-756
    • /
    • 2016
  • Graphite was diffusion-bonded by hot-pressing to W-25Re alloy using a Ti interlayer. For the joining, a uniaxial pressure of 25 MPa was applied at $1600^{\circ}C$ for 2 hrs in an argon atmosphere with a heating rate of $10^{\circ}C\;min^{-1}$. The interfacial microstructure and elemental distribution of the W-25Re/Ti/Graphite joints were analyzed by scanning electron microscopy (SEM). Hot-pressed joints appeared to form a stable interlayer without any micro-cracking, pores, or defects. To investigate the high-temperature stability of the W-25Re/Ti/Graphite joint, an oxy-acetylene torch test was conducted for 30 seconds with oxygen and acetylene at a 1.3:1 ratio. Cross-sectional analysis of the joint was performed to compare the thickness of the oxide layer and its chemical composition. The thickness of W-25Re changed from 250 to $20{\mu}m$. In the elemental analysis, a high fraction of rhenium was detected at the surface oxidation layer of W-25Re, while the W-25Re matrix was found to maintain the initial weight ratio. Tungsten was first reacted with oxygen at a torch temperature over $2500^{\circ}C$ to form a tungsten oxide layer on the surface of W-25Re. Then, the remaining rhenium was subsequently reacted with oxygen to form rhenium oxide. The interfacial microstructure of the Ti-containing interlayer was stable after the torch test at a temperature over $2500^{\circ}C$.

산화 그래핀과 나노 흑연이 폴리스티렌 나노복합재료의 유변물성 및 전기적 물성에 미치는 영향 (Influence of Graphene Oxide and Graphite Nanoplatelets on Rheological and Electrical Properties of Polystyrene Nanocomposites)

  • 염효열;나효열;이성재
    • 폴리머
    • /
    • 제38권4호
    • /
    • pp.502-509
    • /
    • 2014
  • 탄소기반 판상형 나노재료인 산화 그래핀(GO)과 나노 흑연(GNP)은 고분자재료에 전기 전도성을 부여하기 위한 복합재료용 나노필러로 사용되고 있다. 본 연구에서는 폴리스티렌(PS)에 나노필러를 첨가한 PS/GO와 PS/GNP 나노복합재료를 라텍스 기법으로 제조한 다음 유변학적, 전기적 물성을 비교 고찰하였다. PS 입자는 무유화제 유화중합으로 중합하였으며, GO는 흑연으로부터 modified Hummers 방법으로 합성하였다. 친수성인 GO는 첨가제 없이 PS 수성 현탁액에 분산하였으며, GNP는 분산성을 높이기 위해 계면활성제를 첨가하여 분산하였다. 나노필러에 따른 유변물성은 GO가 GNP에 비해 높게 나타났는데, GO는 단일층으로 분산이 가능한 반면, GNP는 다수의 층이 겹쳐진 형태이므로 나노 규모의 균질한 분산을 이루지 못하기 때문이다. 전도성 통로가 형성되는 지점인 전기적 임계점은 PS/GO, PS/GNP 나노복합재료에 대하여 각각 0.50, 5.82 wt%로 나타났다. PS/GO 나노복합재료가 우수한 전기 전도도를 보여주는 이유는 성형 시 열처리에 의해 GO가 환원되기 때문이다.

티타늄 용탕의 산화칼슘 및 흑연과의 반응 및 기포 결함의 형성에 미치는 압력의 영향 (The Reactions of the Ti Melt with CaO and Graphite and the Effect of Pressure on the Formation of Gas Porosity)

  • 배창근;권해욱
    • 한국주조공학회지
    • /
    • 제20권4호
    • /
    • pp.247-253
    • /
    • 2000
  • Titanium was melted in the CaO-coated alumina crucible and the reaction between the melt and the coating layer was negligible. The volume fraction of the gas porosity was decreased with increasing pressure and the sound bar castings with no porosity was obtained under the Ar atmosphere of the pressure of $300kN/mm^2$. The surface of the casting obtained from CaO-coated graphite mold was slightly rougher than that from graphite without coating. The reaction product of titanium melt with the layer of CaO was mainly titanium oxide and that with graphite crucible was titanium cabide with small amount of titanium nitride.

  • PDF

산화처리 탄소 및 이를 이용한 EDLC 특성 (Oxidation-treated of Oxidized Carbons and its Electrochemical Performances for Electric Double Layer Capacitor)

  • 양선혜;김익준;전민제;문성인;김현수;안계혁;이윤표
    • 한국전기전자재료학회논문지
    • /
    • 제20권6호
    • /
    • pp.502-507
    • /
    • 2007
  • The oxidation treatment of several carbon materials with a sodium chlorate and 70 wt.% of nitric acid, combined with heat treatment, were attempted to achieve an electrochemical active material with a larger capacitance. Among pitch, needle coke, calcinated needle coke and natural graphite, the structure of needle coke and calacinated needle coke were changed to the graphite oxide structure with the expansion of the inter-layer. On the other hand, the calcinated needle coke after oxidation and heating at $200^{\circ}C$ has exhibited largest capacitance per weight and volume of 29.5 F/g and 24.5 F/ml at the two-electrode system in the potential range of 0 to 2.5 V. The electrochemical performance of the calcinated needle coke was discussed with the phenomenon of the electric field activation and the formation of new pores between the expanded inter-layer at first charge.

기계적 합금화법에 의한 실리콘계 복합물질의 전지전극특성 (Battery Electrode Characteristics of Si-based Composite by Mechanical Alloying Method)

  • 이철경;이종호;이상우
    • 한국분말재료학회지
    • /
    • 제16권6호
    • /
    • pp.389-395
    • /
    • 2009
  • A Si-CuO-graphite composite was prepared by a mechanical alloying (MA) method. The Si-CuO composite has a mixture structure, where CuO is homogeneously dispersed in Si. Also, $Cu_2O$ and $Cu_3Si$ phases were formed during MA and heat treatment. Graphite with the Si-CuO composite was mixed in the same mill for 30 minutes with weight ratio of Si-CuO composite and graphite as 1:1. The Si-CuO composite was homogeneously covered with graphite. SiC phase was not formed. Electrochemical tests of the composite have been investigated, and the first charge and discharge capacities of the material were about 870mAh/g and 660mAh/g, respectively. Those values are about 76% of the first cycle efficiency. The cycle life of the composite showed that the initial discharge capacity of 660 mAh/g could be maintained up to 92% after 20 cycles.

Facile synthesis of ZnBi2O4-graphite composites as highly active visible-light photocatalyst for the mineralization of rhodamine B

  • Nguyen, Thi Mai Tho;Bui, The Huy;Dang, Nguyen Nha Khanh;Ho, Nguyen Nhat Ha;Vu, Quang Huy;Ngo, Thi Tuong Vy;Do, Manh Huy;Duong, Phuoc Dat;Nguyen, Thi Kim Phuong
    • Korean Journal of Chemical Engineering
    • /
    • 제35권12호
    • /
    • pp.2442-2451
    • /
    • 2018
  • Novel highly active visible-light photocatalysts in the form of zinc bismuth oxide ($ZnBi_2O_4$) and graphite hybrid composites were prepared by coupling via a co-precipitation method followed by calcination at $450^{\circ}C$. The asprepared $ZnBi_2O_4$-graphite hybrid composites were tested for the degradation of rhodamine B (RhB) solutions under visible-light irradiation. The existence of strong electronic coupling between the two components within the $ZnBi_2O_4$-graphite heterostructure suppressed the photogenerated recombination of electrons and holes to a remarkable extent. The prepared composite exhibited excellent photocatalytic activity, leading to more than 93% of RhB degradation at an initial concentration of $50mg{\cdot}L^{-1}$ with 1.0 g catalyst per liter in 150 min. The excellent visible-light photocatalytic mineralization of $ZnBi_2O_4-1.0graphite$ in comparison with pristine $ZnBi_2O_4$ could be attributed to synergetic effects, charge transfer between $ZnBi_2O_4$ and graphite, and the separation efficiency of the photogenerated electrons and holes. The photo-induced $h^+$ and the superoxide anion were the major active species responsible for the photodegradation process. The results demonstrate the feasibility of $ZnBi_2O_4-1.0graphite$ as a potential heterogeneous photocatalyst for environmental remediation.