• Title/Summary/Keyword: grain composition

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The Dielectric Properties of $Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) Ceramics ($Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) 세라믹스의 유전특성)

  • 김부근;김재윤;김강언;정수태;조상희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.248-251
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    • 1999
  • The microwave dielectric properties of The Dielectric Properties of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$ (A = Sr, Ca, x = 0, 0.2 ,0.4 ,0.6, 0.8, 1.0) were investigated. In composition of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O, densities are decreased with increasing x values. Grain sizes are decreased with Sr content and Increased with Ca content. The hexagonally ordered superstructure was observed in $Ba_{1-x}$Sr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the intensity of superlattice increased with x value. In $Ba_{1-x}$Cr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the additional diffraction patterns were shown. The highest value of $\varepsilon$$_{r}$ was shown in x=0.2 of BCMN systems and the value was 41.9. The highest Q$\times$f was shown in x=0.2 of BSMN systems and the value was 68,000. $\tau$$_{f}$ were shown 0 ppm/$^{\circ}C$ near x=0.8.TEX> near x=0.8.0.8.

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Characteristic Analysis and Preparation of Multi-layer TiNOx Thin Films for Solar-thermal Absorber (태양열 흡수판용 복층 TiNOx 박막의 제조와 특성 분석)

  • Oh, Dong-Hyun;Han, Sang-Uk;Kim, Hyun-Hoo;Jang, Gun-Eik;Lee, Yong-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.820-824
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    • 2014
  • TiNOx multi-layer thin films on aluminum substrates were prepared by DC reactive magnetron sputtering method. 4 multi-layers of $TiO_2$/TiNOx(LMVF)/TiNOx(HMVF)/Ti/substrate have been prepared with ratio of Ar and ($N_2+O_2$) gas mixture. $TiO_2$ of top layer is anti-reflection layer on double TiNOx(LMVF)/TiNOx(HMVF) layers and Ti metal of infrared reflection layer. In this study, the crystallinity and surface properties of TiNOx thin films were estimated by X-ray diffraction(XRD) and field emission scanning electron microscopy(FE-SEM), respectively. The grain size of TiNOx thin films shows to increase with increasing sputtering power. The composition of thin films has been investigated using electron probe microanalysis(EPMA). The optical properties with wavelength spectrum were recorded by UV-Vis-NIR spectrophotometry at a range of 200~1,500 nm. The TiNOx multi-layer films show the excellent optical performance beyond 9% of reflectance in those ranges wavelength.

Improvement in Mechanical and Wear Properties of WC-Co by Ultrasonic Nanocrystal Surface Modification Technique (초음파나노표면개질 기술을 적용한 초경의 기계적특성 및 마모 연구)

  • Lee, Seung-Chul;Kim, Jun-Hyong;Choi, Gab-Su;Jang, Young-Do;Amanov, Auezhan;Pyun, Young-Sik
    • Tribology and Lubricants
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    • v.31 no.2
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    • pp.56-61
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    • 2015
  • In this study, we investigated the effectiveness of an ultrasonic nanocrystal surface modification (UNSM) technique on the mechanical and wear properties of tungsten carbide (WC). The UNSM technique is a newly developed surface modification technique that increases the mechanical properties of materials by severe plastic deformation. The objective of this study was to improve the wear resistance of press die made of WC by applying the UNSM technique. We observed the microstructures of the untreated and UNSM-treated specimens using a scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDX) was used to investigate the chemical composition. The SEM observations showed the pore size and the number of pores decreased after the UNSM treatment. We assessed the wear behavior of both the untreated and UNSM-treated specimens using a scratch test. The test results showed that the wear resistance of the UNSM-treated specimens increased by about 46% compared with the untreated specimens. This may be attributed to increased hardness, reduced surface roughness, induced compressive residual stress, and refined grain size following the application of the UNSM technique. In addition, we found that the UNSM treatment increased the carbon concentration to 63% from 33%. We expect that implementing the findings of this study will lead to an increase in the life of press dies.

Dielectric Properties in the Pb1-3x/2Lax[(Mg1/3Ta2/3)0.66Zr0.34]O3 Systems

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
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    • v.26 no.4
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    • pp.70-73
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    • 2017
  • The dielectric constant and loss of poling/non-poling was measured in the $Pb_{1-3x/2}La_x[(Mg_{1/3}Ta_{2/3})_{0.66}Zr_{0.34}]O_3$ samples. The addition of $La^{3+}$ to the $Pb_{1-3x/2}La_x[(Mg_{1/3}Ta_{2/3})_{0.66}Zr_{0.34}]O_3$ did not cause a large change in grain size. But the addition of $La^{3+}$ did show transition temperature, which shifted toward low temperature in the $Pb[(Mg_{1/3}Ta_{2/3})Zr]O_3$ systems. In addition, the dielectric and pyroelectric properties (${\varepsilon}{\sim}20000$, $p{\sim}0.03C/m^2K$) of this system using $La^{3+}$ have been greatly improved. Pyroelectrics $Pb_{0.97}La_{0.02}(Mg_{1/3}Ta_{2/3})_{0.66}Zr_{0.34}]O_3$ system was found to have a relatively high ferroelectric FOMs ($F_V{\sim}0.035m^2/C$, $F_D{\sim}0.52{\times}10^{-4}Pa^{-1/2}$) at room temperature. Spontaneous polarization showed a value of $0.27{\sim}0.35C/m^2$ in the composition added to $La^{3+}$. The piezoelectric constant ($d_{33}=350{\sim}490pC/N$) and electromechanical coupling factor ($k_P=0.25{\sim}0.35$) are obtained in $Pb_{1-3x/2}La_x[(Mg_{1/3}Ta_{2/3})_{0.66}Zr_{0.34}]O_3$ compositions with $La^{3+}$ dopant.

Effects of Al2O3 on the Piezoelectric Properties of Pb(Mn1/3Nb2/3)O3-PbZrO3-PbTiO3 Ceramics (Pb(Mn1/3Nb2/3)O3-PbZrO3-PbTiO3 세라믹스의 압전특성에 미치는 Al2O3의 영향)

  • Kim Mi-Jung;Kim Jae-Chang;Kim Young-Min;Ur Soon-Chul;Kim Il-Ho
    • Korean Journal of Materials Research
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    • v.15 no.7
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    • pp.453-457
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    • 2005
  • Piezoelectric properties of $Pb(Mn_{1/3}Nb_{2/3})O_3-PbZrO_3-PbTiO_3$ ceramics were investigated with $Al_2O_3$ content $(0.0-1.0 wt\%)$. The constituent phases, microstructure, electromechanical coupling factor, dielectric constant, piezoelectric charge and voltage constants were analyzed. Diffraction peaks for (002) and (200) planes were identified by X-ray diffractometer for all the specimens doped with $Al_2O_3$, indicating the MPB (morphotropic phase boundary) composition of tetragonal structures. The highest sintered density of $7.8 g/cm^3$ was obtained for $0.2wt\%\;Al_2O_3-doped$ specimen. Grain size increased by doping $Al_2O_3$ up to $0.3 wt\%$, and it decreased by more doping. Electromechanical coupling factor, dielectric constant, piezoelectric charge and voltage constants increased by doping $Al_2O_3$ up to $0.2wt\%$, and it decreased by more doping. This might result from the formation of oxygen vacancies due to defects in $O^{2-}$ ion sites and the substitution of $Al^{3+}$ ions.

Characteristics of a Turbidite Sediment from the Southern Margin of the Okinawa Trough, Japan (오끼나와해곡 남쪽해역의 저탁류 퇴적물의 특성)

  • 현상민
    • 한국해양학회지
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    • v.30 no.2
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    • pp.69-76
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    • 1995
  • A turbidite core sediment (RN88-PC5) from 2051 m on the deep-sea floor at the southern margin of Okinawa Trough was examined. Sedimentological characteristics were quite different between sandy sediments and hemipelagic sediments and hemipelagic sediments in terms of benthic foraminiferal assemblage, grain-size and chemical composition. All turbidite sandy sediments were clearly transported from shallow area as they include typical coral reef dwelling benthic foraminifera which were not found in the background hemipelagic sediments. These layers also suggest that the sediments were transported by turbidity-related currents and implies that sedimentological mechanisms were different between sandy sediments and hemipelagic sediments. The result of the /SUP 14/ C age dating and the stable oxygen isotopic fluctuation of planktonic foraminifera show a gradual warming trend of the surface water from about 10 Ka to present. Also Termination lb as well as two fresh water input events were recognized at ca2 and 7 ka.

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Gold-Silver mineals and the chemical environments of some gold-silver deposits, Republic of Korea(I) -Cheongju gold-silver mine- (한국(韓國) 일부(一部) 금(金)·은(銀) 광상(鑛床)에서 산출(産出)되는 금(金)·은(銀) 광물(鑛物)과 광상(鑛床)의 생성조건(生成條件)(I) -청주(淸州) 금(金)·은(銀) 광산(鑛山)-)

  • Lee, Hyun Koo;Choi, Jin Woo
    • Economic and Environmental Geology
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    • v.21 no.3
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    • pp.287-307
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    • 1988
  • The Cheongju gold-silver mine is located at approximately $36^{\circ}28^{\prime}$north latitude and $127^{\circ}31^{\prime}$ east longitude in the Cheongju City of the Chung cheong bug Do, South Korea. Gold-Silver bearing hydrothermal quartz veins, occur in Cheongju Granit of Jurassic age. K-Ar isotope data for sericite in quartz vein indicate that the Au-Ag mineralization took place in early Cretaceous ($97.5{\pm}2.18$ MA. Park, et ai, 1986). Three stage of mineralization recognized anre, from early to later, (I) Sulide stage: pyrite, arsenopyrite, pyrrhotite (Hpo), sphalerite, chalcopyrite, electrum and quartz (II) Electrum stage: pyrite, sphalerite, galena, chalcopyrite, electrum and quartz. (III) Silver mineral stage: pyrite, marcasite, pyrrhotite (Mpo), sphalerite, galena, electrum, native silver argentite, fluorite, calcite and quartz. In this paper, mode of occurrences and chemical compositions of electum and native silver have been investigated by means of microscope and EPMA. Electron probe microanalysis shows that an individual grain of electrum is almost homogeneous in composition. Silver content of electrum ranges from 44.7-67.1 atom.%. Gold content of native silver ranges below 0.2 atom. %. Vicker's hardness number (VHN) of electrum and native silver ranges $78.2-81.8kg/mm^{2}$ respectively. The filling temperature of fluid inclusions in quartz ranges from $130-280^{\circ}C$. On the basis of arsenpyrite geothemometer, the equilibrium temperature and sulfur fugacity of the pyrite-arsenopyrite-pyrrhotite(Hpo) assemblage is assumed to be in ange from $300-310^{\circ}C$ and $10^{-10}$ to $10^{-11}$ atm. The estimated ore reserviors on Cheongju mine area are calculated to 8000 T/M, averaing 8.6g/t Au, 27.8 g/t Ag, 1.25% Pb, l.65% Zn.

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Local/Spatial Variation of Settling Velocities of Cohesive Sediments from Han Estuary (한강 하구역 점착성 퇴적물 침강속도의 지엽적/공간적 변화)

  • Seo, Young-Deok;Jin, Jae-Youll;Hwang, Kyu-Nam
    • Journal of Ocean Engineering and Technology
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    • v.22 no.1
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    • pp.37-45
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    • 2008
  • The purpose of this study is to quantify the settling velocities of cohesive sediments from Han estuary and to evaluate their local variation within Han estuary. This study also includes an estimation of their spatial variation, for which the settling velocities of cohesive sediments from Han estuary arecompared with those for sediments from other regions. At the same time, physical-chemical properties, such as grain size distribution, the percentage of organic contents, mineralogical composition etc are measured in this study in order to examine their correlation with settling velocities and their effect on settling velocities. Results from settling tests shaw that the settling velocities of Han estuary mud varies in the range of two orders of magnitude(from 0.01 to 1.5 mm/sec) over the corresponding concentration range of 0.1 to 80 g/L, and a feature of the settling velocity profile is quite different in quantity as compared to those of previous studies for muds from other regions. Particularly in the flocculated settling region, the settling velocity for Han estuary muds is shown to be larger than that of Saemankeum and Keum estuary sediments, while in the hindered settling region all three sediments are shown to have a similar settling velocity. However, local variability of the settling velocities within Han estuary is shown to be insignificant.

Micro-Landform Classification and Topographic Property of Tidal Flat in Julpo-Bay Using Satellite Image (위성영상을 이용한 줄포만 간석지의 미지형 분류와 지형적특성)

  • 조명희;조화룡
    • Korean Journal of Remote Sensing
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    • v.15 no.3
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    • pp.217-225
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    • 1999
  • Through the ISODATA method of unsupervised classification, the micro-landform of Julpo-Bay tidal flat was classified into mudflat, mixedflat, and sandflat using Landsat TM image. Each showed an apparent differences in its topographical characteristics and grain size composition. Mudflat occupied innermost part of the tidal flat, sandflat located closest to the entrance of the bay and mixed flat in the center is. For example, mudlflats are formed with flat faces and tidal channel. Topographically, mudflat consist of tidal channels and flat intermediate surface. Its average relief of them is about 2 meter. Meanwhile, sandflat comprised very flat landform with well-developed ripple marks of less than 10cm average relief. And Mixed flat stood in between. In addition, Out of 7 bands of Landsat TM images, band 5 and 7 provided the highest power level for discrimination between micro-landforms of the tidal flat. Band 4 showed a clear boundary between the land and tidal flat, and band 3 did its share by showing well a boundary between the sea surface and the tidal flat.

Study of the Correlation Between Diatom and Environmental Variables for Palao-Sealevel Reconstruction in the Korea Peninsula: Case Study of the Eastern Tidal Flat of Gomso Bay (한반도 고해수면 변동 복원을 위한 규조-환경변수 상관관계 연구: 곰소만 동부 조간대 지역을 대상으로)

  • Kim, Jeong-Yun;Yoon, Soon-Ock;Yang, Dong Yoon;Hwang, Sang ill
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.2
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    • pp.79-90
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    • 2017
  • This study investigated the correlation between the diatom community and the environmental variables on the tidal flat surface of the eastern part of Gomso Bay in the West coast of Korea in order to utilize the quantitative sea level record as a basic data. 24 sediment samples at 10cm intervals downstream of the Galgok Stream were used for diatom analysis, grain size analysis and CCA. As a result of diatom analysis, marine diatoms dominated at lower altitudes and the ratio of diatoms to fresh water diatoms and brackish diatoms increased toward upland. As a result of CCA, the contribution of environmental variables was analyzed as 25.3% at altitude, 21.6% at sand, 13.3% at skewness, etc. This means that altitude above sea level has the greatest influence on the diatom composition in the tidal flat surface. It suggests that the contribution of environmental variables at altitude above sea level can be used as a basic data for the quantitative records for reconstruction of paleo-sea level.