• 한국세라믹학회지
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• 제29권1호
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• pp.65-73
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• 1992

The effect of grain size on the time-dependent piezoelectrice degradation of a poled PZT of MPB composition Pb0.988Sr0.012 (Zr0.52Ti0.48)O3 with 2.4 mol% of Nb2O5 was studied, and the degradation mechanism was discussed. Changes in the internal bias field and the internal stress both responsible for the time-dependent degradation of poled PZT were examined by the polarization reveral technique, XRD and Vickers indentation, respectively. The piezoelectric degradation increased with increasing time and grain size, and the internal bias field due to space charge diffusion decreased with increasing grain size of poled PZT. The internal bias field, however, was almost insensitive to the degradation time regardless of the grain size. On the other hand, both the x-ray diffraction peak intensity ratio of (002) to (200) and the fracture behavior including the crack propagation support that the ferroelectric domain rearrangement of larger grain size showed rapid relaxation of the internal stress compared with smaller one, which is thought the origin of the larger piezoelectric degradation in the former. In conclusion, the contribution of space charge diffusion on the piezoelectric degradation of PZT is strongly dependent on both the grain size and the composition. Thus, the relaxation of internal stress due to the ferroelectric domain rearrangement as well as the amount and time-dependence of the internal bias field due to space charge diffusion should be considered simultaneously in the degradation mechanism of PZT.

• 한국결정학회지
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• 제8권2호
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• pp.149-153
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• 1997

본 연구는 ZnO-Bi2O3-Co3O4-MnCo3-Cr2O3-Sb2O3를 기본 조성으로 하여 Sb2O3 첨가량(0-0.09mol%) 변화에 따른 grain size와 미세구조 특성을 고찰하고자 하였다. Sb2O3가 첨가되지 않은 조성은 이상 입자 성장에 의해 거대한 ZnO grain이 생성되었으며, Sb2O3를 첨가한 조성은 Zn7Sb2O12 spinel상 생성으로 입자 성장이 억제되어 이상입자 성장이 관찰되지 않았다. Sb2O3 첨가량 증가에 따라 ZnO grain size가 현격하게 감소하였으며 그 미세구조는 조밀하고 균일한 크기의 grain분포를 나타내었다.

• 한국작물학회지
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• 제37권3호
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• pp.244-249
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• 1992

벼 품종간 미립 절대밀도의 변이와 그에 영향하는 미립관련형질들을 구명하기 위하여 통일형 30, Japonica형 72 및 Indica형 133 계 235 품종에 대해 미립의 절대밀도와 모양 및 크기, 경도, 심복백, ADV, amylose 함량, 전분구조를 조사하고 그들 간의 관계를 검토한 결과는 다음과 같다. 1. 백미의 절대밀도는 평균적으로 통일형 1.496g/$cm^3$, Japonica형 1.506g/$cm^3$, Indica형 1.500g/$cm^3$이었고, 출수까지의 생육일수 및 현미의 경도와는 정의 상관을 심복백, 현미의 부피 및 1000립중, 입장과는 부의 상관을 보였다. 2. 편회귀분석 결과 미립의 크기가 절대밀도에 가장 크게 영향하는 것으로 나타났다. 3. 절대밀도의 고, 저에 따른 전분결정구조의 차이는 감별할 수 없었으며, 심복백의 경우 정상배유부분에 비해 전분립자가 둥글고 그 결정조직이 느슨하였다. 4. 미립의 크기가 비슷하고 심복백이 없는 경우 절대밀도의 품종간 차이는 미미한 것으로 나타나서 수량성에는 크게 영향하지 못할 것으로 생각되나, 미질의 측면에서는 검토되어져야 할 것이다.

• E2M - 전기 전자와 첨단 소재
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• 제9권10호
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• pp.1019-1026
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• 1996

In this study, we may be presented the carrier oscillation properties for the low-voltage varistor fabricated by a new method of three composition seed grain, in order to analyze the behavior of carriers at the its equivalent circuit model. The oscillation phenomena of carriers appeared from current-voltage characteristics under knee voltage is shown by the transient flow of nontrapped carriers group in the trap level of intergranular layer, surface state and/or depletion layer. In particularly, current oscillation phenomena is hardly shown in the high electric field. It is that the injected carriers from both electrodes are directly from the conduction band of forward biased ZnO grain through the intergranular layer into the reverse biased ZnO grain, because the trap level in the electric field above the knee voltage is mostly filled.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 하계학술대회 논문집 B
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• pp.1159-1161
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• 1993

This paper may be presented the carrier oscillation properties for the varistor fabricated by a new method of three-composition seed grain, in order to analyze the behavior of carriers at the its equivalent circuit model. The oscillation phenomena of carriers appeared from current-voltage characteristics under knee voltage is shown by the transient flow of non trapped carriers group in the trap level of intergranular layer, surface state and/or depletion layer. However, Current oscillation phenomena is hardly shown in the high electric field. The injected carriers from both electrodes are directly flowed from the conduction band of forward biased grain through the intergranular layer into the reverse biased grain, because the trap level in the electric field above the knee voltage is mostly filled.

• 한국재료학회지
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• 제27권7호
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• pp.369-373
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• 2017

Unidirectionally solidified TiAl alloys were prepared by optically-heated floating zone method at growth rates of 10 to 70 mm/h in flowing argon. The microstructures and tensile properties of these crystal bars were found to depend strongly on the growth rate and alloy composition. TiAl alloys with composition of 47 and 50 at.%Al grown under the condition of 10 mm/h showed $Ti_3Al({\alpha}_2)/TiAl({\gamma})$ layer structures similar to single crystals. As the growth rate increased, the alloys with 47 and 50 at.%Al compositions showed columnar-grain structures. However, the alloys fabricated under the condition of 10 mm/h had a layered structure, but the alloy with increased growth rate consisted of ${\gamma}$ single phase grains. The alloy with a 53 at.%Al composition showed a ${\gamma}$ single phase regardless of the growth rate. Room-temperature tensile tests of these alloys revealed that the columnar-grained material consisting of the layered structure showed a tensile ductility of larger than 4 % and relatively high strength. The high strength is caused by stress concentration at the grain boundaries; this enhances the secondary slip or deformation twinning across the layered structure in the vicinity of the grain boundaries, resulting in the appreciable ductility.

• 한국농공학회지
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• 제17권1호
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• pp.3655-3665
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• 1975

This study was intended to develop a method for measuring the grain separating performance of threshers. The grain separating apparatus used for the experiment was designed and constructed, the function of which was to separate pneumatically mature and immature grain, chaff, straw, dust, and other impurities from the products of threshing. The apparatus has five material outlets where grains and impurities are fallen down by separation depending upon the specific gravity of the material white it moves above the outlets. The principle of design was to separate the mixture of mature grain, immature grain and chaff as distinct as possible, and to induce the mature grains onto the first outlet, the immature grains onto the second and the third, and the straw wastes onto the forth and the fifth outlets. The developed apparatus was tested to evaluate its separating performance with two rice varieties (Tongil and Mine-hikari) at different moisture levels and air velocities. The optimum conditions for operating the apparatus were found from experiment. The results are summarized as follows; 1. The degrees of separation, especially the amount of immature grain contained in the mature paddy, were dependent upon air speed delivered. The optimum air velocities for this apparatus for each levels of grain moisture contents were found from a series of experiments as follows; 14.7-15.3m/sec. for grain of 16 percent moisture content in wet basis, 15.3-16.0m/sec. for 20 percent, and 16.0-16.4m/sec for 24 percent. 2. Composition ratios determined based on the brine separating method was fairly well acted upon the developed apparatus, indicating its recollecting rate of the mature grains as 97.6 to 99.9 percent. The developed separatus acted similarly upon the two rice varieties which had different composition of immature paddy grain. In other words, the separating performance by the apparatus had a good correlation with the one by the brine separating method. 3. As immature grains were separated out unsatisfactory in these experiments than the brine separating method, further investigation may be needed to improve a separating performance of these materials. But the results obtained suggested a possibility of using the tester to replace the current hand separating method, ther eby enabling more consistent test results and also eliminating nearly all costly hand seperating operations.

• 한국세라믹학회지
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• 제49권4호
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• pp.301-307
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• 2012

SiAlON glasses are silicates or alumino-silicates, containing Mg, Ca, Y or rare earth (RE) ions as modifiers, in which nitrogen atoms substitute for oxygen atoms in the glass network. These glasses are found as intergranular films and at triple point junctions in silicon nitride ceramics and these grain boundary phases affect their fracture behaviour. This paper provides an overview of the preparation of M-SiAlON glasses and outlines the effects of composition on properties. As nitrogen substitutes for oxygen in SiAlON glasses, increases are observed in glass transition temperatures, viscosities, elastic moduli and microhardness. These property changes are compared with known effects of grain boundary glass chemistry in silicon nitride ceramics. Oxide sintering additives provide conditions for liquid phase sintering, reacting with surface silica on the $Si_3N_4$ particles and some of the nitride to form SiAlON liquid phases which on cooling remain as intergranular glasses. Thermal expansion mismatch between the grain boundary glass and the silicon nitride causes residual stresses in the material which can be determined from bulk SiAlON glass properties. The tensile residual stresses in the glass phase increase with increasing Y:Al ratio and this correlates with increasing fracture toughness as a result of easier debonding at the glass/${\beta}-Si_3N_4$ interface.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제9권3호
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• pp.971-989
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• 2015

With the development of cloud computing, more and more Web services are deployed on geo-distributed datacenters and are offered to cloud users all over the world. Through service composition technologies, these independent fine-grain services can be integrated to value-added coarse-grain services. During the composition, a number of Web services may provide the same function but differ in performance. In addition, the distribution of cloud datacenters presents a geographically dispersive manner, which elevates the impact of the network on the QoS of composite services. So it is important to select an optimal composition path in terms of QoS when many functionally equivalent services are available. To achieve this objective, we first present a graph model that takes both QoS of Web services and QoS of network into consideration. Then, a novel approach aiming at selecting the optimal composition path that fulfills the user's end-to-end QoS requirements is provided. We evaluate our approach through simulation and compare our method with existing solutions. Results show that our approach significantly outperforms existing solutions in terms of optimality and scalability.

• 한국세라믹학회지
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• 제31권11호
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• pp.1299-1306
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• 1994

Effect of MgO content on microstructural evolution and microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 system was investigated. MgO content was varied from 10 mol% deficiency to 10 mol% excess of stoichiometric composition, respectively. It was found that MgO-deficient specimen showed faster grain growth rate than stoichometric and MgO excess BMT system. Besides, sandwich type precipitates of Ba5Ta4O15 which was formed within the BMT grain, might lead to the anisotropic grain growth of BMT grain. On the contrary, in MgO excess specimen, BMT grain growth rate was retarded by precipitations of MgO phase in grain boundary. Besides, the Q values of MgO-deficient showed lower than MgO-excess due to precipitations of Ba5Ta4O15 within BMT grain.