• Title/Summary/Keyword: grain composition

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The Study of the Properties of $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ Ceramics Modified with $La_2O_3$, $Nb_2O_5$ and $Al_2O_3$ (첨가제에 따른 $Pb(Mg_{1/2} W_{1/2}) O_3-PbTiO_3-ObZrO_3$ 고용체의 특성에 대한 연구)

  • 안영필;황학인;홍진녕
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.17-24
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    • 1985
  • In the composition of $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ the effect of particle size on PbO vaporization were measured, . The initial step of discontinuous vaporization of unreated PbO during the calcining process was depended on the particle size. All additives $La_2O_3Nb_2O_5$ and $Al_2O_3$ inhibited the grain growth of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ +2wt% excess PbO. The dielectric and piezoelectric properties of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ were improved by the addition of 2wt% excess PbO and proper additive. The electromechanical planar coupling factor of 0.65 and mechnical quality factor of 390 could be obtained by adding 5wt% $Nb_2O_5$ to the composition 2wt% excess PbO+$Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$.

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Structural and Dielectric Properties of the (Ba,Sr)$TiO_3$Thin Films Prepared by Sol-Gel Method (Sol-Gel법으로 제조한 (Ba,Sr)$TiO_3$ 박막의 구조 및 유전특성)

  • 이문기;정장호;이성갑;이영희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.711-717
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    • 1998
  • BST(70/30) and BST(50/50) thin films were prepared by Sol-Gel method and studied about the microstructural and dielectric properties with Pt and ITO bottom electrodes. The stock solution was synthesized and spin coated on the Pt/Ti$SiO_2$/Si and Indium Tin Oxide(ITO)/ glass substrate. the coated films were dries at 350$^{\circ}C$ for 10 minutes and annealed at $750^{\circ}C$ for 1 hour for the crystallization. The thin films coated on ITO substrate were crystallized easily and the packing density and roughness of surface were better that those of films coated on Pt substrates. In the BST(50/50) composition the structural properties were similar to the BST(70/30) composition and grain size were decreased with increasing the contents of Sr. The dielectric constant was higher in the BST(50/50) composition compared with the BST(70/30) composition. Using the ITO substrate, the dielectric constant was higher than the Pt substrate while the dielectric loss was showed a reverse trend. The dielectric constant with and increase of temperature was decreased slowly.

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Effect of High Temperature on Leaf Physiological Changes as Chlorophyll composition and Photosynthesis Rate of Rice (벼 등숙기 고온이 잎의 엽록소구성과 광합성 및 생리적 변화에 미치는 영향)

  • Shon, Jiyoung;Kim, Junhwan;Lee, Chung-Kuen;Yang, Woonho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.60 no.3
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    • pp.266-272
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    • 2015
  • High temperature impairs rice grain yield and quality. To understand the effect of high temperature on leaf physiological activity and grain filling, two cultivars of rice that Dongan and Ilpum were exposed to high temperature during ripening stage. Grain filling rate, perfect grain ratio and grain weight of high temperature ($27^{\circ}C{\pm}4^{\circ}C$) treated both rice cultivars were decreased than those of control temperature ($22^{\circ}C{\pm}4^{\circ}C$) treated. The reduction rates of grain filling ratio, perfect grain ratio and grain weight of high temperature treated to control treated rice were higher in Ilpum than Dongan. Chlorophyll contents of rice leaves under high temperature at early ripening stage were higher than those of control temperature, but those were slowly decreased with no difference between temperature treatment since at mid ripening stage. Although chlorophyll a/b ratio under high temperature was decreased from heading to 15 days after heading, that was gradually increased since 15 days after heading. Protein concentrations of rice leaves for ripening stage was a similar pattern with chlorophyll changes. The rate of photosynthesis at 14 days after heading under high temperature was higher than those of control temperature, but there was no difference at those of 7 and 34 days after heading between two temperature treatment. Free sugars under high temperature treated leaves were lower than control temperature. Consequently, these results exhibit that high temperature accelerate leaf physiological activity as chlorophyll synthesis and photosynthesis rate unlike the deterioration of grain filling.

Physicochemical Properties of Selected Cereals and Legumes for the Production of Extruded Multi-grain (압출성형 혼합쌀의 제조에 따른 곡종별 이화학적 특성)

  • Kim, Sung-Su;Chae, Eun-Mi;Lee, Young-Tack
    • Applied Biological Chemistry
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    • v.44 no.1
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    • pp.30-34
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    • 2001
  • Physicochemical properties of milled rice, brown rice, pearled barley, wheat, sorghum, foxtail millet, soybean, and adzuki bean were evaluated for the production of extrusion formed multi-grain. Grain flours showed large differences in chemical composition including starch, protein, fat, ash, and total dietary fiber contents. Grain flours were brighter in the following order of milled rice>pearled barley>soybean>brown rice>wheat>sorghum>adzuki bean>foxtail millet, and most of the grain flours showed red-yellowish color. Mean particle sizes of grain flours were different among various grains, and whole grain flours tended to have coarser particle size than milled grain flours. The amounts of damaged starch in cereal flours were varied from 5.4 to 10.9%, and limited amount of damaged starch was present in legume flours. Water absorption index of grain flours was, in decreasing order, adzuki>bean>milled rice>brown rice>sorghum>wheat>foxtail millet>pearled barley>soybean. Water solubility index was higher in legume flours containing high protein content.

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Yield Comparisons of Different Methods of Waxy Fraction Extraction from Grain Sorghum

  • Weller, Curtis L.;Hwang, Keum-Taek;Schmidt, Bradley J.
    • Food Science and Biotechnology
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    • v.15 no.5
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    • pp.786-791
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    • 2006
  • Three solvent extraction techniques were used to recover waxy tractions from grain sorghum kernels. Yield and chemical composition of the waxy tractions obtained by reflux, bench scale (recirculated solvent), and countercurrent extraction methods were compared. Waxy traction yield from countercurrent extraction (0.200%) was significantly greater (p<0.05) than the yields of wax from both reflux (0.184%) and bench-scale (0.179%) methods. The waxy traction extracted using the bench-scale method showed the greatest relative amount of long-chained (primarily C:28 and C:30) alcohols while the countercurrent-extracted wax showed the greatest relative amount of long-chained fatty acids and fatty aldehydes. Countercurrent extraction removed a higher additive percentage of fatty aldehydes, acids, and alcohols than reflux or bench-scale extraction method.

Structural Properties of $MgTiO_3-SrTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 $MgTiO_3-SrTiO_3$ 세라믹의 구조적 특성)

  • Choi, Eui-Sun;Lee, Moon-Kee;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1774-1776
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    • 1999
  • The (1-x)$MgTiO_3-SrTiO_3$ (x=0,0.1,0.2,0.3) ceramics were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature and composition ratio by XRD, SEM and DT-TGA. Increasing the sintering temperature from $1300^{\circ}C$ to $1600^{\circ}C$, second phase was decreased and grain size was increased. The average grain size of the $0.8MgTiO_3-0.2SrTiO_3$ ceramics sintered at $1600^{\circ}C$ were $3.61{\mu}m$.

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Osprey Forming of HSLA-100 Steels (HSLA-100강의 Osprey 성형)

  • Park, Su-Jung;Lee, Kil-Hong;Lee, Hyun-Kyu
    • Journal of Korea Foundry Society
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    • v.22 no.5
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    • pp.231-237
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    • 2002
  • The structure and properties of HSLA steel obtained by Osprey forming process were investigated. The porosities were generated at the bottom of specimen due to the quenching effect of cold substrate during forming. The steel had a bainitic structure. The grain size were different among positions due to the cooling rates. The elements such as Mn, S, Si, Cr, Mo and etc. were contained in inclusions. They were formed at grain boundries. The size of them was $1{\sim}2{\mu}m$ and has nothing to do with the chemical composition. MnS and NbC were precipitated during rolling and aging.

Effects of Electroplating Current Density and Duty Cycle on Nanocrystal Size and Film Hardness

  • Sun, Yong-Bin
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.67-71
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    • 2015
  • Pulse electroplating was studied to form nanocrystal structure effectively by changing plating current density and duty cycle. When both of plating current density and duty cycle were decreased from $100mA/cm^2$ and 70% to $50mA/cm^2$ and 30%, the P content in the Ni matrix was increased almost up to the composition of $Ni_3P$ compound and the grain growth after annealing was retarded as well. The as-plated hardness values ranging from 660 to 753 HV are mainly based on the formation of nanocrystal structure. On the other hand, the post-anneal hardness values ranging from 898 to 1045 HV, which are comparable to the hardness of hard Cr, are coming from how competition worked between the precipitation of $Ni_3P$ and the grain coarsening. According to the ANOVA and regression analysis, the plating current density showed more strong effect on nanocrystal size and film hardness than the duty cycle.

Microstructure and Mechanical Properties of TiC-Co/Al Composites Prepared by Reaction-Bonded Sintering (반응결합 소결에 의한 TiC-Co/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;남기웅;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.257-269
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    • 1995
  • The TiC-Co/Al reaction-sintered products were prepared by the infiltration of various Co/Al metal mixture into the preform, and their microstructure, phases, and mechanical properties were investigated. With increasing the atomic ratio of Co/Al, tiC grain shape was changed from spherical to platelet particles, and the grain size increased. The crystalline phases found in the liquid matrix formed by the infiltration of Co/Al metal mixture were determined to be Al5Co2 and AlCo by EDS and XRD, and the two crystalline phases were located dominantly between TiC grains, when the Co/Al atomic ratio was lower than an unity. There was a tendency that the density, bending strength and fracture toughness increase with Co/Al atomic ratio until the infiltrated metal was 100% Co. The maximum value was achieved by the composition containing 100% Co infiltrated metal. The Vickers hardness decreased as Co/Al atomic ratio increased.

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The Effect of PbO on Sintering of Undoped PbTiO3 Ceramics Prepared by Sol-Gel Processing (PbO가 Sol-Gel Process로 제조된 순수 PbTiO3 세라믹스의 소결에 미치는 영향)

  • 김선욱;윤만순;김남흥
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.335-340
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    • 1992
  • Undoped PbTiO3 ceramics was successfully prepared by using sol-gel process, which had not been fabricated due to its microcracks created by anisotropic stress during phase transition from cubic to tetragonal phase. Fabrication of undoped PbTiO3 ceramics via sol-gel processing was very much affected by the PbO content of the samples as well as PbO vapor from sintering atmosphere. Excess PbO was found to promote rapid grain growth in PbTiO3 ceramics. After sintering at 1100$^{\circ}C$ average grain size of PbTiO3 ceramics with excess PbO was about 8 times greater than that of stoichiometric composition, which may be due to PbO liquid phase from excess PbO.

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