• Title/Summary/Keyword: grain complex

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Grain Size Dependence of Ionic Conductivity of Polycrystalline Doped Ceria

  • Hong, Seong-Jae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.122-127
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    • 1998
  • Conductivities of polycrystalline ceria doped with several rare earth oxides were measured by AC admittance and DC four probe method. The conductions were separated into grain and grain boundary contributions using the complex admittance technique as well as grain size dependence of conductivity. The grain size dependence of polycrystalline conductivity, which can be adequately described by the so-called brick layer model, appears to give a more reliable measure of the grain conductivity compared to the complex admittance method. Polycrystalline resistivity(1/conductivity) increases linearly with the reciprocal of grain size. The intercept of resistivity vs. inverse grain size plot gives a measure of the grain resistivity and the slope gives a measure of the grain boundary resistivity. It was also noted that errors involved in the analysis of experimental data may be different between the complex admittance method and the impedance method. A greater resolution of the spectra was found in the complex admittance method, insofar as the present work is concerned, suggesting that the commonly used equivalent circuit may require re-evaluation.

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The Effect of PVA-Al(III) Complex on Pore Formation and Grain Growth of $UO_2$ Sintered Pellet (II) (PVA-A(III) 착물이 $Uo_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(II))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.782-790
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    • 1999
  • The compressibility sinterability sintering behaviour and thermal stability of AlOOH added UO2 pellt and PVA-Al(III) complex added UO2 pellet were investigated respectively. Compared with characteristics of AlOOH added UO2 pellet the green density and the sintered density of PVA-Al(III) complex added UO2 pellet were lowered but the grain size and the pore size of that were more increased in accordance with higher compacting pressure. The AlOOH added UO2 pellet had the grain size of about 14${\mu}{\textrm}{m}$ with monomodal pore size distribution while the PVA-Al(III) complex added UO2 pellet had the grain size of about 42 ${\mu}{\textrm}{m}$ with bimodal pore size distribution. The PVA-A(III) complex added UO2 pellet had a similiar open porosity to the AlOOH added UO2 pellet and a lower resintered density change than the AlOOH added UO2 pellet.

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The Effect of PVA-Al(III) Complex on the Pore Formation and Grain Growth of UO$_2$ Sintered Pellet (PVA-Al(III) 착물이 UO$_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(I))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.783-790
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    • 1998
  • The characterization of the complexation reaction of PVA and Al(III) ion at different pH and the sint-ering behaviour of UO2 containing the PVA-Al(III) complexes were investigated. Compared with pure PVA powder the complexed PVA-Al(III) powder had compacter shape and lower decomposition temperature The major phase of PVA-Al(III) complex decomposed at 90$0^{\circ}C$ was $\alpha$-Al2O3 The PVA-Al(III) complex formed at pH 9 had the lowest relative viscosity the highest Al content of 36% and the smallest particle size of 19${\mu}{\textrm}{m}$ While the pure UO2 pellet appeared with bimodal one. The grain size of the pure UO2 pellet was 7${\mu}{\textrm}{m}$ but that of the PVA-Al(III) complex added UO2 pellet was increased up to 36${\mu}{\textrm}{m}$ The largest grain size was ob-tained when the PVA-Al(III) complex formed at pH9 was added and the PVA-Al(III) complex formed at pH 11 had the greatest effect on increasing pore size.

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Impedance Properties of Phase-Pure Titanium Dioxide Ceramics Sintered at Different Temperatures

  • Cui, Liqi;Niu, Ruifeng;Wang, Weitian
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.181-185
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    • 2022
  • In this study, phase-pure titanium dioxide TiO2 ceramics are sintered using standard high-temperature solid-state reaction technique at different temperatures (1,000, 1,100, 1,200, 1,300, 1,400 ℃). The effect of sintering temperature on the densification and impedance properties of TiO2 ceramics is investigated. The bulk density and average grain size increase with the increase of sintering temperature. Impedance spectroscopy analysis (complex impedance Z* and complex modulus M*), performed in a broad frequency range from 100 Hz to 10 MHz, indicates that the TiO2 ceramics are dielectrically heterogeneous, consisting of grains and grain boundaries. The complex impedance Z* -plane indicates the resistance of grains of the TiO2 ceramics increases with increasing sintering temperature, while that of grain boundaries develops in the opposing direction. The complex modulus M*-plane shows a grain capacitance that seems to be independent of the sintering temperature, while that of the grain boundaries decreases with increasing sintering temperature. These results suggest that different sintering temperatures have effects on the microstructure, leading to changes in the impedance properties of TiO2 ceramics.

Prospect of large scale Grain Drying, Storage and Milling Facility Complex in Korea (우리나라의 대규모 곡물 종합조제시설의 문제점 및 전망)

  • Kim, Tae Wook;Park, Kyung Kyoo
    • Current Research on Agriculture and Life Sciences
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    • v.14
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    • pp.37-47
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    • 1996
  • The main objectives of this studies are to present the most desirable rice processing complex model system in a given our situations by comparision and analyzing the major factors and, also recommend the future prospect of the rice processing complex in Korea. There are 3 different rice processing complex models in Korea. Those are concrete bin, flat type steel bin and square bin. These systems have a lot of differences and have their own characteristics such as capital requirement, efficiency, storage capacity and quality controls. The major problems of the existing rice processing centers in Korea are high fixed cost and the unbalnced systems. Following is summary to solve this problems: 1. Development of the large scale harvester and high speed continuous dryer. 2. Quality inspective system of bulk grain and large scale temporary storage facilities. 3. Large size readjustment of arable land. 4. Select the convenient location of rice processing center and formulation of well equipment facilities.

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Complex Modulus of Rough Rice Kernel under Cyclic Loading (주기적(週期的) 반복하중(反復荷重)을 받는 벼의 복소탄성율(複素彈性率))

  • Kim, M.S.;Park, J.M.
    • Journal of Biosystems Engineering
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    • v.16 no.3
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    • pp.263-271
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    • 1991
  • When grains is subjected to oscillating load, the dynamic viscoelastic behavior of the material will be describe the complex modulus of the material. The complex modulus and therefore the storage modulus, the loss modulus, and the phase angle for the sample should be obtainable with a given static viscoelastic property of the material under static load. The complex relaxation moduli of the rough rice kernel were computed from the Burger's model describing creep behavior of the material which were obtained in the previous study. Also, the effects of cyclic load and moisture content of grain on the dynamic viscoelastic behavior of the samples were analized. The storage modulus of the rough rice kernel slightly increased with the frequency applied but at above the frequency of 0.1 Hz it was nearly constant with the frequency, and the loss modulus of the sample very rapidly decreased with increase in the frequency on those frequency ranges. It was shown that the storage modulus and the loss modulus of the sample increased with decrease in grain moisture content. Effect of grain moisture content on the storage modulus of the sample was highly significant than effect of the frequency applied, but effect of the frequency on the loss modulus of the sample was more significant than effect of grain moisture content.

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Analysis of a 6th Industrialization Model in the Saemangeum Grain Complex (새만금 복합곡물단지의 6차산업화 모델 분석)

  • Kim, Yooan;Jung, Chanhoon;Kim, Solhee;Kim, Chanwoo;Suh, Kyo
    • Journal of Korean Society of Rural Planning
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    • v.25 no.2
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    • pp.63-74
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    • 2019
  • As the awareness of food security has increased, the Korean government has established national projects, such as Saemangeum proclaimed land, to secure sources of grain. Saemangeum is a large-scale agricultural area that was constructed to maintain preparedness for unstable food markets. This study aims to develop a $6^{th}$ Industrialization Model (SIM) for Saemangeum Grain Complex by applying feasible strategies to wheat and two-rowed barley which have low self-sufficiency rates. In addition, this study estimates the potential economic value of each development strategy associated with a sixth industrialization model to create higher added values from production, processing and tourism experiences. The strategic plan for primary, secondary, and tertiary industries is to combine cultivating and processing wheat and two-rowed barley for sales and linking them to tourism experience. This study shows value added from the combination of the primary, secondary and tertiary industry of wheat and two-rowed barley are 7.5 and 23.0 times more than those of the primary and tertiary industry combination, respectively. Through branding Saemangeum Grain Complex's products, such as Saemanguem bread and craft beer, would further enhance the economic benefits derived from the complex.

Dynamic Masterplan of the Saemangeum Grain Complex for Progressive Development (점진적 개발 단계를 고려한 새만금 복합곡물단지의 동태적 마스터플랜 수립)

  • Jung, Chanhoon;Kim, Chanwoo;Kim, Solhee;Park, Jinseon;Seo, Donguk;Suh, Kyo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.4
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    • pp.1-13
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    • 2018
  • The grain complex of Saemangeum is created for promoting the foundation of agriculture combined the global competitiveness. However, the masterplan is being also revised with changing of local conditions and social needs. Thus, the dynamic masterplan is needed to consider the change of time for Saemangeum project. The present study was made to set up the dynamic masterplan of Saemangeum grain complex for handling the change such as project progress, local environment, and project conditions flexibly. In this study, the dynamic masterplan for the progressive development of water supply, farmland composition, and introduction facilities is presented to the 6-2 zone in three stages. We believed that the water supply would be possible through the pumping and desalination facilities with the development stages. The farmland composition proceeded for each complex with reclamation, soil preparation, and soft soil processing. And it is planned to carry out crop cultivation from the complex where the construction is completed first. The introduction facilities were analyzed focusing on the silos and forage loading facilities, and the optimal location of them was selected using road and accessibility. The concept of dynamic masterplan may provide the direction for the planning and progress of reclamation project.

Effect of Abnormal Grain Growth and Heat Treatment on Electrical Properties of Semiconducting BaTiO3Ceramics

  • Lee, Joon-Hyung;Cho, Sang-Hee
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.21-25
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    • 2002
  • Effect of abnormal grain growth and heat treatment time on the electrical properties of donor-doped semiconductive BaTiO$_3$ceramics was examined. La-doped BaTiO$_3$ceramics was sintered at 134$0^{\circ}C$ for different times from 10 to 600 min in order to change the volume fraction of the abnormal grains in samples. As a result, samples with different volume fraction of abnormal grain growth from 22 to 100% were prepared. The samples were annealed at 120$0^{\circ}C$ for various times. The resistivity of the sam-ples at room and above Curie temperature was examined. The complex impedance measurement as functions of the volume fraction of abnormal grains and annealing time was conducted. Separation of complex impedance semicircle was observed in a sample in which abnormal and fine grains coexist. The results are discussed from a viewpoint of microstructure-property relationship.

Influence of Coated Urea Complex Fertilizer Application on Growth and Grain Quality of Paddy Rice (피복요소복합비료(被覆尿素複合肥料)의 시용방법(施用方法)이 벼 생육(生育)과 미질(米質)에 미치는 영향(影響))

  • Park, Kyeong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.2
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    • pp.72-77
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    • 1993
  • This study was conducted to evaluate coated urea complex fertilizer (CUC) application for rice growth and its grain quality on clay loam (Deogpyeong series) and sandy loam (Gangseo series) in southern region of Korea, 1992. The coated urea complex fertilizer used in the experiment was CUC I and II. The CUC I is a complex fertilizer consisting of 18-12-13 for $N-P_2O_5-K_2O$ including 50% of coated urea as nitrogen source, and CUC II is the same complex fertilize as mentioned above but it contains 25% of coated urea. Seventy percent of conventional fertilizer for nitrogen level was applied as basal dose of side-band placement (SBP) and whole plowlayer placement (WPP). Greenish degree of rice leaf color at the late growth stage was high in CUC plots regardless of application method and soil series. Amount of nitrogen uptaken by the rice plant at harvesting stage was mush more in the CUC treatment compared to convential fertilizer, and also much more in CUC I than that of CUC II. In the WPP on clay loam, harvest index of CUC treatment was showed very low level, which was reduced more in CUC II plot. In the CUC treatments, perfect rice grain ratio decreased remarkably, and the notched-belly rice kernel ratios among imperfect rice grain increased drastically. In rice grain, Hon-value(Mg to K.N ratio) decreased, protein and amylose contents increased in CUC application plots in WPP. In addition, gel consitency and alkali spreading value related to eating quality in CUC plots were getting longer and lower, respectively. The yield in CUC plot was similar to conventional fertilizing, but significant decreased in SBP. As a result, the rice grain quality became poor with the coated urea complex fertilizer application, but it could be improved by incorporation with fast-release fertilizer.

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