• 한국세라믹학회지
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• 제44권2호
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• pp.110-115
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• 2007

The effects of $TiO_2$ in the glasses on the shrinkage and dielectric properties of BNT-glass composites have been investigated. Without $TiO_2$ addition, BNT-glass composite showed two humps in the shrinkage curve, which are related with crystallization of $BaTi(BO_3)_2\;and\;Bi_4Ti_3O_{12}$. However, the increase of $TiO_2$ addition resulted in the decrease of 2nd hump in the shrinkage. The increased dielectric constant with $TiO_2$ addition might be due to the reduced crystallization of $Bi_4Ti_3O_{12}$. A dielectric constant of 52, a quality factor of 5088 GHz, and a temperature coefficient of resonant frequency of $-0.16ppm/^{\circ}C$ were obtained for a specimen containing $TiO_2$-added glasses, without sacrificing the benefits of high ${\varepsilon}_r$ and low TCF of BNT ceramics.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.88.1-88.1
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• 2011

SOFC는 사용되는 셀의 디자인에 따라 튜브형, 평판형으로 구분되어진다. 평판형의 경우에는 전해질 지지형(ESC), Anode 지지형(ASC) 및 금속 지지형(MSC)로 크게 나눌 수 있다. SOFC 스택은 이와 같은 셀과 밀봉재, 집전체, 분리판의 구성요소를 여러 장으로 적층하여 이루어진다. SOFC 발전시스템은 SOFC 스택과 EBOP, MBOP로 구성되는데, SOFC 발전시스템의 상용화를 위해 선행되어야 할 것은 스택의 안정적 출력 및 신뢰성 확보이다. 즉, 셀, 밀봉재, 분리판 및 집전체로 대변되는 구성요소들이 스택에 장착되었을 때 그 기능을 최대한 발휘하면서도 점진적 또는 급격한 품질저하가 발생되지 말아야 한다. 특히, 밀봉재의 경우 SOFC에 사용되는 연료와 공기의 혼합(Cross-over)을 방지하는 중요한 기능을 담당하고 있으며 여러 장 적층된 분리판의 전기적 단락을 방지해야 한다. 또한 SOFC의 특성상 $700^{\circ}C$ 이상의 고온에서 다른 구성요소와 화학적 반응이 없어야하고 열싸이클(Thermal cycle)을 견딜 수 있도록 충분한 기계적 강도가 보장되어야 하는 등 요구되는 품질기준이 엄격하다. SOFC의 밀봉재는 접합형(Brazing), 압착형(Compressive), 용융-고정형(Glass-ceramic)이 대표적으로 적용되고 있다. 이 중에서 Brazing 물질과 방법은 현재 활발히 연구가 수행 중에 있지만 범용적으로 사용되고 있지는 않은 상태이고 Compressive 밀봉재와 Glass-ceramic 밀봉재가 대면적 SOFC 스택에 사용되어 적용 가능성을 평가받고 있다. 본 연구에서는 SOFC 구성요소의 국산화를 추진하는 지경부과제의 결과물 중 (주)써모텍에서 개발한 Glass-ceramic 밀봉재(RC1) 단품에 대한 특성평가와 실제 단전지 평가를 통해 SOFC 스택 적용 가능성을 평가하였다. 밀봉재 단품에 대한 특성평가는 용융특성, 상분석, 열팽창계수 등의 물리적, 화학적 평가 외에 가스 누설 정도를 평가하는 기밀도 평가와 SOFC의 작동 온도인 $700^{\circ}C$와 상온 분위기를 주기적으로 인가하는 Thermal cycle 특성을 평가하였다. 셀을 한 장 사용하는 단전지(Unit cell) 평가는 RIST에서 자체 제작한 $100{\times}100mm^2$ 평판형 ASC 셀을 사용하여 수행하였으며, 밀봉재는 Dispensing 공정을 통해 구성되었다.

• 대한치과기공학회지
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• 제40권1호
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• pp.9-15
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• 2018

Purpose: The purpose of this study is to investigate the effect of lithium disilicate glass ceramic polishing on the strength of the final prosthesis. Methods: Fourteen lithium disilicate glass ceramic specimens were prepared. These were randomly divided into two groups of seven(LPG: low polishing group, HPG: high polishing group). In LPG, SiC paper was sequentially polished using 300, 600, 800, 1000 grit, and the specifications of the test piece were adjusted. HPG was sequentially polished using 300, 600, 800, 1000, 1200, 1500, and 2000 grit. Two groups of specimens are executed 3- point bending test. Using the statistical program SPSS 22.0, the average values of the strengths of the two groups were compared in the Mann-Whiteney test. The significance level was set at 0.05. Results: The mean strength value of HPG was measured at $307.14{\pm}23.28MPa$ significantly higher than LPG(p<0.001). Conclusion : The final polishing of the prosthesis is aesthetically important but has proven to play an important role in the flexural strength, early fracture, and prolongation of the prosthesis.

• 대한치과기공학회지
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• 제39권1호
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• pp.43-52
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• 2017

Purpose: Physical and chemical properties of gold is most suitable to be restored of teeth to its original state. Recently zirconia was used instead of gold because of esthetical and intimacy of human body. Because of high strength and high abrasion resistance of zirconia, all zirconia artificial tooth lead to wear the original tooth of opposite site. To preserve this original tooth, zirconia artificial tooth covered with dental ceramic glass was used. When joining the zirconia core and dental ceramic glass, difference of their thermal expansion coefficient and wetting ability is generated the residual stress at interface lead to crack. In order to solve this problem, intermediate layer what is called zir-liner was imported to decrease the residual stress and increase the bonding strength. Methods: In this study, to identify the optimum conditions for manufacturing process, various methods to rough the surface of zirconia core were adopted, and vary the thickness of interlayer, and analyzed bond strength. Results: Bond strength of sanding specimens group showed higher than that of non-sanding specimens group, and once applied intermediate layer with sanding specimens showed highest bond strength with 28 MPa. SEM photomicrographs of zirconia cores fired at $1500^{\circ}C$ showed parallel straight lines in sanding and pockmarked surface in blasting surfaces as abrasion traces. Observation of the destruction section after shear test by SEM were carried out. Liner applied non-sanding group and non-liner applied sanding group all showed interfacial crack. Sandblasting group with non-liner showed remained dental ceramic glass on the surface of zirconia. Sandblasting group with once applied liner showed partially remained liner and dental ceramic glass on the surface of zirconia. XRD analysis revealed that sandblasting group showed higher monoclinic peaks than other specimens group and this result was due to the high collision energy for stress induced phase transformation. Conclusions: A study on the improvement of bonding strength between zirconia and dental ceramic glass steadily carried out for the future to practical use.

• Restorative Dentistry and Endodontics
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• 제42권1호
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• pp.1-8
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• 2017

Objectives: The purpose of this study was to evaluate the effect of adhesive luting on the fracture resistance of zirconia compared to that of a composite resin and a lithium disilicate glass ceramic. Materials and Methods: The specimens (dimension: $2mm{\times}2mm{\times}25mm$) of the composite resin, lithium disilicate glass ceramic, and yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) were prepared. These were then divided into nine groups: three non-luting groups, three non-adhesive luting groups, and three adhesive luting groups, for each restorative material. In the non-luting groups, specimens were placed on the bovine tooth without any luting agents. In the non-adhesive luting groups, only zinc phosphate cement was used for luting the specimen to the bovine tooth. In the adhesive luting groups, specimens were pretreated, and the adhesive luting procedure was performed using a self-adhesive resin cement. For all the groups, a flexural test was performed using universal testing machine, in which the fracture resistance was measured by recording the force at which the specimen was fractured. Results: The fracture resistance after adhesive luting increased by approximately 29% in the case of the composite resin, 26% in the case of the lithium disilicate glass ceramic, and only 2% in the case of Y-TZP as compared to non-adhesive luting. Conclusions: The fracture resistance of Y-TZP did not increased significantly after adhesive luting as compared to that of the composite resin and the lithium disilicate glass ceramic.

• 한국세라믹학회지
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• 제38권11호
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• pp.1060-1066
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• 2001

세라믹 인공치관으로 응용을 위해 생체친화적이며 용매에 용해가 잘되고 연소 후 잔류물이 남지 않는 결합제인 PVP로 수계용 알루미나 테이프를 제조하였다. 알루미나 테이프의 인장강도는 결합제(b)와 가소제(p)의 비(b/b+p))에 의해, 그리고 소결체 수축과 밀도는 알루미나(a)와 유기물(o)의 비 (a/(a+o))에 의해 영향을 받았다. 소결된 가공성 알루미나 테이프에 유리를 침투시켜 강화된 세라믹 인공치관용 복합체의 강도는 소결밀도가 증가할수록 높은 값을 보였다.

• 한국재료학회지
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• 제22권10호
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• pp.531-538
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• 2012

Hollow silica spheres were prepared by spray drying of precursor solution of colloidal silica. The precursor solution is composed of 10-20 nm colloidal silica dispersed in a water or ethanol-water mixture solvent with additives of tris hydroxymethyl aminomethane. The effect of pH and concentrations of the precursor and additives on the formation of hollow sphere particles was studied. The spray drying process parameters of the precursor feeding rate, inlet temperature, and gas flow rate are controlled to produce the hollow spherical silica. The mixed solvent of ethanol and water was preferred because it improved the hollowness of the spheres better than plain water did. It was possible to obtain hollow silica from high concentration of 14.3 wt% silica precursor with pH 3. The thermal conductivity and total solar reflectivity of the hollow silica sample was measured and compared with those values of other commercial insulating fillers of glass beads and $TiO_2$ for applications of insulating paint, in which the glass beads are representative of the low thermal conductive fillers and the $TiO_2$ is representative of infrared reflective fillers. The thermal conductivity of hollow silica was comparable to that of the glass beads and the total solar reflectivity was higher than that of $TiO_2$.

• 한국세라믹학회지
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• 제43권7호
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• pp.433-438
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• 2006

In order to examine the working condition of melts in tin bath of float process it was investigated Sn diffusion behavior and solidification rate of melts for alkali-alkaline earth-silica PDP substrate glasses such as commercial CaO rich CS-77 glass, commercial $Al_2O_3$ rich PD-200 glass and self developed $SiO_2$ rich T-series (T-2, T-4, T-6) glasses. In the case of Sn depth and concentration created in glass surface by ion exchange between Sn and alkali, T-series showed lower value than CS-77, especially T-2 is more excellent than PD-200. The solidification rate of melts expressed by cooling time between $log{\eta}=4\;and\;7.6dPa{\cdot}s$ was low for T-series comparing with CS-77 and PD-200. Therefore, it was concluded that T-series is desirable considering forming condition in the tin bath of the float process.

• 한국물환경학회지
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• 제28권2호
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• pp.219-223
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• 2012

The fixed solid catalysts such as glass bead, steel mesh, and $TiO_2$ coated ceramic bead were used to investigate effect of radical production at different frequencies. The radical production rate at 300 kHz was faster than that at 35 kHz without solid, but the tendency was changed with the presence of glass bead. The presence of glass beads create non-continuous points between the solid and liquid phases leading to increased formation of cavitation bubbles. However, the radical production decreased when steel mesh was used at 35 kHz although the surface area of contact with liquid was same when glass bead was used. Hence the solid catalyst did not always enhance the radical production. The radical production using $TiO_2$ coated ceramic bead was dramatically increased at 35 kHz due to the breakage of $TiO_2$ coated ceramic bead. Therefore the radical productions at 300 kHz using fixed solid catalysts generally increased while at 35 kHz the results fluctuated according to the experimental conditions.

• 한국세라믹학회지
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• 제16권2호
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• pp.83-88
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• 1979

The Anorthite is useful compound for some ceramic industries but it is difficult to produce Anorthite because of its high melting point (1553$^{\circ}C$) and narrow firing range. On this study, glass frit was added to Anorthite batch composition to widen firing range and lower melting point. After mixing a glass frit $(Na_2O-CaO-6SiO_2)$ with Anorthite, it was melted and quenched. Ratio of Anorthite vs. glass frit was 9 : 1, 8.5 : 1.5, 8 : 2, 7.5 : 2.5, 7 : 3. In those batch composition added amount of $No_2O$ were between 1.3wt.% and 3.9wt.%. To find the thermal change of the quenched, D.T.A. was surveyed. The quenched were fired at various vitrification temperature and detected by X-Raydiffraction analysis. With addition of glass frit, firing range and vitrification temperature of Anorthite was 100~15$0^{\circ}C$ and 1050~115$0^{\circ}C$ respectively. Optimum amount of glass frit was 20wt.% for the upper mentioned.